北羌塘盆地长蛇山油页岩剖面烃源岩生烃潜力及沉积环境
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摘要
北羌塘盆地长蛇山油页岩位于目前中国最大规模的胜利河—长蛇山海相油页岩带北东,长蛇山南麓,其剖面主要岩性为油页岩、泥晶灰岩、黑色页岩和泥灰岩。本文通过对20件样品进行多项地球化学指标测试,详细评价了长蛇山油页岩剖面烃源岩的有机质丰度、类型及成熟度等指标,并分析了其沉积环境。结果表明:长蛇山油页岩的生烃潜力最好,其次为黑色页岩和泥晶灰岩。总有机碳含量在烃源岩中为0.41%~9.49%,平均为4.02%,在油页岩内含量最高,达到4.53%~9.49%,平均为7.74%;氯仿沥青"A"含量为0.0252%~0.3403%,在油页岩内平均为0.27%,总体为中等—较好烃源岩;有机元素和有机显微组分分析显示干酪根类型以Ⅱ1型为主,少数为Ⅱ2和Ⅲ型;Ro的分布范围为1.08%~1.43%,平均值为1.27%,有机质热演化程度为成熟—过成熟,且在垂向上有机质演化程度逐渐变高。该剖面的烃源岩沉积于盐度较高的还原环境,有机质母质主要以低等水生生物为主。
Located in North Qiangtang Basin in the northern part of the Shengli River-Changshe Mountain oil shale belt(currently the largest marine oil shale belt in China), the Changshe Mountain oil shale section mainly consists of oil shale, micrite limestone, black shale and marl. In order to determine the content of total organic matter, organic matter type, thermal maturity and sedimentary environment of the source rocks along the Changshe Mountain oil shale section, the authors collected twenty samples for multiple organic geochemistry tests. The results show that the oil shale has the best hydrocarbon generation potential, followed by the black shale and micrite limestone. The total organic carbon(TOC) content varies from 0.41% to 9.49%, with an average of 4.02%, and the oil shale samples have the highest values(ranging from 4.53% to 9.49%), with an average of 7.74%. Chloroform bitumen "A" varies from 0.0252% to 0.3403%, and the average value of the oil shale sample is 0.27%, indicating moderate to good source rocks. The kerogen types assessed from organic element composition and organic petrography data show that there is mainly typeⅡ 1 kerogen, with small amounts of type Ⅱ 2 and Ⅲ kerogen. The distribution of Ro ranges from 1.08% to 1.43%, with an average of 1.27%, demonstrating a mature to overmature stage of the organic matter, with the Ro gradually becoming higher along the oil shale section. The source rocks along the Changshe Mountain oil shale section were deposited in a reductive and high-saline water environment, and the organic source material was mainly low-grade hydrobios.
Located in North Qiangtang Basin in the northern part of the Shengli River-Changshe Mountain oil shale belt(currently the largest marine oil shale belt in China), the Changshe Mountain oil shale section mainly consists of oil shale, micrite limestone, black shale and marl. In order to determine the content of total organic matter, organic matter type, thermal maturity and sedimentary environment of the source rocks along the Changshe Mountain oil shale section, the authors collected twenty samples for multiple organic geochemistry tests. The results show that the oil shale has the best hydrocarbon generation potential, followed by the black shale and micrite limestone. The total organic carbon(TOC) content varies from 0.41% to 9.49%, with an average of 4.02%, and the oil shale samples have the highest values(ranging from 4.53% to 9.49%), with an average of 7.74%. Chloroform bitumen "A" varies from 0.0252% to 0.3403%, and the average value of the oil shale sample is 0.27%, indicating moderate to good source rocks. The kerogen types assessed from organic element composition and organic petrography data show that there is mainly typeⅡ 1 kerogen, with small amounts of type Ⅱ 2 and Ⅲ kerogen. The distribution of Ro ranges from 1.08% to 1.43%, with an average of 1.27%, demonstrating a mature to overmature stage of the organic matter, with the Ro gradually becoming higher along the oil shale section. The source rocks along the Changshe Mountain oil shale section were deposited in a reductive and high-saline water environment, and the organic source material was mainly low-grade hydrobios.
