纳米光催化剂处理难降解性有机物的研究进展
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摘要
难降解性有机物来源广泛,性质稳定,能在环境中长期残留,对人类健康和生态环境造成危害。纳米光催化剂因其氧化性强、分解率高、低价安全等优点,在处理难降解性有机物的研究和应用上备受关注。综述了难降解性有机物处理技术的研究现状,阐述了纳米光催化剂处理难降解性有机物的机理和研究进展,并预测了未来光催化技术的发展方向。
With a wide range of sources and stable property,refractory organic matter can remain in the environment for a long time,which is harmful to human health and the ecological environment.Nano-photocatalyst has attracted wide attentions in the research and application of decomposing refractory organic compounds,because of its strong oxidizing property,high decomposition rate,low cost and safety.The research status of refractory organic treatment technologies were reviewed.The mechanism and research progress of nano-photocatalyst for treating refractory organic compounds were described.Finally,the development direction of photocatalytic technology in the future was predicted.
With a wide range of sources and stable property,refractory organic matter can remain in the environment for a long time,which is harmful to human health and the ecological environment.Nano-photocatalyst has attracted wide attentions in the research and application of decomposing refractory organic compounds,because of its strong oxidizing property,high decomposition rate,low cost and safety.The research status of refractory organic treatment technologies were reviewed.The mechanism and research progress of nano-photocatalyst for treating refractory organic compounds were described.Finally,the development direction of photocatalytic technology in the future was predicted.
引文
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[3]徐璇.基于难降解有机污染物特性的光催化-生化废水处理技术[D].重庆:重庆大学,2010.
[4]范子红.SDS-CuO/TiO2光催化剂的制备和污水处理性能实验研究[D].重庆:重庆大学,2009.
[5]黄进,魏世强.多环芳烃的环境效应及其生物标志物在环境风险评价中的应用[J].河南预防医学,2003,14(6):370-374.
[6]孙雪景,王静,焦岩,等.废水中难降解有机物共代谢实验研究[J].吉林建筑工程学院学报,2011,28(6):28-31.
[7]韩柱.低度泄漏特征污染物在居民区扩散过程的模拟研究[D].青岛:青岛科技大学,2011.
[8]赵山峰.黄河水污染事件应急调查监测及水利工程处置措施研究[D].郑州:郑州大学,2011.
[9]张灵.鱼类毒理蛋白质组学研究进展:以海洋青鳉鱼和斑马鱼为例[J].海洋环境科学,2015,34(4):616-621.
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[13]张文浩,王江涛,谭丽菊,等.山东半岛南部近海海水及动物石油烃污染状况[J].海洋环境科学,2010,29(3):378-381.
[14]刘小真,周文斌,胡利娜,等.鄱阳湖区洲滩底质有机氯农药的垂直污染特征[J].生态环境,2008,17(4):1348-1353.
[15]丁真真.难降解有机物废水的处理方法研究现状[J].甘肃科技,2006,22(2):113-115.
[16]喻胜飞.填充活性炭的壳聚糖复合超滤膜的研究[J].化学工程师,2006(11):15-18.
[17]马江权,郭楠,许守勇,等.微滤/纳滤联用技术深度处理印染废水[J].水处理技术,2010,36(9):65-68,100.
[18]金重阳,刘辉,荆志严,等.活性炭纤维处理含多氯联苯废水的研究[J].环境保护科学,1997,23(3):6-7.
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[20]胡学伟.超声-催化氧化-生物组合技术处理垃圾渗滤液的研究[D].昆明:昆明理工大学,2004.
[21]Aivarez P J J,Vogel T M.Degradation of BTEX and their aerobic metablelites by indigenous microorganisms under nitrate reducing condition[J].Wat Sci Tech,1995,31(1):15-18.
[22]周应坤,何成达,卢勇,等.利用缺氧反硝化降解硝基苯的试验[J].水资源保护,2009,25(4):64-66,85.
