Li_2MSiO_4作锂离子电池正极嵌锂插层的研究进展
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摘要
对国内外聚阴离子型化合物硅酸盐Li2MSiO4(M=Fe,Mn,Ni,…)正极材料的研究进展进行了综述,着重从材料的制备与结构改性、嵌/脱锂特性、晶型结构等方面进行阐述。最后讨论硅酸盐正极材料所面临的挑战,并指出改善其综合性能的途径。
A review on recent worldwide research progresses in polyoxyanion compounds Li2MSiO4(M=Fe,Mn,Ni,…) cathode materials is presented,essentially focusing on their synthesis and structural modification me-thods,intercalation/de-intercalation properties,and structural polymorphs.In conclusion,the future challenges of the Li2MSiO4 are remarked,and the possible ways of improving their overall performances are also suggested.
A review on recent worldwide research progresses in polyoxyanion compounds Li2MSiO4(M=Fe,Mn,Ni,…) cathode materials is presented,essentially focusing on their synthesis and structural modification me-thods,intercalation/de-intercalation properties,and structural polymorphs.In conclusion,the future challenges of the Li2MSiO4 are remarked,and the possible ways of improving their overall performances are also suggested.
引文
1 Armand M,Gauthier M,Magnan J F,et al.Synthesismethod for carbon materials based on LixM1-yM′y(XO4)n:US,7585260[P].2007-10-23
2 Nytén A,Abouimrane A,Armand M,et al.Electrochemi-cal performance of Li2FeSiO4as a new Li-battery cathodematerial[J].Electrochem Commun,2005,7:156
3 Nytén A,Stjerndahl M,Rensmo H,et al.Surface charac-terization and stability phenomena in Li2FeSiO4studied byPES/XPS[J].J Mater Chem,2006,16:3483
4 Larsson P,Ahuja R,Nyten A,et al.An ab initio study ofthe Li-ion battery cathode material Li2FeSiO4[J].Electro-chem Commun,2006,8(5):797
5 Nytén A,Kamali S,Haggstrom L,et al.The lithium ex-traction/insertion mechanism in Li2FeSiO4[J].J MaterChem,2006,16:2266
6Dominko R,Bele M,Gaberˇcek M,et al.Structure andelectrochemical performance of Li2MnSiO4and Li2FeSiO4aspotential Li-battery cathode materials[J].ElectrochemCommun,2006,8:217
7 Dominko R,Conte D E,Hanzel D,et al.Impact of synthe-sis conditions on the structure and performance of Li2FeSiO4[J].J Power Sources,2008,178(2):842
8 Dominko R,Bele M,Kokalj A,et al.Li2MnSiO4as a po-tential Li-battery cathode material[J].J Power Sources,2007,174:457
9 Aravindan V,Karthikeyan K,Lee J W,et al.Synthesis andimproved electrochemical properties of Li2MnSiO4cathodes[J].Appl Phys,2011,44:152001
10Peng Z D,Cao Y B,Hu G R,et al.Microwave synthesis ofLi2FeSiO4cathode materials for lithium-ion batteries[J].Chin Chem Lett,2009,20:1000
11 Muraliganth T,Stroukoff K R,Manthiram A.Microwave-solvothermal synthesis of nanostructured Li2MSiO4/C(M=Mn and Fe)cathodes for lithium-ion batteries[J].ChemMater,2010,22:5754
12Guo H,Cao X,Li X,et al.Optimum synthesis of Li2Fe1-x-MnxSiO4/C cathode for lithium ion batteries[J].Electro-chim Acta,2010,55:8036
13 Gong Z L,Li Y X,Yang Y.Synthesis and characterizationof Li2MnxFe1-xSiO4as a cathode material for lithiumion bat-teries[J].Electrochem Solid State Lett,2006,9(12):A542
14 Deng C,Zhang S,Yang S Y.Effect of Mn substitution onthe structural,morphological and electrochemical behaviorsof Li2Fe1-xMnxSiO4synthesized via citric acid assisted sol-gel method[J].J Alloys Compd,2009,487:L18