引文
[1]李景明,王红岩,赵群.中国新能源资源潜力及前景展望[J].天然气工业,2008,28(1):149-153.Li Jingming,Wang Hongyan,Zhao Qun.Potential and prospects on new energy sources in China[J].Natural Gas Industry,2008,28(1):149-153(in Chinese with English abstract).
[2]汤桦,白云来,吴武军.中国西北新能源——油页岩典型特征及开发利用中的几个问题[J].中国地质,2011,38(3):731-741.Tang Hua,Bai Yunlai,Wu Wujun.Typical geological characteristics of the new energy resource of oil shale and some problems concerning its development and utilization[J].Geology in China,2011,38(3):731-741(in Chinese with English abstract).
[3]白云来,马龙,吴武军,等.鄂尔多斯盆地油页岩的主要地质特征及资源潜力[J].中国地质,2009,36(5):1123-1137.Bai Yunlai,Ma Long,Wu Wujun,et al.Geological characteristics and resource potential of oil shale in Ordos basin[J].Geology in China,2009,36(5):1123-1137(in Chinese with English abstract).
[4]刘招君,孟庆涛,柳蓉.中国陆相油页岩特征及成因类型[J].古地理学报,2009,11(1):105-114.Liu Zhaojun,Meng Qingtao,Liu Rong.Characteristics and genetic types of continental oil shales in China[J].Journal of Palaeogeography,2009,11(1):105-114(in Chinese with English abstract).
[5]杜江峰,刘招君,张健,等.吉林松江盆地大拉子组上段油页岩特征及成矿机制[J].中国地质,2008,35(1):79-87.Du Jiangfeng,Liu Zhaojun,Zhang Jian,et al.Characteristics and formation mechanism of oil shale in the upper member of the Dalazi Formation in the Songjiang basin,Jilin[J].Geology in China,2008,35(1):79-87(in Chinese with English abstract).
[6]张海龙,刘招君,史冀忠,等.罗子沟盆地下白垩统大砬子组油页岩成矿规律分析[J].中国地质,2007,34(1):86-91.Zhang Hailong,Liu Zhaojun,Shi Jizhong,et al.Formation characteristics of oil shale in the Lower Cretaceous Dalazi Formation in the Luozigou basin[J].Geology in China,2007,34(1):86-91(in Chinese with English abstract).
[7]汪正江,王剑,陈文西,等.青藏高原北羌塘盆地胜利河上侏罗统海相油页岩的发现[J].地质通报,2007,26(6):764-768.Wang Zhengjiang,Wang Jian,Chen Wenxi,et al.Discovery of the Late Jurassic Shenglihe marine oil shale in the northern Qiangtang basin,Qinghai-Tibet Plateau[J].Geological Bulletin of China,2007,26(6):764-768(in Chinese with English abstract).
[8]王剑,付修根,李忠雄,等.藏北羌塘盆地胜利河—长蛇山油页岩带的发现及其意义[J].地质通报,2009,28(6):691-695.Wangjian,Fu Xiugen,Li Zhongxiong,et al.Discovery of the Shenglihe-Changsheshan oil shale belt in the Qiangtang basin,northern Tibet,China and its significance.Geological Bulletin of China,2009,28(6):691-695(in Chinese with English abstract).
[9]王剑,付修根,杜安道,等.羌塘盆地胜利河海相油页岩地球化学特征及Re-Os定年[J].海相油气地质,2007,12(3):21-26.Wangjian,Fu Xiugen,Du Andao,et al.Organic geochemistry and Re-Os dating of marine oil shale in Shenglihe area,northern Tibet,China[J].Marine Origin Petroleum Geology,2007,12(3):21-26(in Chinese with English abstract).