[23]Kavita G M,David S K.Anaerobic biodegradation of toluene under denitrifying conditions in contaminated groundwater and soil[J].Jour-nal of Hazardous Materials,1996,45:219-232.
[24]陈璐,曾韬,李竹,等.纳米TiO2光催化臭氧化技术在处理难降解有机废水中的应用[J].环境工程,2014,32(S1):125-129.
[25]Fujishima A,Honda K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,37:238-245.
[26]Carey John H.Photodechlorination of PCB's in the presence of titanium dioxide in aqueous suspensions[J].Bull Environ Contam Toxic,1976,16(6):697-701.
[27]Frank S N,Bard A J.Heterogenerous photocatalytic oxidation of cyanide and sulfite in aqueous solutions at semiconductor powder[J].Phys Chem,1977,81(15):1484-1488.
[28]李和兴,朱建.特定结构光催化剂的制备及其构效关系[J].催化学报,2008,14(1):91-98.
[29]Nakata K,Fujishima A.TiO2photocatalysis:design and applications[J].Journal of Photochemistry and Photobiology C(Photochemistry Reviews),2012,13(3):169-189.
[30]赵奇峰,刘宏菊.液相光催化降解有机污染物的研究与进展[J].油气田环境保护,2006(2):39-44,62.
[31]郭光美.纳米TiO2/ZnO复合光催化材料的合成、结构分析及应用[D].保定:河北大学,2004.
[32]黄徽,王超,杨平,等.Bi掺杂介孔CeO2的制备及其可见光催化性能[J].南京工业大学学报(自然科学版),2013,35(6):103-108.
[33]赵占中,谢银德,张冰,等.掺杂改性TiO2可见光光催化剂研究的最新进展[J].硅酸盐通报,2012,31(1):92-95,105.
[34]王伟,王吟,王学江,等.TiO2光催化剂掺杂及负载改性研究进展[J].水处理技术,2013,39(3):1-5.
[35]胡晓洪.炭吸附材料负载掺杂纳米TiO2的制备及其降解有机污染物的研究[D].广州:中国科学院研究生院(广州地球化学研究所),2007.
[36]刘亮,吕珺,李云,等.纳米TiO2/凹凸棒石光催化复合材料的制备及其动力学[J].过程工程学报,2011,11(1):117-123.
[37]徐广飞.纳米Fe3O4及磁性光催化复合材料SnO2/Fe3O4的制备和性能研究[D].杭州:浙江工业大学,2012.
[38]席北斗,刘鸿亮.高效负载型光催化剂制备及其加铂修饰技术[J].环境科学,2002,23(1):66-69.
[39]许怡学,廉世勋,阎建辉,等.贵金属沉积CuO的可见光催化产氢性能[J].湖南理工学院学报(自然科学版),2011,24(3):53-57,82.
[40]楚婷婷.贵金属可控制性沉积及其对CdS可见光分解水产氢的影响[D].郑州:河南大学,2013.
[41]Ming H,Ma Z,Huang,H,et al.Nanoporous TiO2 spheres with narrow pore size distribution and improved visible light photocatalytic abilities[J].Chemical Communications,2011(28),8025-8027.
[42]张伟.TiO2光敏化研究进展[J].广东化工,2009,36(11):94-97.
[43]蔡金华,黄锦汪,叶元坚,等.卟啉敏化二氧化钛复合微球的制备及其光催化性能[J].催化学报,2009,30(5):440-446.
[44]朱红乔.染料光敏化TiO2及赤铁矿光电催化氧化As(Ⅲ)[D].杭州:浙江大学,2014.
[45]Chio W,Termin A,Hoffman M R,et al.The role of metal ion dopants in quantum-sized TiO2:correlation between photoreactivity and charge carrier recombination dynamics[J].J Phys Chem,1994,98(51):13669-13679.
[46]Liang C H,Li F B,Liu C S,et al.The enhancement of adsorption and photocatalytic activity of rare earth ions doped TiO2for the degradation of orange I[J].Dyes And Pigments,76(2),477-484.
