蜜胺纤维的研究进展
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摘要
简述了蜜胺纤维的性能及其国内外研究现状,重点介绍了蜜胺纤维的湿法纺丝、干法纺丝、离心纺丝、静电纺丝、熔融纺丝等纺丝方法;阐述了蜜胺纤维的改性方法如添加增韧剂、降低三聚氰胺的官能度、加入柔性链段或多元共聚改性等方法,以改善其综合性能;并介绍了蜜胺纤维碳化制备多孔富氮碳纤维的方法;展望了蜜胺纤维广阔的应用领域和发展前景。指出我国应加快对蜜胺纤维的开发力度,尽快建成工业化规模的蜜胺纤维生产线,以支撑下游相关产业的快速发展。
The properties of melamine fibers were briefly introduced,as was the research progress of melamine fibers in China and abroad. The spinning methods of melamine fibers were emphatically introduced,including wet spinning,dry spinning,centrifugal spinning,electrostatic spinning,melt spinning. The modification techniques of melamine fibers were described in order to improve their comprehensive properties,such as toughening agent addition,melamine functionality reduction,flexible segment addition or multi-copolymerization modification. The carbonization process for preparing a porous nitrogen-rich carbon fiber from melamine fiber was introduced. The wide application fields and development prospects of melamine fibers were forecasted. It was pointed out that China should enhance the development of melamine fibers and build the commercial melamine fiber production lines as soon as possible in order to support the rapid development of the down-stream industry.
The properties of melamine fibers were briefly introduced,as was the research progress of melamine fibers in China and abroad. The spinning methods of melamine fibers were emphatically introduced,including wet spinning,dry spinning,centrifugal spinning,electrostatic spinning,melt spinning. The modification techniques of melamine fibers were described in order to improve their comprehensive properties,such as toughening agent addition,melamine functionality reduction,flexible segment addition or multi-copolymerization modification. The carbonization process for preparing a porous nitrogen-rich carbon fiber from melamine fiber was introduced. The wide application fields and development prospects of melamine fibers were forecasted. It was pointed out that China should enhance the development of melamine fibers and build the commercial melamine fiber production lines as soon as possible in order to support the rapid development of the down-stream industry.
引文
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[2]罗益锋.高科技合成纤维新进展[J].高科技纤维与应用,2000,25(4):1-8.
[3]高占勇.蜜胺短纤维干法纺丝成套设备的研发[J].国际纺织导报,2012(8):26-28.
[4]汪家铭.三聚氰胺延伸产品蜜胺纤维的国内外技术进展[J].精细化工原料及中间体,2009(1):37-38.
[5]汪家铭.蜜胺纤维发展概况与应用前景[J].化工新型材料,2009,37(7):19-21.
[6]肖倩倩,张生辉,赵雷,等.蜜胺纤维的酸性染料染色[J].印染,2016(6):23-26.
[7]Kent M,朱慧键.Basofil纤维-应用于高温场合的三聚氰胺基纤维[J].产业用纺织品,1995,13(6):30-33.
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[15]Ma P X,Zhang Ruiyun.Synthetic nano-scale fibrous extracellular matrix.[J].J Biomed Mater Res Part B Appl Biomater,1999,46(1):60-72.
[16]Ikegame M,Tajima K,Aida T.Template synthesis of polypyrrole nanofibers insulated within one-dimensional silicate channels:hexagonal versus lamellar for recombination of polarons into bipolarons[J].Angew Chem Int Ed Engl,2003,42(19):2154-2157.
[17]Yang Zhimou,Xu Bing.A simple visual assay based on small molecule hydrogels for detecting inhibitors of enzymes.[J].Chem Commun,2004,10(21):2424-2425.
[18]Li D,Xia Y.Electrospinning of nanofibres:Reinventing the wheel[J].Adv Mater,2004,16(14):1151-1170.
[19]吴宏仁.漫谈熔融纺丝[J].纺织科学研究,1990(2):46-49.
[20]徐建军,施楣梧,姜猛进,等.三聚氰胺甲醛树脂/聚乙烯醇阻燃纤维的制造方法:中国,101016658[P].2007-08-15.
[21]李璐璐,杨彦功.三聚氰胺纤维发展现状及其改性进展[J].合成纤维工业,2014,37(2):56-59.
[22]Xiong Chengdong,Li Xianglong,Hou Teng,et al.Stability and spinnability of modified melamine-formaldehyde resin solution for centrifugal spinning[J].J Appl Polym Sci,2017,135(14):46-72.
[23]杨佳佳.石墨相氮化碳复合材料的制备及光降解性能研究[D].南京:南京理工大学,2017.
[24]Hang Zusheng,Tan Linghua,Cao Xiaomiao,et al.Preparation of melamine microfibers by reaction electrospinning[J].Mater Lett,2011,65(7):1079-1081.
[25]叶喜.改性三聚氰胺-甲醛树脂工艺的研究[J].西南林业大学学报,1997,17(4):43-48.
[26]董书娟,黄司琪,许圣威,等.甲醚化MF改性MF/PVA阻燃纤维的结构与性能[J].合成纤维工业,2011,34(6):21-24.
[27]马超.改性三聚氰胺甲醛树脂增强粘胶纤维的制备及其性能研究[D].天津:天津工业大学,2017.
[28]贺鹏,齐鲁.改性三聚氰胺树脂纤维性能的研究[J].高分子材料科学与工程,2007,23(1):165-168.
