钦杭成矿带南段粤西大金山地区的区域地球化学特征与成矿规律探讨
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摘要
粤西大金山地区位于大金山旋转构造带中,是粤西S、Ag、Pb、W、Sn、Au重要的成矿远景区,该地区矿产地多,矿化类型多,成矿带分布广。其1∶5万水系沉积物综合异常为一个环长35km、宽2~5km,面积约220km2的环带状异常,主要由W、Sn、Bi、Mo、Pb、Zn、Ag、Au等元素组成,具有元素组合复杂,规模大,强度高的特点;环绕着大金山旋转构造带分布有大金山大型钨锡矿、大降坪特大型硫铁矿、高枨大型银铅锌矿、九曲岭中型锡矿、石门头中型铅锌矿等矿床。本文基于化探综合异常,解析各典型矿床特征认为:1大金山地区以"穹隆"为中心,成矿元素自内向外依次形成有规律的水平分带:W、Sn、Bi→Sn→Sn、Pb、Zn、Ag→Ag、Pb、Zn(Au)→Au;2钨锡矿床和铅锌矿床具有清晰的垂直分带规律;3钨锡铅锌银矿床均形成于燕山晚期。在此基础上,建立了大金山地区成矿模式:震旦纪海底火山喷流(气)活动形成的浅变质岩系,为锡铅锌银矿床的形成提供了物质来源;燕山运动早期,在两个区域性北东向断裂带的左旋扭动下,形成大金山旋转构造带;燕山晚期岩浆活动使大金山旋转构造带扩容,且携带部分成矿物质(如钨等)的深源热液溶解了大绀山组地层中的锡、铅、锌、银、金等元素,在各裂隙系统中成矿。
The Dajinshan area of Guangdong province,located in the Dajinshan rotating tectonic belt,is the important metallogenic prospect area for S,Ag,Pb,W,Sn and Au.This area contains many mines and mineralization types and wide distribution of metallogenic belt.The 1∶50000stream sediment survey presents a ring-shaped composite anomaly which is 35 km long and 2~5km wide and covers an area of about 220km2.The elements found in this area are W,Sn,Bi,Mo,Pb,Zn,Ag,Au and etc.,being characteristic of complex element combination,large scale and high anomaly.The main mines surrounding around the Dajinshan tectonic belt contain the Dajinshan W-Sn ore field,the Dajingping pyrite ore field,the Gaocheng Ag-Pb-Zn ore field,the Jiuquling Sn ore field and the Shimentou Pb-Zn ore field.This paper,based on the geochemical anomaly and characteristics of typical deposits,yielded the following understanding.(1)With the dome as the center of the Dajingshan area,the ore-forming elements from the inside to the outside forms regular horizontal zoning:W,Sn,Bi→Sn→Sn,Pb,Zn,Ag→Ag,Pb,Zn(Au)→Au;(2)the vertical zoning of W-Sn and Pb-Zn deposits is clear;(3)W-Sn-Pb-Zn-Ag deposits formed in late Yanshanian.On the basis of the recognition above,the paper established the metallogenic model of the Dajinshan area.The shallow metamorphic rock series formed by Sinian submarine volcano plume(gas)activity provided the source material for the deposits;in early Yanshanian movement,the Dajinshan rotating tectonic belt was formed by sinistral rotation of two regional-scale northeast-trending faults;the late Yanshanian magmatic activity resulted in the expansion of the Dajinshan rotational tectonic belt and drove the deep-sourced hydrothermal fluids carrying part of ore-forming materials such W to dissolve the Sn,Pb,Zn and Ag elements of the Daganshan Formation,and finally these elements precipitated in the various fractures in the tectonic system.
