SSZ-13分子筛合成研究进展
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摘要
综述了SSZ-13分子筛合成及其性能优化的研究近况。介绍了模板剂、晶种、矿化剂和晶化原料等因素对SSZ-13分子筛合成的影响,以及SSZ-13分子筛孔径、晶粒尺寸、骨架稳定性、酸性等性能优化的方法和效果。指出开发价格低廉的模板剂体系,完善合成及性能优化工艺路线,是SSZ-13分子筛研发的重要方向。
Latest researches on the synthesis and performance optimization of SSZ-13 molecular sieves are reviewed.Influences of template agent,seed crystal,mineralizer and crystallization raw materials on the synthesis of SSZ-13 molecular sieve are introduced,and the methods and effects for optimizing the pore size,grain size,skeleton stability and acidity of SSZ-13 molecular sieves are also summarized.It is pointed out that the development trend of SSZ-13 molecular sieves shall focus on developing low-cost template agent systems and perfecting the routes of synthesis and performance optimization.
Latest researches on the synthesis and performance optimization of SSZ-13 molecular sieves are reviewed.Influences of template agent,seed crystal,mineralizer and crystallization raw materials on the synthesis of SSZ-13 molecular sieve are introduced,and the methods and effects for optimizing the pore size,grain size,skeleton stability and acidity of SSZ-13 molecular sieves are also summarized.It is pointed out that the development trend of SSZ-13 molecular sieves shall focus on developing low-cost template agent systems and perfecting the routes of synthesis and performance optimization.
引文
[1]Zones S I. Zeolite SSZ-13 and its method of preparation:US,4544538[P].1985-10-01.
[2]Jamey Bower,Dushyant Barpaga,Sebastian Prodinger,et al.Dynamic adsorption of CO2/N2on cation-exchanged chabazite SSZ-13:A breakthrough analysis[J].ACS Appl Mater Interfaces,2018,10(17):14287-14291.
[3]Moteki Takahiko,Lobo Raul F.A general method for aluminum incorporation into high-silica zeolites prepared in fluoride media[J].Chemistry of Materials,2016,28(2):638-649.
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[6]Martínez-Franco Raquel,Moliner Manuel,Thogersen Joakim R,et al.Efficient one-pot preparation of Cu-SSZ-13 materials using cooperative OSDAs for their catalytic application in the SCR of NOx[J].Chem Cat Chem,2013,5(11):3316-3323.
[7]Cui Yucun,Tong Xueting,Li Ying,et al.One-pot synthesis of NiSSZ-13 zeolite using a nickel-amine complex as an efficient organic template[J].Journal of Materials Science,2017,52(17):10156-10162.
[8]Wang Xiong,Wu Qinming,Chen Chunyu,et al. Atom-economical synthesis of a high silica CHA zeolite using a solvent-free route[J].Chem Commun,2015,51:16920-16923.
[9]Chen Biaohua,Xu Ruinian,Zhang Runduo,et al.Economical way to synthesize SSZ-13 with abundant ion-exchanged Cu+for an extraordinary performance in selective catalytic reduction(SCR)of NOx by ammonia[J]. Environmental Science and Technology,2014,48(23):13909-13916.
[10]Xu Ruinian,Zhang Runduo,Liu Ning,et al.Template design and economical strategy for the synthesis of SSZ-13(CHA-type)zeolite as an excellent catalyst for the selective catalytic reduction of NOx by ammonia[J].Chem Cat Chem,2015,7(23):3842-3847.
[11]Wang Yufeng,Li Yuan,Tang Enqi.Preparation and characterization of SSZ-13 molecular sieve[J]. International Journal of Chemistry,2010,2(1):128-133.
[12]王艳悦,李玉平,贾坤,等.SAPO-34分子筛晶种辅助合成SSZ-13分子筛[J].天然气化工:C1化学与化工,2016,41(4):5-9.
