纳米银材料绿色制备及其在水处理中的应用进展
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摘要
针对纳米银粒子最常用的制备方法化学还原法中化学试剂的大量使用及其对环境的污染,结合近几年国内外的研究成果,介绍了纳米银的绿色制备方法,包括二糖法、多糖法、微生物合成法、植物提取物法等。同时介绍了纳米银离子在净水处理和废水处理方面的应用进展。分析认为,糖类作为还原剂可生成具有良好催化及杀菌性能的纳米银粒子。纳米银的形貌可控制备以及生物合成法中微生物及植物的选择技术等是今后纳米银绿色制备的发展方向。
The most commonly used method for the preparation of silver nanoparticles was chemical reduction method. Thus more chemical reagents were used and made pollution to the environment. The green preparation methods of silver nanoparticles,including two sugar method,polysaccharide method,microbial synthesis method and plant extraction method were introduced based on the domestic and foreign research results in recent years. The application of silver nanoparticles in water and wastewater treatment were also introduced. It is concluded that saccharides could be used as reducing agents to produce silver nanoparticles with good catalytic and germicidal properties. The morphology controlled of silver nanoparticles,the selection of microorganisms and plants in biosynthesis are the development direction of silver nanoparticles green preparation.
The most commonly used method for the preparation of silver nanoparticles was chemical reduction method. Thus more chemical reagents were used and made pollution to the environment. The green preparation methods of silver nanoparticles,including two sugar method,polysaccharide method,microbial synthesis method and plant extraction method were introduced based on the domestic and foreign research results in recent years. The application of silver nanoparticles in water and wastewater treatment were also introduced. It is concluded that saccharides could be used as reducing agents to produce silver nanoparticles with good catalytic and germicidal properties. The morphology controlled of silver nanoparticles,the selection of microorganisms and plants in biosynthesis are the development direction of silver nanoparticles green preparation.
引文
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[25]Goyal G,Hwang J,Aviral J,et al.Green synthesis of silver nanoparticles usingβ-glucan,and their incorporation into doxorubicin-loaded water-in-oil nanoemulsions for antitumor and antibacterial applications[J].Journal of Industrial&Engineering Chemistry,2016,47:179-186.
[26]Jian W,Zhang L,Siu K C,et al.Formation and physiochemical properties of silver nanoparticles with various exopolysaccharides of a medicinal fungus in aqueous solution[J].Molecules,2016,22(50):1-15.
[27]Hussain M A,Shah A,Jantan I,et al.Hydroxypropylcellulose as a novel green reservoir for the synthesis,stabilization,and storage of silver nanoparticles[J].International Journal of Nanomedicine,2015,10:2079-2088.
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[29]Fathima B S,Balakrishnan R M.Biosynthesis and optimization of silver nanoparticles by endophytic fungus Fusarium solani[J].Materials Letters,2014,132(10):428-431.
[30]Singh B R,Singh B N,Singh A,et al.Mycofabricated biosilver nanoparticles interrupt Pseudomonas aeruginosa quorum sensing systems[J].Scientific Reports,2015,5:1-14.
[31]Gade A,Gaikwad S,Duran N,et al.Green synthesis of silver nanoparticles by Phoma glomerata[J].Micron,2014,59(6):52-59.
[32]刘小莉,胡彦新,彭欢欢,等.内生真菌绿色生态法合成纳米银的研究[J].现代食品科技,2017(1):119-124.
[33]Ravichandran V,Vasanthi S,Shalini S,et al.Green synthesis of silver nanoparticles using Atrocarpus altilis,leaf extract and the study of their antimicrobial and antioxidant activity[J].Materials Letters,2016,180:264-267.
[34]Sun Q,Cai X,Li J,et al.Green synthesis of silver nanoparticles using tea leaf extract and evaluation of their stability and antibacterial activity[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2014,444(4):226-231.
[35]Singh S,Saikia J P,Buragohain A K.A novel‘green’synthesis of colloidal silver nanoparticles(SNP)using Dillenia indica,fruit extract[J].Colloids and Surfaces B:Biointerfaces,2013,102:83-85.
