木质纤维生物质半纤维素分离研究进展
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摘要
在一体化的木质纤维生物质精炼过程中,选择性分离半纤维素非常关键。本文对传统和新型溶剂体系分离半纤维素的方法进行了详细综述,综合阐述了国内外研究学者在半纤维素分离方面的相关研究成果,并对不同的分离方法进行了比较和讨论。
Selective isolation of hemicelluloses is critical in an integrated lignocellulosic biorefinery. The isolation of hemicelluloses used traditional and novel solvent systems are detailed reviewed,and the results of hemicelluloses isolation conducted by researchers at home and abroad are comprehensively expounded. Additionally,the advantages and disadvantages of these methods are compared and discussed.
Selective isolation of hemicelluloses is critical in an integrated lignocellulosic biorefinery. The isolation of hemicelluloses used traditional and novel solvent systems are detailed reviewed,and the results of hemicelluloses isolation conducted by researchers at home and abroad are comprehensively expounded. Additionally,the advantages and disadvantages of these methods are compared and discussed.
引文
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[2]Brandt A,Grsvik J,Hallett J P,et al.Deconstruction of lignocellulosic biomass with ionic liquids[J].Green Chemistry,2013,15(3):550.
[3]Peng F,Peng P,Xu F,et al.Fractional purification and bioconversion of hemicelluloses[J].Biotechnology Advances,2012,30:879.
[4]Sun R C,Sun X F.Fractional and structural characterization of hemicelluloses isolated by alkali and alkaline peroxide from barley straw[J].Carbohydrate Polymers,2002,49:415.
[5]Ruzene D S,Silva D P,Vicente A A,et al.An alternative application to the Portuguese agro-industrial residue:wheat straw[J].App-lied Biochemistry Biotechnology,2008,147:85.
[6]Peng P,Peng F,Bian J,et al.Isolation and structural characterization of hemicelluloses from the bamboo species Phyllostachys incarnata Wen[J].Carbohydrate Polymers,2011,86(2):883.
[7]Lawther J M,Sun R C,Banks W B.Effects of extraction conditions and alkali type on yield and composition of wheat straw hemicellulose[J].Journal of Applied Polymer Science,1996,60:1827.
[8]Xu F,Sun J X,Geng Z C,et al.Comparative study of water-soluble and alkali-soluble hemicelluloses from perennial ryegrass leaves(Lolium peree)[J].Carbohydrate Polymers,2007,67:56.
[9]Chen Q Q,Jiang H,Zhang Y,et al.Optimization of extraction and characterization of hemicelluloses from hybrid poplar residues[J].Biomass Chemical Engineering,2013,47(3):39.陈清清,江华,张洋,等.速生杨半纤维素碱法提取工艺的优化和表征[J].生物质化学工程,2013,47(3):39.
[10]Ebringerova A,Heinze T.Xylan and xylan derivatives-biopolymers with valuable properties,1-Naturally occurring xylans structures,isolation procedures and properties[J].Macromolecular Rapid Communications,2000,21:542.
[11]Geng Z C,Sun R C,Sun X F,et al.Comparative study of hemicelluloses released during two-stage treatments with acidic organosolv and alkaline peroxide from Caligonum monogoliacum and Tamarix spp[J].Polymer Degradation and Stability,2003,80:315.
[12]Xu F,Liu C F,Geng Z C,et al.Characterisation of degraded organosolv hemicelluloses from wheat straw[J].Polymer Degradation and Stability,2006,91:1880.
[13]LI R,YANG G H,LV G J,et al.Separation and characterization of hemicelluloses of corn stalks[J].Transactions of China Pulp and Paper,2017,32(3):1.李蕊,杨桂花,吕高金,等.玉米秸秆半纤维素的逐级分离及其结构表征[J].中国造纸学报,2017,32(3):1.
[14]Yue P P,Fu G Q,Hu Y J,et al.Changes of chemical composition and hemicelluloses structure in differently aged bamboo(Neosinocalamus affinis)culms[J].Journal of Agricultural and Food Chemistry,2018,66:9199.