[13]Imai Hiroyuki,Hayashida Nozomu,Yokoi Toshiyuki,et al. Direct crystallization of CHA-type zeolite from amorphous aluminosilicate gel by seed-assisted method in the absence of organic-structure-directing agents[J]. Microporous and Mesoporous Materials,2014,196:341-348.
[14]Liu Zhendong,Wakihara Toru,Oshima Kazunori,et al. Widening synthesis bottlenecks:Realization of ultrafast and continuous-flow synthesis of high-silica zeolite SSZ-13 for NOxremoval[J]. Angewandte Chemie International Edition,2015,54(19):5683-5687.
[15]Eilertsen Einar A,Arstad Bjrnar,Stian Svelle,et al. Single parameter synthesis of high silica CHA zeolites from fluoride media[J].Microporous and Mesoporous Materials,2012,153:94-99.
[16]Zhu Xiaochun,Kosinov Nikolay,Hofmann Jan P,et al.Fluoride-assisted synthesis of bimodal microporous SSZ-13 zeolite[J]. Chem Commun,2016,52(15):3227-3230.
[17]Martín Nuria,Moliner Manuel,Corma Avelino.High yield synthesis of high-silica chabazite by combining the role of zeolite precursors and tetraethylammonium:SCR of NOx[J]. Chem Commun,2015,51(46):9965-9968.
[18]Wu Leilei,Degirmenci Volkan,Magusin Pieter C M M,et al.Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction[J]. Chemical Communications,2012,48(76):9492-9494.
[19]Wu Leilei,Degirmenci Volkan,Magusin Pieter C M M,et al.Mesoporous SSZ-13 zeolite prepared by a dual-template method with improved performance in the methanol-to-olefins reaction[J]. Journal of Catalysis,2013,298:27-40.
[20]Kim Jaeheon,Jo Changbum,Lee Seungjun,et al. Bulk crystal seeding in the generation of mesopores by organosilane surfactants in zeolite synthesis[J]. Journal of Materials Chemistry A,2014,2(30):11905-11912.
[21]Bing Liancheng,Tian Aixiu,Wang Fang,et al. Template-free synthesis of hierarchical SSZ-13 microspheres with high MTO catalytic activity[J]. Chemistry-A European Journal,2018,24(29):7428-7433.
[22]Sommer Linn,Mores Davide,Svelle Stian,et al.Mesopore formation in zeolite H-SSZ-13 by desilication with Na OH[J]. Microporous and Mesoporous Materials,2010,132(3):384-394.
[23]Bohstr9m Zebastian, Arstad Bjrnar, Lillerud Karl Petter.Preparation of high silica chabazite with controllable particle size[J].Microporous and Mesoporous Materials,2014,195:294-302.
[24]Li Z,Navarro M T,Martínez-Triguero J,et al. Synthesis of nanoSSZ-13 and its application in the reaction of methanol to olefins[J].Catalysis Science&Technology,2016,6(15):5856-5863.
[25]Kumar Manjesh,Luo Helen,Romn-Leshkov Yuriy,et al. SSZ-13Crystallization by particle attachment and deterministic pathways to crystal size control[J]. J Am Chem Soc,2015,137(40):13007-13017.
[26]Fickel Dustin W,Lobo Raul F. Copper coordination in Cu-SSZ-13and Cu-SSZ-16 investigated by variable-temperature XRD[J]. The Journal of Physical Chemistry C,2010,114(3):1633-1640.
[27]Zhang Yu,Wang Hongning,Chen Ruoyu. Improved hightemperature hydrothermal stability of Cu-SSZ-13 by an ammonium hexafluorosilicate treatment[J]. RSC Advances,2015,5(83):67841-67848.
[28]Yamanaka Naoki,Itakura Masaya,Kiyozumi Yoshimichi,et al.Acid stability evaluation of CHA-type zeolites synthesized by interzeolite conversion of FAU-type zeolite and their membrane application for dehydration of acetic acid aqueous solution[J]. Microporous and Mesoporous Materials,2012,158:141-147.
