石墨烯类复合材料电磁屏蔽研究进展
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摘要
石墨烯作为新兴碳质材料,因其优异的力学性能、电学性能和热学性能,已成为材料领域研究的热点。而石墨烯本身即具有吸收电磁波的能力,所以其在电磁屏蔽领域也将成为重要的研究对象。本文主要介绍了石墨烯的来源、改性方法,以及电磁屏蔽的原理和计算方法,同时综述了近几年石墨烯类复合材料电磁屏蔽的研究进展。
Graphene as a new carbon material, has become a hot topic in the fi eld of materials because of its excellent mechanical, electrical and thermal properties. Graphene itself has the ability to absorb electromagnetic waves, so graphene will become an important research object in the fi eld of electromagnetic shielding. In this paper, the source of graphene, the modifi cation method, the principle and calculation method of electromagnetic shielding were introduced, and the research progress of the electromagnetic shielding of graphene-based composites was reviewed.
Graphene as a new carbon material, has become a hot topic in the fi eld of materials because of its excellent mechanical, electrical and thermal properties. Graphene itself has the ability to absorb electromagnetic waves, so graphene will become an important research object in the fi eld of electromagnetic shielding. In this paper, the source of graphene, the modifi cation method, the principle and calculation method of electromagnetic shielding were introduced, and the research progress of the electromagnetic shielding of graphene-based composites was reviewed.
引文
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[28]Stankovich S,Piner R D,Nguyen S T,et al.Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets[J].Carbon,2006,44(15):3 342-3 347.
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[32]蒋静,贾红兵,王经逸,等.石墨烯/聚合物复合材料的研究进展[J].合成橡胶工业,2011,34(6):482-488.
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[35]Wu F F,Lu Y G,Shao G L,et al.Preparation of polyacrylonitrile/graphene oxide by in situ polymerization[J].Polym Int,2012,61(9):1 394-1 399.
[36]陈宇,张好斌,于中振.聚合物/石墨烯纳米复合材料电磁屏蔽研究进展[J].安全与电磁兼容,2016(5):49-85.
[37]袁冰清,郁黎明,盛雷梅.石墨烯/聚苯胺复合材料的电磁屏蔽性能[J].复合材料学报,2013,30(1):22-26.
[38]Varrla E,Venkataraman S,Sundara R.Functionalized graphene-PVDF foam composites for EMI shielding[J].Macromol Mater Eng,2011,296:894-898.
[39]Song W L,Cao M S,Lu M M,et al.Flexible graphene/polymer composite films in sandwich structures for effective electromagnetic interference shielding[J].Carbon,2014,66:67-76.
[40]Zhang H B,Yan Q,Zheng W G,et al.Tough graphenepolymer microcellular foams for electromagnetic interference shielding[J].ACS Appl Mater Interfaces,2011,3(3):918-924.
[41]Zhang H B,Zheng W G,Yan Q,et al.Electrically conductive polyethylene terephthalate/grapheme nanocomposites prepared by melt compounding[J].Polymer,2010,51(5):1 191-1 196.
[42]Yan D X,Ren P G,Pang H,et al.Efficient electromagnetic interference shielding of lightweight graphene/polystyrene composite[J].Journal of Materials Chemistry,2012,22:18 772-18 774.
[43]Liang J J,Wang Y,Huang Y,et al.Electromagnetic interference shielding of grapene/epoxy composites[J].Carbon,2009,47:922-925.
[44]Basavaraja C,Kim W J,Kim Y D,et al.Synthesis of polyaniline-gold/graphene oxide composite and microwave absorption characteristics of the composite films[J].Materials Letter,2011,65(19):3 120-3 123.
[45]莫尊理,高倩.石墨烯/聚吡咯复合材料的制备及其导电性能研究[J].西北师范大学学报,2012,48(2):47-50.
[46]Avanish P S,Monika M,Amita C,et al.Graphene oxide/ferrofluid/cement composites for electromagnetic interference shielding application[J].Nanotechnology,2011,DOI:10.1088/0957-4484/22/46/465701.
[47]李桃安,毛倩瑾,郑付营,等.镀银铜粉电磁屏蔽水性涂料的制备及性能研究[J].化学工业与工程,2011,28(3):9-13.