[15]Li Y,Liu W,Hou Q X,et al.Release of acetic acid and its effect on the dissolution of carbohydrates in the autohydrolysis pretreatment of poplar prior to chemi-thermomechanical pulping[J].Industrial&Engineering Chemistry Research,2014,53:8366.
[16]Yuan M T,Zhai H M,Feng N J,et al.Characterization of Hemicelluloses and Lignin Change of Wheat Straw in Autohydrolysis Process[J].Journal of Cellulose Science and Technology,2015,23(2):55.袁梅婷,翟华敏,冯年捷,等.麦草自水解过程中半纤维素和木质素的变化特性[J].纤维素科学与技术,2015,23(2):55.
[17]Svrd A,Brnnvall E,Edlund U.Rapeseed straw as a renewable source of hemicelluloses:Extraction,characterization and film formation[J].Carbohydrate Polymers,2015,133:179.
[18]Teng C,Yan Q J,Jiang Z Q,et al.Production of xylooligosaccharides from the steam explosion liquor of corncobs coupled with enzymatic hydrolysis using a thermostable xylanase[J].Bioresource Technology,2010,101,7679.
[19]Wang K,Jiang J X,Xu F,et al.Influence of steaming explosion time on the physicchemical properties of cellulose from Lespedeza stalks(Lespedeza crytobotrya)[J].Bioresource Technology,2009,100:5288.
[20]Wang K,Xu F,Sun R C,et al.Influence of incubation time on the physicochemical properties of the isolated hemicelluloses from steamexploded Lespedeza stalks[J].Industrial&Engineering Chemistry Research,2010,49:8797.
[21]Xiong J,Ye J,Liang W Z,et al.Influence of Microwave on the Ultrastructure of Cellulose I[J].Journal of South China University of Technology(Natural Science Edition),2000,28(3):84.熊键,叶君,梁文正,等.微波对纤维素I超分子结构的影响[J].华南理工大学学报(自然科学版),2000,28(3):84.
[22]Peng D,Zhou X S.Extraction of hemicellulose by acid or alkali with the assistance of microwave irradiation[J].Paper Science&Technology,2013,32(6):45.彭缔,周雪松.微波辅助下酸碱抽提半纤维素的研究[J].造纸科学与技术,2013,32(6):45.
[23]Hou X F,Wang Z N,Sun J,et al.A microwave-assisted aqueous ionic liquid pretreatment to enhance enzymatic hydrolysis of Eucalyptus and its mechanism[J].Bioresource Technology,2019,272:99.
[24]Li H L,Wang X H,Liu C Y,et al.An efficient pretreatment for the selectively hydrothermal conversion of corncob into furfural:The combined mixed ball milling and ultrasonic pretreatments[J].Industrial Crops and Products,2016,94:721.
[25]Sun R C,Tomkinson J.Characterization of hemicelluloses obtained by classical and ultrasonically assisted extractions from wheat straw[J].Carbohydrate Polymers,2002,50(3):263.
[26]MA Z Y,LV Y N.Study on Alkaline Extraction of Hemicelluloses from Bagasse Pith with Ultrasound-Assisted[J].China Pulp&Paper,2018,37(1):19.马志宇,吕艳娜.超声波辅助稀碱法提取蔗髓半纤维素的工艺探究[J].中国造纸,2018,37(1):19.
[27]Miyafuji H,Miyata K,Saka S,et al.Reaction behavior of wood in an ionic liquid,1-ethyl-3-methylimidazolium chloride[J].Journal of Wood Science,2009,55(3):215.
[28]Mohtar S S,Busu T N Z T M,Md Noor A M,et al.An ionic liquid treatment and fractionation of cellulose,hemicellulose and lignin from oil palm empty fruit bunch[J].Carbohydrate Polymers,2017,166:291.
[29]Mohtar S S,Tengku Malim Busu T N Z,Md Noor A M,et al.Extraction and characterization of lignin from oil palm biomass via ionic liquid dissolution and non-toxic aluminium potassium sulfate dodecylhydrate precipitation processes[J].Bioresource Technology,2015,192:212.