[10]Fu X G,Wang J,Qu W J,et al.Re-Os(ICP-MS)dating of marine oil shale in the Qiangtang basin,northern Tibet plateau,China[J].Oil Shale,2008,25(1):47-55.
[11]曾胜强,王剑,陈明,等.北羌塘盆地索瓦组上段的时代、古气候及石油地质特征[J].现代地质,2012,26(1):10-21.Zeng Shengqiang,Wang Jian,Chen Ming,et al.Geological age,paleoclimate and petroleum geological characteristics of the Upper part of the Suowa Formation in the North Qiangtang basin[J].Geoscience,2012,26(1):10-21(in Chinese with English abstract).
[12]付修根,王剑,汪正江,等.藏北羌塘盆地晚侏罗世海相油页岩生物标志物特征、沉积环境分析及意义[J].地球化学,2007,36(5):486-496.Fu Xiugen,Wang Jian,Wang Zhengjiang,et al.Biomarkers and sedimentary environment of Late Jurassic marine oil shale in Qiangtang basin,northern Xizang and its geological significance[J].Geochimica,2007,36(5):486-496(in Chinese with English abstract).
[13]Fu X G,Wang J,Tan F W,et al.Geochemical and palynological investigation of the Shengli River marine oil shale(China):Implications for paleoenvironment and paleoclimate[J].International Journal of Coal Geology,2009,78(3):217-224.
[14]李忠雄,何江林,熊兴国,等.藏北羌塘盆地上侏罗—下白垩统胜利河油页岩特征及其形成环境[J].吉林大学学报(地球科学版),2010,40(2):264-272.Li Zhongxiong,He Jianglin,Xiong Xingguo,et al.The Upper Jurassic-Lower Cretaceous Shenglihe oil shales and their formation in the Qiangtang Basin,Northern Xizang[J].Journal of Jilin University(Earth Science Edition),2010,40(2):264-272(in Chinese with English abstract).
[15]Fu X G,Wang J,Tan F W,et al.Sedimentological investigations of the Shengli River-Changshe Mountain oil shale(China):Relationships with oil shale Formation[J].Oil Shale,2009,26(3):373-381.
[16]付修根,王剑,汪正江,等.藏北羌塘盆地海相油页岩沉积环境[J].新疆石油地质,2007,28(5):529-533.Fu Xiugen,Wang Jian,Wang Zhengjiang,et al.Marine oil shale depositional environment of Qiangtang basin in northern Tibet[J].Xinjiang Petroleum Geology,2007,28(5):529-533(in Chinese with English abstract).
[17]Fu X G,Wang J,Zeng Y H,et al.Geochemistry and origin of rare earth elements(REEs)in the Shengli River oil shale,northern Tibet,China[J].Chemie der Erde,2011,71(1):21-30.
[18]Fu X G,Wang J,Zeng Y H,et al.Concentrations and modes of occurrence of platinum group elements in the Shengli River oil shale,northern Tibet,China[J].Fuel,2010,89(12):3623-3629.
[19]Fu X G,Wang J,Zeng Y H,et al.REE geochemistry of marine oil shale from the Changshe Mountain area,northern Tibet,China[J].International Journal of Coal Geology,2010,81(3):191-199.
[20]Fu X G,Wang J,Zeng Y H,et al.Geochemistry of platinum group elements in marine oil shale from the Changshe Mountain area(China):Implications for modes of occurrence and origins[J].International Journal of Coal Geology,2011,86(2-3):169-176.
[21]鲁兵,李永铁,刘忠.青藏高原的盆地形成与分类[J].石油学报,2000,21(2):21-26.Lu Bing,Li Yongtie,Liu Zhong.Formation and classification of the basins in the Qinghai-Tibet Plateau[J].Acta Petrolei Sinica,2000,21(2):21-26(in Chinese with English abstract).
[22]Kapp P,Yin A,Manning C E,et al.Blueschist-bearing metamorphic core complexes in the Qiangtang block reveal deep crustal structure of northern Tibet[J].Geology,2000,28(1):19-22.