15Li L M,Guo H J,Li X H,et al.Effects of roasting tem-perature and modification on properties of Li2FeSiO4/Ccathode[J].J Power Sources,2009,189:45
16 Kokalj A,Dominko R,Mali G,et al.Beyond one-electronreaction in Li cathode materials:Designing Li2MnxFe1-x-SiO4[J].Chem Mater,2007,19:3633
17 Guo H J,Xiang K X,Cao X,et al.Preparation and charac-teristics of Li2FeSiO4/C composite for cathode of lithium ionbatteries[J].Trans Nonferrous Met Soc Chin,2009,19:166
18 Aravindan V,Karthikeyan K,Kang K S,et al.Influence ofcarbon towards improved lithium storage properties ofLi2MnSiO4cathodes[J].J Mater Chem,2011,21:2470
19 Kam K C,Gustafsson T,Thomas J O.Synthesis and elec-trochemical properties of nanostructured Li2FeSiO4/C catho-de material for Li-ion batteries[J].Solid State Ionics,2010,192:356
20 Gong Z L,Li Y X,Yang Y.Synthesis and electrochemicalperformance of Li2CoSiO4as cathode material for lithium ionbatteries[J].J Power Sources,2007,174(2):524
21Li Y X,Gong Z L,Yang Y.Synthesis and characterizationof Li2MnSiO4/C nano-composite cathode material for lithiumion batteries[J].J Power Sources,2007,174(2):528
22 Gong Z L,Li Y X,He G N,et al.NanostructuredLi2FeSiO4electrode material synthesized through hydrother-mal-assisted sol-gel process[J].Electrochem Solid-StateLett,2008,11:A60
23Zhang S,Deng C,Fu B L,et al.Effects of Cr doping on theelectrochemical properties of Li2FeSiO4cathode material forlithium-ion batteries[J].Electrochim Acta,2010,55:8482
24 Deng C,Zhang S,Yang S Y,et al.Synthesis and characte-rization of Li2Fe0.97M0.03SiO4(M=Zn2+,Cu2+,Ni 2+)catho-de materials for lithium ion batteries[J].J PowerSources,2011,196:386
25Saiful Islam M,Robert Dominko,Christian Masquelier,etal.Silicate cathodes for lithium batteries:Alternatives tophosphates?[J].J Mater Chem,2011,21:9811
26 Nishimura S,Hayase S,Kanno R,et al.Structure ofLi2FeSiO4[J].J Am Chem Soc,2008,130:13212
27 Boulineau A,Sirisopanaporn C,Dominko R,et al.Poly-morphism and structural defects in Li2FeSiO4[J].DaltonTrans,2010,39:6310
28Sirisopanaporn C,Boulineau A,Hanzel D,et al.Crystalstructure of a new polymorph of Li2FeSiO4[J].InorgChem,2010,49(16):7446
29 Robert Armstrong A,Navaratnarajah Kuganathan,SaifulIslam M,et al.Structure and lithium transport pathways inLi2FeSiO4cathodes for lithium batteries[J].J Am ChemSoc,2011,133(33):13031
30Sirisopanaporn C,Masquelier C,Bruce P G,et al.Depen-dence of Li2FeSiO4electrochemistry on structure[J].J AmChem Soc,2011,133(5):1263
31 Saraciba A,van der Ven A,Arroyo-de Dompablo M E.Crystal structure,energetics,and electrochemistry ofLi2FeSiO4polymorphs from first principles calculations[J].Chem Mater,2012,24(3):495
32Politaev V V,Petrenko A A,Nalbandyan V B,et al.Crys-tal structure,phase relations and electrochemical propertiesof monoclinic Li2MnSiO4[J].J Solid State Chem,2007,180(3):1045
33 Mali G,Meden A,Dominko R.Li-6 MAS NMR spectrosco-py and first-principles calculations as a combined tool for theinvestigation of Li2MnSiO4polymorphs[J].Chem Com-mun,2010,46(19):3306
34 Arroyo-deDompablo M E,Dominko R,Gallardo-Amores JM,et al.On the energetic stability and electrochemistry ofLi2MnSiO4polymorphs[J].Chem Mater,2008,20:5574