[29]Fan Chi,Chen Zhen,Pang Lei,et al.The influence of Si/Al ratio on the catalytic property and hydrothermal stability of Cu-SSZ-13 catalysts for NH3-SCR[J]. Applied Catalysis A:General,2018,550:256-265.
[30]Zhu Qingjun,Hinode Mayumi,Yokoi Toshiyuki,et al. Synthesis,characterization and catalytic studies of CHA zeotype materials containing boron and iron[J].Catalysis Communications,2009,10(5)447-450.
[2]Jamey Bower,Dushyant Barpaga,Sebastian Prodinger,et al.Dynamic adsorption of CO2/N2on cation-exchanged chabazite SSZ-13:A breakthrough analysis[J].ACS Appl Mater Interfaces,2018,10(17):14287-14291.
[3]Moteki Takahiko,Lobo Raul F.A general method for aluminum incorporation into high-silica zeolites prepared in fluoride media[J].Chemistry of Materials,2016,28(2):638-649.
[4]Zones S I.Preparation of molecular sieves using a structure directing agent and an N,N,N-Triakyl benzyl quaternary ammonium cation:US,20080075656A1[P].2008-05-27.
[5]Ren Limin,Zhu Longfeng,Yang Chengguang,et al. Designed copper-amine complex as an efficient template for one-pot synthesis of Cu-SSZ-13 zeolite with excellent activity for selective catalytic reduction of NOxby NH3[J].Chemical Communications,2011,47(35):9789-9791.
[6]Martínez-Franco Raquel,Moliner Manuel,Thogersen Joakim R,et al.Efficient one-pot preparation of Cu-SSZ-13 materials using cooperative OSDAs for their catalytic application in the SCR of NOx[J].Chem Cat Chem,2013,5(11):3316-3323.
[7]Cui Yucun,Tong Xueting,Li Ying,et al.One-pot synthesis of NiSSZ-13 zeolite using a nickel-amine complex as an efficient organic template[J].Journal of Materials Science,2017,52(17):10156-10162.
[8]Wang Xiong,Wu Qinming,Chen Chunyu,et al. Atom-economical synthesis of a high silica CHA zeolite using a solvent-free route[J].Chem Commun,2015,51:16920-16923.
[9]Chen Biaohua,Xu Ruinian,Zhang Runduo,et al.Economical way to synthesize SSZ-13 with abundant ion-exchanged Cu+for an extraordinary performance in selective catalytic reduction(SCR)of NOx by ammonia[J]. Environmental Science and Technology,2014,48(23):13909-13916.
[10]Xu Ruinian,Zhang Runduo,Liu Ning,et al.Template design and economical strategy for the synthesis of SSZ-13(CHA-type)zeolite as an excellent catalyst for the selective catalytic reduction of NOx by ammonia[J].Chem Cat Chem,2015,7(23):3842-3847.
[11]Wang Yufeng,Li Yuan,Tang Enqi.Preparation and characterization of SSZ-13 molecular sieve[J]. International Journal of Chemistry,2010,2(1):128-133.
[12]王艳悦,李玉平,贾坤,等.SAPO-34分子筛晶种辅助合成SSZ-13分子筛[J].天然气化工:C1化学与化工,2016,41(4):5-9.
[13]Imai Hiroyuki,Hayashida Nozomu,Yokoi Toshiyuki,et al. Direct crystallization of CHA-type zeolite from amorphous aluminosilicate gel by seed-assisted method in the absence of organic-structure-directing agents[J]. Microporous and Mesoporous Materials,2014,196:341-348.
[14]Liu Zhendong,Wakihara Toru,Oshima Kazunori,et al. Widening synthesis bottlenecks:Realization of ultrafast and continuous-flow synthesis of high-silica zeolite SSZ-13 for NOxremoval[J]. Angewandte Chemie International Edition,2015,54(19):5683-5687.
