可燃固体废弃物热解气化技术及工程化模拟研究进展
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摘要
简要介绍了目前国内城市生活垃圾的产生现状及其主要的处理方法。概述了典型可燃固体废弃物的热解气化实验进展和基于Aspen Plus平台模拟的研究现状以及热解气化技术的应用情况。分析总结了热解温度和加热速率对热解产物分布及其产量的影响,以及空气燃料比和气化温度对气化过程的影响。基于Aspen Plus平台的热解气化模型能够很好地模拟实际热解气化过程,具有较好的可靠性和实用性。指出可燃固废热解气化实验今后的研究重点及Aspen Plus平台模拟研究的着重考虑因素。
The status of combustible municipal solid waste and the main methods of waste disposal in China were briefly introduced. The experimental research progress and the simulation study based on Aspen Plus in typical combustible solid waste pyrolysis and gasification were summarized, and its application status was overviewed. The effects of pyrolysis temperature and heating process on the distribution of pyrolysis products and yields, as well as the effects of air-fuel ratio and gasification temperature on the gasification process were comprehensively analyzed. The actual pyrolysis and gasification processes can be simulated well by the model based on Aspen Plus, the result was reliable and applicable. The research direction of combustible solid waste pyrolysis and gasification was discussed, and the important considerations for developing Aspen Plus model were also figure out.
The status of combustible municipal solid waste and the main methods of waste disposal in China were briefly introduced. The experimental research progress and the simulation study based on Aspen Plus in typical combustible solid waste pyrolysis and gasification were summarized, and its application status was overviewed. The effects of pyrolysis temperature and heating process on the distribution of pyrolysis products and yields, as well as the effects of air-fuel ratio and gasification temperature on the gasification process were comprehensively analyzed. The actual pyrolysis and gasification processes can be simulated well by the model based on Aspen Plus, the result was reliable and applicable. The research direction of combustible solid waste pyrolysis and gasification was discussed, and the important considerations for developing Aspen Plus model were also figure out.
引文
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[2]中华人民共和国国家统计局.中国统计年鉴[M].北京:中国统计出版社,2008-2014.
[3]刘军伟,雷廷宙,杨树华,等.浅议我国垃圾焚烧发电的现状及发展趋势[J].中外能源,2012,17(6):29-34.
[4]刘永,蒋云峰,邓蜀平,等.基于Aspen Plus软件的煤气化过程模拟评述[J].河南化工,2010,27(14):25-27.DOI:10.3969/j.issn.1003-3467.2010.14.010.
[5]KAUSHAL P,TYAGI R.Advanced simulation of biomass gasification in a fluidized bed reactor using ASPEN PLUS[J].Renewable energy,2017,101:629-636.DOI:10.1016/j.renene.2016.09.011.
[6]SOTUDEH-GHAREBAAGH R,LEGROS R,CHAOUKI J,et al.Simulation of circulating fluidized bed reactors using Aspen Plus[J].Fuel,1998,77(4):327-337.DOI:10.1016/S0016-2361(97)00211-1.
[7]CHENG S,WANG Q,JI H S.Simulation of hydrogen production from biomass catalytic gasification[C]//Proceedings of 2010 International Conference on Digital Manufacturing and Automation(ICDMA).Changsha:IEEE,2010:370-374.DOI:10.1109/ICDMA.2010.335.
[8]RUPESH S,MURALEEDHARAN C,ARUN P.ASPEN plus modelling of air-steam gasification of biomass with sorbent enabled CO2 capture[J].Resource-efficient technologies,2016,2(2):94-103.DOI:10.1016/j.reffit.2016.07.002.
[9]KONG X D,ZHONG W M,DU W L,et al.Three stage equilibrium model for coal gasification in entrained flow gasifiers based on aspen plus[J].Chinese journal of chemical engineering,2013,21(1):79-84.DOI:10.1016/S1004-9541(13)60444-9.
[10]袁浩然,鲁涛,熊祖鸿,等.城市生活垃圾热解气化技术研究进展[J].化工进展,2012,31(2):421-427.
[11]WANG H,CHEN D,YUAN G,et al.Morphological characteristics of waste polyethylene/polypropylene plastics during pyrolysis and representative morphological signal characterizing pyrolysis stages[J].Waste management,2013,33(2):327-339.DOI:10.1016/j.wasman.2012.10.013.
[12]AHMAD I,KHAN M I,KHAN H,et al.Pyrolysis study of polypropylene and polyethylene into premium oil products[J].International journal of green energy,2015,12(7):663-671.DOI:10.1080/15435075.2014.880146.
[13]MARCILLA A,BELTRáN M I,NAVARRO R.Thermal and catalytic pyrolysis of polyethylene over HZSM5 and HUSY zeolites in a batch reactor under dynamic conditions[J].Applied catalysis B:environmental,2009,86(1/2):78-86.DOI:10.1016/j.apcatb.2008.07.026.
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[15]LOPEZ-URIONABARRENECHEA A,DE MARCO I,CABALLERO B M,et al.Catalytic stepwise pyrolysis of packaging plastic waste[J].Journal of analytical and applied pyrolysis,2012,96:54-62.DOI:10.1016/j.jaap.2012.03.004.
[16]JORDAN K J,SUIB S L,KOBERSTEIN J T.Determination of the degradation mechanism from the kinetic parameters of dehydrochlorinated poly(vinyl chloride)decomposition[J].The journal of physical chemistry B,2001,105(16):3174-3181.DOI:10.1021/jp003223k.
[17]DONAJ P J,KAMINSKY W,BUZETO F,et al.Pyrolysis of polyolefins for increasing the yield of monomers’recovery[J].Waste management,2012,32(5):840-846.DOI:10.1016/j.wasman.2011.10.009.
