苏皖地区凹凸棒石黏土的特征和应用发展方向
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摘要
阐明了凹凸棒石晶体生长方式、不同类型的凹凸棒石黏土矿石微结构特征及其与生长方式之间的内在联系,凹凸棒石矿物学特性及其与晶体结构、晶体形貌的联系,凹凸棒石吸附性能、胶体性能的本质、凹凸棒石酸活化反应机制及其效应,凹凸棒石中不同类型的水脱除温度及其与晶体结构、形貌、比表面积、表面酸碱性质演变的关系。简述了凹凸棒石解聚分散、提纯纳米复合材料制备和应用研究进展,富白云石凹凸棒石黏土加工和应用研究进展。指明了苏皖地区不同类型凹凸棒石黏土矿石加工应用发展方向。
The growth pattern and the microstructure characteristics of different palygorskite clays from Jiangsu and Anhui provinces,China, as well as their relationship were represented. The mineralogy of palygorskite clays and the related crystal structure and morphology were described. The essence of adsorption and colloidal properties of palygorskite clays, and the mechanism and effect of acid activation were elucidated. The desorption temperature of different water in palygorskite clays and the corresponding evolution of crystal structure, morphology, specific surface area and surface acid-base properties were discussed. The development on the dispersion and purification of palygorskite clays was given, and the preparation and application of nano-composites based on palygorskite clays were introduced. In addition, the preparation and application of dolomite-rich palygorskite clays were also represented.
The growth pattern and the microstructure characteristics of different palygorskite clays from Jiangsu and Anhui provinces,China, as well as their relationship were represented. The mineralogy of palygorskite clays and the related crystal structure and morphology were described. The essence of adsorption and colloidal properties of palygorskite clays, and the mechanism and effect of acid activation were elucidated. The desorption temperature of different water in palygorskite clays and the corresponding evolution of crystal structure, morphology, specific surface area and surface acid-base properties were discussed. The development on the dispersion and purification of palygorskite clays was given, and the preparation and application of nano-composites based on palygorskite clays were introduced. In addition, the preparation and application of dolomite-rich palygorskite clays were also represented.
引文
[1]陈天虎,谢巧勤,徐晓春.中国黄土中的纳米矿物[M].北京:科学出版社,2012:122-123.
[2]陈天虎,徐晓春,岳书仓.苏皖地区凹凸棒石黏土纳米矿物学及地球化学[M].北京:科学出版社,2004:77-78.
[3]孔德军,陈天虎,刘海波,等.煅烧凹凸棒石的水化处理对其结构和吸附NH3的影响[J].硅酸盐学报,2011,39(11):1867-1871.KONG D J,CHEN T H,LIU H B et al.J Chin Ceram Soc,2011,39(11):1867-1871.
[4]姚超,曾永斌,曹燕媛,等.聚苯胺/凹凸棒石纳米复合材料对甲基橙的吸附性能[J].硅酸盐学报,2010,38(4):671-677.YAO C,ZENG Y B,CAO Y Y,et al.J Chin Ceram Soc,2010,38(4):671-677.
[5]CHEN T H,LIU H B,LI J H,et al.Effect of thermal treatment onadsorption-desorption of ammonia and sulfur dioxide on palygorskite:Change of surface acid-alkali properties[J].Chem Eng J,2011,166(3):1017-1021.
[6]高东升,陈天虎,吴雪平,等.苏皖凹凸棒石粘土水悬浮液流变性能研究[J].岩石矿物学杂志,2009,28(6):665-669.GAO D S,CHEN T H,WU X P,et al.Acta Petrol Miner(in Chinese),2009,28(6):665-669.
[7]LIU H B,CHEN T H,CHANG D Y,et al.The difference of thermal stability between Fe-substituted palygorskite and Al-rich palygorskite[J].J Thermal Anal Calorim,2013,111(1):409-415.
[8]陈天虎,王健,庆承松,等.凹凸棒石热处理结构、形貌和表面性质变化[J].硅酸盐学报,2006,34(11):1406-1410.CHEN T H,WAGN J,QING C S,et al.J Chin Ceram Soc,2006,34(11):1406-1410.
[9]谢品晶,陈天虎,庆承松,等.热处理凹凸棒石结构演化[J].地学前缘,2014,21(5):338-345.XIE Jingjing,CHEN Tianhu,QING Chengsong,et al.Earth Sci Front(in Chinese),2014,21(5):338-345.
[10]HUO C L,YANG H M.Preparation and enhanced photocatalytic activity of Pd-CuO/palygorskite nanocomposites[J].Appl Clay Sci,2013,74(74):87-94.