[36]Mashwani Z U,Khan M A,Khan T,et al.Applications of plant terpenoids in the synthesis of colloidal silver nanoparticles[J].Advances in Colloid&Interface Science,2016,234:132-141.
[37]Shankar S S,Rai A,Ahmad A,et al.Rapid synthesis of Au,Ag,and bimetallic Au core-Ag shell nanoparticles using Neem(Azadirachta indica)leaf broth[J].Journal of Colloid and Interface Science,2004,275(2):496-502.
[38]Sheny D S,Mathew J,Philip D.Synthesis characterization and catalytic action of hexagonal gold nanoparticles using essential oils extracted from Anacardium occidentale[J].Spectrochimica Acta Part A Molecular&Biomolecular Spectroscopy,2012,97(6):306-310.
[39]Kathiravan V,Ravi S,Ashokkumar S,et al.Green synthesis of silver nanoparticles using Croton sparsiflorus morong leaf extract and their antibacterial and antifungal activities[J].Spectrochimica Acta Part A Molecular&Biomolecular Spectroscopy,2015,139(139C):200-205.
[40]Ghosh S,Vandana V.Nano-structured mesoporous silica/silver composite:Synthesis,characterization and targeted application towards water purification[J].Materials Research Bulletin,2017,88:291-300.
[41]Xia Y,Jiang X,Zhang J,et al.Synthesis and characterization of antimicrobial nanosilver/diatomite nanocomposites and its water treatment application[J].Applied Surface Science,2017,396:1760-1764.
[42]Sondi I,Salopek-Sondi B.Silver nanoparticles as antimicrobial agent:a case study on E.coli as a model for Gramnegative bacteria[J].Journal of Colloid&Interface Science,2004,275(1):177-182.
[43]Vidhu V K,Philip D.Catalytic degradation of organic dyes using biosynthesized silver nanoparticles[J].Micron,2013,56(1):54-62.
[44]Edison T N J I,Atchudan R,Kamal C,et al.Caulerpa racemosa:a marine green alga for eco-friendly synthesis of silver nanoparticles and its catalytic degradation of methylene blue[J].Bioprocess and Biosystems Engineering,2016(9):1-8.
[45]Joseph S,Mathew B.Facile synthesis of silver nanoparticles and their application in dye degradation[J].Materials Science&Engineering B,2015,195(1):90-97.
[46]Joseph S,Mathew B.Microwave-assisted green synthesis of silver nanoparticles and the study on catalytic activity in the degradation of dyes[J].Journal of Molecular Liquids,2015,204:184-191.
[47]刘威,薛文平,孙德栋,等.橘皮炭负载纳米银催化剂催化氧化含氰废水的研究[J].煤炭加工与综合利用,2014(12):52-56.
[48]杨芬,朱勋乐.Ag/Bi2WO6的制备及光催化氧化性能[J].广州化工,2014(22):63-64.
[49]Chen M,Lei Y,Lan Z,et al.Effect of nano/micro-Ag compound particles on the bio-corrosion,antibacterial properties and cell biocompatibility of Ti-Ag alloys[J].Materials Science&Engineering C Materials for Biological Applications,2017,75:906-917.
[50]Ghaedi M,Heidarpour S,Kokhdan S N,et al.Comparison of silver and palladium nanoparticles loaded on activated carbon for efficient removal of Methylene blue:Kinetic and isotherm study of removal process[J].Powder Technology,2012,228(228):18-25.
[51]Kazmi S J,Shehzad M A,Mehmood S,et al.Effect of varied Ag nanoparticles functionalized CNTs on its anti-bacterial activity against E.coli[J].Sensors&Actuators A Physical,2014,216(3):287-294.
[52]Huang L J,Wang Y X,Tang J G,et al.Preparation of graphene/silver nanohybrid composite with good surface-enhanced Raman scattering characteristics[J].International Journal of Electrochemical Science,2016,11:398-405.
[53]Ghosh S,Vandana V.Nano-structured mesoporous silica/silver composite:Synthesis,characterization and targeted application towards water purification[J].Materials Research Bulletin,2017,88:291-300.
