钛酸钡介电陶瓷中变价稀土离子的价态鉴定及缺陷化学的研究进展
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摘要
在介电陶瓷材料领域,本文回顾十年来吉林化工学院材料科学与工程研究中心(RCMSE)对钛酸钡陶瓷中四种变价稀土离子(Ce、Pr、Eu、Tb)价态及位占据鉴定的研究进展,简介我们利用变价稀土离子在双稀土掺杂钛酸钡陶瓷(DRBT)所取得的研究成果.
In the field of dielectric materials,this paper reviews the research advances in the identifications on valence states and site occupations of four kinds of valence-variable rare-earth ions( Ce,Pr,Eu,and Tb) in Ba Ti O3 ceramics for a decade in Research Center for Materials Science and Engineering( RCMSE),Jilin Institute of Chemical Technology. Some research findings are introduced briefly for the applications of these valence-variable rare-earth ions in double rare-earth-doped Ba Ti O3 ceramics( DRBT).
In the field of dielectric materials,this paper reviews the research advances in the identifications on valence states and site occupations of four kinds of valence-variable rare-earth ions( Ce,Pr,Eu,and Tb) in Ba Ti O3 ceramics for a decade in Research Center for Materials Science and Engineering( RCMSE),Jilin Institute of Chemical Technology. Some research findings are introduced briefly for the applications of these valence-variable rare-earth ions in double rare-earth-doped Ba Ti O3 ceramics( DRBT).
引文
[1]H.Kishi,Y.Mizuno,H.Chazono,Base-metal electrodemultilayer ceramic capacitors:past,present and future perspectives[J].Jpn.J.Appl.Phys.,2003,41,1-15.
[2]D.F.K.Hennings,B.Schreinemacher,H.Schreinemacher,High-permittivity dielectric ceramics with high endurance[J].J.Euro.Ceram.Soc.,1994,13(1):81-88.
[3]D.Lu,M.Toda,M.Sugano,High-permittivity double rare-earth-doped barium titanate ceramics with diffuse phase transition[J].J.Am.Ceram.Soc.,2006,89(10):3112-3123.
[4]D.Lu,X.Sun,M.Toda,A novel high-k‘Y5V’barium titanate ceramics co-doped with lanthanum and cerium[J].J.Phys.Chem.Solids,2007,68(4):650-664.
[5]D.Lu,M.Toda,Dielectric temperature characteristics of high-k(Ba,La)(Ti,Ce)O3ceramics[J].J.Ceram.Soc.Jpn.2006,114(7):612-619.
[6]F.D.Morrison,D.C.Sinclair,J.M.S.Skakle,et al.,Novel doping mechanism for very-high-permittivity barium titanate ceramics[J].J.Am.Ceram.Soc.,1998,81(7)1957-1960.
[7]A.Chen,Y.Zhi,J.Zhi,et al.,Synthesis and characterization of Ba(Ti1-xCex)O3ceramics[J].J.Eur.Ceram.Soc.,1997,17(10):1217-1221.
[8]路大勇,镧系离子对钛酸钡陶瓷结构的修改在介电领域的进展[J].吉林化工学院学报,2008,25(1):34-41
[9]R.D.Shannon,Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides,Acta Crystallogr.Sect A,1976,32:751-767.
[10]D.Makovec,Z.Samardzija,D.Kolar,Solid solubility of cerium in Ba Ti O3[J].J.Solid State Chem.,1996,123:30-38.
[11]D.Hennings,A.Schnell,G.Simon,Diffuse ferroelectric phase transitions in Ba(Ti1-yZry)O3ceramics[J].J.Am.Ceram.Soc.,1982,65(11):539-544.
[12]D.Lu,D.Han,X.Sun,Mutual solid solubility and phase equilibrium in the system Ba Ti O3-Ba Ce O3[J].Jpn.J.Appl.Phys.,2012,51(7):071501.
[13]D.Lu,D.Han,X.Sun,et al.,Raman evidence for BaSite Ce3+in Ba Ti O3[J].Jpn.J.Appl.Phys.2013,52(11):111501.