The Dajinshan area of Guangdong province,located in the Dajinshan rotating tectonic belt,is the important metallogenic prospect area for S,Ag,Pb,W,Sn and Au.This area contains many mines and mineralization types and wide distribution of metallogenic belt.The 1∶50000stream sediment survey presents a ring-shaped composite anomaly which is 35 km long and 2~5km wide and covers an area of about 220km2.The elements found in this area are W,Sn,Bi,Mo,Pb,Zn,Ag,Au and etc.,being characteristic of complex element combination,large scale and high anomaly.The main mines surrounding around the Dajinshan tectonic belt contain the Dajinshan W-Sn ore field,the Dajingping pyrite ore field,the Gaocheng Ag-Pb-Zn ore field,the Jiuquling Sn ore field and the Shimentou Pb-Zn ore field.This paper,based on the geochemical anomaly and characteristics of typical deposits,yielded the following understanding.(1)With the dome as the center of the Dajingshan area,the ore-forming elements from the inside to the outside forms regular horizontal zoning:W,Sn,Bi→Sn→Sn,Pb,Zn,Ag→Ag,Pb,Zn(Au)→Au;(2)the vertical zoning of W-Sn and Pb-Zn deposits is clear;(3)W-Sn-Pb-Zn-Ag deposits formed in late Yanshanian.On the basis of the recognition above,the paper established the metallogenic model of the Dajinshan area.The shallow metamorphic rock series formed by Sinian submarine volcano plume(gas)activity provided the source material for the deposits;in early Yanshanian movement,the Dajinshan rotating tectonic belt was formed by sinistral rotation of two regional-scale northeast-trending faults;the late Yanshanian magmatic activity resulted in the expansion of the Dajinshan rotational tectonic belt and drove the deep-sourced hydrothermal fluids carrying part of ore-forming materials such W to dissolve the Sn,Pb,Zn and Ag elements of the Daganshan Formation,and finally these elements precipitated in the various fractures in the tectonic system.
引文
Chen Duofu,Ma Shaogang,Dong Weiquan,Chen Xianpei,Chen Guangqian,Gao Jiyuan.1998.Pb and Nd iostopesof the Dajiangping pyrite deposit,Guangdong Province,and its metallicore source.Mineral Deposits,17(3):215~223(in Chinese with English abstract).
Chen Xianpei,Chen Duofu.1992.Sedimentary petrology and geochemistry of the Sinian Period in Southern China.In:Li Jiliang,ed.Study on the Structure and Evolution of Oceanic Continental Lithosphere in Southeast China.Beijing:China Science and Technology Press,163~181(in Chinese with English abstract).
Du Xin,Liu Juntao,Wang Yaping.2004.Geological character and ore genesis of the Lawu copper-lead-zinc polymetallic ore deposit.Mineral Resources and Geology,18(5):410~414(in Chinese with English abstract).
Feng Ting.2010.Geological featutes of Pb-Zn-Ag polymetallic orebody in dajiangping pyrite ore-district,yunfu,Guangdong Province.Geology and Mineral Resources of South China,(1):26~29(in Chinese with English abstract).
Guo Min.2012.Geological Feature and prospecting potential of Dajinshan W-Sn deposit,Yunfu,Guangdong Province.Geology and Mineral Resources of South China,(04):376~382+391(in Chinese with English abstract).
Guo Min.2013.Zoning regular of metallogenetic elements in Dajinshan area,Yunfu,Guangdong Province.Jinlin Geology,(01):113~119(in Chinese with English abstract).
He Junguo,Zhou Yongzhang,Zhang Chengbo,Yang Zhijun,Shi Guiyong,Fu wei.2003.Ore controlling conditions and mineralization distribution of Jinziwo tin polymetallic deposit in yunfu,Guangdong Province.Mineral Resources and Geology,(05):598~601(in Chinese with English abstract).
Li Jingang,Chen Zhiwen,Li Ziwei.2006.Geological character and ore genesis of Gaocheng Ag polymetallic ore deposit,Yunfu.West-China Exploration Engineering,(09):124~126(in Chinese without English abstract).
Li Kuang,Hu Kai,Jiang Shaoyong,Song Shiming.2006.Geochemical characteristics of He-Ar isotopes and rare earth elements in the Dajiangping pyrite deposit in western Guangdong.Journal of Nanjing University(Natural Sciences),(06):611~620(in Chinese with English abstract).
Luo Dalve.2004.Geological characteristics and origin of Pb-Zn-Ag deposits in Daganshan area of Guangdong Province.Geology and Mineral Resources of South China,(02):9~14(in Chinese with English abstract).
