耐高温尼龙材料的研究进展
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摘要
耐高温尼龙在汽车、电子电器等领域具有广泛的应用,但目前高端耐高温尼龙被国外尼龙生产巨头所控制,国内主要依赖进口。本文在总结国内外耐高温尼龙的种类,主要制备工艺,改性和应用研究进展。重点分析了耐高温尼龙的合成工艺和功能化改性方向,并指出开发新工艺,寻找新原料,合理调控耐热性能是目前国内企业的主要发展方向。
The high temperature resistance is widely used in auto industry and electrical industry. The synthesis and high-performance nylon with well heat resistance is monopolized by international enterprises,i. e.,Dupont and much of the consumed high-performance nylon is imported from these international enterprises. The classification,synthesis method and technology,modification and application of high temperature resistance nylon were comprehensive introduced.The key progress of technology of semi-aromatic nylon,development of new technology and new raw materials were the key factor to fasten the R&D high temperature resistance. Some proposals were put forward for the future development of high temperature resistance nylon.
The high temperature resistance is widely used in auto industry and electrical industry. The synthesis and high-performance nylon with well heat resistance is monopolized by international enterprises,i. e.,Dupont and much of the consumed high-performance nylon is imported from these international enterprises. The classification,synthesis method and technology,modification and application of high temperature resistance nylon were comprehensive introduced.The key progress of technology of semi-aromatic nylon,development of new technology and new raw materials were the key factor to fasten the R&D high temperature resistance. Some proposals were put forward for the future development of high temperature resistance nylon.
引文
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[23]王飞,王浩江,雷祖碧.尼龙12回收料的增韧及耐高温热氧老化改性研究[J].合成材料老化与应用,2017,46(6):8-10.
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[25] Mahboobeh Yousefian-Arani,Alireza Sharif,Ahmad Reza Bahramian.Semi-aromatic polyamide-based nanocomposites:I. in-situ polymerization in the presence of graphene oxide[J]. Polymer Bulletin,2018,75(12):5387-5402.
[26] Xue-BaoLin. Li Chen,Jia-Wei Long,Du Shuang-Lan,YuZhongWang. A hybrid flame retardant for semi-aromatic polyamide:Unique structure towards self-compatibilization and flame retardation[J]. Chemical Engineering Journal,2018,334:1046-1054.
[27] Washio Isao,Ebata Hiroki,Ogasawara Hideto,et al. Semi-aromatic polyamide resin composition and molded article containing same[P].2017.
[2]刘宇辰,李迎春,曲振,等.耐高温PA10T/11共聚尼龙的合成与表征[J].塑料工业,2012,40(10):20-23.
[3]崔小明. DSM公司推出耐高温生物质尼龙[J].合成纤维工业,2010(6):7.
[4]高原,梁效礼,杨冬,等.一种耐高温低吸湿性共聚尼龙及其制备方法[P]. CN:103923314 A,2014.
[5]罗湘安,曾祥斌,宁凯军,等.一种耐高温尼龙多元共聚物及其制备方法[P]. CN:103834006 A,2014.
[6]杨桂生,田文伟.阻燃耐高温尼龙共聚物及其制备方法[P]. CN:106589353A,2017.
[7]杨桂生,田文伟.一种半芳香共聚尼龙的制备方法[P]. CN:103923313 A,2014.
[8]赵志.多元共聚半芳香尼龙的合成与性能研究[D].湘潭:湘潭大学,2015.
[9]韩冰,张声春,张春祥,等.半芳香共聚尼龙6T/6的合成与结晶性能研究[J].塑料工业,2013,41(9):21-23.
[10]王双.半芳香聚酰胺PA6T/66的合成工艺及性能研究[D].郑州:郑州大学,2014.
[11] Cakirs S,Nieuwenhuizen M M L,Janssen P G A,et al. Incorporation of a semi-aromatic nylon salt into polyamide 6 by solid-state or melt polymerization[J]. Polymer,2012,53(23):5242-5250.
[12] Papaspyrides C D,Porfyris A D,Rulkens R,et al. The effect of diamine length on the direct solid state polycondensation of semiaromatic nylon salts[J]. Journal of Polymer Science,Part A:Polymer chemistry,2016,54(16):2493-2506.
[13] Seda Cakira,Lidia Jasinska-Walc,Maurizio Villani,et al. Koning.Morphology and local chain structure of polyamide 6 modified in thesolid state with a semi-aromatic nylon salt[J]. Materials Today Communications,2015,2:e62-e69.
[14] Cai-Liang Zhang,Li Wan,Xue-Ping Gu,et al. A Study on a Prepolymerization Process of Aromatic-Contained Polyamide Copolymers PA(66-co-6T)via One-Step Polycondensation[J].Macromolecular Reaction Engineering,2015,9:512-521.
[15] Gang Zhang,Guang-Ming Yan,Hao-Hao Ren,et al. Effects of a trans-or cis-cyclohexane unit on the thermal and rheological properties of semi-aromatic polyamides[J]. Polymer Chemistry,2016,7:44-53.
[16] Gang Zhang,Yu-xuan Zhou,Yan Li,et al. Investigation of the synthesis and properties of isophorone and ether units based semiaromatic polyamides[J]. RSC Adv.,2015,5:49958-49967.
[17] Shumin Peng,Lu Peng,Chunwang Yi,et al. A Novel Synthetic Strategy for Preparing Semi-aromatic Components Modified Polyamide 6Polymer[J]. Journal of Polymer Science,Part A:Polymer Chemistry,2018,56:959-967.
[18] Wutong Feng, Pingli Wang, Guangji Zou, et al. Synthesis and characterization of semiaromatic copolyamide 10T/1014 with high performance and flexibility[J]. Designed Monomers and Polymers,2018,21(1):33-42.
[19] Qi X,Wang W,Zhang J,et al. Aqueously soluble semi-aromatic copolyamides with dual-functional groups as sizing agent[J]. Journal of Applied Polymer Science,2019,DOI:10.1002/APP.47132.
[20] Bingxiao Liu, Guosheng Hu, Jingting Zhang, et al. Synthesis,characterization and thermal decomposition kinetics of a bio-based transparent nylon 10I/10T. Designed and Monomers and Polymers,2018,21(1):182-192.
[21] Xueke Sun,Kancheng Mai,Chuanhui Zhang,et al. Nonisothermal crystallization kinetics of bio-based semi-aromatic polyamides[J].Journal of Thermal Analysis and Calorimetry,2017,130:1021-1030.
[22]李庆丰,李荣.一种耐高温半芳香族尼龙复合材料及其制备方法[P]. CN:103834161A,2014.
[23]王飞,王浩江,雷祖碧.尼龙12回收料的增韧及耐高温热氧老化改性研究[J].合成材料老化与应用,2017,46(6):8-10.
[24]郑培生,郑海滨.耐高温尼龙[P].CN:107915988A,2018.
[25] Mahboobeh Yousefian-Arani,Alireza Sharif,Ahmad Reza Bahramian.Semi-aromatic polyamide-based nanocomposites:I. in-situ polymerization in the presence of graphene oxide[J]. Polymer Bulletin,2018,75(12):5387-5402.
[26] Xue-BaoLin. Li Chen,Jia-Wei Long,Du Shuang-Lan,YuZhongWang. A hybrid flame retardant for semi-aromatic polyamide:Unique structure towards self-compatibilization and flame retardation[J]. Chemical Engineering Journal,2018,334:1046-1054.
[27] Washio Isao,Ebata Hiroki,Ogasawara Hideto,et al. Semi-aromatic polyamide resin composition and molded article containing same[P].2017.