金属表面耐高温防腐涂料的研究进展
详细信息    查看全文 | 推荐本文 |
  • 英文篇名:Research Progress of High Temperature Resistant Anticorrosive Coatings on Metal Surface
  • 作者:杨宏波 ; 刘朝辉 ; 丁逸栋 ; 林锐 ; 班国东 ; 陶睿
  • 英文作者:YANG Hong-bo;LIU Zhao-hui;DING Yi-dong;LIN Rui;BAN Guo-dong;TAO Rui;Department of Chemistry & Materials,PLA Logistic Engineering University;
  • 关键词:耐高温涂层 ; 金属防腐 ; 有机硅涂料 ; 无机涂料 ; 复合涂料
  • 英文关键词:high temperature resistant coatings;;metal anti-corrosion;;organic silicone resin coatings;;inorganic coatings;;compound coatings
  • 中文刊名:BMJS
  • 英文刊名:Surface Technology
  • 机构:中国人民解放军后勤工程学院化学与材料工程系;
  • 出版日期:2017-03-20
  • 出版单位:表面技术
  • 年:2017
  • 期:v.46
  • 基金:重庆市研究生科研创新项目(CYS16238);; 重庆市自然科学基金(cstc2014jcyj A50026)~~
  • 语种:中文;
  • 页:BMJS201703036
  • 页数:7
  • CN:03
  • ISSN:50-1083/TG
  • 分类号:228-234
摘要
长时间处于高温环境中,金属易发生氧化腐蚀,从而丧失机械性能直至破坏,严重影响了使用效能的发挥。在金属表面涂覆耐高温涂层,因施工简便、成本较低、耐热性能好等优点而获得广泛应用,对于防止材料高温腐蚀、节约资源等具有重要的经济意义。对目前常用的耐高温涂料进行分类,包括有机耐高温涂料和无机耐高温涂料两大类,重点介绍了有机硅树脂耐高温涂料和无机耐高温涂料,并简单描述了有机-无机复合耐高温涂料的有关情况。对不同类别耐高温涂料的化学组成、物理性能和耐热机理等进行了阐述,并结合涂料的结构特点对各自优缺点进行了分析与比较。根据耐高温涂料在现代工业发展中的重要作用,介绍了国内外关于耐高温涂料的研究进展和应用情况,指出了不同类别耐高温涂料在使用过程中存在的问题。最后结合当前工业社会向信息化社会转变的时代背景以及研究耐高温涂层的技术意义,对耐高温涂料的发展趋势进行了展望。
        Metal was susceptible to oxidation corrosion when being placed in high temperature surroundings for a long time,leading to loss of mechanical properties and even complete damage,thus seriously affecting development of application performance.As a widely used heat-prevention technology featuring in simple construction,low cost and good heat resistance,depositing high temperature resistant coatings on metal surface was of great economic significance to prevent high temperature corrosion and save resources.The common high temperature resistant coatings were classified in this paper,including organic and inorganic categories.The organic silicone resin and inorganic coatings were introduced in detail,while the organic-inorganic compound high temperature resistant coatings were described in brief.Chemical composition,physical property and heat-resisting mechanism were expounded.Merits and demerits of the coatings were analyzed and compared by combining their structural features.According to the important role of high temperature resistant coatings in modern industrial development,research progress and application status of such high temperature resisting coatings at home and abroad were introduced,the problems of different coatings present during application were also proposed.Finally,the developing tendency is expected by referring to time background of transforming to informational society from industrial society and technical significance of studying such coatings.
引文
[1]闫实.有机硅耐高温涂层的制备和防护机理研究[D].重庆:后勤工程学院,2015.YAN Shi.Preparation and Study of Protective Mechanism of Silicone Resin High Temperature Coatings[D].Chongqing:Logistical Engineering University,2015.
    [2]PUNCKT C,B?LSCHER M,ROTERMUND H H,et al.Sudden Onset of Pitting Corrosion on Stainless Steel as a Critical Phenomenon[J].Science,2004,35(44):1133—1136.
    [3]PICCIOTTI M,PICCIOTTI F.Selecting Corrosion-resistant Materials[J].Chem.Eng.Prog,2006,102:45—52.
    [4]XIAO J,CHEN J M,ZHOU H D.Study of Several Organic Resin Coatings as Anti-ablation Coatings for Supersonic Craft Control Actuator[J].Materials Science and Engineering,2007,15:23—30.
    [5]王海庆,李丽,庄光山.涂料与涂装技术[M].北京:化学工业出版社,2012:1—7.WANG Hai-qing,LI Li,ZHUANG Guang-shan.Coatings and Painting Technology[M].Beijing:Chemical Industry Press,2012:1—7.