[48]周全,汪岳峰,魏大鹏.AuCl3掺杂石墨烯的电磁屏蔽特性研究[J].光学仪器,2014,36(5):438-448.
[2]Brumfiel G.Graphene gets ready for the big time[J].Nature,2009,458:390-391.
[3]Service R F.Carbon sheets an atom thick give rise to graphene dreams[J].Science,2009,324:875-877.
[4]Kim K S,Zhao Y,Jang H,et al.Large-scale pattem growth of graphene films for stretchable transparent electrodes[J].Nature,2009,457:706-710.
[5]Yan J,Wei T,Shao B,et al.Preparation of a graphene nanosheet/polyaniline composite with high specific capacitance[J].Carbon,2010,48(2):487-493.
[6]Geim A K,Novoselov K S.The rise of graphene[J].Nature Mater,2007,6:183-191.
[7]Chen J H,Jang C,Xiao S,et al.Intrinsic and extrinsic performance limits of graphene devices on SiO2[J].Nat Nanotechnol,2008,3:206-209.
[8]Balandin A A,Ghosh S,Bao W Z,et al.Superior thermal conductivity of single-layer graphene[J].Nano Lett,2008,8:902-907.
[9]Lee C G,Wei X D,Kysar J W,et al.Measurement of the elastic properties and intrnsic strength of monolayer graphene[J].Science,2008,321:385-388.
[10]李友良,应淑妮,陈国贵.石墨烯在电磁屏蔽与吸波材料方面的应用及研究进展[J].新材料产业,2013(9):37-47.
[11]李旭,赵卫峰,陈国华.石墨烯的制备与表征研究[J].材料导报,2008,22(8):48-52.
[12]古映雪,邱小勇,胡启明.电磁屏蔽材料的研究进展[J].材料导报,2005,19(2):53-56.
[13]吴定超.汽车电磁兼容仿真预测技术的研究[D].长春:吉林大学,2009.
[14]王华.Ag/RGO/聚苯胺复合材料的制备及其电磁屏蔽性能的研究[D].绵阳:西南科技大学,2017.
[15]王婵媛,王希晰,曹茂盛.轻质石墨烯基电磁屏蔽材料的研究进展[J].材料工程,2016,44(10):109-118.
[16]司琼.电磁屏蔽涂料的研究现状及发展趋势[J].上海涂料,2005,43(4):26-28.
[17]张龙,魏光辉,胡小锋,等.材料电磁脉冲屏蔽效能研究进展[J].电讯技术,2011,51(9):143-147.
[18]汝强,胡社军,胡显奇,等.电磁屏蔽理论及屏蔽材料的制备[J].包装工程,2004(5):21-23.
[19]何益艳,杜仕国,施冬梅.铜系电磁屏蔽涂料的研究[J].现代涂料与涂装,2002(5):1-2.
[20]Stankovich S,Dikin D A,Piner R K,et al.Synthesis of graphene based nanosheets via chemical reduction of exfoliated graphite oxide[J].Carbon,2007,45(7):1 558-1 565.
[21]王亚飞,李楠,赵生俊,等.石墨烯的改性研究进展[EB/OL].北京:中国科技论文在线[2013-12-24].http://www.paper.edu.cn/releasepaper/content/201312-809.
[22]覃信茂,谢卓成,谢泉.石墨烯改性研究进展[J].电子元件与材料,2014,33(3):1-3.
[23]胡圣飞,张帆,张荣,等.石墨烯表面改性及其在聚合物导电复合材料中的应用研究[J].高分子材料科学与工程,2017,33(8):184-190.
[24]王栋.共价键功能化石墨烯研究进展[J].碳素,2014(4):14-21.
[25]Wang J Y,Yang S Y,Huang Y L,et al.Preparation and properties of graphene oxide/polyimide composite films with low dielectric constant and ultrahigh strength via in situ polymerization[J].J Mater Chem,2011,21:13 569-13 575.
[26]Tang G,Jiang Z G,Li X,et al.Three dimensional graphene aerogels and their electrically conductive composites[J].Carbon,2014,77:592-599.