Peng Shaomei,Fu Lifen,Zhou Guoqiang.1995.Shearing Anatectic Mechanism of Gneissic Granitic Rocks and Tectonic Evolution of Yunkai Area.Wuhan:China University of Geosciences Press,80~159(in Chinese with English abstract).
Sharpe R,Gemmell J B.2000.Sulfur isotope characteristics of the Archean Cu-Zn Gossan Hill VHMS deposit,Western Australia Mineralium Deposita.35(6):533~550.
Tang Juxing,Huang Yong,Li Zhijun,Deng Qi,Lang Xinghai,Chen Yuan,Zhang Li.2009.Element geochemical characteristics of Xiongcun Cu-Au deposit in Xaitongmoin County,Tibet.Mineral Deposits,28(1):16(in Chinese with English abstract).
Tao Yan,Gao Zhenmin,Ma Deyun,Li Xiaobiao,Pu Chuanjie,Li Hongyang.2004.Zonal distribution of geochemical anomalies in Axizhai ore run of Gejiu tin deposit and exploration significance.Acta Mineralogica Sinica,24(2):143~148(in Chinese with English abstract).
Wang Changming,Deng Jun,Zhang Shouting,Ye Huishou.2006.Endogentic metallogenic systems of Nannihu Mo-W-Cu-Pb-ZnAg ore forming area.Geological Science and Technology Information,25(6):47~52(in Chinese with English abstract).
Wang Denghong,Chen Yuchuan,Li Huaqin,Chen Zhenghong,Yu Jinjie,Lu Yuanfa,Li Jiyu.2003.Geological and geochemical features of the Furong tin deposit in Hunan and their significance for mineral prospecting.Geological Bulletin of China,22(1):50(in Chinese with English abstract).
Wang Henian,Li Hongyan,Wang Yinxi,Wang Haihong.1996.Metallogenic age of Dajiangping massive sulfide deposits in Guangdong Province:Rb-Sr geochronology of silicolite.Chinese Science Bulletin,21:1960~1962(in Chinese)
Wu Guozhong,Chen Zhenghui,Xiao Guangming.2012.Research on the geological features and forming age of hostrock of the Gaocheng lead-zinc deposit,Yunfu,Guangdong.Geotectonica et Metallogenia,03:434~439(in Chinese with English abstract).
Wu Yuanming,Zeng Junyue.2014.Vertical zoning regularity of Da'ao ore section in Dajingshan W-Sn polymetallic deposit,Eastern Nanling Range.Geology and Mineral Resources of South China,30(2):118~123(in Chinese with English abstract).
Wu Zonghua,Jin Yangfen.1993.Some problems concerning element zoning and its application to geological ore-prospecting.Geophysical&Geochemical Exploration,17(1):7~13(in Chinese with English abstract).
Yu Changfa,Zhao Haijie,Chen Maohong,Luo Dalve,Guo Min,Wang Zhihua.2012.Geochemical features and petrogenesis of the Dajinshan granites in west Guangdong Province.Geology in China,(06):1670~1689(in Chinese with English abstract).
Yu Changfa,Mao Jingwen,Zhao Haijie,Chen Maohong,Luo Dalve,Guo Min.2012.Geological characteristics and ages of granites and related mineralization in the Dajinshan tungsten-tin polymetallic deposit,western Guangdong Province.Acta Petrologica Sinica,28(12):3967~3979(in Chinese with English abstract).
Yu Jiaming,Zhang Hui,Lu Xuepu,Cui Lixin,Zhao Kun.2007.An analysis of the regional geochemical exploration anomaly element zoning and mineral potential.Jinlin Geology,26(2):37~46(in Chinese with English abstract).
Zhang Baogui,Zhang Qian,Pan Jiayong,Cao Yu-bo.1994.Trace element characteristics and their geological significance of Dajiangping pyrite deposit,western Guangdong.Geology and exploration,30(3):66~71(in Chinese with English abstract).