[11]高薇,陈天虎,庆承松,等.坡缕石/磁性铁氧化物/Ti02复合光催化剂性能实验研究[J].岩石矿物学杂志,2009,28(2):185-190.GAO W,CHEN T H,QING C S,et al.Acta Petrologica et Mineralogica Acta Petrol Miner(in Chinese),2009,28(2):185-190.
[12]潘敏,陈天虎,黄晓鸣,等.凹凸棒石/氢氧化物纳米复合材料对磷的吸附热力学[J].硅酸盐学报,2009,37(10):1673-1677.PAN M,CHEN T H,HUANG X M,et al.J Chin Ceram Soc,2009,37(10):1673-1677.
[13]陈天虎,冯有亮,史晓莉.凹凸棒石与酸反应纳米尺度研究:产物和结构演化[J].硅酸盐学报,2003,31(10):959-964.CHEN T H,FENG Y L,SHI X L,et al.J Chin Ceram Soc,2003,31(10):959-964.
[14]彭书传,宋磊,马步春,等.棒状活性二氧化硅补强橡胶[J].硅酸盐学报,2009,37(1):103-106.PENG S C,SONG L,MA B C,et al.J Chin Ceram Soc,2006,34(11):1406-1410.
[15]姚超,左士祥,杜郢,等.凹凸棒石的表面改性及其在脲醛树脂中的应用[J].硅酸盐学报,2011,39(4):630-634.YAO C,ZUO S X,DU Y,et al.J Chin Ceram Soc,2006,34(11):1406-1410.
[16]王海洋,邵佳敏,唐颂超.PET/纳米凹凸棒母料复合材料性能与结构研究[J].工程塑料应用,2008,36(1):17-19.WANG H Y,SHAO J M,TANG S C.Eng Plastic Appl(in Chinese),2006,34(11):1406-1410.
[17]CHEN T H,LIU H B,SHI P C,et al.CO_2 reforming of toluene as model compound of biomass tar on Ni/Palygorskite[J].Fuel,2013,107:699-705.
[18]SONG L,CHEN T H,XIE J J,et al.Catalytic decomposition of toluene over La_(1-x)SrMnO_3/palygorskite synthesized catalysts[J].Chem Eng Technol,2013,39(3):31-42.
[19]LIU H B,CHEN T H,CHANG D Y,et al.Effect of preparation method of palygorskite-supported Fe and Ni catalysts on catalytic cracking of biomass tar[J].Chem Eng J,2012,188:108-112.
[20]LIU H B,CHEN T H,CHEN D,et al.Catalytic cracking biomass tar derived from rice hull gasification with palygorskite-supported Ni and Fe[J].J Mol Catal A:2012,363-364:304-310.
[21]ZOU X H,CHEN T H,LIU H B,et al.An insight into the effect of calcination conditions on catalytic cracking:of toluene over3Fe8Ni/palygorskite:Catalysts characterization and performance[J].Fuel,2017,190:47-57.
[22]LIU H B,CHEN T H,CHANG D Y,et al.Effect of rehydration on structure and surface property of thermally treated palygorskite[J].J Colloid Interface Sci,2013,393:87-91.
[23]颜文昌,袁鹏,谭道永,等.富镁与贫镁坡缕石的红外光谱[J].硅酸盐学报,2013,41(1):89-95.YANG W C,YANG P,TANG D Y,et al.J Chin Ceram Soc,2013,41(1):89-95.
[24]谢晶晶,陈天虎,陈冬,等.~(27)Al魔角旋转核磁共振研究热处理凹凸棒石结构中Al配位变化[J].硅酸盐学报,2014,41(2):235-239.XIE J J,CHEN T H,CHEN D,et al.J Chin Ceram Soc,2014,41(2):235-239.
[25]陈天虎,彭书传,黄川徽,等.从苏皖凹凸棒石粘土制备纯凹凸棒石[J].硅酸盐学报,2004,32(8):965-969.CHEN T H,PENG S C,HUANG C H,et al.J Chin Ceram Soc,2004,32(8):965-969.
[26]王礼君,惠剑,陈权,等.基于异丙醉蒸汽爆破的凹凸棒石黏土微纳米化及晶束解离[J].硅酸盐学报,2015,43(8):1156-1161.WANG L J,HUI J,CHEN Q,et al.J Chin Ceram Soc,2015,43(8):1156-1161.
[27]WANG W B,WANG A Q.Recent progress in dispersion of palygorskite crystal bundles for nanocomposites[J].Appl Clay Sci,2016,119:18-30.
[28]XU J X,WANG W B.Effects of solvent treatment and high-pressure homogenization process on dispersion properties of palygorskite[J].Powder Technol,2013,652-660.
[29]XU J X,WANG W B,Wang Aiqin.Enhanced microscopic structure and properties of palygorskite by associated extrusion and high-pressure homogenization process[J].Appl Clay Sci,2014,95:365-370.
