湖泊中硫的地球化学循环效应研究
摘要
硫是湖泊中参与生命物质循环的主要元素,同时也是控制湖泊氧化还原反应的主要元素之一。硫在湖泊中地球化学循环的本质是氧化还原反应,在其循环的过程中会对湖泊环境产生重要的影响。文章从湖泊中硫的地球化学循环机理、控制因素、以及循环过程中对环境可能产生的各种效应进行了分析。建议合理利用硫的地球化学循环效应来保护湖泊生态环境,即利用硫的地球化学循环过程中积极方面来改善湖泊环境,同时尽可能的降低循环过程中对湖泊生态环境造成的不利影响。
Sulfur is the main element involved in the circulation of life materials in lakes, and it is also one of the main elements controlling the redox reaction of lakes. The geochemical cycle of sulfur in lakes is accomplished by redox reactions, which has an important impact on the lake environment. This paper analyzes the geochemical cycle mechanism, control factors of sulfur in lakes and various effects that might occur in the environment during the cycle. It was recommended to rationally utilize the geochemical cycle effect of sulfur to protect the lake's ecological environment. Specifically, the positive aspects of the geochemical cycle of sulfur were used to improve the lake environment while minimizing the adverse effects on the lake's ecological environment during the cycle.
Sulfur is the main element involved in the circulation of life materials in lakes, and it is also one of the main elements controlling the redox reaction of lakes. The geochemical cycle of sulfur in lakes is accomplished by redox reactions, which has an important impact on the lake environment. This paper analyzes the geochemical cycle mechanism, control factors of sulfur in lakes and various effects that might occur in the environment during the cycle. It was recommended to rationally utilize the geochemical cycle effect of sulfur to protect the lake's ecological environment. Specifically, the positive aspects of the geochemical cycle of sulfur were used to improve the lake environment while minimizing the adverse effects on the lake's ecological environment during the cycle.
引文
[1]胡正义,徐成凯.土壤中的硫与环境质量[M].北京:科学出版社,2002:283-307.
[2]马荣华,杨桂山,段洪涛,等.中国湖泊的数量、面积与空间分布[J].中国科学:地球科学,2011,41(03):394-401.
[3]李玉照,刘永,颜小品.基于DPSIR模型的流域生态安全评价指标体系研究[J].北京大学学报(自然科学版),2012,48(06):971-981.
[4]丁之勇,蒲佳,吉力力·阿不都外力.中国主要湖泊表层沉积物重金属污染特征与评价分析[J].环境工程,2017,35(06):136-141+102.
[5]苗慧,沈峥,蒋豫,等.巢湖表层沉积物氮、磷、有机质的分布及污染评价[J].生态环境学报,2017,26(12):2120-2125.
[6]CAROHN C F,KUMAR PS,SARAVANAN A,et al., Efficient techniques for the removal of toxic heavy metals from aquatic environment:A review[J]. Joumal of environmental chemical engineering. 2017(5):2782-2799.
[7]王中良.中国西南喀斯特湖泊硫酸盐来源的硫同位素示踪研究[A].中国矿物岩石地球化学学会第11届学术年会论文集[C].中国矿物岩石地球化学学会,2007:2.
[8]Mossmann J R Aplitl A,Curtis C D,et a1.,Geochemistry of inorganic sulphur in organic-Rich sediments from the Peru Margin[J]. Geohimica et Cosmochica Acta. 1991(55):3581-3595.
[9]Werner Eckert, Alexandra V Turchyn, Gilad Antler, and Alexey Kamyshny Jr,Annual sulfur cycle in a warm monomictic lake with sub-millimolar sulfate concentrations Nadav Knossow1[J].Barak Blonder1,Geochem Trans. 2015(16).
[10]余芬芳.外源硫酸盐对武汉墨水湖沉积物营养盐和重金属的作用[D].华中农业大学,2013.
[11]J. A. Hardy and W. A. Hamilton, Curr. Microbiol. 1981,259(6).
[12]L. V. Zamana and S. V. Borzenko. Hydrogen Sulfide and Other Reduced Forms of Sulfur in Oxic Waters of Lake Doroninskoe[J].Eastern Transbaikalia. Doklady Earth Sciences. 2007(417):1268-1271.
[13]吴丰昌,万国江,黄荣贵,等.湖泊水体中硫酸盐增高的环境效应研究[J].环境科学学报,1998(01):30-35.
[14]罗莎莎,万国江.湖泊沉积物中硫的地球化学循环机制研究[J].四川环境,2000(03):1-3.
[15]Wetzel, Robert G, Limnology:Lake and River Ecosystems(Third ed.)[J]. New York:Academic Press. 2001.
[16]J o咬rg Overmann J. Thomas Beatty, H. Roy Krause, Ken J.Hall, the sulfur cycle in the chemocline of a meromictic salt lake,Limnology and Oceanography. 41(1996)147-156.
[17]L. V. Zamana and S. V. Borzenko,Elemental Sulfur in the Brine of Lake Doroninskoe(Eastern Transbaikalia)[J]. Doklady Earth Sciences,2011(438):775-778.
[18]W. Eckert,Y. Z. Yacobi,and H. G. A Bloom of a Brown Phototrophic Sulfur Bacterium in Lake Kinneret:Hydrochemical Aspects[J]. Truper Microb Ecol. 1990(20):273-282.
[19]Holmer M, Storkholm E. Sulphate reduction and suphur cycling in lake sediments:a review[J]. Freshwater Biology. 2001(46):431-451.