[23]赵文津,赵逊,蒋忠惕,等.西藏羌塘盆地的深部构造特征与含油气远景评价[J].中国地质,2006,33(1):1-13.Zhao Wenjin,Zhao Xun,Jiang Zhongti,et al.Deep structure and petroleum prospect evaluation of the Qiangtang basin,Tibet[J].Geology in China,2006,33(1):1-13(in Chinese with English abstract).
[24]陈文彬,伊海生,谭富文,等.南羌塘侏罗系烃源岩氯仿沥青“A”组分碳同位素特征[J].中国地质,2010,37(6):1740-1746.Chen Wenbin,Yi Haisheng,Tan Fuwen,et al.Carbon isotope characteristics of the components of chloroform bitumen“A”of Jurassic hydrocarbon source rocks in south Qiangtang basin[J].Geology in China,2010,37(6):1740-1746(in Chinese with English abstract).
[25]谭富文,王剑,李永铁,等.羌塘盆地侏罗纪末—早白垩世沉积特征与地层问题[J].中国地质,2004,31(4):400-405.Tan Fuwen,Wang Jian,Li Yongtie,et al.Late Jurassic-Early Cretaceous strata and their sedimentary characteristics in the Qiangtang basin,northern Tibet[J].Geology in China,2004,31(4):400-405(in Chinese with English abstract).
[26]陈文彬,廖忠礼,付修根,等.北羌塘盆地布曲组烃源岩生物标志物特征及意义[J].沉积学报,2007,25(5):808-814.Chen Wenbin,Liao Zhongli,Fu Xiugen,et al.Biomarker characteristics and significance of hydrocarbon source rocks in Buqu Formation of the north Qiangtang basin[J].Acta Sedmentologica Sinica,2007,25(5):808-814(in Chinese with English abstract).
[27]李忠雄,杜佰伟,汪正江,等.藏北羌塘盆地中侏罗统石油地质特征[J].石油学报,2008,29(6):797-803.Li Zhongxiong,Du Baiwei,Wang Zhengjiang,et al.Petroleum geologic characteristics of the Middle Jurassic strata in Qiangtang basin of northern Xizang area[J].Acta Petrolei Sinica,2008,29(6):797-803(in Chinese with English abstract).
[28]赵政璋,李永铁,叶和飞,等.青藏高原羌塘盆地石油地质[M].北京:科学出版社,2001.Zhao Zhengzhang,Li Yongtie,Ye Hefei,et al.Petroleum Geology of Qiangtang Basin in Qinghai-Xizang Plateau[M].Beijing:Science Press,2001(in Chinese).
[29]傅家谟,秦匡宗.干酪根地球化学[M].广州:广东科技出版社,1995:443-468.Fu Jiamo,Qin Kuangzong.Kerogen Geochemistry[M].Guangzhou:Guangdong Science and Technology Press,1995,443-468(in Chinese).
[30]Tissot B T,Durand B,Espitalie J,et al.Influence of nature and diagenesis of organic matter on formation of petroleum[J].AAPG Bulletin,1974,58(3):499-506.
[31]梅博文,刘希江.我国原油中异戊间二烯烃的分布及其地质环境的关系[J].石油与天然气地质,1980,1(2):99-115.Mei Bowen,Liu Xijiang.The distribution of isoprenoid alkanes in China’s crude oil and its relation with the geologic environment[J].Oil&Gas Geology,1980,1(2):99-115(in Chinese with English abstract).
[32]王铁冠.生物标志物地球化学研究[M].武汉:中国地质大学出版社,1990.Wang Tieguan.Research on Geochemistry of Biomakers[M].Wuhan:China University of Geoscicences Press,1990(in Chinese).
