湘西唐家寨铅锌矿床锶、硫同位素及其对成矿物质来源的指示意义
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摘要
唐家寨铅锌矿床位于湘西龙山—洛塔铅锌矿区的中部。对闪锌矿开展了锶同位素测试分析,通过成矿年龄(372Ma)的校正,得到初始(~(87)Sr/~(86)Sr)i的范围为0.70904~0.71143,平均值为0.70998(n=10),大于矿床形成时的海水Sr同位素,远小于富含有机质的下寒武统石牌组页岩层的Sr同位素,推测成矿流体中的Sr,可能是由具有较低Sr同位素组成的成矿期的海水混染了具有高Sr同位素的下寒武统石牌组页岩层而致。9件闪锌矿和方铅矿样品的δ~(34)SV-CDT值介于14.78‰~17.21‰,平均值为15.84‰,比同期(早奥陶世)海相硫酸盐硫同位素组成的平均值(29.5‰)低13.66‰,符合该矿床成矿温度(100~200℃)条件下硫同位素的分馏效应(10‰~20‰),表明硫化物中还原硫可能主要来源于赋矿地层中海相硫酸盐的热化学还原作用(TSR)。
The Tangjiazhai Pb-Zn deposit is located in the middle of the Longshan-Luota mining field in western Hunan Province,China, and is an important lead and zinc reserve base for Hunan Province. Sr isotope compositions measured for sphalerite were age-corrected by 372 Ma. As a result, the(~(87)Sr/~(86)Sr)ivalues range from 0.70904 to 0.71143 with an average value of 0.70998(n=10) which is higher than that of the seawaterin the mineralized age(372 Ma),and lower than that of Lower Cambrian Shipai Formation shale enriched in organic matter. Speculation can be made is that Sr in ore-forming fluids is sourced from seawater(372 Ma) with relatively lower Sr contaminated high Sr Lower Cambrian Shipai Formation shale. Sphalerite and galena are measured for sulfur isotope composition. The δ~(34)SV-CDTvalues of them have a range from 14.78‰ to 7.21‰ with a mean of 15.84‰(n=9) which is lower13.66‰ than that of the Early Ordovician seawater sulfate. This variation conforms to sulfur isotope fractionation of 10‰-20‰ when the mineralized temperature is from 100 ℃ to 200 ℃.These evidences indicate that the reduced sulfur in the sulfides probably derive from the Thermochemical Sulfate Reduction(TSR) of seawater sulfate within the ore-bearing strata.
The Tangjiazhai Pb-Zn deposit is located in the middle of the Longshan-Luota mining field in western Hunan Province,China, and is an important lead and zinc reserve base for Hunan Province. Sr isotope compositions measured for sphalerite were age-corrected by 372 Ma. As a result, the(~(87)Sr/~(86)Sr)ivalues range from 0.70904 to 0.71143 with an average value of 0.70998(n=10) which is higher than that of the seawaterin the mineralized age(372 Ma),and lower than that of Lower Cambrian Shipai Formation shale enriched in organic matter. Speculation can be made is that Sr in ore-forming fluids is sourced from seawater(372 Ma) with relatively lower Sr contaminated high Sr Lower Cambrian Shipai Formation shale. Sphalerite and galena are measured for sulfur isotope composition. The δ~(34)SV-CDTvalues of them have a range from 14.78‰ to 7.21‰ with a mean of 15.84‰(n=9) which is lower13.66‰ than that of the Early Ordovician seawater sulfate. This variation conforms to sulfur isotope fractionation of 10‰-20‰ when the mineralized temperature is from 100 ℃ to 200 ℃.These evidences indicate that the reduced sulfur in the sulfides probably derive from the Thermochemical Sulfate Reduction(TSR) of seawater sulfate within the ore-bearing strata.
引文
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Du Yudiao,Liu Jiajun,Yu Xinqi,Zhou Xiang,Yang Heming,Yang Longbo.2013.The sources of metallogenic materials and mineralization of the Xiaoyao W-polymetallic deposit in Anhui Province:Evidence from carbon.Sulfur and lead isotopes[J].Geology in China,40(2):566-579(in Chinese with English abstract).
Duan Qifa,Cao Liang,Zeng Jiankang,Zhou Yun,Tang Chaoyang,Li Kun.2014.Rb-Sr dating of sphalerites from Shizishan Pb-Zn deposit in Huayuan ore concentration area,western Hunan and its geological significance[J].Erath Science--Journal of China University of Geosciences,39(8):977-986+999(in Chinese with English abstract).
Kuang Wenlong,Liu Xinhua,Chen Niansheng,Yu Peiran,Chen Xinyue.2008.Main geochemical characteristics of lead-zinc deposits in Xiaguangrong ore district,northwestern Hunan[J].Chinese Journal of Geology,43(4):685-694(in Chinese with English abstract).
Kuang Wenlong,Xiang Shichao,Xiao Wenzhou,Chen Wei,Yang Shaoxiang,Yu Peiran,Chen Niansheng.2015.Metallogenic geological characteristics and genesis of lead-zinc deposit in northwestern Hunan[J].Mineral Deposits,34(5):1072-1082(in Chinese with English abstract).
Li Kun,Wu Changxiong,Tang Chaoyang,Duan Qifa,Yu Yushuai.2014.Carbon and oxygen isotopes of Pb-Zn ore deposits in western Hunan and eastern Guizhou Provinces and their implications for the ore-forming process[J].Geology in China,41(5):1608-1619(in Chinese with English abstract).