[47]潘仲巍,郭燕红,张秋君,等.掺杂镧铒对纳米二氧化钛薄膜光催化性能的影响[J].商丘师范学院学报,2008,24(9):65-69.
[48]高岳君,许宜铭.氟离子掺杂和吸附对二氧化钛光催化活性的影响[J].物理化学学报,2012,28(3):641-646.
[2]Radjenovic J,Petrovic M,Barcelo D.Advanced mass,spectrometric methods applied to the study of fate and removal of pharmaceuticals in wastewater treatment[J].Trac-Trends In Analytical Chemistry,2007,26(11):1132-1144.
[3]徐璇.基于难降解有机污染物特性的光催化-生化废水处理技术[D].重庆:重庆大学,2010.
[4]范子红.SDS-CuO/TiO2光催化剂的制备和污水处理性能实验研究[D].重庆:重庆大学,2009.
[5]黄进,魏世强.多环芳烃的环境效应及其生物标志物在环境风险评价中的应用[J].河南预防医学,2003,14(6):370-374.
[6]孙雪景,王静,焦岩,等.废水中难降解有机物共代谢实验研究[J].吉林建筑工程学院学报,2011,28(6):28-31.
[7]韩柱.低度泄漏特征污染物在居民区扩散过程的模拟研究[D].青岛:青岛科技大学,2011.
[8]赵山峰.黄河水污染事件应急调查监测及水利工程处置措施研究[D].郑州:郑州大学,2011.
[9]张灵.鱼类毒理蛋白质组学研究进展:以海洋青鳉鱼和斑马鱼为例[J].海洋环境科学,2015,34(4):616-621.
[10]程瑛.中国台湾食用油脂工业概况[J].中国台湾农业情况,1985(4):15-14.
[11]寿鹿,赵倩,徐晓群,等.难降解有机物对海洋生物影响的研究进展[J].海洋开发与管理,2008,25(5):86-89.
[12]杨丹,卢冰,潘建明,等.南极企鹅粪土地层、机体组织与卵中POPs含量分布及其生态环境意义[J].环境科学研究,2009,22(4):427-433.
[13]张文浩,王江涛,谭丽菊,等.山东半岛南部近海海水及动物石油烃污染状况[J].海洋环境科学,2010,29(3):378-381.
[14]刘小真,周文斌,胡利娜,等.鄱阳湖区洲滩底质有机氯农药的垂直污染特征[J].生态环境,2008,17(4):1348-1353.
[15]丁真真.难降解有机物废水的处理方法研究现状[J].甘肃科技,2006,22(2):113-115.
[16]喻胜飞.填充活性炭的壳聚糖复合超滤膜的研究[J].化学工程师,2006(11):15-18.
[17]马江权,郭楠,许守勇,等.微滤/纳滤联用技术深度处理印染废水[J].水处理技术,2010,36(9):65-68,100.
[18]金重阳,刘辉,荆志严,等.活性炭纤维处理含多氯联苯废水的研究[J].环境保护科学,1997,23(3):6-7.
[19]林中祥,程康华.萃取法去除硝基苯生产废水中的硝基酚[J].环境导报,2000(2):18-20.
[20]胡学伟.超声-催化氧化-生物组合技术处理垃圾渗滤液的研究[D].昆明:昆明理工大学,2004.
[21]Aivarez P J J,Vogel T M.Degradation of BTEX and their aerobic metablelites by indigenous microorganisms under nitrate reducing condition[J].Wat Sci Tech,1995,31(1):15-18.
[22]周应坤,何成达,卢勇,等.利用缺氧反硝化降解硝基苯的试验[J].水资源保护,2009,25(4):64-66,85.
[23]Kavita G M,David S K.Anaerobic biodegradation of toluene under denitrifying conditions in contaminated groundwater and soil[J].Jour-nal of Hazardous Materials,1996,45:219-232.
[24]陈璐,曾韬,李竹,等.纳米TiO2光催化臭氧化技术在处理难降解有机废水中的应用[J].环境工程,2014,32(S1):125-129.
