超结构聚苯乙烯膜在织物上的呈色性能
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摘要
对纺织品采用结构色显色,可降低传统印染工艺对环境造成的污染.以无皂乳液聚合法制备了尺寸为340±10 nm的单分散聚苯乙烯微球,通过垂直沉积自组装法在织物上制备出超结构聚苯乙烯膜,以及改变织物的基底颜色和基底致密度来研究超结构聚苯乙烯膜的自组装和呈色效果.结果表明:当乳液浓度为1 wt%,干燥温度40℃,可以在织物表面自主装出具有明显蓝色的超结构聚苯乙烯膜.在致密度较高的织物基底中,纤维之间的孔隙较小,自组装产生的超结构形貌良好,呈现较明亮的蓝色;白色织物作为基底时,会反射其它波长的入射光,超结构聚苯乙烯膜的呈色效果较弱;黑色织物基底可以吸收其它波长的杂散光,超结构聚苯乙烯膜在其表面呈现明显的蓝色.
Structural coloration of textiles could reduce environmental pollution caused by traditional printing and dyeing technology.Monodisperse polystyrene microspheres with the size of 340±10 nm were prepared by soap-free emulsion polymerization.Superstructure polystyrene films were prepared on fabrics by vertical deposition self-assembly method,and the self-assembly and color rendering effect of the superstructure polystyrene films were studied by changing the color and the density of the substrate.The results showed that the superstructure polystyrene film with obvious blue color could be installed on the fabric surface independently when the emulsion concentration was 1 wt% and the drying temperature was 40 ℃.On the fabric substrate with high density,because of the small pore between the fibers,the morphology of the superstructure film produced by self-assembly was good and the film showed bright blue.When the white fabric was used as substrate,the incident light of other wavelengths would be reflected,and the color effect of the superstructure polystyrene film was weaker.The black fabric substrate could absorb stray light of other wavelengths and blue color was observed on the surface of the superstructure polystyrene film.
Structural coloration of textiles could reduce environmental pollution caused by traditional printing and dyeing technology.Monodisperse polystyrene microspheres with the size of 340±10 nm were prepared by soap-free emulsion polymerization.Superstructure polystyrene films were prepared on fabrics by vertical deposition self-assembly method,and the self-assembly and color rendering effect of the superstructure polystyrene films were studied by changing the color and the density of the substrate.The results showed that the superstructure polystyrene film with obvious blue color could be installed on the fabric surface independently when the emulsion concentration was 1 wt% and the drying temperature was 40 ℃.On the fabric substrate with high density,because of the small pore between the fibers,the morphology of the superstructure film produced by self-assembly was good and the film showed bright blue.When the white fabric was used as substrate,the incident light of other wavelengths would be reflected,and the color effect of the superstructure polystyrene film was weaker.The black fabric substrate could absorb stray light of other wavelengths and blue color was observed on the surface of the superstructure polystyrene film.
引文
[1] 孙冬阳,徐秋燕,李强,等.丝绸织物棉用活性染料染色工艺探讨[J].武汉纺织大学学报,2016,29(3):25-31.
[2] 刘杰,杜长森,张丽平,等.阳离子化棉织物的纳米乳胶荧光颜料染色[J].纺织学报,2016,37(10):56-61.
[3] Wu H T,Huang K Y,Lee K T.Supercritical fluidassisted dispersion of CI pigment violet 23 in an organic medium[J].Powder Technology,2011,206(3):322-326.
[4] 龚 ,卢永凯,王红凤,等.孔雀羽毛的纳米结构生色机理及其仿生结构器件的应用初探[J].北京大学学报(自然科学版),2010,46(5):859-862.
[5] 张珂.蝶翅鳞片极化敏感结构色效应结构起源及光学机理探究[D].上海:上海交通大学,2015.
[6] Azofeifa D E,Hernández Jiménez M,Libby E,et al.A quantitative assessment approach of feasible optical mechanisms contributing to structural color of golden-like Chrysina aurigans,scarab beetles[J].Journal of Quantitative Spectroscopy & Radiative Transfer,2015,160(4):63-74.
[7] 刘志福.基于光子晶体的结构色纤维制备及其显色性能研究[D].上海:东华大学,2013.
[8] Zhang X,Wang F,Wang L,et al.Designing composite films of SiO2/TiO2/PDMS with long lasting invariable colors and enhanced mechanical robustness[J].Dyes and Pigments,2017,138(10):182-189.
[9] Ahu G D,Thierry S.Recent advances in the biomimicry of structural colours[J].Chemical Society Reviews,2016,45(24):6 698-6 724.
[10] 张骜,袁伟.结构生色及其染整应用(三)[J].印染,2012,38(15):44-46.