[30]Raj T,Gaur R,Dixit P,et al.Ionic liquid pretreatment of biomass for sugars production:Driving factors with a plausible mechanism for higher enzymatic digestibility[J].Carbohydrate Polymers,2016,149:369.
[31]Lv B L.The studies on the solubility and dissolution mechanism of cellulose and xylan in ionic liquids[D].Lanzhou:Lanzhou University,2016.吕本莲.离子液体对纤维素和聚木糖的溶解性能及溶解机理研究[D].兰州:兰州大学,2016.
[32]Shuai L,Questell-Santiago Y M,Luterbacher J S.A mild biomass pretreatment usingγ-valerolactone for concentrated sugar production[J].Green Chemistry,2016,18:937.
[33]Wu M,Yan Z Y,Zhang X M,et al.Integration of mild acid hydrolysis inγ-valerolactone/water system for enhancement of enzymatic saccharification from cotton stalk[J].Bioresource Technology,2016,200:23.
[34]Alonso D M,Wettstein S G,Mellmer M A,et al.Integrated conversion of hemicellulose and cellulose from lignocellulosic biomass[J].Energy&Environmental Science,2013,6:76.
[35]Abbott A P,Capper G,Davies D L,et al.Novel solvent properties of choline chloride/urea mixtures[J].Chemical Communications,2003,1:70.
[36]Satlewal A,Agrawal R,Bhagia Samarthya,et al.Natural deep eutectic solvents for lignocellulosic biomass pretreatment:Recent developments,challenges and novel opportunities[J].Biotechnology Advances,2018,36:2032.
[37]Soares B,Tavares D J P,Amaral J L,et al.Enhanced solubility of lignin monomeric model compounds and technical lignins in aqueous solutions of deep eutectic solvents[J].ACS Sustainable Chemistry Engineering,2017,5:4056.
[38]Morais E S,Mendonca P V,Coelho J F J,et al.Deep eutectic solvent aqueous solutions as efficient media for the solubilization of hardwood xylans[J].Chem.Sus.Chem.,2018,11:753.
[39]Kumar A K,Pravakar M.Natural deep eutectic solvent mediated pretreatment of rice straw:bioanalytical characterization of lignin extract and enzymatic hydrolysis of pretreated biomass residue[J].Environmental Science and Pollution Research,2016,23(10):9265.
[40]Hou X D,Feng G J,Ye M,et al.Significantly enhanced enzymatic hydrolysis of rice straw via a high-performance two-stage deep eutectic solvents synergistic pretreatment[J].Bioresource Technology,2017,238:139.
[2]Brandt A,Grsvik J,Hallett J P,et al.Deconstruction of lignocellulosic biomass with ionic liquids[J].Green Chemistry,2013,15(3):550.
[3]Peng F,Peng P,Xu F,et al.Fractional purification and bioconversion of hemicelluloses[J].Biotechnology Advances,2012,30:879.
[4]Sun R C,Sun X F.Fractional and structural characterization of hemicelluloses isolated by alkali and alkaline peroxide from barley straw[J].Carbohydrate Polymers,2002,49:415.
[5]Ruzene D S,Silva D P,Vicente A A,et al.An alternative application to the Portuguese agro-industrial residue:wheat straw[J].App-lied Biochemistry Biotechnology,2008,147:85.
[6]Peng P,Peng F,Bian J,et al.Isolation and structural characterization of hemicelluloses from the bamboo species Phyllostachys incarnata Wen[J].Carbohydrate Polymers,2011,86(2):883.
[7]Lawther J M,Sun R C,Banks W B.Effects of extraction conditions and alkali type on yield and composition of wheat straw hemicellulose[J].Journal of Applied Polymer Science,1996,60:1827.
[8]Xu F,Sun J X,Geng Z C,et al.Comparative study of water-soluble and alkali-soluble hemicelluloses from perennial ryegrass leaves(Lolium peree)[J].Carbohydrate Polymers,2007,67:56.
