锰的氧化矿物及锰系复合矿物材料在环境污染中的应用
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摘要
锰的氧化矿物具有表面效应、水合效应、孔道结构、氧化催化效应和离子交换效应等性质,在环境污染治理和生态环境修复方面展现出很好的应用前景,基于锰的氧化矿物性能特点,开发锰系复合矿物材料并应用于环境污染治理成为近年来环境矿物材料研究的热点。锰的氧化矿物及锰系复合矿物材料是一类重要的环境矿物材料,在治理大气污染、水体污染和固体废弃物资源回收利用方面,具有成本低、效果好、无二次污染及资源可回收利用等优点。
Manganese oxide minerals have surface effects,hydration effects and pore structure,catalytic oxidation effects and ion exchange properties.Manganese oxide minerals have good application prospect in environmental pollution control and ecological restoration.At the same time,relying on the characteristics of manganese oxide minerals,the development of manganese compound mineral materials used in environmental pollution control has become the focus of environmental mineral materials research in recent years.Manganese oxide minerals and manganese compound mineral materials is a kind of important environmental mineral materials,which have been used in air pollution,water pollution and solid waste recycling.The method has the advantages of low cost,good effect,no pollution,resource utilization recyclable and so on.
Manganese oxide minerals have surface effects,hydration effects and pore structure,catalytic oxidation effects and ion exchange properties.Manganese oxide minerals have good application prospect in environmental pollution control and ecological restoration.At the same time,relying on the characteristics of manganese oxide minerals,the development of manganese compound mineral materials used in environmental pollution control has become the focus of environmental mineral materials research in recent years.Manganese oxide minerals and manganese compound mineral materials is a kind of important environmental mineral materials,which have been used in air pollution,water pollution and solid waste recycling.The method has the advantages of low cost,good effect,no pollution,resource utilization recyclable and so on.
引文
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[2]鲁安怀,王长秋,李艳.矿物学环境属性概论[M].北京:科学出版社,2015.
[3]Chen T H,Huang X M,Pan M,et al.Treatment of coking wastewater by using manganese and magnesium ores[J].Journal of Hazardous Materials,2009,168(2-3):843-847.
[4]Post J E.Manganese oxide minerals:crystal structures and economic and environmental significance[J].Proceedings of the National Academy of Sciences of the United States of America,1999,96(7):3447-3454.
[5]高翔,鲁安怀,郑辙,等.锰的氧化物和氢氧化物在污染水体净化中的应用研究现状[J].矿物岩石,2002,22(1):77-82.
[6]Sihaib Z,Puleo F,Garcia-Vargas J M,et al.Manganese oxide-based catalysts for toluene oxidation[J].Applied Catalysis B Environmental,2017,209:689-700.
[7]Jia J,Zhang P,Chen L.Catalytic decomposition of gaseous ozone over manganese dioxides with different crystal structures[J].Applied Catalysis B Environmental,2016,189:210-218.
[8]饶丹丹,孙波,乔俊莲,等.三价锰的性质、产生及环境意义[J].化学进展,2017,29(9):1142-1153.
[9]刘瑞,秦善,鲁安怀,等.锰氧化物和氢氧化物中的孔道结构矿物及其环境属性[J].矿物岩石,2003,23(4):28-33.
[10]Turner S,Buseck P R.Manganese oxide tunnel structures and their intergrowths[J].Science,1979,203(4379):456-458.
[11]Hadermann J,Abakumov A M,Gillie L,et al.Manganese oxide tunnel structures determined with TEM[J].Acta Crystallographica,2006,62(18):2877-2886.
[12]Gamble T,Gillette E,Sang B L,et al.Probing porous structure of single manganese oxide mesorods with ionic current[J].Journal of Physical Chemistry C,2017,117(47):24836-24842.
[13]高雯雯,弓莹,高艳宁,等.负载铈-锰活性炭对兰炭废水的吸附研究[J].硅酸盐通报,2017,36(1):197-204.
[14]彭陈亮,闵凡飞,赵晴,等.微细矿物颗粒表面水化膜研究现状及进展综述[J].矿物学报,2012,32(4):515-522.
[15]Li Y,Kanda Y,Shinto H,et al.Fragile structured layers on surfaces detected by dynamic atomic force microscopy in aqueous electrolyte solutions[J].Advanced Powder Technology,2005,16(3):213-229.
[16]卢寿慈,翁达.界面分选原理及应用[M].北京:冶金工业出版社,1992
[17]赵巍,刘凡,冯雄汉,等.不同锰氧化度水钠锰矿的XPS研究[J].中南大学学报(自然科学版),2012,43(2):776-782.
[18]冯雄汉.几种常见氧化锰矿物的合成、转化及表面化学性质[D].武汉:华中农业大学,2004.
[19]Tripathy S S,Kanungo S B.Adsorption of Co2+,Ni2+,Cu2+,and Zn2+,from 0.5 M Na Cl and major ion sea water on a mixture ofδ-Mn O2,and amorphous Fe OOH[J].Journal of Colloid&Interface Science,2005,284(1):30-38.
[20]陆泗进,谭文峰,刘凡,等.一种改进的盐滴定法测定氧化锰矿物的电荷零点[J].土壤学报,2006,43(5):756-763.
[21]刘迎新,秦善,刘瑞,等.孔道结构矿物及其晶体结构特征[J].北京大学学报(自然科学版),2004,40(6):993-1000.