[18]CHOWLU A C K,REDDY P K,GHOSHAL A K.Pyrolytic decomposition and model-free kinetics analysis of mixture of polypropylene(PP)and low-density polyethylene(LDPE)[J].Thermochimica acta,2009,485(1/2):20-25.DOI:10.1016/j.tca.2008.12.004.
[19]MIANDAD R,BARAKAT M A,ABURIAZAIZA A S,et al.Effect of plastic waste types on pyrolysis liquid oil[J].International biodeterioration&biodegradation,2017,119:239-252.DOI:10.1016/j.ibiod.2016.09.017.
[20]WU C H,CHANG C Y,TSENG C H.Pyrolysis products of uncoated printing and writing paper of MSW[J].Fuel,2002,81(6):719-725.DOI:10.1016/S0016-2361(01)00180-6.
[21]WU C H,CHANG C Y,TSENG C H,et al.Pyrolysis product distribution of waste newspaper in MSW[J].Journal of analytical and applied pyrolysis,2003,67(1):41-53.DOI:10.1016/S0165-2370(02)00016-5.
[22]肖刚,池涌,倪明江,等.纸类废弃物流化床热解气化研究[J].工程热物理学报,2007,28(1):161-164.DOI:10.3321/j.issn:0253-231X.2007.01.052.
[23]YANG H P,YAN R,CHEN H P,et al.Characteristics of hemicellulose,cellulose and lignin pyrolysis[J].Fuel,2007,86(12/13):1781-1788.DOI:10.1016/j.fuel.2006.12.013.
[24]KINATA S E,LOUBAR K,PARASCHIV M,et al.Slow pyrolysis of CCB-treated wood for energy recovery:influence of chromium,copper and boron on pyrolysis process and optimization[J].Journal of analytical and applied pyrolysis,2013,104:210-217.DOI:10.1016/j.jaap.2013.08.002.
[25]温俊明,池涌,罗春鹏,等.城市生活垃圾典型有机组分混合热解特性的研究[J].燃料化学学报,2004,32(5):563-568.DOI:10.3969/j.issn.0253-2409.2004.05.011.
[26]张加权.典型城市生活垃圾组分流化床热解气化特性及反应机理研究[D].杭州:浙江大学,2005.
[27]XING S Y,YUAN H R,HUHETAOLI,et al.Characterization of the decomposition behaviors of catalytic pyrolysis of wood using copper and potassium over thermogravimetric and Py-GC/MS analysis[J].Energy,2016,114:634-646.DOI:10.1016/j.energy.2016.07.154.
[28]CHEN S,MENG A H,LONG Y Q,et al.TGA pyrolysis and gasification of combustible municipal solid waste[J].Journal of the energy institute,2015,88(3):332-343.DOI:10.1016/j.joei.2014.07.007.
[29]王毓,翁俊桀,贾良元,等.光电离质谱结合GC/MS研究棉麻织物的热解[J].质谱学报,2015,36(1):8-15.DOI:10.7538/zpxb.youxian.2014.0047.
[30]陈国艳,曾纪进,杨庆昌.城市生活垃圾典型组分的热解特性研究[J].工业炉,2012,34(6):39-41,45.DOI:10.3969/j.issn.1001-6988.2012.06.012.
[31]MIRANDA R,SOSA_BLANCO C,BUSTOS-MARTíNEZ D,et al.Pyrolysis of textile wastes:I.Kinetics and yields[J].Journal of analytical and applied pyrolysis,2007,80(2):489-495.DOI:10.1016/j.jaap.2007.03.008.
[32]陈江,黄立维,章旭明.垃圾衍生燃料热重–红外联用法的热解特性[J].环境科学与技术,2008,31(1):29-32.DOI:10.3969/j.issn.1003-6504.2008.01.008.
[33]BUAH W K,CUNLIFFE A M,WILLIAMS P T.Characterization of products from the pyrolysis of municipal solid waste[J].Process safety and environmental protection,2007,85(5):450-457.DOI:10.1205/psep07024.
[34]HWANG I H,KOBAYASHI J,KAWAMOTO K.Characterization of products obtained from pyrolysis and steam gasification of wood waste,RDF,and RPF[J].Waste management,2014,34(2):402-410.DOI:10.1016/j.wasman.2013.10.009.
[35]EFIKA E C,ONWUDILI J A,WILLIAMS P T.Products from the high temperature pyrolysis of RDF at slow and rapid heating rates[J].Journal of analytical and applied pyrolysis,2015,112:14-22.DOI:10.1016/j.jaap.2015.01.004.
[36]BEGUM S,RASUL M G,AKBAR D.A numerical investigation of municipal solid waste gasification using aspen plus[J].Procedia engineering,2014,90:710-717.DOI:10.1016/j.proeng.2014.11.800.
[37]NIKOO M B,MAHINPEY N.Simulation of biomass gasification in fluidized bed reactor using ASPEN PLUS[J].Biomass and bioenergy,2008,32(12):1245-1254.DOI:10.1016/j.biombioe.2008.02.020.
[38]MATHIEU P,DUBUISSON R.Performance analysis of a biomass gasifier[J].Energy conversion and management,2002,43(9/12):1291-1299.DOI:10.1016/S0196-8904(02)00015-8.
[39]SHEN L H,GAO Y,XIAO J.Simulation of hydrogen production from biomass gasification in interconnected fluidized beds[J].Biomass and bioenergy,2008,32(2):120-127.DOI:10.1016/j.biombioe.2007.08.002.
[40]ABDELOUAHED L,AUTHIER O,MAUVIEL G,et al.Detailed modeling of biomass gasification in dual fluidized bed reactors under Aspen Plus[J].Energy&fuels,2012,26(6):3840-3855.DOI:10.1021/ef300411k.
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