制备抗硫性负载钯甲烷低温氧化催化剂的研究进展
|
摘要
介绍了耐硫性负载钯甲烷氧化催化剂的研究现状,比较了3种不同的提高催化剂耐硫性的方法。其中,重点介绍了钯硫化物催化剂。该方法是对传统抗硫方法的一次突破,通过以Pd_xS_y组分取代PdO活性相使催化剂具备真正意义上的抗硫性。重点对气相、液相硫化方法进行了概述,并对该领域的研究前景进行了展望。
The recent process of the sulfur-tolerant palladium catalyst for catalytic oxidation of methane is reviewed and compares the difference of three method for improving sulfur tolerance of catalyst.Among them,Pd_xS_y catalyst is emphatically introduced.This method is a breakthrough to the traditional method of sulfur resistance.The catalyst has real sulfur resistance by replacing the PdO activity with PdxSycomponents.The method of vapor phase and liquid phase vulcanization are mainly summarized,and the prospect of the research in this field is proposed as well.
The recent process of the sulfur-tolerant palladium catalyst for catalytic oxidation of methane is reviewed and compares the difference of three method for improving sulfur tolerance of catalyst.Among them,Pd_xS_y catalyst is emphatically introduced.This method is a breakthrough to the traditional method of sulfur resistance.The catalyst has real sulfur resistance by replacing the PdO activity with PdxSycomponents.The method of vapor phase and liquid phase vulcanization are mainly summarized,and the prospect of the research in this field is proposed as well.
引文
[1] Ordóez S,Hurtado P,Sastre H. Methane catalytic combustion over Pd/Al2O3in presence of sulphur dioxide:development of a deactivation model[J]. Applied Catalysis A:General,2004,259(1):41-48.
[2] Ciuparu D,Pfefferle L. Methane combustion activity of supported palladium catalysts after partial reduction[J].Applied Catalysis A-General,2001,218(1/2):197-209.
[3]余倩倩,马磊.含硫气氛下催化剂PdxSy/Si O2催化甲烷低温燃烧反应[J].化工生产与技术,2015(2):12-15.
[4] Persson K,Pfefferle L D,Schwartz W. Stability of palladium-based catalysts during catalytic combustion of methane:The influence of water[J]. Applied Catalysis B-Environmental,2007,74(3/4):242-250.
[5] Hicks R F,Qi H H,Young M L. Effect of catalyst structure on methane oxidation over palladium on alumina[J].Journal of Catalysis,1990,122(2):295-306.
[6] Escandón L S,Ordóez S,Vega A. Sulphur poisoning of palladium catalysts used for methane combustion:Effect of the support[J]. Journal of Hazardous Materials,2008,153(1/2):742-750.
[7] Lampert J K,Kazi M S,Farrauto R J. Palladium catalyst performance for methane emissions abatement from lean burn natural gas vehicles[J]. Applied Catalysis B Environmental,1997,14(3/4):211-223.
[8] Gandhi H S,Shelef M. Effects of sulphur on noble metal automotive catalysts[J]. Applied Catalysis,1991,77(2):175-186.
[9]王录平,杨锡尧,庞礼.担体酸性对铂催化剂的表面性质和催化性能的电子调变效应[J].物理化学学报,1986,2(5):424-431.
[10]肖天存,安立敦,张卫民.负载型贵金属催化剂硫中毒机理——不同载体的钯催化剂上硫的吸附及转化[J].分子催化,1991,5(4):308-315.
[11] Meeyoo V,Trimm D L,Cant N W. The effect of sulphur containing pollutants on the oxidation activity of precious metals used in vehicle exhaust catalysts[J]. Applied Catalysis B:Environmental,1998,16(2):L101-L104.
[12] Meeyoo V,Lee J H,Trimm D L. Hydrogen sulphide emission control by combined adsorption and catalytic combustion[J]. Catalysis Today,1998,44(1/2/3/4):67-72.
[13]薛彬,何洪,戴洪兴.氧化铈和铈锆固溶体对Pd催化剂抗硫性能影响的研究[J].工业催化,2007(9):19-24.
[14] Venezia A M,Carlo G D,Liotta L F,et al. Effect of Ti(IV)loading on CH4oxidation activity and SO2tolerance of Pd catalysts supported on silica SBA-15 and HMS[J].Applied Catalysis B:Environmental,2011,42/43(1/2/3/4):425-428.
[15] Liotta L F,Di Carlo G,Pantaleo G. Pd/Co3O4catalyst for CH4emissions abatement:study of SO2poisoning effect[J]. Topics in Catalysis,2007,42/43(1/2/3/4):425-428.