[9]Chen Q Q,Jiang H,Zhang Y,et al.Optimization of extraction and characterization of hemicelluloses from hybrid poplar residues[J].Biomass Chemical Engineering,2013,47(3):39.陈清清,江华,张洋,等.速生杨半纤维素碱法提取工艺的优化和表征[J].生物质化学工程,2013,47(3):39.
[10]Ebringerova A,Heinze T.Xylan and xylan derivatives-biopolymers with valuable properties,1-Naturally occurring xylans structures,isolation procedures and properties[J].Macromolecular Rapid Communications,2000,21:542.
[11]Geng Z C,Sun R C,Sun X F,et al.Comparative study of hemicelluloses released during two-stage treatments with acidic organosolv and alkaline peroxide from Caligonum monogoliacum and Tamarix spp[J].Polymer Degradation and Stability,2003,80:315.
[12]Xu F,Liu C F,Geng Z C,et al.Characterisation of degraded organosolv hemicelluloses from wheat straw[J].Polymer Degradation and Stability,2006,91:1880.
[13]LI R,YANG G H,LV G J,et al.Separation and characterization of hemicelluloses of corn stalks[J].Transactions of China Pulp and Paper,2017,32(3):1.李蕊,杨桂花,吕高金,等.玉米秸秆半纤维素的逐级分离及其结构表征[J].中国造纸学报,2017,32(3):1.
[14]Yue P P,Fu G Q,Hu Y J,et al.Changes of chemical composition and hemicelluloses structure in differently aged bamboo(Neosinocalamus affinis)culms[J].Journal of Agricultural and Food Chemistry,2018,66:9199.
[15]Li Y,Liu W,Hou Q X,et al.Release of acetic acid and its effect on the dissolution of carbohydrates in the autohydrolysis pretreatment of poplar prior to chemi-thermomechanical pulping[J].Industrial&Engineering Chemistry Research,2014,53:8366.
[16]Yuan M T,Zhai H M,Feng N J,et al.Characterization of Hemicelluloses and Lignin Change of Wheat Straw in Autohydrolysis Process[J].Journal of Cellulose Science and Technology,2015,23(2):55.袁梅婷,翟华敏,冯年捷,等.麦草自水解过程中半纤维素和木质素的变化特性[J].纤维素科学与技术,2015,23(2):55.
[17]Svrd A,Brnnvall E,Edlund U.Rapeseed straw as a renewable source of hemicelluloses:Extraction,characterization and film formation[J].Carbohydrate Polymers,2015,133:179.
[18]Teng C,Yan Q J,Jiang Z Q,et al.Production of xylooligosaccharides from the steam explosion liquor of corncobs coupled with enzymatic hydrolysis using a thermostable xylanase[J].Bioresource Technology,2010,101,7679.
[19]Wang K,Jiang J X,Xu F,et al.Influence of steaming explosion time on the physicchemical properties of cellulose from Lespedeza stalks(Lespedeza crytobotrya)[J].Bioresource Technology,2009,100:5288.
[20]Wang K,Xu F,Sun R C,et al.Influence of incubation time on the physicochemical properties of the isolated hemicelluloses from steamexploded Lespedeza stalks[J].Industrial&Engineering Chemistry Research,2010,49:8797.
[21]Xiong J,Ye J,Liang W Z,et al.Influence of Microwave on the Ultrastructure of Cellulose I[J].Journal of South China University of Technology(Natural Science Edition),2000,28(3):84.熊键,叶君,梁文正,等.微波对纤维素I超分子结构的影响[J].华南理工大学学报(自然科学版),2000,28(3):84.
[22]Peng D,Zhou X S.Extraction of hemicellulose by acid or alkali with the assistance of microwave irradiation[J].Paper Science&Technology,2013,32(6):45.彭缔,周雪松.微波辅助下酸碱抽提半纤维素的研究[J].造纸科学与技术,2013,32(6):45.
[23]Hou X F,Wang Z N,Sun J,et al.A microwave-assisted aqueous ionic liquid pretreatment to enhance enzymatic hydrolysis of Eucalyptus and its mechanism[J].Bioresource Technology,2019,272:99.
