脂肪酸单体碳同位素的沉积学记录及其环境意义
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摘要
湖泊/水库沉积物是有机化学领域的重要研究载体,与其他自然记录比较,它具有信息丰富、时间分辨率高、记录连续性好和覆盖面广等优点。自20世纪80年代以来,在古环境/古气候的研究中,沉积物有机质分子的标志物研究发挥了无可取代的作用。脂肪酸及其单体碳同位素的分布特征与环境意义是目前研究热点。以沉积物为研究载体,采用文献荟萃的方法,探讨了脂肪酸及其单体碳同位素技术在有机质溯源、流域内植被的恢复和气候的反演等方面的研究进展。结果表明:脂类化合物在来源上存在重叠,脂肪酸的研究可以作为正构烷烃分子标志物研究的补充。与单体碳同位素组成特征的联合应用,能够准确地对沉积有机质进行溯源,可以充分揭示保存在陆源脂肪酸中的气候环境信息,为指示气候和环境变化提供重要的线索。在重建区域性的气候和环境状况方面具有广阔的应用前景。
Lake sediment is an important media for molecular organic chemistry research.It has the advantages such as storing large amount of information,high temporal resolution and wide geographical coverage.Since the 1980 s,the sedimentary organic matter molecular geochemistry in the study of paleoclimate has played an irreplaceable role.The investigation of global change has focused on the fatty acid and its compound-specific carbon isotopic distribution.Using the methods of extensive search of literatures and summaries,we discussed the literatures of fatty acid and its compound-specific carbon isotopic distribution for the identification of organic matter resources,reconstruction of vegetation and recovery of paleovegetation and paleoclimate.The result shows that the lipid compound has some superpositions in source.The research of fatty acids can be the supplements of n-alknes.And the combination with the compound-specific characteristics of carbon isotopic can trace the organic matter accurately.It can not only reveal the climate and environment information stored in the terrestrial fatty acid but also provide important clues to indicate the climate and environmental changes.It has a broad application prospect in the reconstruction of vegetation,regional climate and environmental conditions.
Lake sediment is an important media for molecular organic chemistry research.It has the advantages such as storing large amount of information,high temporal resolution and wide geographical coverage.Since the 1980 s,the sedimentary organic matter molecular geochemistry in the study of paleoclimate has played an irreplaceable role.The investigation of global change has focused on the fatty acid and its compound-specific carbon isotopic distribution.Using the methods of extensive search of literatures and summaries,we discussed the literatures of fatty acid and its compound-specific carbon isotopic distribution for the identification of organic matter resources,reconstruction of vegetation and recovery of paleovegetation and paleoclimate.The result shows that the lipid compound has some superpositions in source.The research of fatty acids can be the supplements of n-alknes.And the combination with the compound-specific characteristics of carbon isotopic can trace the organic matter accurately.It can not only reveal the climate and environment information stored in the terrestrial fatty acid but also provide important clues to indicate the climate and environmental changes.It has a broad application prospect in the reconstruction of vegetation,regional climate and environmental conditions.
引文
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[21]欧杰,王延华,杨浩,等.湖泊沉积物中正构烷烃和碳同位素的分布特征及其环境意义[J].南京师大学报:自然科学版,2012,35(3):98-105.
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[23]Sehouten S,KleinBreteler W C M,Blokker P.et al.Biosynthetic effects on the stable carbon isotopic compositions of algal lipids:implications for deciphering the carbon isotopic biomaker record[J].Biochemical Journal,1998,62(8):1397-1406.
[24]Brassell S C,Eglinton G,maxwell J R.Natural background of Alkanes in the aquatic environment[J].Aquatic Pollutants,1978:69-86.
[25]Volkman J K.A review of sterol markers for marine and terrigenous organic matter[J].Organic Geochemistry,1986,9(2):83-99.
[26]欧杰,王延华,杨浩,等.正构烷烃及单体碳同位素记录的石臼湖生态环境演变研究[J].环境科学,2013,34(2):484-493.
[27]Yamamoto M,Shiraiwa Y.Inonye I.Physiological responses of lipids in Emiliania huxleyi and Gephyrocapsa oceanica(Haptophyceae)to growth status and their implications for alkenone paleothermometry[J].Organic Geochemistry,2000,31:799-811.
[28]欧杰.石臼湖地区百年尺度生态环境演变与人类活动关系研究[D].南京:南京师范大学,2013.
[29]吴能友,邬黛黛,叶瑛,等.南海东北部东砂海域沉积物烃类有机地球化学研究及其意义[J].南海地质研究,2007(1):1-14.
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[31]Naraoka H,Ishiwatari R.Molecular and isotopic abundances of long-chain n-fatty acids in open marine sediments if the westeren North Pacific[J].Chemical Geology,2000,165(1/2):23-36.
[32]段毅,文启斌,罗斌杰.南沙海洋和甘南沼泽现代沉积物中单个脂肪酸碳同位素组成及其成因[J].地球化学,1995,24(3):270-276.
[33]薛博.漳江口红树林湿地沉积物有机质来源追溯[D].福建厦门:厦门大学,2007.
[34]Kawamura K,Ishiwatari R.Polyunsaturated fatty acids in a lacustrine sediment as a possible indicator of paleoclimate[J].Geochimica et Cosmochimica Acta,1981,45(2):149-155.
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