多电子反应高能锂二次电池正极材料的研究进展
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摘要
如何提升正极材料的容量以改善锂离子电池性能是最近研究热点,基于多电子反应机制是提高锂离子电池能量密度的有效途径。综述了近年来基于多电子反应锂离子电池正极材料的研究状况,重点阐述了以聚阴离子型化合物、金属氟化物及单质硫为代表的正极材料的最新研究进展,展望了基于多电子反应体系的构筑对新型化学电源和相关能源材料发展的指导意义。
Recently,how to improve the capacity of anode material to ameliorate the battery performance of lithium ion is a hot spot,based on multi-electron reaction mechanism is a effective way to improve Lithium-ion batteries'energy density.Recent status of Li-ion battery anode material based on multi-electron reaction was overviewed.It was emphatically introduced that the latest research development of representative anode materials,such as polyanionic compounds,metal fluoride and sulfur.Thus the significance of development of secondary batteries based on multi-electron reaction,and their key materials for new chemical battery systems and related energy materials were given.
Recently,how to improve the capacity of anode material to ameliorate the battery performance of lithium ion is a hot spot,based on multi-electron reaction mechanism is a effective way to improve Lithium-ion batteries'energy density.Recent status of Li-ion battery anode material based on multi-electron reaction was overviewed.It was emphatically introduced that the latest research development of representative anode materials,such as polyanionic compounds,metal fluoride and sulfur.Thus the significance of development of secondary batteries based on multi-electron reaction,and their key materials for new chemical battery systems and related energy materials were given.
引文
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[2]Yang J L,Kang X C,Hu L,et al.Nanocrystalline Li2FeSiO4Synthesized by carbon frameworks as an advanced cathode material for Li-ion batteries[J].J Mater Chem A,2014,2(19):6870-6878.
[3]Zhu H,Wu X Z,Zan L,et al.Superior electrochemical capability of Li2FeSiO4/C/G composite as cathode material for Li-ion batteries[J].Electrochim Acta,2014,117(20):34-40.
[4]Li Y,Gong Z,Yang Y.Synthesis and characterization of Li2MnSiO4/C nanocomposite cathode material for lithium ion batteries[J].J Power Sources,2007,174(2):528-532.
[5]邱坤,曹余良,艾新平,等.第17届全国固态离子学学术会议论文摘要集[C].包头:内蒙古科技大学,2014,265.
[6]李东林,马守龙,李严,等.EDTA辅助合成Li2MnSiO4/C纳米复合锂离子电池正极材料及性能[J].无机化学学报,2014,30(5):20156-20162.
[7]Gaubicher J,Wurm C,Goward G,et al.Rhombohedral form of Li3V2(PO4)3as a cathode in Li-ion batteries[J].Chem Mater,2000,12(11):3240-3242.
[8]Lai C,Chen Z,Zhou H,et al.Mn-doped Li3V2(PO4)3nanocrystal with enhanced electrochemical properties based on aerosol synthesis method[J].J Mater Sci,2015,(50):3075-3082.
[9]王艳,刘金玉,焦连升,等.Li3V2(PO4)3正极材料的研究现状与发展[J].河北民族师范学院学报,2015,35(2):56-60.
[10]江虹,徐江海,郭瑞松,等.CeO2与碳共包覆Li3V2(PO4)3正极材料低温电化学性能[J].硅酸盐学报,2016,44(1):6-12.
[11]Duan W,Hu Z,Zhang K,et al.Li3V2(PO4)3@C core-shell nanocomposite as a superior cathode material for lithium-ion batteries[J].Nanoscale,2013,5(14):6485-6490.
[12]Li D,Tian M,Xie R,et al.Three-dimensionally ordered macroporous Li3V2(PO4)3/C nanocomposite cathode material for high-capacity and high-rate Li-ion batteries[J].Nanoscale,2014,6(6):3302-3308.
[13]Zhu X,Yan Z,Wu W,et al.Manipulating size of Li3V2(PO4)3with reduced graphene oxide:towards high-performance composite cathode for lithium ion batteries[J].Sci Rep,2014,4(4):5768.
[14]张艳丽,王莉,何向明,等.铁基氟化物锂电正极材料研究现状[J].储能科学与技术,2016,5(1):44-57.
[15]Fan X L,Luo C,Julia Lamb,et al.PEDOT encapsulated FeOFnanorod cathodes for high energy lithium-ion batteries[J].Nano Lett,2015,15(11),7650-7656.
[16]Bai Y,Zhou X Z,Jia Z,et al.Understanding the combined effects of microcrystal growth and band gap reduction for Fe1-xTixF3nanocomposites as cathode materials for lithium-ion batteries[J].Nano Energy,2015,17(4),140-151.
[17]Chung S H,Manthiram A.A polyethylene glycol-supported microporous carbon coating as a polysulfide trap for utilizing pure sulfur cathodes in lithium-sulfur batteries[J].Advanced Materials,2014,26(43):7352-7357.
[18]陈人杰,赵腾,吴锋,等.高比能锂硫电池正极材料[J].中国科学:化学,2014,44(8):1298-1312.
[19]Manthiram A,Fu Y Z,Su Y S.Challenges and prospects of lithium sulfur batteries[J].Accounts of Chemical Research,2013,46(5):1125-1134.
[20]Chen L,Shaw L L.Recent advances in lithium sulfur batteries[J].Journal of Power Sources,2014,267(3):770-783.
[21]Ding N,Chien S W,Andy H T S.Key parameters in design of lithium sulfur batteries[J].Journal of Power Sources,2014,269(4):111-116.
[22]Song J C,Choo M J,Noh H J,et al.Perfluorinated ionomer-enveloped sulfur cathodes for lithium-sulfur batteries[J].Chem Sus Chem,2014,7(12):3341-3346.
[23]Fang X,Peng H.A revolution in electrodes:recent progress in rechargeable lithium-sulfur batteries[J].Small,2015,11(13):1488-1511.
[24]刁岩,谢凯,洪晓斌,等.Li-S电池硫正极性能衰减机理分析及研究现状概述[J].化学学报,2013,71(4):508-518.
[25]胡菁菁,李国然,高学平.锂/硫电池的研究现状、问题及挑战[J].无机材料学报,2013,28(11):1181-1186.
[26]Zhu J,Yang D,Yin Z,et al.Graphene and graphene-based materials for energy storage applications[J].Small,2014,10(17):3480-3498.
[27]Manthiram A,Fu Y,Chung S,et al.Rechargeable lithium-sulfur batteries[J].Chem Rev,2014,114(23):11751-11787.
[28]Xin S,Yin Y X,Wan L J,et al.Encapsulation of sulfur in a hollow porous carbon substrate for superior Li-S batteries with long lifespan[J].Particle&Particle System Characterization,2013,30(4):321-325.
[29]Z W Seh,Li W Y,Cha J J,et al.Sulphur-TiO2yolk-shell nanoarchitecture with internal void space for long-cycle lithium-sulphur batteries[J].Nature Communications,2013,4(4):1331-1336.