Zhang Qian,Zhang Baogui,Cao Yubo,Pan Jiayong,Zeng Tianyu,Hao Shuzhi.1993.Preliminary discussion on sulfur and lead isotope compositions of the Dajiangping pyrite deposit in western Guangdong Province.Acta Geologica Sinica,67(3):232~242(in Chinese with English abstract).
Zhang Zhongjin,Fang Jingwen,Li Guoping,Shao Libo.2006.Geochemical characteristics and ore-prospecting vista of Dadongshan area,northern Guangdong Province.Geophysical&Geochemical Exploration,30(3):220~223(in Chinese with English abstract).
Zhao Haijie,Yu Changfa,Guan Bingting,Hu Yaoguo,Xu Mingjun.2012.Geochronology and petrogenesis of biotite granite from the Gaocheng Pb-Zn-Ag deposit,in western Guangdong Province,China.Acta Petrologica Sinica,28(12):3951~3966(in Chinese with English abstract).
Zheng Wenbao,Chen Yuchuan,Song Xin,Tang Juxing,Ying Lijuan,Li Fengji,Tang Xiaoqian.2010.Element distribution of Jiama copper-polymetallic deposit in Tibet and its geological significance.Mineral Deposits,29(5):775~784(in Chinese with English abstract).
Zhuang Wenming,Peng Zhuolun,Lin Xiaoming,Zhang Xianhe,Jiang Lianting.2011.Metallogenetic zonation and exploring direction of ore-deposits in the Changkeng-Chashan ore-field,Guangdong Province.Earth Science Frontiers,18(1):102~109(in Chinese with English abstract).
陈多福,马绍刚,董维权,陈先沛,陈光谦,高计元.1998.广东大降坪黄铁矿矿床的铅、铷同位素及金属成矿物质来源探讨.矿床地质,17(3):215~223.
陈先沛,陈多福.1992.华南震旦纪的沉积岩石学及元素地球化学.见:李继亮主编.中国东南海陆岩石圈结构与演化研究.北京:中国科学技术出版社,163~181.
杜欣,刘俊涛,王亚平.2004.西藏拉屋铜铅锌多金属矿床地质特征及成因分析.矿产与地质,18(5):410~414.
冯婷.2010.广东省云浮大降坪黄铁矿区铅锌银多金属矿体地质特征.华南地质与矿产,(1):26~29.
郭敏.2012.广东云浮大金山钨锡矿床地质特征及找矿潜力分析.华南地质与矿产,(04):376~382+391.
郭敏.2013.广东云浮大金山地区成矿元素分带规律.吉林地质,(01):113~119.
何俊国,周永章,张澄博,杨志军,石贵勇,付伟.2003.广东云浮金子窝锡多金属矿床控矿条件与矿化分布规律.矿产与地质,(05):598~601.
李金刚,陈植文,李自卫.2006.云浮高枨银多金属矿特征及成因.西部探矿工程,(09):124~126.
李贶,胡凯,蒋少涌,宋世明.2006.粤西大降坪黄铁矿矿床He-Ar同位素和稀土元素组成及成矿物质来源探讨.南京大学学报(自然科学版),(06):611~620.
罗大略.2004.广东大绀山地区铅锌银矿地质特征及成因探讨.华南地质与矿产,(02):9~14.
彭少梅,符力奋,周国强.1995.云开地块构造演化及片麻状花岗岩石的剪切深熔成因.武汉:中国地质大学出版社,80~159.
唐菊兴,黄勇,李志军,邓起,郎兴海,陈渊,张丽.2009.西藏谢通门县雄村铜金矿床元素地球化学特征.矿床地质,28(1):16.
陶琰,高振敏,马德云,李晓彪,普传杰,李红阳.2004.个旧锡矿阿西寨矿段化探异常分带及找矿意义.矿物学报,24(2):143~148.
王长明,邓军,张寿庭,叶会寿.2006.河南南泥湖Mo-W-Cu-Pb-ZnAg-Au成矿区内生成矿系统.地质科技情报,25(6):47~52.
王登红,陈毓川,李华芹,陈正宏,余金杰,路远发,李寄嵎.2003.湖南芙蓉锡矿的地质地球化学特征及找矿意义.地质通报,22(1):50.