[11] Ge J P,Yin Y D.Responsive photonic crystals[J].Angewandte Chemie International Edition,2011,50(7):1 492-1 498.
[12] Josephson D P,Miller M,Stein A.Inverse opal SiO2 photonic crystals as structurally-colored pigments with additive primary colors[J].Zeitschrift Fur Anorganische und Allgemeine Chemie,2014,640(3-4):655-662.
[13] Lai C F,Wang Y C,Wu C L,et al.Preparation of colloidal photonic crystal containing CuO nanoparticles with tunable structural colors[J].Royal Society of Chemistry,2015,5(127):1 051-1 057.
[14] Li S,Zheng J,Zhao Y,et al.Preparation of a three-dimensional ordered macroporous titanium dioxide material with polystyrene colloid crystal as a template[J].Journal of Applied Polymer Science,2010,107(6):3 903-3 908.
[15] 周之燕,王秀峰,师杰,等.自组装法制备聚苯乙烯光子晶体的研究进展[J].材料导报,2010,24(21):113-117.
[16] 李晓菁,乔冠军,陈杰瑢,等.TiO2光子晶体的光子带隙及其应用[J].化学进展,2008,20(4):491-498.
[17] 李义臣,刘国金,邵建中,等.二氧化硅/聚甲基丙烯酸甲酯光子晶体在涤纶织物上的结构生色[J].纺织学报,2016,37(10):62-67.
[18] 王莉丽,王秀峰,刘派,等.蓝色聚苯乙烯胶体晶体膜的制备及其呈色机理研究[J].人工晶体学报,2016,45(6):1 482-1 486.
[2] 刘杰,杜长森,张丽平,等.阳离子化棉织物的纳米乳胶荧光颜料染色[J].纺织学报,2016,37(10):56-61.
[3] Wu H T,Huang K Y,Lee K T.Supercritical fluidassisted dispersion of CI pigment violet 23 in an organic medium[J].Powder Technology,2011,206(3):322-326.
[4] 龚 ,卢永凯,王红凤,等.孔雀羽毛的纳米结构生色机理及其仿生结构器件的应用初探[J].北京大学学报(自然科学版),2010,46(5):859-862.
[5] 张珂.蝶翅鳞片极化敏感结构色效应结构起源及光学机理探究[D].上海:上海交通大学,2015.
[6] Azofeifa D E,Hernández Jiménez M,Libby E,et al.A quantitative assessment approach of feasible optical mechanisms contributing to structural color of golden-like Chrysina aurigans,scarab beetles[J].Journal of Quantitative Spectroscopy & Radiative Transfer,2015,160(4):63-74.
[7] 刘志福.基于光子晶体的结构色纤维制备及其显色性能研究[D].上海:东华大学,2013.
[8] Zhang X,Wang F,Wang L,et al.Designing composite films of SiO2/TiO2/PDMS with long lasting invariable colors and enhanced mechanical robustness[J].Dyes and Pigments,2017,138(10):182-189.
[9] Ahu G D,Thierry S.Recent advances in the biomimicry of structural colours[J].Chemical Society Reviews,2016,45(24):6 698-6 724.
[10] 张骜,袁伟.结构生色及其染整应用(三)[J].印染,2012,38(15):44-46.
[11] Ge J P,Yin Y D.Responsive photonic crystals[J].Angewandte Chemie International Edition,2011,50(7):1 492-1 498.
[12] Josephson D P,Miller M,Stein A.Inverse opal SiO2 photonic crystals as structurally-colored pigments with additive primary colors[J].Zeitschrift Fur Anorganische und Allgemeine Chemie,2014,640(3-4):655-662.
[13] Lai C F,Wang Y C,Wu C L,et al.Preparation of colloidal photonic crystal containing CuO nanoparticles with tunable structural colors[J].Royal Society of Chemistry,2015,5(127):1 051-1 057.
[14] Li S,Zheng J,Zhao Y,et al.Preparation of a three-dimensional ordered macroporous titanium dioxide material with polystyrene colloid crystal as a template[J].Journal of Applied Polymer Science,2010,107(6):3 903-3 908.
[15] 周之燕,王秀峰,师杰,等.自组装法制备聚苯乙烯光子晶体的研究进展[J].材料导报,2010,24(21):113-117.
[16] 李晓菁,乔冠军,陈杰瑢,等.TiO2光子晶体的光子带隙及其应用[J].化学进展,2008,20(4):491-498.
[17] 李义臣,刘国金,邵建中,等.二氧化硅/聚甲基丙烯酸甲酯光子晶体在涤纶织物上的结构生色[J].纺织学报,2016,37(10):62-67.
[18] 王莉丽,王秀峰,刘派,等.蓝色聚苯乙烯胶体晶体膜的制备及其呈色机理研究[J].人工晶体学报,2016,45(6):1 482-1 486.