[27]Liu K,Chen S,Luo Y,et al.Edge-functionalized graphene as reinforement of epoxy-based conductive composite for electrical interconnects[J].Compos Sci Technol,2013,88:84-91.
[28]Stankovich S,Piner R D,Nguyen S T,et al.Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets[J].Carbon,2006,44(15):3 342-3 347.
[29]王平华,王志刚,刘春华等.基于π-π相互作用合成星型聚丙烯腈-石墨烯复合材料[J].功能高分子学报,2010,23(4):391-395.
[30]孙凤梅,赵春宝,赵玮.叶绿素铜钠非共价改性石墨烯的研究[J].化工新型材料,2015,43(9):198-200.
[31]陈小乙.石墨烯的功能化改性及应用研究[D].上海:复旦大学,2012.
[32]蒋静,贾红兵,王经逸,等.石墨烯/聚合物复合材料的研究进展[J].合成橡胶工业,2011,34(6):482-488.
[33]Chen Y H,Yao X Y,Zhou X F,et al.Poly(lactic acid)/graphene nanocomposites prepared via solution blending using chloroform as a mutual solvent[J].J Nanosci Nanotechnol,2011,11(9):7 813-7 819.
[34]Achaby M E,Arrakhiz F Z,Vaudreuil S,et al.Preparation and characterization of melt-blended graphene nanosheetspoly(vinylidene fluoride)nanocomposites with enhanced properties[J].J Appl Polym Sci,2013,127(6):4 697-4 707.
[35]Wu F F,Lu Y G,Shao G L,et al.Preparation of polyacrylonitrile/graphene oxide by in situ polymerization[J].Polym Int,2012,61(9):1 394-1 399.
[36]陈宇,张好斌,于中振.聚合物/石墨烯纳米复合材料电磁屏蔽研究进展[J].安全与电磁兼容,2016(5):49-85.
[37]袁冰清,郁黎明,盛雷梅.石墨烯/聚苯胺复合材料的电磁屏蔽性能[J].复合材料学报,2013,30(1):22-26.
[38]Varrla E,Venkataraman S,Sundara R.Functionalized graphene-PVDF foam composites for EMI shielding[J].Macromol Mater Eng,2011,296:894-898.
[39]Song W L,Cao M S,Lu M M,et al.Flexible graphene/polymer composite films in sandwich structures for effective electromagnetic interference shielding[J].Carbon,2014,66:67-76.
[40]Zhang H B,Yan Q,Zheng W G,et al.Tough graphenepolymer microcellular foams for electromagnetic interference shielding[J].ACS Appl Mater Interfaces,2011,3(3):918-924.
[41]Zhang H B,Zheng W G,Yan Q,et al.Electrically conductive polyethylene terephthalate/grapheme nanocomposites prepared by melt compounding[J].Polymer,2010,51(5):1 191-1 196.
[42]Yan D X,Ren P G,Pang H,et al.Efficient electromagnetic interference shielding of lightweight graphene/polystyrene composite[J].Journal of Materials Chemistry,2012,22:18 772-18 774.
[43]Liang J J,Wang Y,Huang Y,et al.Electromagnetic interference shielding of grapene/epoxy composites[J].Carbon,2009,47:922-925.
[44]Basavaraja C,Kim W J,Kim Y D,et al.Synthesis of polyaniline-gold/graphene oxide composite and microwave absorption characteristics of the composite films[J].Materials Letter,2011,65(19):3 120-3 123.
[45]莫尊理,高倩.石墨烯/聚吡咯复合材料的制备及其导电性能研究[J].西北师范大学学报,2012,48(2):47-50.
[46]Avanish P S,Monika M,Amita C,et al.Graphene oxide/ferrofluid/cement composites for electromagnetic interference shielding application[J].Nanotechnology,2011,DOI:10.1088/0957-4484/22/46/465701.
[47]李桃安,毛倩瑾,郑付营,等.镀银铜粉电磁屏蔽水性涂料的制备及性能研究[J].化学工业与工程,2011,28(3):9-13.
[48]周全,汪岳峰,魏大鹏.AuCl3掺杂石墨烯的电磁屏蔽特性研究[J].光学仪器,2014,36(5):438-448.