[54]Tang C,Hu D,Cao Q,et al.Silver nanoparticles-loaded activated carbon fibers using chitosan as binding agent:Preparation,mechanism,and their antibacterial activity[J].Applied Surface Science,2017,394:457-465.
[2]Theamdee P,Rutnakornpituk B,Wichai U,et al.Recyclable silver-magnetite nanocomposite for antibacterial application[J].Journal of Industrial&Engineering Chemistry,2015,29:63-70.
[3]Yan Y,Tang H,Li J,et al.Self-assembly synthesis of a unique stable cocoon-like hematite@C nanoparticle and its application in lithium ion batteries[J].Journal of Colloid&Interface Science,2016,495:157-167.
[4]Yuan M,Su F,Chen Y.Synthesis of nano-Cu/graphene oxide composites by supercritical CO2-assisted deposition as a novel material for reducing friction and wear[J].Chemical Engineering Journal,2015,281:11-19.
[5]Wang Y,Yang J,Yu J,et al.Ag nanoparticle-multiply alkylated cyclopentane composite ultrathin films fabricated by one step dip coating process and its tribological performances[J].Surface&Coatings Technology,2014,239(1):65-69.
[6]Guo S,Zhang S,Sun S.Tuning nanoparticle catalysis for the oxygen reduction reaction[J].Angewandte Chemie International Edition,2013,52(33):8526-8544.
[7]An X,Long Y,Ni Y.Cellulose nanocrystal/hexadecyltrimethylammonium bromide/silver nanoparticle composite as a catalyst for reduction of 4-nitrophenol[J].Carbohydrate Polymers,2017,156:253-258.
[8]Varadavenkatesan T,Selvaraj R,Vinayagam R.Phyto-synthesis of silver nanoparticles from Mussaenda erythrophylla,leaf extract and their application in catalytic degradation of methyl orange dye[J].Journal of Molecular Liquids,2016,221:1063-1070.
[9]Ajitha B,Reddy Y A K,Reddy P S,et al.Instant biosynthesis of silver nanoparticles using Lawsonia inermis,leaf extract:Innate catalytic,antimicrobial and antioxidant activities[J].Journal of Molecular Liquids,2016,219:474-481.
[10]Guo S,Wang E.Noble metal nanomaterials:Controllable synthesis and application in fuel cells and analytical sensors[J].Nano Today,2011,6(3):240-264.
[11]Howes P D,Chandrawati R,Stevens M M.Bionanotechnology colloidal nanoparticles as advanced biological sensors[J].Science,2014,346(6205):1247390.
[12]Wang Z,Han P,Mao X,et al.Sensitive detection of glutathione by using DNA-templated copper nanoparticles as electrochemical reporters[J].Sensors&Actuators B Chemical,2016,238:325-330.
[13]Fekry A M.A new simple electrochemical moxifloxacin hydrochloride sensor built on carbon paste modified with silver nanoparticles[J].Biosensors&Bioelectronics,2017,87:1065-1070.
[14]Wang A Z,Langer R,Farokhzad O C.Nanoparticle delivery of cancer drugs[J].Annual Review of Medicine,2012,63(63):185-198.
[15]Du J,Singh H,Yi T H.Antibacterial,anti-biofilm and anticancer potentials of green synthesized silver nanoparticles using benzoin gum(Styrax benzoin)extract[J].Bioprocess&Biosystems Engineering,2016,39(12):1923-1931.
[16]Ye Y D,Xia L,Xu D D,et al.DNA-stabilized silver nanoclusters and carbon nanoparticles oxide:A sensitive platform for label-free fluorescence turn-on detection of HIVDNA sequences[J].Biosensors&Bioelectronics,2016,85:837-843.
[17]Dankovich T A,Gray D G.Bactericidal paper impregnated with silver nanoparticles for point-of-use water treatment[J].Environmental Science&Technology,2011,45(5):1992-1998.
[18]Zhang T,Song Y J,Zhang X Y,et al.Synthesis of silver nanostructures by multistep methods[J].Sensors,2014,14(14):5860-5889.