Liang Xinquan,Guo Dingliang.2002.Deep tectonic activation and its shallow response in Hunan Province[J].Chinese Journal of Geology,37(3):332-342(in Chinese with English abstract).
Liu Jinsong,Zou Xianwu,Tang Chaoyang,Cui Sen,Xia Jie,Zhao Wuqiang.2015.Geological characteristics of Pb-Zn deposit and prospecting directions in Songtao,Guizhou Province and Jiwei,Hunan Province[J].Geology and Exploration,51(4):634-645(in Chinese with English abstract).
Liu Xuelong,Li Wenchang,Zhang Na,Yang Fucheng,Kang Jian,Zhang Biao.2016.Characteristics of sulfur and lead Isotopes and tracing of mineral sources in the Tongchanggou porphyry Mo(Cu)deposit at the southern edge of Geza arc belt,Yunnan[J].Geology in China,43(1):209-220(in China with English abstract).
Machel H G,Krouse H R,Sassen R.1995.Products and distinguishing criteria of bacterial and thermochemical sulfate reduction[J].Applied Geochemistry,10(4):373-389.
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Mc Arthur J M,Burnett J,Hancock J M.1992.Strontium isotopes at K/T boundary:discussion[J].Nature,355(6355):28.
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Ohmoto H,Kaiser C J,Geer K A.1990.Systematics of sulphur isotopes in recent marine sediments and ancient sediment-hosted basemetal deposits[C]//Herbert H R,Ho S E(eds.).Stable Isotopes and fluid processes in Mineralization,23:70-120.
Ohmoto H,Rye R.1979.Isotopes of sulfur and carbon[C]//Geochemistry of Hydrothermal Ore Deposits,509-567.
Schneider J,Boni M,Lapponi F,Bechst?dt,T.2002.Carbonatehosted zinc-lead deposits in the Lower Cambrian of Hunan,South China:a radiogenic(Pb,Sr)isotope study[J].Economic Geology,97:1815-1827.
Team 405 of bureau of geology and mineral resources of Hunan province.1988.Metallogenic Regularity and its Prediction of Yutang Orefield in Huayuan County Hunan Province[M].Beijing:Geological Publishing House,1-1100(in Chinese).
Wang Xilong,Liu Jiajun,Zhai Degao,Wang Jianping,Zhang Qibin,Zhang Anli.2014.A study of isotope geochemistry and sources of ore-forming materials of the Bianjiadayuan silver polymetallic deposit in Linxi,Inner Mongolia[J].Geology in China,41(4):1288-1303(in Chinese with English abstract).
Wang Yunfeng,Yang Hongmei.2016.Sulfur isotope tracing of oreforming hydrothermal fluid for metallic sulfide deposit[J].Advances in Earth Science,31(6):595-602(in Chinese with English abstract).
Wang Yunfeng,Yang Hongmei,Qiu Xiaofei,Lu Shansong,Cai Yingxiong.2016.Ore-forming materials sources of the Shizishan Pb-Zn deposit in western Hunan Province,China[J].Acta Geological Sinica(English Edition),90(5):1929-1930.
Wen Kedong,Li Guozhen,Liu Haotian.2011.Analysis on Shale Gasforming condition of Lower Cambrian in middle Yangtze Block[J].Petroleum Technology of Jianghan,21(3):1-5(in Chinese).
Wu Genyao.2002.The Yanshanian orogeny and late Mesozoic activation in China continent[J].Chinese Journal of Geology,37(4):453-461(in Chinese with English abstract).
Yang Shaoxiang,Lao Ketong.2007a.A tentative discussion on genesis of lead-zinc deposits in northwest Hunan[J].Mineral Deposits,26(3):330-340(in Chinese with English abstract).
Yang Shaoxiang,Lao Ketong.2007b.Geological characteristics and ore indicators of lead-zinc deposits in northwestern Hunan,China[J].Geological Bulletin of China,26(7):899-908(in Chinese with English abstract).
Yang Shaoxiang,Yu Peiran,Lao Ketong.2006.Pb-Zn deposits metallogenic regularity and prospecting direction in northwestern of Hunan,China[J].Land and Resources Herald,92-98(in Chinese).
Zheng Yongfei,Chen Jiangfeng.2000.Stable Isotope Geochemistry[M].Beijing:Science Press,1-468.
Zhou Yun,Duan Qifa,Chen Yuchuan,Tang Juxing,Cao Liang,Gan Jinmu.2015.Rb-Sr dating and tracer study of quartz from the Jiangjiaya lead-zinc deposit in western Hunan[J].Geology in China,42(2):597-606(in Chinese with English abstract).
鲍珏敏,张安源.1989.湘西北龙山铅锌矿带沉积相及成矿作用[J].桂林冶金地质学院学报,9(4):309-410.
蔡春芳,李宏涛.2005.沉积盆地热化学硫酸盐还原作用评述[J].地球科学进展,20(10):1100-1105.
蔡应雄,杨红梅,段瑞春,卢山松,张利国,刘重芃,邱啸飞.2014.湘西-黔东下寒武统铅锌矿床流体包裹体和硫,铅,碳同位素地球化学特征[J].现代地质,28(1):29-41.
陈奋宁,计文化,张海军,陈守建,辜平阳,杜兵盈.2016.唐古拉地区拉卜查日组牙形石的发现、锶同位素组成及地层学意义[J].中国地质,43(4):1139-1148.
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