[33]伊海生,林金辉,赵西西,等.西藏高原沱沱河盆地渐新世—中新世湖相碳酸盐岩稀土元素地球化学特征与正铕异常成因初探[J].沉积学报,2008,26(1):1-10.Yi Haisheng,Lin Jinhui,Zhao Xixi,et al.Geochemistry of rare earth elements and origin of positive Europium anomaly in Miocene to Oligocene lacustrine carbonates from Tuotuohe basin of Tibetan Plateau[J].Acta Sedmentologica Sinica,2008,26(1):1-10(in Chinese with English abstract).
[34]Powell T,Mckirdy D M.Relationship between ratio of pristance to phytane,crude oil composition and geological environments in Australia[J].Nature,1973,243(12):37-39.
[35]卢双舫,张敏.油气地球化学[M].北京:石油工业出版社,2008,65-77.Lu Shuangfang,Zhang Min.Geochemistry of Oil and Gas[M].Beijing:Petroleum Industry Press,2008,65-77(in Chinese).
[36]Moldowan J M,Carlson R M K,et al.Rearranged hopanes in sediments and petroleum[J].Geochimica et Cosmochimica Acta,1991,55:3333-3353.
[37]Peters K E,Moldowan J M.The Biomarker Guide:Interpreting Molecular Fossils in Petroleum and Ancient Sediments[M].Prentice Hall Inc.,1993:1-347.
[38]Shanmugam,G.Significance of coniferous rain forests and related organic matter in generating commercial quantities of oil,Gippsland Basin,Australia[J].American Association of Petroleum Geologists Bulletin,1985,69(8):1241-1254.
[39]付修根,王剑,汪正江,等.藏北羌塘盆地胜利河油页岩干酪根特征及碳同位素指示意义[J].地球学报,2009,30(5):643-650.Fu Xiugen,Wang Jian,Wang Zhengjiang,et al.Characteristics of kerogens and their carbon isotope implications for the Shengli River oil shale in Qiangtang Basin,Northern Tibet.Acta Geoscientica Sinica,2009,30(5):643-650(in Chinese with English abstract).
[40]王剑,付修根,李忠雄,等.北羌塘盆地油页岩形成环境及其油气地质意义[J].沉积与特提斯地质,2010,30(3):11-17.Wang Jian,Fu Xiugen,Li Zhongxiong,et al.Formation and significance of the oil shales from the North Qiangtang basin[J].Sedimentary Geology and Tethyan Geology,2010,30(3):11-17(in Chinese with English abstract).
[2]汤桦,白云来,吴武军.中国西北新能源——油页岩典型特征及开发利用中的几个问题[J].中国地质,2011,38(3):731-741.Tang Hua,Bai Yunlai,Wu Wujun.Typical geological characteristics of the new energy resource of oil shale and some problems concerning its development and utilization[J].Geology in China,2011,38(3):731-741(in Chinese with English abstract).
[3]白云来,马龙,吴武军,等.鄂尔多斯盆地油页岩的主要地质特征及资源潜力[J].中国地质,2009,36(5):1123-1137.Bai Yunlai,Ma Long,Wu Wujun,et al.Geological characteristics and resource potential of oil shale in Ordos basin[J].Geology in China,2009,36(5):1123-1137(in Chinese with English abstract).
[4]刘招君,孟庆涛,柳蓉.中国陆相油页岩特征及成因类型[J].古地理学报,2009,11(1):105-114.Liu Zhaojun,Meng Qingtao,Liu Rong.Characteristics and genetic types of continental oil shales in China[J].Journal of Palaeogeography,2009,11(1):105-114(in Chinese with English abstract).
[5]杜江峰,刘招君,张健,等.吉林松江盆地大拉子组上段油页岩特征及成矿机制[J].中国地质,2008,35(1):79-87.Du Jiangfeng,Liu Zhaojun,Zhang Jian,et al.Characteristics and formation mechanism of oil shale in the upper member of the Dalazi Formation in the Songjiang basin,Jilin[J].Geology in China,2008,35(1):79-87(in Chinese with English abstract).