[15]Eilertsen Einar A,Arstad Bjrnar,Stian Svelle,et al. Single parameter synthesis of high silica CHA zeolites from fluoride media[J].Microporous and Mesoporous Materials,2012,153:94-99.
[16]Zhu Xiaochun,Kosinov Nikolay,Hofmann Jan P,et al.Fluoride-assisted synthesis of bimodal microporous SSZ-13 zeolite[J]. Chem Commun,2016,52(15):3227-3230.
[17]Martín Nuria,Moliner Manuel,Corma Avelino.High yield synthesis of high-silica chabazite by combining the role of zeolite precursors and tetraethylammonium:SCR of NOx[J]. Chem Commun,2015,51(46):9965-9968.
[18]Wu Leilei,Degirmenci Volkan,Magusin Pieter C M M,et al.Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction[J]. Chemical Communications,2012,48(76):9492-9494.
[19]Wu Leilei,Degirmenci Volkan,Magusin Pieter C M M,et al.Mesoporous SSZ-13 zeolite prepared by a dual-template method with improved performance in the methanol-to-olefins reaction[J]. Journal of Catalysis,2013,298:27-40.
[20]Kim Jaeheon,Jo Changbum,Lee Seungjun,et al. Bulk crystal seeding in the generation of mesopores by organosilane surfactants in zeolite synthesis[J]. Journal of Materials Chemistry A,2014,2(30):11905-11912.
[21]Bing Liancheng,Tian Aixiu,Wang Fang,et al. Template-free synthesis of hierarchical SSZ-13 microspheres with high MTO catalytic activity[J]. Chemistry-A European Journal,2018,24(29):7428-7433.
[22]Sommer Linn,Mores Davide,Svelle Stian,et al.Mesopore formation in zeolite H-SSZ-13 by desilication with Na OH[J]. Microporous and Mesoporous Materials,2010,132(3):384-394.
[23]Bohstr9m Zebastian, Arstad Bjrnar, Lillerud Karl Petter.Preparation of high silica chabazite with controllable particle size[J].Microporous and Mesoporous Materials,2014,195:294-302.
[24]Li Z,Navarro M T,Martínez-Triguero J,et al. Synthesis of nanoSSZ-13 and its application in the reaction of methanol to olefins[J].Catalysis Science&Technology,2016,6(15):5856-5863.
[25]Kumar Manjesh,Luo Helen,Romn-Leshkov Yuriy,et al. SSZ-13Crystallization by particle attachment and deterministic pathways to crystal size control[J]. J Am Chem Soc,2015,137(40):13007-13017.
[26]Fickel Dustin W,Lobo Raul F. Copper coordination in Cu-SSZ-13and Cu-SSZ-16 investigated by variable-temperature XRD[J]. The Journal of Physical Chemistry C,2010,114(3):1633-1640.
[27]Zhang Yu,Wang Hongning,Chen Ruoyu. Improved hightemperature hydrothermal stability of Cu-SSZ-13 by an ammonium hexafluorosilicate treatment[J]. RSC Advances,2015,5(83):67841-67848.
[28]Yamanaka Naoki,Itakura Masaya,Kiyozumi Yoshimichi,et al.Acid stability evaluation of CHA-type zeolites synthesized by interzeolite conversion of FAU-type zeolite and their membrane application for dehydration of acetic acid aqueous solution[J]. Microporous and Mesoporous Materials,2012,158:141-147.
[29]Fan Chi,Chen Zhen,Pang Lei,et al.The influence of Si/Al ratio on the catalytic property and hydrothermal stability of Cu-SSZ-13 catalysts for NH3-SCR[J]. Applied Catalysis A:General,2018,550:256-265.
[30]Zhu Qingjun,Hinode Mayumi,Yokoi Toshiyuki,et al. Synthesis,characterization and catalytic studies of CHA zeotype materials containing boron and iron[J].Catalysis Communications,2009,10(5)447-450.