[24]Li H L,Wang X H,Liu C Y,et al.An efficient pretreatment for the selectively hydrothermal conversion of corncob into furfural:The combined mixed ball milling and ultrasonic pretreatments[J].Industrial Crops and Products,2016,94:721.
[25]Sun R C,Tomkinson J.Characterization of hemicelluloses obtained by classical and ultrasonically assisted extractions from wheat straw[J].Carbohydrate Polymers,2002,50(3):263.
[26]MA Z Y,LV Y N.Study on Alkaline Extraction of Hemicelluloses from Bagasse Pith with Ultrasound-Assisted[J].China Pulp&Paper,2018,37(1):19.马志宇,吕艳娜.超声波辅助稀碱法提取蔗髓半纤维素的工艺探究[J].中国造纸,2018,37(1):19.
[27]Miyafuji H,Miyata K,Saka S,et al.Reaction behavior of wood in an ionic liquid,1-ethyl-3-methylimidazolium chloride[J].Journal of Wood Science,2009,55(3):215.
[28]Mohtar S S,Busu T N Z T M,Md Noor A M,et al.An ionic liquid treatment and fractionation of cellulose,hemicellulose and lignin from oil palm empty fruit bunch[J].Carbohydrate Polymers,2017,166:291.
[29]Mohtar S S,Tengku Malim Busu T N Z,Md Noor A M,et al.Extraction and characterization of lignin from oil palm biomass via ionic liquid dissolution and non-toxic aluminium potassium sulfate dodecylhydrate precipitation processes[J].Bioresource Technology,2015,192:212.
[30]Raj T,Gaur R,Dixit P,et al.Ionic liquid pretreatment of biomass for sugars production:Driving factors with a plausible mechanism for higher enzymatic digestibility[J].Carbohydrate Polymers,2016,149:369.
[31]Lv B L.The studies on the solubility and dissolution mechanism of cellulose and xylan in ionic liquids[D].Lanzhou:Lanzhou University,2016.吕本莲.离子液体对纤维素和聚木糖的溶解性能及溶解机理研究[D].兰州:兰州大学,2016.
[32]Shuai L,Questell-Santiago Y M,Luterbacher J S.A mild biomass pretreatment usingγ-valerolactone for concentrated sugar production[J].Green Chemistry,2016,18:937.
[33]Wu M,Yan Z Y,Zhang X M,et al.Integration of mild acid hydrolysis inγ-valerolactone/water system for enhancement of enzymatic saccharification from cotton stalk[J].Bioresource Technology,2016,200:23.
[34]Alonso D M,Wettstein S G,Mellmer M A,et al.Integrated conversion of hemicellulose and cellulose from lignocellulosic biomass[J].Energy&Environmental Science,2013,6:76.
[35]Abbott A P,Capper G,Davies D L,et al.Novel solvent properties of choline chloride/urea mixtures[J].Chemical Communications,2003,1:70.
[36]Satlewal A,Agrawal R,Bhagia Samarthya,et al.Natural deep eutectic solvents for lignocellulosic biomass pretreatment:Recent developments,challenges and novel opportunities[J].Biotechnology Advances,2018,36:2032.
[37]Soares B,Tavares D J P,Amaral J L,et al.Enhanced solubility of lignin monomeric model compounds and technical lignins in aqueous solutions of deep eutectic solvents[J].ACS Sustainable Chemistry Engineering,2017,5:4056.
[38]Morais E S,Mendonca P V,Coelho J F J,et al.Deep eutectic solvent aqueous solutions as efficient media for the solubilization of hardwood xylans[J].Chem.Sus.Chem.,2018,11:753.
[39]Kumar A K,Pravakar M.Natural deep eutectic solvent mediated pretreatment of rice straw:bioanalytical characterization of lignin extract and enzymatic hydrolysis of pretreated biomass residue[J].Environmental Science and Pollution Research,2016,23(10):9265.
[40]Hou X D,Feng G J,Ye M,et al.Significantly enhanced enzymatic hydrolysis of rice straw via a high-performance two-stage deep eutectic solvents synergistic pretreatment[J].Bioresource Technology,2017,238:139.