[14]D.Han,D.Lu,X.Sun,Structural evolution and dielectric properties of(Ba1-xNdx)(Ti1-yFey)O3ceramics[J].J.Alloy.Compd.,2013,576:24-29.
[15]F.A.Kr9ger and H.J.Vink,in:F.Seitz and D.Turnbull(Ed.),Relations between the Concentrations of Imperfections in Crystalline Solids,in Solid State Physics[M].Academic Press,New York,1956,p.307.
[16]D.Lu,D.Han,In-situ diffuse phase transition at the Curie point of Ba Ti O3induced by amphoteric Ce3+/Ce4+ions[J].Ceram.Int.,2013,39(8):9727-9730.
[17]D.Lu,X.Sun,B.Liu,et al.,Structural and dielectric properties,electron paramagnetic resonance,and defect chemistry of Pr-doped Ba Ti O3ceramics[J].J.Alloy.Compd.,2014,615:25-34.
[18]D.Lu,Q.Liu,T.Ogata,et al.,Tetragonal phase stabilization caused by Pr ions in Ba(Ti0.99Mn0.01)O3with mixed phases[J].Jpn.J.Appl.Phys.,2011,50(3):035806.
[19]D.Lu,T.Koda,H.Suzuki,et al.,Structure and dielectric properties of Eu-doped barium titanate ceramics[J].J.Ceram.Soc.Jpn.,2005,113(11):721-727.
[20]D.Lu,X.Sun,M.Toda,Electron spin resonance investigations and compensation mechanism of europiumdoped barium titanate ceramics[J].Jpn.J.Appl.Phys.2006,45(11):8782-8788.
[21]D.Lu,M.Sugano,X.Sun,et al.,X-ray photoelectron spectroscopy study on Ba1-xEuxTi O3[J].Appl.Surf.Sci.,2005,242(3-4):318-325.
[22]D.Lu,T.Ogata,H.Unuma,X.Li,N.Li,X.Sun,Self-compensation characteristics of Eu ions in Ba Ti O3,Solid State Ionics,2011,201(1):6-10.
[23]D.Lu,L.Zhang,X.Sun,Defect chemistry of a high-k‘Y5V’(Ba0.95Eu0.05)Ti O3ceramic[J].Ceram.Int.2013,39(6):6369-6377.
[24]D.Lu,Y.Liang,Valence states and dielectric properties of fine-grained Ba Ti O3ceramics co-doped with double valence-variable europium and chromium[J].Ceram.Int.,2018,in press.
[25]L.A.Xue,Y.Chen,R.J.Brook,The influence of ionic radii on the incorporation of trivalent dopants into BaTi O3[J].Mater.Sci.Eng.B,1988,1(2):193-201.
[26]M.T.Buscaglia,V.Buscaglia,M.Viviani,P.Nanni,M.Hanuskova,Influence of foreign ions on the crystal structure of Ba Ti O3[J].J.Eur.Ceram.Soc.,2000,20(12):1997-2007.
[27]M.T.Buscaglia,V.Buscaglia,M.Viviani,et al.,Atomistic simulation of dopant Incorporation in barium titanate[J].J.Am.Ceram.Soc.,2001,84(2):376-384.
[28]Y.-X.Li,X.Yao,X.-S.Wang,Y.-B.Hao,Study of dielectric properties of rare earth(Dy,Tb,Eu)doped barium titanate sintered in pure nitrogen[J].Ceram.Int.2012,38(S1):S29-S32.
[29]Y.Tsur,T.D.Dunbar,C.A.Randall,Crystal and defect chemistry of rare earth cations in Ba Ti O3[J].J.Electroceram.,2001,7(1):25-34.
[30]D.Lu,Self-adjustable site occupations between Ba-site Tb3+and Ti-site Tb4+ions in terbium-doped barium titanate ceramics[J].Solid State Ionics,2015,276:98-106.
[31]D.Lu,Y.Peng,Dielectric properties and exploration of self-compensation mode of Tb in Ba Ti O3ceramics[J].J.Ceram.Soc.Jpn.,2016,124(4):455-459.