[19]Oluwafemi O S,Lucwaba Y,Gura A,et al.A facile completely‘green’size tunable synthesis of maltose-reduced silver nanoparticles without the use of any accelerator[J].Colloids&Surfaces B Biointerfaces,2013,102(1):718-723.
[20]Oluwafemi O S,Vuyelwa N,Scriba M,et al.Green controlled synthesis of monodispersed,stable and smaller sized starch-capped silver nanoparticles[J].Materials Letters,2013,106(9):332-336.
[21]Filippo E,Serra A,Buccolieri A,et al.Green synthesis of silver nanoparticles with sucrose and maltose:Morphological and structural characterization[J].Journal of NonCrystalline Solids,2010,356(6/7/8):344-350.
[22]Yakout S M,Mostafa A A.A novel green synthesis of silver nanoparticles using soluble starch and its antibacterial activity[J].International Journal of Clinical&Experimental Medicine,2014,8(3):3538-3544.
[23]Yang N,Wei X F,Li W H.Sunlight irradiation induced green synthesis of silver nanoparticles using peach gum polysaccharide and colorimetric sensing of H2O2[J].Materials Letters,2015,154:21-24.
[24]Anuradha K,Bangal P,Madhavendra S S.Macromolecular arabinogalactan polysaccharide mediated synthesis of silver nanoparticles,characterization and evaluation[J].Macromolecular Research,2016,24(2):152-162.
[25]Goyal G,Hwang J,Aviral J,et al.Green synthesis of silver nanoparticles usingβ-glucan,and their incorporation into doxorubicin-loaded water-in-oil nanoemulsions for antitumor and antibacterial applications[J].Journal of Industrial&Engineering Chemistry,2016,47:179-186.
[26]Jian W,Zhang L,Siu K C,et al.Formation and physiochemical properties of silver nanoparticles with various exopolysaccharides of a medicinal fungus in aqueous solution[J].Molecules,2016,22(50):1-15.
[27]Hussain M A,Shah A,Jantan I,et al.Hydroxypropylcellulose as a novel green reservoir for the synthesis,stabilization,and storage of silver nanoparticles[J].International Journal of Nanomedicine,2015,10:2079-2088.
[28]Venkatpurwar V,Pokharkar V.Green synthesis of silver nanoparticles using marine polysaccharide:Study of invitro,antibacterial activity[J].Materials Letters,2011,65(65):999-1002.
[29]Fathima B S,Balakrishnan R M.Biosynthesis and optimization of silver nanoparticles by endophytic fungus Fusarium solani[J].Materials Letters,2014,132(10):428-431.
[30]Singh B R,Singh B N,Singh A,et al.Mycofabricated biosilver nanoparticles interrupt Pseudomonas aeruginosa quorum sensing systems[J].Scientific Reports,2015,5:1-14.
[31]Gade A,Gaikwad S,Duran N,et al.Green synthesis of silver nanoparticles by Phoma glomerata[J].Micron,2014,59(6):52-59.
[32]刘小莉,胡彦新,彭欢欢,等.内生真菌绿色生态法合成纳米银的研究[J].现代食品科技,2017(1):119-124.
[33]Ravichandran V,Vasanthi S,Shalini S,et al.Green synthesis of silver nanoparticles using Atrocarpus altilis,leaf extract and the study of their antimicrobial and antioxidant activity[J].Materials Letters,2016,180:264-267.
[34]Sun Q,Cai X,Li J,et al.Green synthesis of silver nanoparticles using tea leaf extract and evaluation of their stability and antibacterial activity[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2014,444(4):226-231.
[35]Singh S,Saikia J P,Buragohain A K.A novel‘green’synthesis of colloidal silver nanoparticles(SNP)using Dillenia indica,fruit extract[J].Colloids and Surfaces B:Biointerfaces,2013,102:83-85.
[36]Mashwani Z U,Khan M A,Khan T,et al.Applications of plant terpenoids in the synthesis of colloidal silver nanoparticles[J].Advances in Colloid&Interface Science,2016,234:132-141.