王鹤年,李红艳,王银喜,王海红.1996.广东大降坪块状硫化物矿床形成时代-硅质岩Rb-Sr同位素研究.科学通报,21:1960~1962.
武国忠,陈郑辉,肖光铭.2012.广东云浮高枨银铅锌多金属矿区成矿地质特征及成岩时代研究.大地构造与成矿学,(03):434~439.
吴远明,曾钧跃.2014.南岭东段大金山钨锡多金属矿床大坳矿段垂向分带规律浅析.华南地质与矿产,30(2):118~123.
伍宗华,金仰芬.1993.元素分带及其在地质找矿中应用的几个问题.物探与化探,17(1):7~13.
余长发,赵海杰,陈懋弘,罗大略,郭敏,王志华.2012.粤西大金山花岗岩体地球化学特征及岩石成因探讨.中国地质,(06):1670~1689.
余长发,毛景文,赵海杰,陈懋弘,罗大略,郭敏.2012.粤西大金山钨锡多金属矿床地质特征及成岩成矿年代学研究.岩石学报,28(12):3967~3979.
于家明,张辉,陆学普,崔立新,赵坤.2007.区域化探异常元素分带与找矿远景分析.吉林地质,26(2):37~46.
张宝贵,张乾,潘家永,曹裕波.1994.粤西大降坪超大型黄铁矿床微量元素特征及其成因意义.地质与勘探,30(3):66~71.
张乾,张宝贵,曹裕波,潘家永,曾天育,郝淑芝.1993.粤西大降坪黄铁矿床硫、铅同位素组成初步研究.地质学报,67(3):232~242.
张忠进,方敬文,李国平,邵立波.2006.粤北大东山地区地球化学特征与找矿前景.物探与化探,30(3):220~223.
赵海杰,余长发,关炳庭,胡耀国,徐明君.2012.粤西高枨铅锌银矿区黑云母花岗岩的年代学及岩石成因.岩石学报,28(12):3951~3966.
郑文宝,陈毓川,宋鑫,唐菊兴,应立娟,黎枫佶,唐晓倩.2010.西藏甲玛铜多金属矿元素分布规律及地质意义.矿床地质,29(5):775~784.
庄文明,彭卓伦,林小明,张献河,姜莲婷.2011.广东长坑-茶山矿田成矿元素分带规律与找矿方向.地学前缘,18(1):102~109.
1广东省地质调查院.2013.广东省云浮市大金山地区钨锡多金属矿普查报告(内部资料).
2云浮市九曲岭锡矿.2008.广东省云浮市云安县九曲岭矿区锡矿资源储量核实报告(内部资料).
3安徽扬子矿业有限公司.2007.广东省云安县高枨矿区铅锌银矿详查报告(内部资料).
4中国有色金属工业总公司广东933队.1988.广东省云浮县莳田锡铅锌银矿区大塘肚-金子窝区段普查评价报告(内部资料).
5广东省地质矿产局723队.1965.广东云浮大降坪黄铁矿区勘探报告(内部资料).
Chen Xianpei,Chen Duofu.1992.Sedimentary petrology and geochemistry of the Sinian Period in Southern China.In:Li Jiliang,ed.Study on the Structure and Evolution of Oceanic Continental Lithosphere in Southeast China.Beijing:China Science and Technology Press,163~181(in Chinese with English abstract).
Du Xin,Liu Juntao,Wang Yaping.2004.Geological character and ore genesis of the Lawu copper-lead-zinc polymetallic ore deposit.Mineral Resources and Geology,18(5):410~414(in Chinese with English abstract).
Feng Ting.2010.Geological featutes of Pb-Zn-Ag polymetallic orebody in dajiangping pyrite ore-district,yunfu,Guangdong Province.Geology and Mineral Resources of South China,(1):26~29(in Chinese with English abstract).
Guo Min.2012.Geological Feature and prospecting potential of Dajinshan W-Sn deposit,Yunfu,Guangdong Province.Geology and Mineral Resources of South China,(04):376~382+391(in Chinese with English abstract).
Guo Min.2013.Zoning regular of metallogenetic elements in Dajinshan area,Yunfu,Guangdong Province.Jinlin Geology,(01):113~119(in Chinese with English abstract).