[16] Liotta L F,Di Carlo G,Pantaleo G. Combined CO/CH4oxidation tests over Pd/Co3O4monolithic catalyst:Effects of high reaction temperature and SO2exposure on the deactivation process[J]. Applied Catalysis B-Environmental,2007,75:182-188.
[17] Corro G,Cano C,Fierro J L G. A study of Pt-Pd/γ-Al2O3catalysts for methane oxidation resistant to deactivation by sulfur poisoning[J]. Journal of Molecular Catalysis A:Chemical,2010,315(1):35-42.
[18] Ryu C K,Ryoo M W,Ryu I S. Catalytic combustion of methane over supported bimetallic Pd catalysts:Effects of Ru or Rh addition[J]. Catalysis Today,1999,47(1/2/3/4):141-147.
[19] Epling W S,Hoflund G B. Catalytic oxidation of methane over Zr O2-supported Pd catalysts[J]. Journal of Catalysis,1999,182(1):5-12.
[20] Hurtadon P,Ordóez S,Sastre H. Combustion of methane over Palladium catalyst in the presence of inorganic compounds:inhibition and deactivation phenomena[J]. Applied Catalysis B:Environmental,2004,47(2):85-93.
[21] Santamaria. Hydrogenation of 1,3-butadiene on Pd/Si O2in presence of H2S. Deactivation and reactivation of the catalyst[J]. Cell Motility&the Cytoskeleton,1992,21(3):187-198.
[22] Zirka A A,Mashkina A V. Liquid-phase hydrogenation of thiophenes on palladium sulfide catalysts[J]. Kinetics and Catalysis,2000,41(3):388-393.
[23] Mashkina A V,Zirka A A. Activity of palladium sulfide catalysts in the reaction of gas-phase hydrogenation of 2-methylthiophene[J]. Kinetics&Catalysis,2000,41(4):521-526.
[24] Yoshimura Y,Toba M,Matsui T. Active phases and sulfur tolerance of bimetallic Pd-Pt catalysts used for hydrotreatment[J]. Applied Catalysis A General,2007,322(4):152-171.
[25] Vázquez A,Pedraza F,Fuentes S. Influence of sulfidation on the morphology and hydrodesulfurization activity of palladium particles on silica[J]. Journal of Molecular Catalysis,1992,75(1):63-70.
[26] Yan H,Yang J,Ma G. Visible-light-driven hydrogen production with extremely high quantum efficiency on PtPd S/Cd S photocatalyst[J]. Journal of Catalysis,2009,266(2):165-168.
[27] Chiang Y Y. Formation of Pd S compounds in direct metallization via Pd/Sn catalyst activation[J]. Journal of the Electrochemical Society,1999,146(9):3255-3258.
[28] Schultz M,Matijevi E. Preparation and properties of nanosized Pd S dispersions for electrolytic plating[J]. Colloids&Surfaces A Physicochemical&Engineering Aspects,1998,131(1/2/3):173-179.
[29]徐伟,张群峰,李小年.炭载硫化钯催化剂的水相合成及其催化性能研究[J].高校化学工程学报,2014(6):1269-1274.
[30]陈安娜,马磊.硫化处理对负载钯催化剂甲烷低温催化燃烧性能的影响[J].工业催化,2013,21(6):22-25.
[2] Ciuparu D,Pfefferle L. Methane combustion activity of supported palladium catalysts after partial reduction[J].Applied Catalysis A-General,2001,218(1/2):197-209.
[3]余倩倩,马磊.含硫气氛下催化剂PdxSy/Si O2催化甲烷低温燃烧反应[J].化工生产与技术,2015(2):12-15.
[4] Persson K,Pfefferle L D,Schwartz W. Stability of palladium-based catalysts during catalytic combustion of methane:The influence of water[J]. Applied Catalysis B-Environmental,2007,74(3/4):242-250.
[5] Hicks R F,Qi H H,Young M L. Effect of catalyst structure on methane oxidation over palladium on alumina[J].Journal of Catalysis,1990,122(2):295-306.
[6] Escandón L S,Ordóez S,Vega A. Sulphur poisoning of palladium catalysts used for methane combustion:Effect of the support[J]. Journal of Hazardous Materials,2008,153(1/2):742-750.
[7] Lampert J K,Kazi M S,Farrauto R J. Palladium catalyst performance for methane emissions abatement from lean burn natural gas vehicles[J]. Applied Catalysis B Environmental,1997,14(3/4):211-223.
[8] Gandhi H S,Shelef M. Effects of sulphur on noble metal automotive catalysts[J]. Applied Catalysis,1991,77(2):175-186.
[9]王录平,杨锡尧,庞礼.担体酸性对铂催化剂的表面性质和催化性能的电子调变效应[J].物理化学学报,1986,2(5):424-431.