[37]Shankar S S,Rai A,Ahmad A,et al.Rapid synthesis of Au,Ag,and bimetallic Au core-Ag shell nanoparticles using Neem(Azadirachta indica)leaf broth[J].Journal of Colloid and Interface Science,2004,275(2):496-502.
[38]Sheny D S,Mathew J,Philip D.Synthesis characterization and catalytic action of hexagonal gold nanoparticles using essential oils extracted from Anacardium occidentale[J].Spectrochimica Acta Part A Molecular&Biomolecular Spectroscopy,2012,97(6):306-310.
[39]Kathiravan V,Ravi S,Ashokkumar S,et al.Green synthesis of silver nanoparticles using Croton sparsiflorus morong leaf extract and their antibacterial and antifungal activities[J].Spectrochimica Acta Part A Molecular&Biomolecular Spectroscopy,2015,139(139C):200-205.
[40]Ghosh S,Vandana V.Nano-structured mesoporous silica/silver composite:Synthesis,characterization and targeted application towards water purification[J].Materials Research Bulletin,2017,88:291-300.
[41]Xia Y,Jiang X,Zhang J,et al.Synthesis and characterization of antimicrobial nanosilver/diatomite nanocomposites and its water treatment application[J].Applied Surface Science,2017,396:1760-1764.
[42]Sondi I,Salopek-Sondi B.Silver nanoparticles as antimicrobial agent:a case study on E.coli as a model for Gramnegative bacteria[J].Journal of Colloid&Interface Science,2004,275(1):177-182.
[43]Vidhu V K,Philip D.Catalytic degradation of organic dyes using biosynthesized silver nanoparticles[J].Micron,2013,56(1):54-62.
[44]Edison T N J I,Atchudan R,Kamal C,et al.Caulerpa racemosa:a marine green alga for eco-friendly synthesis of silver nanoparticles and its catalytic degradation of methylene blue[J].Bioprocess and Biosystems Engineering,2016(9):1-8.
[45]Joseph S,Mathew B.Facile synthesis of silver nanoparticles and their application in dye degradation[J].Materials Science&Engineering B,2015,195(1):90-97.
[46]Joseph S,Mathew B.Microwave-assisted green synthesis of silver nanoparticles and the study on catalytic activity in the degradation of dyes[J].Journal of Molecular Liquids,2015,204:184-191.
[47]刘威,薛文平,孙德栋,等.橘皮炭负载纳米银催化剂催化氧化含氰废水的研究[J].煤炭加工与综合利用,2014(12):52-56.
[48]杨芬,朱勋乐.Ag/Bi2WO6的制备及光催化氧化性能[J].广州化工,2014(22):63-64.
[49]Chen M,Lei Y,Lan Z,et al.Effect of nano/micro-Ag compound particles on the bio-corrosion,antibacterial properties and cell biocompatibility of Ti-Ag alloys[J].Materials Science&Engineering C Materials for Biological Applications,2017,75:906-917.
[50]Ghaedi M,Heidarpour S,Kokhdan S N,et al.Comparison of silver and palladium nanoparticles loaded on activated carbon for efficient removal of Methylene blue:Kinetic and isotherm study of removal process[J].Powder Technology,2012,228(228):18-25.
[51]Kazmi S J,Shehzad M A,Mehmood S,et al.Effect of varied Ag nanoparticles functionalized CNTs on its anti-bacterial activity against E.coli[J].Sensors&Actuators A Physical,2014,216(3):287-294.
[52]Huang L J,Wang Y X,Tang J G,et al.Preparation of graphene/silver nanohybrid composite with good surface-enhanced Raman scattering characteristics[J].International Journal of Electrochemical Science,2016,11:398-405.
[53]Ghosh S,Vandana V.Nano-structured mesoporous silica/silver composite:Synthesis,characterization and targeted application towards water purification[J].Materials Research Bulletin,2017,88:291-300.
[54]Tang C,Hu D,Cao Q,et al.Silver nanoparticles-loaded activated carbon fibers using chitosan as binding agent:Preparation,mechanism,and their antibacterial activity[J].Applied Surface Science,2017,394:457-465.