[30]WANG Qin,ZHANG Junping,WANG A Q.Freeze-drying:A versatile method to overcome re-aggregation and improve dispersion stability of palygorskite for sustained release of ofloxacin[J].Appl Clay Sci,2014,87:7-13.
[31]WANG W B,WANG F F,KANG Y R,et al.Nanoscale dispersion crystal bundles of palygorskite by associated modification with phytic acid and high-pressure homogenization for enhanced colloidal properties[J].Powder Technol,2015,269:85-92.
[32]刘悦,刘元法,王兴国,等.凹凸棒石脱色大豆油的热力学研究[J].食品科学,2008,29(12):164-167.LIU Y,LIU Y F,WANG X G,et al.Food Sci(in Chinese),2008,29(12):164-167.
[33]CAI D Q,WU Z Y,JIANG J,et al.Controlling nitrogen migration through micro-nano networks[J].Sci Rep,2014,4(2):3665.
[34]CAI D Q,WU Z Y,JIANG J,et al.A unique technology to transform inorganic nanorods into nano-networks[J].Nanotechnology,2009,20(25):255302.
[35]YANG H M,TANG A D,OUYANG J,et al.From natural attapulgite to mesoporous materials:methodology,characterization and structural evolution[J].J Phys Chem B,2010,114(7):2390-2398.
[36]HE X,FU I J,YANG H M.Insight into the nature of Au-Au_2O_3functionalized palygorskite[J].Appl Clay Sci,2014,100(2):118-122.
[37]HE X,WANG J J,SHU Z,et al.Y_2O_3 functionalized natural palygorskite as an adsorbent for methyl blue removal[J].RSC Adv,2016,6(48):41765-41771.
[38]HE X,YANG H M.Au nanoparticles assembled on palygorskite:Au-Au_2O_3 coexistence and enhanced catalytic property[J].J Mol Catal A:Chem,2013,379(1):219-224.
[39]HUO C L,YANG H M.Attachment of nickel oxide nanoparticles on the surface of palygorskite nanofibers[J].J Colloid Interface Sci,2012,384(1):55-60.
[40]HUO C L,YANG H M.Synthesis and characterization of ZnO/palygorskite[J].Appl Clay Sci,2015,50(3):362-366.
[41]KONG Y,WEI J X,WANG Z L.Heavy Metals Removal from Solution by Polyaniline/Palygorskite Composite[J].J Appl Polym Sci,2011,122(3):2054-2059.
[42]LIANG X F,HAN J,XU Y M.In situ field-scale remediation of Cd polluted paddy soil using sepiolite and palygorskite[J].Geoderma,2014,S235-236(4):9-18.
[43]LIANG X F,XU Y M,TAN X.Heavy metal adsorbents mercapto and amino functionalized palygorskite:Preparation and characterization[J].Colloids Surf A:Physicochem Eng Aspects,2013,426(21):98-105.
[44]HAN J XU Y M,LIANG X F.Sorption stability and mechanism exploration of palygorskite as immobilization agent for Cd in polluted soil[J].Water Air Soil Pollut,2014,225(10):2160-2172.
[45]ZHANG J P,WANG A Q.Adsorption of Pb(II)from aqueous solution by chitosan-g-poly/attapulgite/sodium humate composite hydrogels[J].J Chem Eng Data,2010,55(7):2379-2384.
[46]ZHOU S Y,XUE A L,ZHAO Y J.Competitive adsorption of Hg~(2+),Pb~(2+)and Co~(2+)ions on polyacrylamide/attapulgite[J].Desalination,2011,270(1-3):269-274.
[47]MU B,WANG AQ.Adsorption of dyes onto palygorskite and its composites:A review[J].J Environ Chem Eng,2016,(4):1274-1294.
[48]ZHANG Y J,ZANG J P,WANG A Q.From Maya Blue to biomimetic pigments:Durable biomimetic pigments with self-cleaning property[J].J Mater Chem A,2016,(4):901-907.
[49]TIAN G Y,WANG W B,WANG D D,et al.Novel environment friendly inorganic red pigments based on attapulgite[J].Powder Technol,2017,315:60-67.
[50]XU J X,WANG W B,WANG A Q.Stable formamide/palygorskite nanostructure hybrid material fortified by high-pressure homogenization[J].Powder Technol,2017,318:1-7.
[51]WANG Q,MU B,ZHANG Y,et al.Palygorskite-based hybrid fluorescent pigment:preparation,spectroscopic characterization and environmental stability[J].Micropor Mesopor Mater,2016,224:107-115.
