航空航天用镁合金的研究进展
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摘要
基于航空航天结构轻量化发展的需求,对高性能镁合金的研究进展进行了回顾,重点介绍了AZ系、ZK系、Mg-RE系和Mg-Li系合金在航空航天领域的研究进展与应用现状。综述了先进镁合金研发的技术与应用瓶颈,以及目前最常用的合金化和热处理等合金性能改进方法,介绍了镁合金研究在未来航空航天领域的发展趋势。
In recent years, structural light-mass design of aerospace parts is urgently summoned in the aerospace area. This paper reviews the high-performance magnesium alloys related to this area. It introduces research progress and applications of many series magnesium alloys, such as AZ, ZK, Mg-RE, Mg-Li, as well as obstacles of their current development in terms of technology and applications. The alloy performance improving methods of alloying and heat-treating for these magnesium alloys are reviewed. The future development trends of magnesium alloys in the aerospace area are also proposed.
In recent years, structural light-mass design of aerospace parts is urgently summoned in the aerospace area. This paper reviews the high-performance magnesium alloys related to this area. It introduces research progress and applications of many series magnesium alloys, such as AZ, ZK, Mg-RE, Mg-Li, as well as obstacles of their current development in terms of technology and applications. The alloy performance improving methods of alloying and heat-treating for these magnesium alloys are reviewed. The future development trends of magnesium alloys in the aerospace area are also proposed.
引文
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[7] ALSUBAIE S A,HUANG Y,LANGDON T G.Hardness evolution of AZ80 magnesium alloy processed by HPT at different temperatures[J].Journal of Materials Research and Technology,2017,6(4):378-384.
[8] XU N,BAO Y F,SHEN J.Enhanced strength and ductility of high pressure die casting AZ91D Mg alloy by using cold source assistant friction stir processing[J].Materials Letters,2017,190:24-27.
[9] 颜孙荣,金涛.AZ91铸造镁合金屈服行为的实验研究[J].科学技术与工程,2017,17(26):1-7.
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[11] 丁文江,付彭怀,彭立明,等.先进镁合金材料及其在航空航天领域中的应用[J].航天器环境工程,2011,28(2):103-109.
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[38] 王斌,易丹青,罗文海,等.SEM原位观察ZK60(0.9Y)镁合金板材的断裂行为[J].北京科技大学学报,2009,31(5):585-590.
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[42] 李大全.Mg-Y-Sm-Zr系镁合金组织性能研究[D].上海:上海交通大学,2008.
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[45] 蒲治军,陈东杰,张奎,等.关于镁合金中长周期有序结构的研究综述[J].材料导报,2017,31(7):79-93.
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[2] 赵怿,董刚,赵博.镁合金在航空领域应用的研究进展[J].有色金属工程,2015,5(2):23-27.
[3] WESTENGEN H,RASHED H M M A.Magnesium alloys:properties and applications[J].Reference Module in Materials Science Engineering,2016:1-8.
[4] LIU Y,LI F,LI X W,et al.Properties of rolled AZ31 magnesium alloy sheet fabricated by continuous variable cross-section direct extrusion[J].Journal of Materials Engineering and Performance,2018,27(4):1-9.
[5] HU H J,SUN Z.Microstructure evolution during extrusion-shear process of as cast AZ31 magnesium alloy[J].Physics of Metals and Metallography,2018,119(7):627-633.
[6] LIU W J,JIANG B,LUO S Q,et al.Mechanical properties and failure behavior of AZ61 magnesium alloy at high temperatures[J].Journal of Materials Science,2018,53(11):8536-8544.
[7] ALSUBAIE S A,HUANG Y,LANGDON T G.Hardness evolution of AZ80 magnesium alloy processed by HPT at different temperatures[J].Journal of Materials Research and Technology,2017,6(4):378-384.
[8] XU N,BAO Y F,SHEN J.Enhanced strength and ductility of high pressure die casting AZ91D Mg alloy by using cold source assistant friction stir processing[J].Materials Letters,2017,190:24-27.
[9] 颜孙荣,金涛.AZ91铸造镁合金屈服行为的实验研究[J].科学技术与工程,2017,17(26):1-7.