[6]张海龙,刘招君,史冀忠,等.罗子沟盆地下白垩统大砬子组油页岩成矿规律分析[J].中国地质,2007,34(1):86-91.Zhang Hailong,Liu Zhaojun,Shi Jizhong,et al.Formation characteristics of oil shale in the Lower Cretaceous Dalazi Formation in the Luozigou basin[J].Geology in China,2007,34(1):86-91(in Chinese with English abstract).
[7]汪正江,王剑,陈文西,等.青藏高原北羌塘盆地胜利河上侏罗统海相油页岩的发现[J].地质通报,2007,26(6):764-768.Wang Zhengjiang,Wang Jian,Chen Wenxi,et al.Discovery of the Late Jurassic Shenglihe marine oil shale in the northern Qiangtang basin,Qinghai-Tibet Plateau[J].Geological Bulletin of China,2007,26(6):764-768(in Chinese with English abstract).
[8]王剑,付修根,李忠雄,等.藏北羌塘盆地胜利河—长蛇山油页岩带的发现及其意义[J].地质通报,2009,28(6):691-695.Wangjian,Fu Xiugen,Li Zhongxiong,et al.Discovery of the Shenglihe-Changsheshan oil shale belt in the Qiangtang basin,northern Tibet,China and its significance.Geological Bulletin of China,2009,28(6):691-695(in Chinese with English abstract).
[9]王剑,付修根,杜安道,等.羌塘盆地胜利河海相油页岩地球化学特征及Re-Os定年[J].海相油气地质,2007,12(3):21-26.Wangjian,Fu Xiugen,Du Andao,et al.Organic geochemistry and Re-Os dating of marine oil shale in Shenglihe area,northern Tibet,China[J].Marine Origin Petroleum Geology,2007,12(3):21-26(in Chinese with English abstract).
[10]Fu X G,Wang J,Qu W J,et al.Re-Os(ICP-MS)dating of marine oil shale in the Qiangtang basin,northern Tibet plateau,China[J].Oil Shale,2008,25(1):47-55.
[11]曾胜强,王剑,陈明,等.北羌塘盆地索瓦组上段的时代、古气候及石油地质特征[J].现代地质,2012,26(1):10-21.Zeng Shengqiang,Wang Jian,Chen Ming,et al.Geological age,paleoclimate and petroleum geological characteristics of the Upper part of the Suowa Formation in the North Qiangtang basin[J].Geoscience,2012,26(1):10-21(in Chinese with English abstract).
[12]付修根,王剑,汪正江,等.藏北羌塘盆地晚侏罗世海相油页岩生物标志物特征、沉积环境分析及意义[J].地球化学,2007,36(5):486-496.Fu Xiugen,Wang Jian,Wang Zhengjiang,et al.Biomarkers and sedimentary environment of Late Jurassic marine oil shale in Qiangtang basin,northern Xizang and its geological significance[J].Geochimica,2007,36(5):486-496(in Chinese with English abstract).
[13]Fu X G,Wang J,Tan F W,et al.Geochemical and palynological investigation of the Shengli River marine oil shale(China):Implications for paleoenvironment and paleoclimate[J].International Journal of Coal Geology,2009,78(3):217-224.
[14]李忠雄,何江林,熊兴国,等.藏北羌塘盆地上侏罗—下白垩统胜利河油页岩特征及其形成环境[J].吉林大学学报(地球科学版),2010,40(2):264-272.Li Zhongxiong,He Jianglin,Xiong Xingguo,et al.The Upper Jurassic-Lower Cretaceous Shenglihe oil shales and their formation in the Qiangtang Basin,Northern Xizang[J].Journal of Jilin University(Earth Science Edition),2010,40(2):264-272(in Chinese with English abstract).
[15]Fu X G,Wang J,Tan F W,et al.Sedimentological investigations of the Shengli River-Changshe Mountain oil shale(China):Relationships with oil shale Formation[J].Oil Shale,2009,26(3):373-381.