[32]D.Lu,M.Toda,T.Ogata,X.-Y.Sun,Point defect characteristics of high-k double rare-earth-doped Ba Ti O3ceramics with diffuse phase transition by electron spin resonance[J].Jpn.J.Appl.Phys.,2009,48(2):021401.
[33]D.Lu,Influence of dc bias field on dielectric properties of high-k Y5V(Ba,La)(Ti,Ce)O3ceramic[J].Mater.Lett.,2009,63(20):1722-1724.
[34]D.Lu,Y.Zheng,A high-permittivity and low-loss(Ba1-x Ndx)(Ti1-y-x/4Cey)O3ceramic[J].Mater.Lett.2018,223:25-28.
[35]D.Han,Q.Liu,Y.Wang,C.et al.,Novel Raman spectroscopy of a strong high-k diffuse phase transition(Ba1-xSmx)(Ti0.95-x/4Ce0.05)O3ceramics[J].Ceram.Int.,2016,42(7):8815-8821.
[36]D.Lu,D.Guan,H.Li,Multiplicity of photoluminescence in Raman spectroscopy and defect chemistry of(Ba1-x Rx)(Ti1-xHox)O3(R=La,Pr,Nd,Sm)dielectric ceramics[J].Ceram.Int.,2018,44(2):1483-1492.
[37]D.Lu,D.Guan,Photoluminescence associated with the site occupations of Ho3+ions in Ba Ti O3[J].Sci.Rep.,2017,7:6125.
[38]D.Lu,S.Cui,Defects characterisation of Dy-doped BaTi O3ceramics via electron paramagnetic resonance[J].J.Eur.Ceram.Soc.,2014,34(10):2217-2227.
[39]D.Lu,S.Cui,Q.Liu,X.Sun,Dielectric properties and defect chemistry of barium titanate ceramics co-doped R and Dy ions(R=Eu,Gd,Tb)[J].Ceram.Int.,2016,42(13):14364-14373.
[40]D.Lu,Y.Peng,X.Yu,X.Sun,Dielectric properties and defect chemistry of La and Tb co-doped Ba Ti O3ceramics[J].J.Alloy.Compd.,2016,681:128-138.
[41]D.Lu,X.-Y.Yu,J.-W.Liu,Mixed-valent structure,dielectric properties and defect chemistry of Ca1-3 x/2TbxCu3Ti4-xTbxO12ceramics[J].Ceram.Int.,2017,43(12):8664-8676.
[42]J.Liu,D.Lu,X.Yu,Q.Liu,Q.Tao,H.Change,P.Zhu,*Dielectric properties of Eu-doped Ca Cu3Ti4O12with different compensation mechanisms[J].Acta Metall.Sin-Engl.,2017,30(2):97-103.
[43]Q.Liu,J.Liu,D.Lu,et al.,Colossal dielectric behavior and relaxation in Nd-doped Ba Ti O3at low temperature[J].Ceram.Int.,2018,44(6):7251-7258.
[2]D.F.K.Hennings,B.Schreinemacher,H.Schreinemacher,High-permittivity dielectric ceramics with high endurance[J].J.Euro.Ceram.Soc.,1994,13(1):81-88.
[3]D.Lu,M.Toda,M.Sugano,High-permittivity double rare-earth-doped barium titanate ceramics with diffuse phase transition[J].J.Am.Ceram.Soc.,2006,89(10):3112-3123.
[4]D.Lu,X.Sun,M.Toda,A novel high-k‘Y5V’barium titanate ceramics co-doped with lanthanum and cerium[J].J.Phys.Chem.Solids,2007,68(4):650-664.
[5]D.Lu,M.Toda,Dielectric temperature characteristics of high-k(Ba,La)(Ti,Ce)O3ceramics[J].J.Ceram.Soc.Jpn.2006,114(7):612-619.
[6]F.D.Morrison,D.C.Sinclair,J.M.S.Skakle,et al.,Novel doping mechanism for very-high-permittivity barium titanate ceramics[J].J.Am.Ceram.Soc.,1998,81(7)1957-1960.
[7]A.Chen,Y.Zhi,J.Zhi,et al.,Synthesis and characterization of Ba(Ti1-xCex)O3ceramics[J].J.Eur.Ceram.Soc.,1997,17(10):1217-1221.