[25]Fujishima A,Honda K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,37:238-245.
[26]Carey John H.Photodechlorination of PCB's in the presence of titanium dioxide in aqueous suspensions[J].Bull Environ Contam Toxic,1976,16(6):697-701.
[27]Frank S N,Bard A J.Heterogenerous photocatalytic oxidation of cyanide and sulfite in aqueous solutions at semiconductor powder[J].Phys Chem,1977,81(15):1484-1488.
[28]李和兴,朱建.特定结构光催化剂的制备及其构效关系[J].催化学报,2008,14(1):91-98.
[29]Nakata K,Fujishima A.TiO2photocatalysis:design and applications[J].Journal of Photochemistry and Photobiology C(Photochemistry Reviews),2012,13(3):169-189.
[30]赵奇峰,刘宏菊.液相光催化降解有机污染物的研究与进展[J].油气田环境保护,2006(2):39-44,62.
[31]郭光美.纳米TiO2/ZnO复合光催化材料的合成、结构分析及应用[D].保定:河北大学,2004.
[32]黄徽,王超,杨平,等.Bi掺杂介孔CeO2的制备及其可见光催化性能[J].南京工业大学学报(自然科学版),2013,35(6):103-108.
[33]赵占中,谢银德,张冰,等.掺杂改性TiO2可见光光催化剂研究的最新进展[J].硅酸盐通报,2012,31(1):92-95,105.
[34]王伟,王吟,王学江,等.TiO2光催化剂掺杂及负载改性研究进展[J].水处理技术,2013,39(3):1-5.
[35]胡晓洪.炭吸附材料负载掺杂纳米TiO2的制备及其降解有机污染物的研究[D].广州:中国科学院研究生院(广州地球化学研究所),2007.
[36]刘亮,吕珺,李云,等.纳米TiO2/凹凸棒石光催化复合材料的制备及其动力学[J].过程工程学报,2011,11(1):117-123.
[37]徐广飞.纳米Fe3O4及磁性光催化复合材料SnO2/Fe3O4的制备和性能研究[D].杭州:浙江工业大学,2012.
[38]席北斗,刘鸿亮.高效负载型光催化剂制备及其加铂修饰技术[J].环境科学,2002,23(1):66-69.
[39]许怡学,廉世勋,阎建辉,等.贵金属沉积CuO的可见光催化产氢性能[J].湖南理工学院学报(自然科学版),2011,24(3):53-57,82.
[40]楚婷婷.贵金属可控制性沉积及其对CdS可见光分解水产氢的影响[D].郑州:河南大学,2013.
[41]Ming H,Ma Z,Huang,H,et al.Nanoporous TiO2 spheres with narrow pore size distribution and improved visible light photocatalytic abilities[J].Chemical Communications,2011(28),8025-8027.
[42]张伟.TiO2光敏化研究进展[J].广东化工,2009,36(11):94-97.
[43]蔡金华,黄锦汪,叶元坚,等.卟啉敏化二氧化钛复合微球的制备及其光催化性能[J].催化学报,2009,30(5):440-446.
[44]朱红乔.染料光敏化TiO2及赤铁矿光电催化氧化As(Ⅲ)[D].杭州:浙江大学,2014.
[45]Chio W,Termin A,Hoffman M R,et al.The role of metal ion dopants in quantum-sized TiO2:correlation between photoreactivity and charge carrier recombination dynamics[J].J Phys Chem,1994,98(51):13669-13679.
[46]Liang C H,Li F B,Liu C S,et al.The enhancement of adsorption and photocatalytic activity of rare earth ions doped TiO2for the degradation of orange I[J].Dyes And Pigments,76(2),477-484.
[47]潘仲巍,郭燕红,张秋君,等.掺杂镧铒对纳米二氧化钛薄膜光催化性能的影响[J].商丘师范学院学报,2008,24(9):65-69.
[48]高岳君,许宜铭.氟离子掺杂和吸附对二氧化钛光催化活性的影响[J].物理化学学报,2012,28(3):641-646.