35 Robert Armstrong A,Christopher Lyness,Michel Menet-rier,et al.Structural polymorphism in Li2CoSiO4intercala-tion electrodes:A combined diffraction and NMR study[J].Chem Mater,2010,22:1892
36Lyness C,Delobel B,Armstrong A R,et al.The lithiumintercalation compound Li2CoSiO4and its behaviour as apositive electrode for lithium batteries[J].Chem Commun,2007(46):4890
37Liivat A,Thomas J O.A DFT study of VO43-polyanionsubstitution into the Li-ion battery cathode materialLi2FeSiO4[J].Comput Mater Sci,2010,50:191
38 Kuganathan N,Islam M S.Li2MnSiO4lithium battery ma-terial:Atomic-scale study of defects,lithium mobility,andtrivalent dopants[J].Chem Mater,2009,21:5196
2 Nytén A,Abouimrane A,Armand M,et al.Electrochemi-cal performance of Li2FeSiO4as a new Li-battery cathodematerial[J].Electrochem Commun,2005,7:156
3 Nytén A,Stjerndahl M,Rensmo H,et al.Surface charac-terization and stability phenomena in Li2FeSiO4studied byPES/XPS[J].J Mater Chem,2006,16:3483
4 Larsson P,Ahuja R,Nyten A,et al.An ab initio study ofthe Li-ion battery cathode material Li2FeSiO4[J].Electro-chem Commun,2006,8(5):797
5 Nytén A,Kamali S,Haggstrom L,et al.The lithium ex-traction/insertion mechanism in Li2FeSiO4[J].J MaterChem,2006,16:2266
6Dominko R,Bele M,Gaberˇcek M,et al.Structure andelectrochemical performance of Li2MnSiO4and Li2FeSiO4aspotential Li-battery cathode materials[J].ElectrochemCommun,2006,8:217
7 Dominko R,Conte D E,Hanzel D,et al.Impact of synthe-sis conditions on the structure and performance of Li2FeSiO4[J].J Power Sources,2008,178(2):842
8 Dominko R,Bele M,Kokalj A,et al.Li2MnSiO4as a po-tential Li-battery cathode material[J].J Power Sources,2007,174:457
9 Aravindan V,Karthikeyan K,Lee J W,et al.Synthesis andimproved electrochemical properties of Li2MnSiO4cathodes[J].Appl Phys,2011,44:152001
10Peng Z D,Cao Y B,Hu G R,et al.Microwave synthesis ofLi2FeSiO4cathode materials for lithium-ion batteries[J].Chin Chem Lett,2009,20:1000
11 Muraliganth T,Stroukoff K R,Manthiram A.Microwave-solvothermal synthesis of nanostructured Li2MSiO4/C(M=Mn and Fe)cathodes for lithium-ion batteries[J].ChemMater,2010,22:5754
12Guo H,Cao X,Li X,et al.Optimum synthesis of Li2Fe1-x-MnxSiO4/C cathode for lithium ion batteries[J].Electro-chim Acta,2010,55:8036
13 Gong Z L,Li Y X,Yang Y.Synthesis and characterizationof Li2MnxFe1-xSiO4as a cathode material for lithiumion bat-teries[J].Electrochem Solid State Lett,2006,9(12):A542
14 Deng C,Zhang S,Yang S Y.Effect of Mn substitution onthe structural,morphological and electrochemical behaviorsof Li2Fe1-xMnxSiO4synthesized via citric acid assisted sol-gel method[J].J Alloys Compd,2009,487:L18
15Li L M,Guo H J,Li X H,et al.Effects of roasting tem-perature and modification on properties of Li2FeSiO4/Ccathode[J].J Power Sources,2009,189:45
16 Kokalj A,Dominko R,Mali G,et al.Beyond one-electronreaction in Li cathode materials:Designing Li2MnxFe1-x-SiO4[J].Chem Mater,2007,19:3633
17 Guo H J,Xiang K X,Cao X,et al.Preparation and charac-teristics of Li2FeSiO4/C composite for cathode of lithium ionbatteries[J].Trans Nonferrous Met Soc Chin,2009,19:166
18 Aravindan V,Karthikeyan K,Kang K S,et al.Influence ofcarbon towards improved lithium storage properties ofLi2MnSiO4cathodes[J].J Mater Chem,2011,21:2470