He Junguo,Zhou Yongzhang,Zhang Chengbo,Yang Zhijun,Shi Guiyong,Fu wei.2003.Ore controlling conditions and mineralization distribution of Jinziwo tin polymetallic deposit in yunfu,Guangdong Province.Mineral Resources and Geology,(05):598~601(in Chinese with English abstract).
Li Jingang,Chen Zhiwen,Li Ziwei.2006.Geological character and ore genesis of Gaocheng Ag polymetallic ore deposit,Yunfu.West-China Exploration Engineering,(09):124~126(in Chinese without English abstract).
Li Kuang,Hu Kai,Jiang Shaoyong,Song Shiming.2006.Geochemical characteristics of He-Ar isotopes and rare earth elements in the Dajiangping pyrite deposit in western Guangdong.Journal of Nanjing University(Natural Sciences),(06):611~620(in Chinese with English abstract).
Luo Dalve.2004.Geological characteristics and origin of Pb-Zn-Ag deposits in Daganshan area of Guangdong Province.Geology and Mineral Resources of South China,(02):9~14(in Chinese with English abstract).
Peng Shaomei,Fu Lifen,Zhou Guoqiang.1995.Shearing Anatectic Mechanism of Gneissic Granitic Rocks and Tectonic Evolution of Yunkai Area.Wuhan:China University of Geosciences Press,80~159(in Chinese with English abstract).
Sharpe R,Gemmell J B.2000.Sulfur isotope characteristics of the Archean Cu-Zn Gossan Hill VHMS deposit,Western Australia Mineralium Deposita.35(6):533~550.
Tang Juxing,Huang Yong,Li Zhijun,Deng Qi,Lang Xinghai,Chen Yuan,Zhang Li.2009.Element geochemical characteristics of Xiongcun Cu-Au deposit in Xaitongmoin County,Tibet.Mineral Deposits,28(1):16(in Chinese with English abstract).
Tao Yan,Gao Zhenmin,Ma Deyun,Li Xiaobiao,Pu Chuanjie,Li Hongyang.2004.Zonal distribution of geochemical anomalies in Axizhai ore run of Gejiu tin deposit and exploration significance.Acta Mineralogica Sinica,24(2):143~148(in Chinese with English abstract).
Wang Changming,Deng Jun,Zhang Shouting,Ye Huishou.2006.Endogentic metallogenic systems of Nannihu Mo-W-Cu-Pb-ZnAg ore forming area.Geological Science and Technology Information,25(6):47~52(in Chinese with English abstract).
Wang Denghong,Chen Yuchuan,Li Huaqin,Chen Zhenghong,Yu Jinjie,Lu Yuanfa,Li Jiyu.2003.Geological and geochemical features of the Furong tin deposit in Hunan and their significance for mineral prospecting.Geological Bulletin of China,22(1):50(in Chinese with English abstract).
Wang Henian,Li Hongyan,Wang Yinxi,Wang Haihong.1996.Metallogenic age of Dajiangping massive sulfide deposits in Guangdong Province:Rb-Sr geochronology of silicolite.Chinese Science Bulletin,21:1960~1962(in Chinese)
Wu Guozhong,Chen Zhenghui,Xiao Guangming.2012.Research on the geological features and forming age of hostrock of the Gaocheng lead-zinc deposit,Yunfu,Guangdong.Geotectonica et Metallogenia,03:434~439(in Chinese with English abstract).
Wu Yuanming,Zeng Junyue.2014.Vertical zoning regularity of Da'ao ore section in Dajingshan W-Sn polymetallic deposit,Eastern Nanling Range.Geology and Mineral Resources of South China,30(2):118~123(in Chinese with English abstract).
Wu Zonghua,Jin Yangfen.1993.Some problems concerning element zoning and its application to geological ore-prospecting.Geophysical&Geochemical Exploration,17(1):7~13(in Chinese with English abstract).
Yu Changfa,Zhao Haijie,Chen Maohong,Luo Dalve,Guo Min,Wang Zhihua.2012.Geochemical features and petrogenesis of the Dajinshan granites in west Guangdong Province.Geology in China,(06):1670~1689(in Chinese with English abstract).