[22]Shkolnikov E I,Borover G Y,Tarasevich M R,et al.Pore structure of electrolytic manganese dioxide[J].Soviet Electrochemistry,1991,27:21-26.
[23]乔志国,屠霄霞,周怀阳.深海铁锰结核中锰矿物的微观特征[J].自然杂志,2016,38(4):263-270.
[24]Kumari A,Natarajan K A.Cathodic reductive dissolution and surface adsorption behavior of ocean manganese nodules[J].Hydrometallurgy,2002,64(3):247-255.
[25]Randhawa N S,Jana R K,Das N N.Removal of Cd2+ions from aqueous solution by adsorption using manganese nodules leaching residue[C].International Conference on Mineral Processing Technology.2011.
[26]Lee J H,Gilje J,Zeitlin H,et al.Low-temperature interaction of sulfur dioxide with Pacific ferromanganese nodules[J].Environmental Science&Technology,2002,12(13):1428-1431.
[27]孙传尧,谭欣,周秀英,等.大洋多金属结核及富钴结壳矿物材料的研究述评(Ⅱ)[J].国外金属矿选矿,2003,40(10):4-11.
[28]张翰林,李艳,鲁安怀,等.自然界水钠锰矿日光催化作用模拟实验研究[J].南京大学学报(自然科学),2017,53(5):831-840.
[29]Frydendal R,Paoli E A,Chorkendorff I,et al.Toward an active and stable catalyst for oxygen evolution in acidic media:Ti-stabilized Mn O2[J].Advanced Energy Materials,2016,5(22):1-9.
[30]Zhao S,Liu T,Zhang Y,et al.Cr-doped Mn O2nanostructure:morphology evolution and electrochemical properties[J].Journal of Materials Science Materials in Electronics,2016,27(4):3265-3270.
[31]鲁安怀.矿物学环境属性研究新进展(代序)[J].岩石矿物学杂志,2015,34(6):795-802.
[32]刘凡,冯雄汉,陈秀华,等.氧化锰矿物的生物成因及其性质的研究进展[J].地学前缘,2008,15(6):66-73.
[33]Butler E C,Chen L,Hansel C M,et al.Biological versus mineralogical chromium reduction:potential for reoxidation by manganese oxide[J].Environmental Science Processes&Impacts,2015,17(11):1930-1940.
[34]廖兵,伍碧,孙维义,等.软锰矿浆烟气同步脱硫脱硝资源化利用新工艺[J].环境工程,2013,31(2):57-61.
[35]Chen H,Wang Y,Lv Y K.Catalytic oxidation of NO over Mn O2with different crystal structures[J].Rsc.Advances,2016,6(59):54032-54040.
[36]You Z,Li G,Zhang Y,et al.Extraction of manganese from iron rich Mn O2ores via selective sulfation roasting with SO2followed by water leaching[J].Hydrometallurgy,2015,156:225-231.
[37]Parida K,Satapathy P K,Sahoo A K,et al.Studies on indian ocean manganese nodules:I.physicochemical characteristics and catalytic activity of ferromanganese nodules[J].Journal of Colloid&Interface Science,1995,187(2):453.
[38]朱晓燕,叶瑛,沈忠悦.大洋锰结核在功能性材料领域的应用前景与研究进展[J].有色金属工程,2004,56(41):61-65.
[39]解智博,宋艳军,梁金生,等.锰基催化剂低温选择催化还原处理NOx的研究现状与展望[J].材料导报,2017,31(11):38-43.
[40]张晓东,李红欣,侯扶林,等.锰氧化物材料的制备及应用进展[J].化工学报,2017,68(6):2249-2257.
[41]Kim D G,Nhung T T,Ko S O.Enhanced adsorption of heavy metals with biogenic manganese oxide immobilized on zeolite[J].Ksce Journal of Civil Engineering,2016,20(6):2189-2196.
[42]鲁安怀,卢晓英.天然铁锰氧化物及氢氧化物环境矿物学研究[J].地学前缘,2000,7(2):473-483.
[43]Mayanna S,Peacock C L,Schffner F,et al.Biogenic precipitation of manganese oxides and enrichment of heavy metals at acidic soil p H[J].Chemical Geology,2015,402:6-17.
[44]张嵌,冯雄汉,邱国红,等.不同氧化锰矿物对光催化降解苯酚的影响[J].矿物学报,2011,31(2):263-273.
[45]Lin K,Song L,Zhou S,et al.Formation of brominated phenolic contaminants from natural manganese oxides-catalyzed oxidation of phenol in the presence of Br-[J].Chemosphere,2016,155:266-273.
[46]刘菲菲,李艳,丁竑瑞,等.几种锰氧化物矿物能带结构研究[J].矿物岩石地球化学通报,2017,36(3):476-482.
[47]Siddiquie F N,Shaif M.Hydrometallurgical processing of manganese ores:a review[J].International Journal of Geosciences,2015,6(4):350-372.
[48]李进中.生物质还原浸出氧化锰矿石的过程与机理[D].长沙:中南大学,2012.
[49]Ringwood A E,Kesson S E,Ware N G,et al.Immobilisation of high level nuclear reactor wastes in SYNROC[J].Nature,1979,278(5701):219-223.
[50]Whittle K R,Maddrell E R,Ashbrook S E,et al.Structural studies of Hollandite based radioactive wasteformd[J].Mrs Online Proceeding Library,2003,807:07262.
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