[10] 吴国华,陈玉狮,丁文江.镁合金在航空航天领域研究应用现状与展望[J].载人航天,2016,22(3):281-292.
[11] 丁文江,付彭怀,彭立明,等.先进镁合金材料及其在航空航天领域中的应用[J].航天器环境工程,2011,28(2):103-109.
[12] 王目孔,孙建新,刘新超.铸造镁合金研究与应用进展[J].有色金属,2012(2):56-59.
[13] 刘睿辰.浅谈航空航天工程中的合金材料[J].中国战略新兴产业,2018(4):170.
[14] 宋佩维,井晓天,郭学锋.往复挤压Mg-4Al-2Si镁合金的组织细化与力学性能[J].中国有色金属学报,2007,17(1):111-117.
[15] KIM J J,KIM D H,SHIN K S,et al.Modification of Mg2Si morphology in squeeze cast Mg-Al-Zn-Si alloys by Ca or P addition[J].Scripta Materialia,1999,41(3):333-340.
[16] 高爱华,张建新.热处理对往复挤压Mg-Sn-Al-Zn-Si合金组织与性能的影响[J].金属热处理,2018,43(1):215-220.
[17] YAGI S,SENGOKU A,KUBOTA K,et al.Surface modification of ACM522 magnesium alloy by plasma electrolytic oxidation in phosphate electrolyte[J].Corrosion Science,2012,57(2):74-80.
[18] YAGI S,KUWABARA K,FUKUTA Y,et al.Formation of self-repairing anodized film on ACM522 magnesium alloy by plasma electrolytic oxidation[J].Corrosion Science,2013,73(13):188-195.
[19] BARIL E,LABELLE P,PEKGULERYUZ M.Elevated temperature Mg-Al-Sr:creep resistance,mechanical properties,and microstructure[J].Journal of the Minerals,Metals & Materials Society,2003,55(11):34-39.
[20] TONG G D,LIU H F,LIU Y H.Effect of rare earth additions on microstructure and mechanical properties of AZ91 magnesium alloys[J].Transactions of Nonferrous Metals Society of China,2010,20(Suppl 2):336-340.
[21] LIN H,YANG M B,TANG H,et al.Effect of minor Sc on the microstructure and mechanical properties of AZ91 magnesium alloy[J].Progress in Natural Science:Materials International,2018,28(1):66-73.
[22] ZHANG D D,ZHANG D P,BU F Q,et al.Effects of minor Sr addition on the microstructure,mechanical properties and creep behavior of high pressure die casting AZ91-0.5RE based alloy[J].Materials Science and Engineering:A,2017,693:51-59.
[23] 周谢,黄鹿,李琴.铒对铸态AZ91D镁合金腐蚀的影响[J].稀土,2018,39(1):127-131.
[24] SONG Y L,WANG Z,LIU Y H,et al.Influence of erbium,cerium on the stress corrosion cracking behavior of AZ91 alloy in humid atmosphere[J].Advanced Engineering Materials,2017,19(7):17-21.
[25] CHEN X H,LIU L Z,PAN F S.Strength improvement in ZK60 magnesium alloy induced by pre-deformation and heat treatment[J].Journal of Wuhan University of Technology (Materials Science Edition),2016,31(2):393-398.
[26] 王贵生.热处理工艺对轧制ZK60镁合金的微观组织和高周疲劳性能影响[D].太原:太原理工大学,2016.
[27] CHEN W Z,WANG X,HU L X,et al.Fabrication of ZK60 magnesium alloy thin sheets with improved ductility by cold rolling and annealing treatment[J].Materials & Design,2012,40:319-323.
[28] 李艳,张治民,薛勇.时效处理对AZ80和ZK60镁合金微观组织和力学性能的影响[J].中国有色金属学报,2011,21(4):739-744.
[29] 臧千昊,刘忠明,陈洪美,等.热处理对双辊铸轧ZK60镁合金组织及阻尼性能的影响[J].稀有金属材料与工程,2016,45(6):1578-1582.
[30] 陈立佳,徐海健,车欣,等.热处理对挤压变形Mg-7%Zn-0.6%Zr镁合金疲劳性能的影响[J].材料热处理学报,2013,34(11):17-20.