[10]肖天存,安立敦,张卫民.负载型贵金属催化剂硫中毒机理——不同载体的钯催化剂上硫的吸附及转化[J].分子催化,1991,5(4):308-315.
[11] Meeyoo V,Trimm D L,Cant N W. The effect of sulphur containing pollutants on the oxidation activity of precious metals used in vehicle exhaust catalysts[J]. Applied Catalysis B:Environmental,1998,16(2):L101-L104.
[12] Meeyoo V,Lee J H,Trimm D L. Hydrogen sulphide emission control by combined adsorption and catalytic combustion[J]. Catalysis Today,1998,44(1/2/3/4):67-72.
[13]薛彬,何洪,戴洪兴.氧化铈和铈锆固溶体对Pd催化剂抗硫性能影响的研究[J].工业催化,2007(9):19-24.
[14] Venezia A M,Carlo G D,Liotta L F,et al. Effect of Ti(IV)loading on CH4oxidation activity and SO2tolerance of Pd catalysts supported on silica SBA-15 and HMS[J].Applied Catalysis B:Environmental,2011,42/43(1/2/3/4):425-428.
[15] Liotta L F,Di Carlo G,Pantaleo G. Pd/Co3O4catalyst for CH4emissions abatement:study of SO2poisoning effect[J]. Topics in Catalysis,2007,42/43(1/2/3/4):425-428.
[16] Liotta L F,Di Carlo G,Pantaleo G. Combined CO/CH4oxidation tests over Pd/Co3O4monolithic catalyst:Effects of high reaction temperature and SO2exposure on the deactivation process[J]. Applied Catalysis B-Environmental,2007,75:182-188.
[17] Corro G,Cano C,Fierro J L G. A study of Pt-Pd/γ-Al2O3catalysts for methane oxidation resistant to deactivation by sulfur poisoning[J]. Journal of Molecular Catalysis A:Chemical,2010,315(1):35-42.
[18] Ryu C K,Ryoo M W,Ryu I S. Catalytic combustion of methane over supported bimetallic Pd catalysts:Effects of Ru or Rh addition[J]. Catalysis Today,1999,47(1/2/3/4):141-147.
[19] Epling W S,Hoflund G B. Catalytic oxidation of methane over Zr O2-supported Pd catalysts[J]. Journal of Catalysis,1999,182(1):5-12.
[20] Hurtadon P,Ordóez S,Sastre H. Combustion of methane over Palladium catalyst in the presence of inorganic compounds:inhibition and deactivation phenomena[J]. Applied Catalysis B:Environmental,2004,47(2):85-93.
[21] Santamaria. Hydrogenation of 1,3-butadiene on Pd/Si O2in presence of H2S. Deactivation and reactivation of the catalyst[J]. Cell Motility&the Cytoskeleton,1992,21(3):187-198.
[22] Zirka A A,Mashkina A V. Liquid-phase hydrogenation of thiophenes on palladium sulfide catalysts[J]. Kinetics and Catalysis,2000,41(3):388-393.
[23] Mashkina A V,Zirka A A. Activity of palladium sulfide catalysts in the reaction of gas-phase hydrogenation of 2-methylthiophene[J]. Kinetics&Catalysis,2000,41(4):521-526.
[24] Yoshimura Y,Toba M,Matsui T. Active phases and sulfur tolerance of bimetallic Pd-Pt catalysts used for hydrotreatment[J]. Applied Catalysis A General,2007,322(4):152-171.
[25] Vázquez A,Pedraza F,Fuentes S. Influence of sulfidation on the morphology and hydrodesulfurization activity of palladium particles on silica[J]. Journal of Molecular Catalysis,1992,75(1):63-70.
[26] Yan H,Yang J,Ma G. Visible-light-driven hydrogen production with extremely high quantum efficiency on PtPd S/Cd S photocatalyst[J]. Journal of Catalysis,2009,266(2):165-168.
[27] Chiang Y Y. Formation of Pd S compounds in direct metallization via Pd/Sn catalyst activation[J]. Journal of the Electrochemical Society,1999,146(9):3255-3258.
[28] Schultz M,Matijevi E. Preparation and properties of nanosized Pd S dispersions for electrolytic plating[J]. Colloids&Surfaces A Physicochemical&Engineering Aspects,1998,131(1/2/3):173-179.
[29]徐伟,张群峰,李小年.炭载硫化钯催化剂的水相合成及其催化性能研究[J].高校化学工程学报,2014(6):1269-1274.
[30]陈安娜,马磊.硫化处理对负载钯催化剂甲烷低温催化燃烧性能的影响[J].工业催化,2013,21(6):22-25.