Yu Changfa,Mao Jingwen,Zhao Haijie,Chen Maohong,Luo Dalve,Guo Min.2012.Geological characteristics and ages of granites and related mineralization in the Dajinshan tungsten-tin polymetallic deposit,western Guangdong Province.Acta Petrologica Sinica,28(12):3967~3979(in Chinese with English abstract).
Yu Jiaming,Zhang Hui,Lu Xuepu,Cui Lixin,Zhao Kun.2007.An analysis of the regional geochemical exploration anomaly element zoning and mineral potential.Jinlin Geology,26(2):37~46(in Chinese with English abstract).
Zhang Baogui,Zhang Qian,Pan Jiayong,Cao Yu-bo.1994.Trace element characteristics and their geological significance of Dajiangping pyrite deposit,western Guangdong.Geology and exploration,30(3):66~71(in Chinese with English abstract).
Zhang Qian,Zhang Baogui,Cao Yubo,Pan Jiayong,Zeng Tianyu,Hao Shuzhi.1993.Preliminary discussion on sulfur and lead isotope compositions of the Dajiangping pyrite deposit in western Guangdong Province.Acta Geologica Sinica,67(3):232~242(in Chinese with English abstract).
Zhang Zhongjin,Fang Jingwen,Li Guoping,Shao Libo.2006.Geochemical characteristics and ore-prospecting vista of Dadongshan area,northern Guangdong Province.Geophysical&Geochemical Exploration,30(3):220~223(in Chinese with English abstract).
Zhao Haijie,Yu Changfa,Guan Bingting,Hu Yaoguo,Xu Mingjun.2012.Geochronology and petrogenesis of biotite granite from the Gaocheng Pb-Zn-Ag deposit,in western Guangdong Province,China.Acta Petrologica Sinica,28(12):3951~3966(in Chinese with English abstract).
Zheng Wenbao,Chen Yuchuan,Song Xin,Tang Juxing,Ying Lijuan,Li Fengji,Tang Xiaoqian.2010.Element distribution of Jiama copper-polymetallic deposit in Tibet and its geological significance.Mineral Deposits,29(5):775~784(in Chinese with English abstract).
Zhuang Wenming,Peng Zhuolun,Lin Xiaoming,Zhang Xianhe,Jiang Lianting.2011.Metallogenetic zonation and exploring direction of ore-deposits in the Changkeng-Chashan ore-field,Guangdong Province.Earth Science Frontiers,18(1):102~109(in Chinese with English abstract).
陈多福,马绍刚,董维权,陈先沛,陈光谦,高计元.1998.广东大降坪黄铁矿矿床的铅、铷同位素及金属成矿物质来源探讨.矿床地质,17(3):215~223.
陈先沛,陈多福.1992.华南震旦纪的沉积岩石学及元素地球化学.见:李继亮主编.中国东南海陆岩石圈结构与演化研究.北京:中国科学技术出版社,163~181.
杜欣,刘俊涛,王亚平.2004.西藏拉屋铜铅锌多金属矿床地质特征及成因分析.矿产与地质,18(5):410~414.
冯婷.2010.广东省云浮大降坪黄铁矿区铅锌银多金属矿体地质特征.华南地质与矿产,(1):26~29.
郭敏.2012.广东云浮大金山钨锡矿床地质特征及找矿潜力分析.华南地质与矿产,(04):376~382+391.
郭敏.2013.广东云浮大金山地区成矿元素分带规律.吉林地质,(01):113~119.
何俊国,周永章,张澄博,杨志军,石贵勇,付伟.2003.广东云浮金子窝锡多金属矿床控矿条件与矿化分布规律.矿产与地质,(05):598~601.
李金刚,陈植文,李自卫.2006.云浮高枨银多金属矿特征及成因.西部探矿工程,(09):124~126.
李贶,胡凯,蒋少涌,宋世明.2006.粤西大降坪黄铁矿矿床He-Ar同位素和稀土元素组成及成矿物质来源探讨.南京大学学报(自然科学版),(06):611~620.