[16]付修根,王剑,汪正江,等.藏北羌塘盆地海相油页岩沉积环境[J].新疆石油地质,2007,28(5):529-533.Fu Xiugen,Wang Jian,Wang Zhengjiang,et al.Marine oil shale depositional environment of Qiangtang basin in northern Tibet[J].Xinjiang Petroleum Geology,2007,28(5):529-533(in Chinese with English abstract).
[17]Fu X G,Wang J,Zeng Y H,et al.Geochemistry and origin of rare earth elements(REEs)in the Shengli River oil shale,northern Tibet,China[J].Chemie der Erde,2011,71(1):21-30.
[18]Fu X G,Wang J,Zeng Y H,et al.Concentrations and modes of occurrence of platinum group elements in the Shengli River oil shale,northern Tibet,China[J].Fuel,2010,89(12):3623-3629.
[19]Fu X G,Wang J,Zeng Y H,et al.REE geochemistry of marine oil shale from the Changshe Mountain area,northern Tibet,China[J].International Journal of Coal Geology,2010,81(3):191-199.
[20]Fu X G,Wang J,Zeng Y H,et al.Geochemistry of platinum group elements in marine oil shale from the Changshe Mountain area(China):Implications for modes of occurrence and origins[J].International Journal of Coal Geology,2011,86(2-3):169-176.
[21]鲁兵,李永铁,刘忠.青藏高原的盆地形成与分类[J].石油学报,2000,21(2):21-26.Lu Bing,Li Yongtie,Liu Zhong.Formation and classification of the basins in the Qinghai-Tibet Plateau[J].Acta Petrolei Sinica,2000,21(2):21-26(in Chinese with English abstract).
[22]Kapp P,Yin A,Manning C E,et al.Blueschist-bearing metamorphic core complexes in the Qiangtang block reveal deep crustal structure of northern Tibet[J].Geology,2000,28(1):19-22.
[23]赵文津,赵逊,蒋忠惕,等.西藏羌塘盆地的深部构造特征与含油气远景评价[J].中国地质,2006,33(1):1-13.Zhao Wenjin,Zhao Xun,Jiang Zhongti,et al.Deep structure and petroleum prospect evaluation of the Qiangtang basin,Tibet[J].Geology in China,2006,33(1):1-13(in Chinese with English abstract).
[24]陈文彬,伊海生,谭富文,等.南羌塘侏罗系烃源岩氯仿沥青“A”组分碳同位素特征[J].中国地质,2010,37(6):1740-1746.Chen Wenbin,Yi Haisheng,Tan Fuwen,et al.Carbon isotope characteristics of the components of chloroform bitumen“A”of Jurassic hydrocarbon source rocks in south Qiangtang basin[J].Geology in China,2010,37(6):1740-1746(in Chinese with English abstract).
[25]谭富文,王剑,李永铁,等.羌塘盆地侏罗纪末—早白垩世沉积特征与地层问题[J].中国地质,2004,31(4):400-405.Tan Fuwen,Wang Jian,Li Yongtie,et al.Late Jurassic-Early Cretaceous strata and their sedimentary characteristics in the Qiangtang basin,northern Tibet[J].Geology in China,2004,31(4):400-405(in Chinese with English abstract).
[26]陈文彬,廖忠礼,付修根,等.北羌塘盆地布曲组烃源岩生物标志物特征及意义[J].沉积学报,2007,25(5):808-814.Chen Wenbin,Liao Zhongli,Fu Xiugen,et al.Biomarker characteristics and significance of hydrocarbon source rocks in Buqu Formation of the north Qiangtang basin[J].Acta Sedmentologica Sinica,2007,25(5):808-814(in Chinese with English abstract).
[27]李忠雄,杜佰伟,汪正江,等.藏北羌塘盆地中侏罗统石油地质特征[J].石油学报,2008,29(6):797-803.Li Zhongxiong,Du Baiwei,Wang Zhengjiang,et al.Petroleum geologic characteristics of the Middle Jurassic strata in Qiangtang basin of northern Xizang area[J].Acta Petrolei Sinica,2008,29(6):797-803(in Chinese with English abstract).