[31] DING R G,CHUNG C W,CHIU Y L.Microstructure and mechanical property of ECAPed ZE41 magnesium alloy[J].Journal of Physics Conference Series,2010,241(1):012105.
[32] SIEBERT-TIMMER A,FLETCHER M,BICHLER L,et al.Creep performance of wrought AX30 and EZ33 magnesium alloys[J].Canadian Metallurgical Quarterly,2013,52(4):430-438.
[33] RYSPAEV T,TROJANOVá Z,PADALKA O,et al.Microstructure of superplastic QE22 and EZ33 magnesium alloys[J].Materials Letters,2008,62(24):4041-4043.
[34] 刘莉滋.合金化对Mg-Zn-Zr镁合金电磁屏蔽性能和力学性能的影响[D].重庆:重庆大学,2015.
[35] 曾祥亮.合金元素Cd和Nd对ZK60镁合金力学性能及腐蚀性能的影响[D].长沙:中南大学,2009.
[36] 王忠军,付学丹.稀土Er对ZK60镁合金变形行为的影响[J].辽宁科技大学学报,2016,39(3):181-190.
[37] 胡林,王斌,周玲伶,等.稀土元素Y和Nd对ZK60合金组织与性能的影响[J].有色金属设计,2015,42(2):25-28.
[38] 王斌,易丹青,罗文海,等.SEM原位观察ZK60(0.9Y)镁合金板材的断裂行为[J].北京科技大学学报,2009,31(5):585-590.
[39] 吴伟,张禄廷,陈立佳,等.通道角度挤压对两种镁合金拉伸性能的影响[J].沈阳工业大学学报,2003,25(1):18-22.
[40] 兴成尧.Mg-Y-Nd-xGd 稀土镁合金的组织与性能[D].哈尔滨:哈尔滨工业大学,2007.
[41] 刘志杰.砂型铸造Mg-4Y-2Nd-1Gd 镁合金微观组织与力学行为研究[D].上海:上海交通大学,2013.
[42] 李大全.Mg-Y-Sm-Zr系镁合金组织性能研究[D].上海:上海交通大学,2008.
[43] 黄丽华,张涛,章晓波.热处理和挤压对WE53镁合金组织与力学性能的影响[J].有色金属科学与工程,2014,5(6):67-70.
[44] 陈巧旺,汤爱涛,许婷熠,等.高性能铸造稀土镁合金的发展[J].材料导报,2016,30(17):1-9.
[45] 蒲治军,陈东杰,张奎,等.关于镁合金中长周期有序结构的研究综述[J].材料导报,2017,31(7):79-93.
[46] ZHU Y M,MORTON A J,NIE J F.The 18R and 14H long-period stacking ordered structures in Mg-Y-Zn alloys[J].Acta Materialia,2010,58(8):2936-2947.
[47] LIU H,BAI J,YAN K,et al.Comparative studies on evolution behaviors of 14H LPSO precipitates in as-cast and as-extruded Mg-Y-Zn alloys during annealing at 773 K[J].Materials & Design,2016,93:9-18.
[48] 李亚妮.高性能Mg-Gd-Y-Zn-Mn合金组织与力学性能研究[D].重庆:重庆大学,2014.
[49] 黄秀洪.挤压、轧制变形对高强度Mg-Gd-Y-Zn-Mn合金组织性能的影响研究[D].重庆:重庆大学,2015.
[50] 邓娟.Mg-xGd-0.6Zr合金组织与性能研究[D].重庆:重庆大学,2010.
[51] 小岛阳.镁锂合金[J].金属,1987,57(5):14-15.
[52] HAUSER F E,LANDON P R,DORN J E.Deformation and fracture of alpha solid solutions of lithium in magnesium[J].Transactions of ASM,1958,50:856-883.
[53] AGNEW S R,YOO M H,TOME C N.Application of texture simulation to understanding mechanical behavior of Mg and solid solution alloys containing Li or Y[J].Acta Materialia,2001,49(20):4277-4289.
[54] JACKSON R J,FROST P D.Properties and current applications of magnesium-lithium alloys[R].NASA,SP-5068,1967.
[55] GALANOV A,TATAKIN A N,ELKIN F M.Russian magnesium alloys[J].Light Metal Age,2002(9/10):44-47.
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