    [6]郭中宝,刘杰民,范慧俐,等.环氧改性有机硅树脂涂料耐温性能研究[J].化工新型材料,2007,35(4):57—59.GUO Zhong-bao,LIU Jie-min,FAN Hui-li,et al.Research on Heat Resistance of Epoxy Modified Silicone Coatings[J].New Chemical Materials,2007,35(4):57—59.
    [7]周其凤,范星河,谢晓峰.耐高温聚合物及其复合材料[M].北京:化学工业出版社,2004:75—76.ZHOU Qi-feng,FAN Xing-he,XIE Xiao-feng.High Temperature Resistant Polymer and Composite Materials[M].Beijing:Chemical Industry Press,2004:75—76.
    [8]王国平.新型有机-无机复合耐蚀耐高温涂料的制备研究[D].成都:四川大学,2005.WANG Guo-ping.Study on the Preparation of the Organic and In-organic Compound Coating with Corrosion and High Temperature Resistance[D].Chengdu:Sichuan University,2005.
    [9]徐忠苹,韩文礼,张彦军,等.耐高温涂料研究进展[J].全面腐蚀控制,2011,25(7):8—12.XU Zhong-ping,HAN Wen-li,ZHANG Yan-jun,et al.Research Development of High Temperature Resistant Coating[J].Total Corrosion Control,2011,25(7):8—12.
    [10]李静.换热器用耐高温防腐蚀导热涂料的研究[D].广州:华南理工大学,2013.LI Jing.The Study of High Temperature Resistance and Anticorrosion Thermal Conductive Coating Used on Heat Exchanger[D].Guangzhou:South China University of Technology,2013.
    [11]张艳中,马培良.氟树脂涂料的研究及应用[J].浙江化工,2007(8):007.ZHANG Yan-zhong,MA Pei-liang.Research and Application Progresses in Fluoro-contained Resin Coatings[J].Zhejiang Chemical Industry,2007(8):007.
    [12]汤清琼.硼硅酸盐玻璃介质类高温涂料的研究[D].北京:北京工业大学,2010.TANG Qing-qiong.Researchon High-temperature Coating Containing Borosilicate Glass Medium[D].Beijing:Beijing University of Technology,2010.
    [13]赵陈超,章基凯.有机硅树脂及其应用[M].北京:化学工业出版社,2011.ZHAO Chen-chao,ZHANG Ji-kai.Organic Silicone Resin and Application[M].Beijing:Chemical Industry Press,2011.
    [14]明耀强,胡剑峰,张宇帆,等.有机硅树脂耐高温改性研究进展[J].广东化工,2014,41(24):49—50.MING Yao-qiang,HU Jian-feng,ZHANG Yu-fan,et al.Development of Heat-resistant Modification of Silicone Resin[J].Guangdong Chemical Engineering,2014,41(24):49—50.
    [15]李霞.热防护有机硅耐高温涂料研究[D].北京:航天动力设计研究院,2015.LI Xia.Research on Organic Silicone High Temperature Resistant Coatings of Heat Protective Property[D].Beijing:Institute of Space Power Design,2015.
    [16]郑宏建.颜填料对高温漆性能的影响[J].广州化工,2015,43(14):78—79.ZHENG Hong-jian.Effect of Pigment and Coatings on the Properties of High Temperature Paint[J].Guangzhou Chemical Industry,2015,43(14):78—79.
    [17]殷树梅,王志浩,孙红岩.有机硅涂料的研究及应用进展[J].有机硅材料,2011,25(6):414—417.YIN Shu-mei,WANG Zhi-hao,SUN Hong-yan.Status of Research and Application of Silicone Coating[J].Silicone Material,2011,25(6):414—417.
    [18]肖颖.聚氨酯改性硅树脂的合成与性能研究[D].北京:北京化工大学,2012.XIAO Ying.The Preparationand Properties of Silicone Resin Modifiedby Polyurethane[D].Beijing:Beijing Univrsity of Chemical Technology,2012.
    [19]王海侨,李营,苟国立,等.有机硅耐高温涂料二次成膜机理的探讨[J].涂料工业,2005,35(10):17—20.WANG Hai-qiao,LI Ying,GOU Guo-li,et al.Discussion about Mechanisms on Secondary Film Formation of Organosilicone Coating[J].Paint&Coatings Technology,2005,35(10):17—20.
    [20]刘媛.关于耐高温有机硅涂料及粘接剂的特性及应用探究[J].化工中间体,2015(1):32—33.LIU Yuan.Application of High Temperature Silicone Paint and Adhesive[J].Chenmical Intermediate,2015(1):32—33.