[8]路大勇,镧系离子对钛酸钡陶瓷结构的修改在介电领域的进展[J].吉林化工学院学报,2008,25(1):34-41
[9]R.D.Shannon,Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides,Acta Crystallogr.Sect A,1976,32:751-767.
[10]D.Makovec,Z.Samardzija,D.Kolar,Solid solubility of cerium in Ba Ti O3[J].J.Solid State Chem.,1996,123:30-38.
[11]D.Hennings,A.Schnell,G.Simon,Diffuse ferroelectric phase transitions in Ba(Ti1-yZry)O3ceramics[J].J.Am.Ceram.Soc.,1982,65(11):539-544.
[12]D.Lu,D.Han,X.Sun,Mutual solid solubility and phase equilibrium in the system Ba Ti O3-Ba Ce O3[J].Jpn.J.Appl.Phys.,2012,51(7):071501.
[13]D.Lu,D.Han,X.Sun,et al.,Raman evidence for BaSite Ce3+in Ba Ti O3[J].Jpn.J.Appl.Phys.2013,52(11):111501.
[14]D.Han,D.Lu,X.Sun,Structural evolution and dielectric properties of(Ba1-xNdx)(Ti1-yFey)O3ceramics[J].J.Alloy.Compd.,2013,576:24-29.
[15]F.A.Kr9ger and H.J.Vink,in:F.Seitz and D.Turnbull(Ed.),Relations between the Concentrations of Imperfections in Crystalline Solids,in Solid State Physics[M].Academic Press,New York,1956,p.307.
[16]D.Lu,D.Han,In-situ diffuse phase transition at the Curie point of Ba Ti O3induced by amphoteric Ce3+/Ce4+ions[J].Ceram.Int.,2013,39(8):9727-9730.
[17]D.Lu,X.Sun,B.Liu,et al.,Structural and dielectric properties,electron paramagnetic resonance,and defect chemistry of Pr-doped Ba Ti O3ceramics[J].J.Alloy.Compd.,2014,615:25-34.
[18]D.Lu,Q.Liu,T.Ogata,et al.,Tetragonal phase stabilization caused by Pr ions in Ba(Ti0.99Mn0.01)O3with mixed phases[J].Jpn.J.Appl.Phys.,2011,50(3):035806.
[19]D.Lu,T.Koda,H.Suzuki,et al.,Structure and dielectric properties of Eu-doped barium titanate ceramics[J].J.Ceram.Soc.Jpn.,2005,113(11):721-727.
[20]D.Lu,X.Sun,M.Toda,Electron spin resonance investigations and compensation mechanism of europiumdoped barium titanate ceramics[J].Jpn.J.Appl.Phys.2006,45(11):8782-8788.
[21]D.Lu,M.Sugano,X.Sun,et al.,X-ray photoelectron spectroscopy study on Ba1-xEuxTi O3[J].Appl.Surf.Sci.,2005,242(3-4):318-325.
[22]D.Lu,T.Ogata,H.Unuma,X.Li,N.Li,X.Sun,Self-compensation characteristics of Eu ions in Ba Ti O3,Solid State Ionics,2011,201(1):6-10.
[23]D.Lu,L.Zhang,X.Sun,Defect chemistry of a high-k‘Y5V’(Ba0.95Eu0.05)Ti O3ceramic[J].Ceram.Int.2013,39(6):6369-6377.
[24]D.Lu,Y.Liang,Valence states and dielectric properties of fine-grained Ba Ti O3ceramics co-doped with double valence-variable europium and chromium[J].Ceram.Int.,2018,in press.
[25]L.A.Xue,Y.Chen,R.J.Brook,The influence of ionic radii on the incorporation of trivalent dopants into BaTi O3[J].Mater.Sci.Eng.B,1988,1(2):193-201.
[26]M.T.Buscaglia,V.Buscaglia,M.Viviani,P.Nanni,M.Hanuskova,Influence of foreign ions on the crystal structure of Ba Ti O3[J].J.Eur.Ceram.Soc.,2000,20(12):1997-2007.