[28]赵政璋,李永铁,叶和飞,等.青藏高原羌塘盆地石油地质[M].北京:科学出版社,2001.Zhao Zhengzhang,Li Yongtie,Ye Hefei,et al.Petroleum Geology of Qiangtang Basin in Qinghai-Xizang Plateau[M].Beijing:Science Press,2001(in Chinese).
[29]傅家谟,秦匡宗.干酪根地球化学[M].广州:广东科技出版社,1995:443-468.Fu Jiamo,Qin Kuangzong.Kerogen Geochemistry[M].Guangzhou:Guangdong Science and Technology Press,1995,443-468(in Chinese).
[30]Tissot B T,Durand B,Espitalie J,et al.Influence of nature and diagenesis of organic matter on formation of petroleum[J].AAPG Bulletin,1974,58(3):499-506.
[31]梅博文,刘希江.我国原油中异戊间二烯烃的分布及其地质环境的关系[J].石油与天然气地质,1980,1(2):99-115.Mei Bowen,Liu Xijiang.The distribution of isoprenoid alkanes in China’s crude oil and its relation with the geologic environment[J].Oil&Gas Geology,1980,1(2):99-115(in Chinese with English abstract).
[32]王铁冠.生物标志物地球化学研究[M].武汉:中国地质大学出版社,1990.Wang Tieguan.Research on Geochemistry of Biomakers[M].Wuhan:China University of Geoscicences Press,1990(in Chinese).
[33]伊海生,林金辉,赵西西,等.西藏高原沱沱河盆地渐新世—中新世湖相碳酸盐岩稀土元素地球化学特征与正铕异常成因初探[J].沉积学报,2008,26(1):1-10.Yi Haisheng,Lin Jinhui,Zhao Xixi,et al.Geochemistry of rare earth elements and origin of positive Europium anomaly in Miocene to Oligocene lacustrine carbonates from Tuotuohe basin of Tibetan Plateau[J].Acta Sedmentologica Sinica,2008,26(1):1-10(in Chinese with English abstract).
[34]Powell T,Mckirdy D M.Relationship between ratio of pristance to phytane,crude oil composition and geological environments in Australia[J].Nature,1973,243(12):37-39.
[35]卢双舫,张敏.油气地球化学[M].北京:石油工业出版社,2008,65-77.Lu Shuangfang,Zhang Min.Geochemistry of Oil and Gas[M].Beijing:Petroleum Industry Press,2008,65-77(in Chinese).
[36]Moldowan J M,Carlson R M K,et al.Rearranged hopanes in sediments and petroleum[J].Geochimica et Cosmochimica Acta,1991,55:3333-3353.
[37]Peters K E,Moldowan J M.The Biomarker Guide:Interpreting Molecular Fossils in Petroleum and Ancient Sediments[M].Prentice Hall Inc.,1993:1-347.
[38]Shanmugam,G.Significance of coniferous rain forests and related organic matter in generating commercial quantities of oil,Gippsland Basin,Australia[J].American Association of Petroleum Geologists Bulletin,1985,69(8):1241-1254.
[39]付修根,王剑,汪正江,等.藏北羌塘盆地胜利河油页岩干酪根特征及碳同位素指示意义[J].地球学报,2009,30(5):643-650.Fu Xiugen,Wang Jian,Wang Zhengjiang,et al.Characteristics of kerogens and their carbon isotope implications for the Shengli River oil shale in Qiangtang Basin,Northern Tibet.Acta Geoscientica Sinica,2009,30(5):643-650(in Chinese with English abstract).
[40]王剑,付修根,李忠雄,等.北羌塘盆地油页岩形成环境及其油气地质意义[J].沉积与特提斯地质,2010,30(3):11-17.Wang Jian,Fu Xiugen,Li Zhongxiong,et al.Formation and significance of the oil shales from the North Qiangtang basin[J].Sedimentary Geology and Tethyan Geology,2010,30(3):11-17(in Chinese with English abstract).