    [21]赖琛,唐绍裘.耐高温防腐涂料的研制[J].电镀与涂饰,2002,21(1):29—34.LAI Chen,TANG Shao-qiu.Development of Heat Resistant and Anticorrosive Coating[J].Electroplating&Finishing,2002,21(1):29—34.
    [22]段伟,张良均,胡峰,等.常温固化环氧改性有机硅耐高温涂料的研制[J].现代涂料与涂装,2009,12(11):13—26.DUAN Wei,ZHANG Liang-jun,HU Feng,et al.Development of Room Temperature Curing Epoxy Resin Modified Silicone Heat-resistant Coating[J].Modern Paint and Finishing,2009,12(11):13—26.
    [23]汪长春,包启宇.丙烯酸酯涂料[M].北京:化学工业出版社,2005:43—45.WANG Chang-chun,BAO Qi-yu.Acrylate Coating[M].Beijing:Chemical Industry Press,2005:43—45.
    [24]王晓明.水性丙烯酸树脂涂料的研究[D].南京:南京航空航天大学,2012.WANG Xiao-ming.Study of Water-Borne Acrylic Resin Coating[D].Nanjing:Nanjing University of Aeronautics and Astronautics,2012.
    [25]SASCHA Herrwerth,ANNIKA K?nig,MARION.Silicone Resins for High-temperature-resistant Coatings[J].Paint(5)Coatings Industry,2015(2):34—35.
    [26]朱江.耐高温涂层的研究[D].上海:华东理工大学,2011.ZHU Jiang.Research of Heat-resistance Coatings[D].Shanghai:East China University of Technology,2011.
    [27]李绍雄,刘益军.聚氨酯树脂及其应用[M].北京:化学工业出版社,2002:310—311.LI Shao-xiong,LIU Yi-jun.Polyurethane Resin and Application[M].Beijing:Chemical Industry Press,2002:310—311.
    [28]HERNANDEZ R,WEKSLER J,PADSALGIKAR A,et al.Microstructural Organization of Three-phase Polydime-thylsiloxane-based Segmented Polyurethanes[J].Macromolecules.2007,40:5441.
    [29]TAEYI C,JADWIGA W,AJAY P,et al.Influence of Soft Segment Composition on Phase-separated Microstructure of Polydimethylsiloxane-based Segmented Polyurethane Copolymers[J].Polymer,2009,50:2320—2327.
    [30]李霞,王晓洁,刘新东.环氧改性有机硅耐热涂料的配方研究[J].电镀与涂饰,2015,34(10):537—541.LI Xia,WANG Xiao-jie,LIU Xin-dong.Study on Formulation of Heat-resistant Epoxy-modified Silicone Coating[J].Electroplating&Finishing,2015,34(10):537—541.
    [31]JIN W Y,YU J L,SANG B L,et al.Erect of Dimethylpolysiloxane Liquid on the Cryogenic Tensile Strength and Thermal Contraction Behavior of Epoxy Resins[J].Cryogenics,2014,61:63—69.
    [32]何彦萱,尚小琴,汤敏妮,等.环氧改性有机硅耐高温树脂的合成与性能[J].电镀与涂饰,2013,32(6):62—64.HE Yan-xuan,SHANG Xiao-qin,TANG Min-ni,et al.Synthesis and Property of Epoxy-modified Organic Silicone Resin with High Temperature Resistance[J].Electroplating&Finishing,2013,32(6):62—64.
    [33]YIN X,DUAN H,WANG X,et al.An Investigation on Synthesis of Alkyd Resin with Sorbitol[J].Progress in Organic Coatings,2014,77(3):674—678.
    [34]AIGBODION A I,OKIEIMEN F E.An Investigation of the Utilization of African Locust Bean Seed Oil in the Preparation of Alkyd Resins[J].Ind Crops Pra,2001,13(1):29.
    [35]吴松浩.改性有机硅树脂耐高温涂料的研制[D].沈阳:沈阳理工大学,2012.WU Song-hao.Modified Silicone Resin High Temperature Resistant Coating's Development[D].Shenyang:Shenyang Ligong University,2012.
    [36]王亦工,陈华辉,裴嵩峰,等.水性无机硅酸锌防腐涂料的研究进展[J].腐蚀科学与防护技术,2006,18(1):41—45.WANG Yi-gong,CHEN Hua-hui,PEI Song-feng,et al.Development of Waterborne Inorganic Zinc Silicate Anticorrosion Coatings[J].Corrosion Scienceand Protection Technology,2006,18(1):41—45.