[27]M.T.Buscaglia,V.Buscaglia,M.Viviani,et al.,Atomistic simulation of dopant Incorporation in barium titanate[J].J.Am.Ceram.Soc.,2001,84(2):376-384.
[28]Y.-X.Li,X.Yao,X.-S.Wang,Y.-B.Hao,Study of dielectric properties of rare earth(Dy,Tb,Eu)doped barium titanate sintered in pure nitrogen[J].Ceram.Int.2012,38(S1):S29-S32.
[29]Y.Tsur,T.D.Dunbar,C.A.Randall,Crystal and defect chemistry of rare earth cations in Ba Ti O3[J].J.Electroceram.,2001,7(1):25-34.
[30]D.Lu,Self-adjustable site occupations between Ba-site Tb3+and Ti-site Tb4+ions in terbium-doped barium titanate ceramics[J].Solid State Ionics,2015,276:98-106.
[31]D.Lu,Y.Peng,Dielectric properties and exploration of self-compensation mode of Tb in Ba Ti O3ceramics[J].J.Ceram.Soc.Jpn.,2016,124(4):455-459.
[32]D.Lu,M.Toda,T.Ogata,X.-Y.Sun,Point defect characteristics of high-k double rare-earth-doped Ba Ti O3ceramics with diffuse phase transition by electron spin resonance[J].Jpn.J.Appl.Phys.,2009,48(2):021401.
[33]D.Lu,Influence of dc bias field on dielectric properties of high-k Y5V(Ba,La)(Ti,Ce)O3ceramic[J].Mater.Lett.,2009,63(20):1722-1724.
[34]D.Lu,Y.Zheng,A high-permittivity and low-loss(Ba1-x Ndx)(Ti1-y-x/4Cey)O3ceramic[J].Mater.Lett.2018,223:25-28.
[35]D.Han,Q.Liu,Y.Wang,C.et al.,Novel Raman spectroscopy of a strong high-k diffuse phase transition(Ba1-xSmx)(Ti0.95-x/4Ce0.05)O3ceramics[J].Ceram.Int.,2016,42(7):8815-8821.
[36]D.Lu,D.Guan,H.Li,Multiplicity of photoluminescence in Raman spectroscopy and defect chemistry of(Ba1-x Rx)(Ti1-xHox)O3(R=La,Pr,Nd,Sm)dielectric ceramics[J].Ceram.Int.,2018,44(2):1483-1492.
[37]D.Lu,D.Guan,Photoluminescence associated with the site occupations of Ho3+ions in Ba Ti O3[J].Sci.Rep.,2017,7:6125.
[38]D.Lu,S.Cui,Defects characterisation of Dy-doped BaTi O3ceramics via electron paramagnetic resonance[J].J.Eur.Ceram.Soc.,2014,34(10):2217-2227.
[39]D.Lu,S.Cui,Q.Liu,X.Sun,Dielectric properties and defect chemistry of barium titanate ceramics co-doped R and Dy ions(R=Eu,Gd,Tb)[J].Ceram.Int.,2016,42(13):14364-14373.
[40]D.Lu,Y.Peng,X.Yu,X.Sun,Dielectric properties and defect chemistry of La and Tb co-doped Ba Ti O3ceramics[J].J.Alloy.Compd.,2016,681:128-138.
[41]D.Lu,X.-Y.Yu,J.-W.Liu,Mixed-valent structure,dielectric properties and defect chemistry of Ca1-3 x/2TbxCu3Ti4-xTbxO12ceramics[J].Ceram.Int.,2017,43(12):8664-8676.
[42]J.Liu,D.Lu,X.Yu,Q.Liu,Q.Tao,H.Change,P.Zhu,*Dielectric properties of Eu-doped Ca Cu3Ti4O12with different compensation mechanisms[J].Acta Metall.Sin-Engl.,2017,30(2):97-103.
[43]Q.Liu,J.Liu,D.Lu,et al.,Colossal dielectric behavior and relaxation in Nd-doped Ba Ti O3at low temperature[J].Ceram.Int.,2018,44(6):7251-7258.