罗大略.2004.广东大绀山地区铅锌银矿地质特征及成因探讨.华南地质与矿产,(02):9~14.
彭少梅,符力奋,周国强.1995.云开地块构造演化及片麻状花岗岩石的剪切深熔成因.武汉:中国地质大学出版社,80~159.
唐菊兴,黄勇,李志军,邓起,郎兴海,陈渊,张丽.2009.西藏谢通门县雄村铜金矿床元素地球化学特征.矿床地质,28(1):16.
陶琰,高振敏,马德云,李晓彪,普传杰,李红阳.2004.个旧锡矿阿西寨矿段化探异常分带及找矿意义.矿物学报,24(2):143~148.
王长明,邓军,张寿庭,叶会寿.2006.河南南泥湖Mo-W-Cu-Pb-ZnAg-Au成矿区内生成矿系统.地质科技情报,25(6):47~52.
王登红,陈毓川,李华芹,陈正宏,余金杰,路远发,李寄嵎.2003.湖南芙蓉锡矿的地质地球化学特征及找矿意义.地质通报,22(1):50.
王鹤年,李红艳,王银喜,王海红.1996.广东大降坪块状硫化物矿床形成时代-硅质岩Rb-Sr同位素研究.科学通报,21:1960~1962.
武国忠,陈郑辉,肖光铭.2012.广东云浮高枨银铅锌多金属矿区成矿地质特征及成岩时代研究.大地构造与成矿学,(03):434~439.
吴远明,曾钧跃.2014.南岭东段大金山钨锡多金属矿床大坳矿段垂向分带规律浅析.华南地质与矿产,30(2):118~123.
伍宗华,金仰芬.1993.元素分带及其在地质找矿中应用的几个问题.物探与化探,17(1):7~13.
余长发,赵海杰,陈懋弘,罗大略,郭敏,王志华.2012.粤西大金山花岗岩体地球化学特征及岩石成因探讨.中国地质,(06):1670~1689.
余长发,毛景文,赵海杰,陈懋弘,罗大略,郭敏.2012.粤西大金山钨锡多金属矿床地质特征及成岩成矿年代学研究.岩石学报,28(12):3967~3979.
于家明,张辉,陆学普,崔立新,赵坤.2007.区域化探异常元素分带与找矿远景分析.吉林地质,26(2):37~46.
张宝贵,张乾,潘家永,曹裕波.1994.粤西大降坪超大型黄铁矿床微量元素特征及其成因意义.地质与勘探,30(3):66~71.
张乾,张宝贵,曹裕波,潘家永,曾天育,郝淑芝.1993.粤西大降坪黄铁矿床硫、铅同位素组成初步研究.地质学报,67(3):232~242.
张忠进,方敬文,李国平,邵立波.2006.粤北大东山地区地球化学特征与找矿前景.物探与化探,30(3):220~223.
赵海杰,余长发,关炳庭,胡耀国,徐明君.2012.粤西高枨铅锌银矿区黑云母花岗岩的年代学及岩石成因.岩石学报,28(12):3951~3966.
郑文宝,陈毓川,宋鑫,唐菊兴,应立娟,黎枫佶,唐晓倩.2010.西藏甲玛铜多金属矿元素分布规律及地质意义.矿床地质,29(5):775~784.
庄文明,彭卓伦,林小明,张献河,姜莲婷.2011.广东长坑-茶山矿田成矿元素分带规律与找矿方向.地学前缘,18(1):102~109.
1广东省地质调查院.2013.广东省云浮市大金山地区钨锡多金属矿普查报告(内部资料).
2云浮市九曲岭锡矿.2008.广东省云浮市云安县九曲岭矿区锡矿资源储量核实报告(内部资料).
3安徽扬子矿业有限公司.2007.广东省云安县高枨矿区铅锌银矿详查报告(内部资料).
4中国有色金属工业总公司广东933队.1988.广东省云浮县莳田锡铅锌银矿区大塘肚-金子窝区段普查评价报告(内部资料).
5广东省地质矿产局723队.1965.广东云浮大降坪黄铁矿区勘探报告(内部资料).