    [37]GEETA P,DEEPAK S,PRAMOD K.Ethyl Silicate Binders for High Performance Coatings[J].Progress in Organic Coatings,2001(42):1—14.
    [38]GAGGIANO R,MORIAME P,BIESEMANS M,et al.Mechanism of Formation of Silicate Thin Films on Porous Anodic Alumina[J].Surface&Coatings Technology,2011(205):5210—5217.
    [39]ISTVAN H,MUKESH A,RUNBO L,et al.Monitoring the Structure of Water Soluble Silicates[J].Catalysis Today,2007,126:196—202.
    [40]朱秋华.水性无机耐高温涂料的研制及其性能研究[D].南京:东南大学,2007.ZHU Qiu-hua.Preparation and Properties of Waterborne Inorganic High Temperature Resistant Coatings[D].Nanjing:Southeast University,2007.
    [41]阳飞,闫龙龙,郝西鹏,等.硅溶胶-有机硅改性聚酯复合涂料的合成及应用[J].电镀与涂饰,2015,34(18):1015—1020.YANG Fei,YAN Long-long,HAO Xi-peng.Preparation and Application of Silica Sol-Organosilicon-Modified Polyester Composite Coating[J].Electroplating&Finishing,2015,34(18):1015—1020.
    [42]王峥,郝超伟,马清芳,等.国内有机硅耐高温涂料研究进展[J].杭州师范大学学报(自然科学版),2011,10(6):510—513.WANG Zheng,HAO Chao-wei,MA Qing-fang,et al.Domestic Research Development of Organosilicone Heat Resistant Coatings[J].Journal of Hangzhou Normal University(Natural Science Edition),2011,10(6):510—513.
    [43]幸松民.有机硅合成工艺及产品应用[M].北京:化工出版社,1995.XING Song-min.Organic Silicone Synthesis Technology and Product Application[M].Beijing:Chemical Industry Press,1995.
    [44]DOUCETTE J J J,FRANCHITTO A R.Three Dimensionally Reinforced Ablative/Insulative Composite:U.S.,5985405[P].1999-11-16.
    [45]TANAKA R.Research and Development of Ultra-High Temperature Materials in Japan[J].Materials at High Temperatures,2000,17(4):457—464.
    [46]ROUSSI E,TSETSEKOU A,TSIOURVAS D,et al.Novel Hybrid Organo-Silicate Corrosion Resistant Coatings Based on Hyperbranched Polymers[J].Surface&Coatings Technology,2011(205):3235—3244.
    [47]赵珂,吴晓琳,桑舒琦.航天领域用耐高温绝缘有机硅涂料的研制[J].上海涂料,2011,49(9):1—3.ZHAO Ke,WU Xiao-lin,SANG Shu-qi.The Preparation of High Temperature Insulating Silicone Coatins for Aerospace Field[J].Shanghai Coatings,2011,49(9):1—3.
    [48]王海侨,李营,苟国立,等.有机硅耐高温涂料的研究[J].北京化工大学学报,2006,33(1):59—62.WANG Hai-qiao,LI Ying,GOU Guo-li,et al.Preparation of Organjc Silicone Coating with High-temperature Resistance[J].Journal of Beijing University of Chemical Industry,2006,33(1):59—62.
    [49]何岩.有机-无机复合型防腐耐高温涂料的制备与研究[D].大连:大连交通大学,2014.HE Yan.Preparation of Organic-Inorganic Composite Hightemperature Corrosion Coating[D].Dalian:Dalian Jiaotong University,2014.
    [50]傅敏,狄志刚,朱晓丰,等.无铬环保磷酸盐基高温防腐涂料[J].涂料工业,2010,40(12):49—52.FU Min,DI Zhi-gang,ZHU Xiao-feng,et al.Chromium-free Environmental Friendly Phosphate-based High Temperature Anticorrosion Coatings[J].Paint(5)Coatings Industry,2010,40(12):49—52.
    [51]MADHU B,VIPIN S,FIRDOUS H.Development of a Heat Resistant UV-curable Epoxy Coating[J].Progress in Organic Coatings,2005,53:239—245.
    [52]SHAILESH K D,ROHIT B,ASKHANN A.Effect of Nano-Zn O Addition on the Silicone-modified Alkyd-based Waterborne Coatings on Its Mechanical and Heat-resistance Properties[J].Progress in Organic Coatings,2009,84:39—46.
    [53]付敏.高温防护涂料研究与应用现状[J].涂料技术与文摘,2014,35(12):34—36.FU Min.Research and Application of High Temperature Protective Coatings[J].Coatings Technology&Abstracts,2014,35(12):34—36.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700