[20]尹希杰,周怀阳,杨群慧,等.珠江口淇澳岛海岸带沉积物中硫酸盐还原和不同形态硫的分布[J].海洋学报,2010,32(3):31-39.
[21]Berner R.A. New geochemical classification of sedimentary environ-ments[J].Sediment Petrology,1981(51):359-365.
[22]步青云.浅水湖泊溶解氧变化对沉积物磷-氮的影响[D].中国环境科学研究院,2006.
[23]Luther G W. Pyrite synthesis via polysulfide compounds[J].Geochimica et Cosmochimica Acta. 1991(55):2839-2849.
[24]李海波,曹梦华,吴丁山,等.硫化亚铁稳定化修复重金属污染湖泊底泥的效率及机理[J].环境工程学报,2017,11(05):3258-3263.
[25]贾振邦,梁涛,林健枝,等.酸可挥发硫对香港河流沉积物中重金属的毒性作用[J].北京大学学报(自然科学版),1998(Z1):247-254.
[2]马荣华,杨桂山,段洪涛,等.中国湖泊的数量、面积与空间分布[J].中国科学:地球科学,2011,41(03):394-401.
[3]李玉照,刘永,颜小品.基于DPSIR模型的流域生态安全评价指标体系研究[J].北京大学学报(自然科学版),2012,48(06):971-981.
[4]丁之勇,蒲佳,吉力力·阿不都外力.中国主要湖泊表层沉积物重金属污染特征与评价分析[J].环境工程,2017,35(06):136-141+102.
[5]苗慧,沈峥,蒋豫,等.巢湖表层沉积物氮、磷、有机质的分布及污染评价[J].生态环境学报,2017,26(12):2120-2125.
[6]CAROHN C F,KUMAR PS,SARAVANAN A,et al., Efficient techniques for the removal of toxic heavy metals from aquatic environment:A review[J]. Joumal of environmental chemical engineering. 2017(5):2782-2799.
[7]王中良.中国西南喀斯特湖泊硫酸盐来源的硫同位素示踪研究[A].中国矿物岩石地球化学学会第11届学术年会论文集[C].中国矿物岩石地球化学学会,2007:2.
[8]Mossmann J R Aplitl A,Curtis C D,et a1.,Geochemistry of inorganic sulphur in organic-Rich sediments from the Peru Margin[J]. Geohimica et Cosmochica Acta. 1991(55):3581-3595.
[9]Werner Eckert, Alexandra V Turchyn, Gilad Antler, and Alexey Kamyshny Jr,Annual sulfur cycle in a warm monomictic lake with sub-millimolar sulfate concentrations Nadav Knossow1[J].Barak Blonder1,Geochem Trans. 2015(16).
[10]余芬芳.外源硫酸盐对武汉墨水湖沉积物营养盐和重金属的作用[D].华中农业大学,2013.
[11]J. A. Hardy and W. A. Hamilton, Curr. Microbiol. 1981,259(6).
[12]L. V. Zamana and S. V. Borzenko. Hydrogen Sulfide and Other Reduced Forms of Sulfur in Oxic Waters of Lake Doroninskoe[J].Eastern Transbaikalia. Doklady Earth Sciences. 2007(417):1268-1271.
[13]吴丰昌,万国江,黄荣贵,等.湖泊水体中硫酸盐增高的环境效应研究[J].环境科学学报,1998(01):30-35.
[14]罗莎莎,万国江.湖泊沉积物中硫的地球化学循环机制研究[J].四川环境,2000(03):1-3.
[15]Wetzel, Robert G, Limnology:Lake and River Ecosystems(Third ed.)[J]. New York:Academic Press. 2001.
[16]J o咬rg Overmann J. Thomas Beatty, H. Roy Krause, Ken J.Hall, the sulfur cycle in the chemocline of a meromictic salt lake,Limnology and Oceanography. 41(1996)147-156.
[17]L. V. Zamana and S. V. Borzenko,Elemental Sulfur in the Brine of Lake Doroninskoe(Eastern Transbaikalia)[J]. Doklady Earth Sciences,2011(438):775-778.
[18]W. Eckert,Y. Z. Yacobi,and H. G. A Bloom of a Brown Phototrophic Sulfur Bacterium in Lake Kinneret:Hydrochemical Aspects[J]. Truper Microb Ecol. 1990(20):273-282.
[19]Holmer M, Storkholm E. Sulphate reduction and suphur cycling in lake sediments:a review[J]. Freshwater Biology. 2001(46):431-451.
[20]尹希杰,周怀阳,杨群慧,等.珠江口淇澳岛海岸带沉积物中硫酸盐还原和不同形态硫的分布[J].海洋学报,2010,32(3):31-39.
[21]Berner R.A. New geochemical classification of sedimentary environ-ments[J].Sediment Petrology,1981(51):359-365.
[22]步青云.浅水湖泊溶解氧变化对沉积物磷-氮的影响[D].中国环境科学研究院,2006.
[23]Luther G W. Pyrite synthesis via polysulfide compounds[J].Geochimica et Cosmochimica Acta. 1991(55):2839-2849.
[24]李海波,曹梦华,吴丁山,等.硫化亚铁稳定化修复重金属污染湖泊底泥的效率及机理[J].环境工程学报,2017,11(05):3258-3263.
[25]贾振邦,梁涛,林健枝,等.酸可挥发硫对香港河流沉积物中重金属的毒性作用[J].北京大学学报(自然科学版),1998(Z1):247-254.