19 Kam K C,Gustafsson T,Thomas J O.Synthesis and elec-trochemical properties of nanostructured Li2FeSiO4/C catho-de material for Li-ion batteries[J].Solid State Ionics,2010,192:356
20 Gong Z L,Li Y X,Yang Y.Synthesis and electrochemicalperformance of Li2CoSiO4as cathode material for lithium ionbatteries[J].J Power Sources,2007,174(2):524
21Li Y X,Gong Z L,Yang Y.Synthesis and characterizationof Li2MnSiO4/C nano-composite cathode material for lithiumion batteries[J].J Power Sources,2007,174(2):528
22 Gong Z L,Li Y X,He G N,et al.NanostructuredLi2FeSiO4electrode material synthesized through hydrother-mal-assisted sol-gel process[J].Electrochem Solid-StateLett,2008,11:A60
23Zhang S,Deng C,Fu B L,et al.Effects of Cr doping on theelectrochemical properties of Li2FeSiO4cathode material forlithium-ion batteries[J].Electrochim Acta,2010,55:8482
24 Deng C,Zhang S,Yang S Y,et al.Synthesis and characte-rization of Li2Fe0.97M0.03SiO4(M=Zn2+,Cu2+,Ni 2+)catho-de materials for lithium ion batteries[J].J PowerSources,2011,196:386
25Saiful Islam M,Robert Dominko,Christian Masquelier,etal.Silicate cathodes for lithium batteries:Alternatives tophosphates?[J].J Mater Chem,2011,21:9811
26 Nishimura S,Hayase S,Kanno R,et al.Structure ofLi2FeSiO4[J].J Am Chem Soc,2008,130:13212
27 Boulineau A,Sirisopanaporn C,Dominko R,et al.Poly-morphism and structural defects in Li2FeSiO4[J].DaltonTrans,2010,39:6310
28Sirisopanaporn C,Boulineau A,Hanzel D,et al.Crystalstructure of a new polymorph of Li2FeSiO4[J].InorgChem,2010,49(16):7446
29 Robert Armstrong A,Navaratnarajah Kuganathan,SaifulIslam M,et al.Structure and lithium transport pathways inLi2FeSiO4cathodes for lithium batteries[J].J Am ChemSoc,2011,133(33):13031
30Sirisopanaporn C,Masquelier C,Bruce P G,et al.Depen-dence of Li2FeSiO4electrochemistry on structure[J].J AmChem Soc,2011,133(5):1263
31 Saraciba A,van der Ven A,Arroyo-de Dompablo M E.Crystal structure,energetics,and electrochemistry ofLi2FeSiO4polymorphs from first principles calculations[J].Chem Mater,2012,24(3):495
32Politaev V V,Petrenko A A,Nalbandyan V B,et al.Crys-tal structure,phase relations and electrochemical propertiesof monoclinic Li2MnSiO4[J].J Solid State Chem,2007,180(3):1045
33 Mali G,Meden A,Dominko R.Li-6 MAS NMR spectrosco-py and first-principles calculations as a combined tool for theinvestigation of Li2MnSiO4polymorphs[J].Chem Com-mun,2010,46(19):3306
34 Arroyo-deDompablo M E,Dominko R,Gallardo-Amores JM,et al.On the energetic stability and electrochemistry ofLi2MnSiO4polymorphs[J].Chem Mater,2008,20:5574
35 Robert Armstrong A,Christopher Lyness,Michel Menet-rier,et al.Structural polymorphism in Li2CoSiO4intercala-tion electrodes:A combined diffraction and NMR study[J].Chem Mater,2010,22:1892
36Lyness C,Delobel B,Armstrong A R,et al.The lithiumintercalation compound Li2CoSiO4and its behaviour as apositive electrode for lithium batteries[J].Chem Commun,2007(46):4890
37Liivat A,Thomas J O.A DFT study of VO43-polyanionsubstitution into the Li-ion battery cathode materialLi2FeSiO4[J].Comput Mater Sci,2010,50:191
38 Kuganathan N,Islam M S.Li2MnSiO4lithium battery ma-terial:Atomic-scale study of defects,lithium mobility,andtrivalent dopants[J].Chem Mater,2009,21:5196