[29]杨东昌.改性三聚氰胺树脂与粘胶共混后制备纤维及其性能的分析[D].天津:天津工业大学,2016.
[30]毕慧平.三聚氰胺纤维改性及工艺研究[D].南京:南京理工大学,2004.
[31]李鑫,张寿春,沈小华.新型蜜胺基活性碳纤维的制备研究[J].太原理工大学学报,2016,47(6):696-700.
[32]秦川丽,党新茹,王维杰,等.三聚氰胺甲醛树脂/聚乙烯醇水溶液通过高压静电纺丝技术直接制备含氮碳纤维膜电极的方法:中国,102800490A.3[P].2012-11-28.
[2]罗益锋.高科技合成纤维新进展[J].高科技纤维与应用,2000,25(4):1-8.
[3]高占勇.蜜胺短纤维干法纺丝成套设备的研发[J].国际纺织导报,2012(8):26-28.
[4]汪家铭.三聚氰胺延伸产品蜜胺纤维的国内外技术进展[J].精细化工原料及中间体,2009(1):37-38.
[5]汪家铭.蜜胺纤维发展概况与应用前景[J].化工新型材料,2009,37(7):19-21.
[6]肖倩倩,张生辉,赵雷,等.蜜胺纤维的酸性染料染色[J].印染,2016(6):23-26.
[7]Kent M,朱慧键.Basofil纤维-应用于高温场合的三聚氰胺基纤维[J].产业用纺织品,1995,13(6):30-33.
[8]Blccmberg H.A new flame-retardant fiber[J].Tech Text,1994,37(10):94-97.
[9]Kent G M,Ott K.Melamine-containing fabrics with improved comfort:US,5853880[P].1998-12-29.
[10]Kent G M,Ott K.Melamine-containing fabrics with improved comfort:US,5918453[P].1999-07-06.
[11]Kent G M,Ott K.Melamine-containing fabrics with improved comfort:US,6013366[P].2000-01-11.
[12]李刚,赵昆,唐志有,等.一种蜜胺纤维干法纺丝方法:中国,104831373 A[P].2015-08-12.
[13]Guenther E,Reuther W.Modified melamine-formaldehyde resins:US,5939515[P].1999-08-17.
[14]Lilani H N.Melamine thermal protective fabric and core-spun heat resistant yarn for making the same:EP,0722673 A1[P].1996-07-24.
[15]Ma P X,Zhang Ruiyun.Synthetic nano-scale fibrous extracellular matrix.[J].J Biomed Mater Res Part B Appl Biomater,1999,46(1):60-72.
[16]Ikegame M,Tajima K,Aida T.Template synthesis of polypyrrole nanofibers insulated within one-dimensional silicate channels:hexagonal versus lamellar for recombination of polarons into bipolarons[J].Angew Chem Int Ed Engl,2003,42(19):2154-2157.
[17]Yang Zhimou,Xu Bing.A simple visual assay based on small molecule hydrogels for detecting inhibitors of enzymes.[J].Chem Commun,2004,10(21):2424-2425.
[18]Li D,Xia Y.Electrospinning of nanofibres:Reinventing the wheel[J].Adv Mater,2004,16(14):1151-1170.
[19]吴宏仁.漫谈熔融纺丝[J].纺织科学研究,1990(2):46-49.
[20]徐建军,施楣梧,姜猛进,等.三聚氰胺甲醛树脂/聚乙烯醇阻燃纤维的制造方法:中国,101016658[P].2007-08-15.
[21]李璐璐,杨彦功.三聚氰胺纤维发展现状及其改性进展[J].合成纤维工业,2014,37(2):56-59.
[22]Xiong Chengdong,Li Xianglong,Hou Teng,et al.Stability and spinnability of modified melamine-formaldehyde resin solution for centrifugal spinning[J].J Appl Polym Sci,2017,135(14):46-72.
[23]杨佳佳.石墨相氮化碳复合材料的制备及光降解性能研究[D].南京:南京理工大学,2017.
[24]Hang Zusheng,Tan Linghua,Cao Xiaomiao,et al.Preparation of melamine microfibers by reaction electrospinning[J].Mater Lett,2011,65(7):1079-1081.
[25]叶喜.改性三聚氰胺-甲醛树脂工艺的研究[J].西南林业大学学报,1997,17(4):43-48.
[26]董书娟,黄司琪,许圣威,等.甲醚化MF改性MF/PVA阻燃纤维的结构与性能[J].合成纤维工业,2011,34(6):21-24.
[27]马超.改性三聚氰胺甲醛树脂增强粘胶纤维的制备及其性能研究[D].天津:天津工业大学,2017.
[28]贺鹏,齐鲁.改性三聚氰胺树脂纤维性能的研究[J].高分子材料科学与工程,2007,23(1):165-168.
[29]杨东昌.改性三聚氰胺树脂与粘胶共混后制备纤维及其性能的分析[D].天津:天津工业大学,2016.
[30]毕慧平.三聚氰胺纤维改性及工艺研究[D].南京:南京理工大学,2004.
[31]李鑫,张寿春,沈小华.新型蜜胺基活性碳纤维的制备研究[J].太原理工大学学报,2016,47(6):696-700.
[32]秦川丽,党新茹,王维杰,等.三聚氰胺甲醛树脂/聚乙烯醇水溶液通过高压静电纺丝技术直接制备含氮碳纤维膜电极的方法:中国,102800490A.3[P].2012-11-28.