[52]ZHANG Y J,FAN L,CHEN H,et al.Learning from ancient Maya:Preparation of stable palygorskite/methylene blue@SiO_2 Maya Blue-like pigment[J].Micropor Mesopor Mater,2015,211:124-133.
[53]牟斌,汪琴,王爱勤.CoAl2O_4/凹凸棒石杂化颜料的制备.吉林大学学报(地球科学版),2015,45:1501.MOU B,WANG Q,WANG A Q.J Jilin Unv:Earth Sci Ed(in Chinese),2015,45:1501.
[54]MU B,KANG Y R,WANG A Q.Preparation of a polyelectrolytecoated magnetic attapulgite composite for the adsorption of precious metals[J].J Mater Chem A,2013,1(15):4804-4811.
[55]MU B,ZHANG W B,SHAO S J,et al.Glycol assisted synthesis of graphene/MnO_2/polyaniline ternary composites for high performance supercapacitor electrodes[J].Phys Chem Chem Phys,2014,16(17):7872-7880.
[56]赵晓兵,张作松,李霞章,等.g-C_3N_4-CeO_2/ATP复合材料的制备及可见光催化性能[J].硅酸盐学报,2015,43(11):1650-1655.ZHAO X B,ZHANG Z S,LI Z X,et al.J Chin Ceram Soc,2015,43(11):1650-1655.
[57]姚超,王文娟,陈志刚,等.聚吡咯/凹凸棒石纳米复合材料的制备及导电性能[J].硅酸盐学报,2009,37(12):2031-2036.YAO C,WANG W J,CHEN Z G,et al.J Chin Ceram Soc,2009,37(12):2031-2036.
[58]姚超,曾永斌,曹燕媛,等.聚苯胺/凹凸棒石纳米复合材料对甲基橙的吸附性能[J].硅酸盐学报,2010,38(4):671-676.YAO C,ZENG Y B,CAO Y Y,et al.J Chin Ceram Soc,2010,38(4):671-676.
[59]李霞章,姚超,陈志刚.凹凸棒石/Ce_(1-x)Zr_xO_2纳米复合材料的制备及其催化氧化性能[J].硅酸盐学报,2011,39(8):1307-1310.LI X Z,YAO C,CHEN Z G,et al.J Chin Ceram Soc,2011,39(8):1307-1310.
[60]李金虎,张先龙,陈天虎,等.凹凸棒石负载锰氧化物低温SCR催化剂表征及对氨的吸脱附[J].催化学报,2010,31(4):454-460.LI J H,ZHANG X L,CHEN T H,et al.Chin J Catal(in Chinese),2010,31(4):454-460.
[61]施培超,陈天虎,张先龙,等.生物质焦油组分甲苯在Ni/凹凸棒石上的CO_2催化重整[J].催化学报,2010,31(10):1281-1285.SHI P C,CHEN T H,ZHANG X L,et al.Chin J Catal(in Chinese),2010,31(10):1281-1285.
[62]刘海波,陈天虎,石莹,等.凹凸棒石粘土负载Ni催化裂解生物质焦油[J].硅酸盐学报,2011,39(4):590-595.LIU H B,CHEN T H,SHI Y,et al.J Chin Ceram Soc,2011,39(4):590-595.
[63]MA J Z,ZHU C Z,LU J,et al.Catalytic degradation of gaseous benzene by using TiO_2/goethite immobilized on palygorskite:Preparation,characterization,mechanism and kinetics[J].Solid State Sci,2015,49:1-7.
[64]ZHU C Z,WANG X H,HUANG Q,et al.Removal of gaseous carbon bisulfide using dielectric barrier discharge plasmas combined with Ti02coated attapulgite catalyst[J].Chem Eng J,2013,225(6):567-573.
[65]SONG L,CHEN T H,XIE J J,et al.Catalytic decomposition of toluene over La_(1-x)SrMnO_3/palygorskite synthesized catalysts[J].Chem Eng Technol,2013,39(3):31-42.
[66]ZHANG J H,ZHANG L L,HUANG J.A cost-effective magnetic photocatalyst palygorskite-TiO_2-Fe_xO_y with excellent performance for dye photodegredation under visible light[J].Nano,2014,9(6):20-28.
[67]ZHANG L L,LIU J Q,TANG C,et al.Palygorskite and SnO_2-TiO_2 for the photodegradation of phenol[J].Appli Clay Sci,2011,51(1/2):68-73.
[68]JIANG J L,XU Y,DUANMU C S.Preparation and catalytic properties of sulfonated carbon-palygorskite solid acid catalyst[J].Appl Clay Sci,2014,95(6):260-264.
[69]XIE J J,CHEN T H,XING B B,et al.The thermochemical activity ofdolomite occurred in dolomite-palygorskite clay[J].Appl Clay Sci,2016,119:42-48.
[70]LI L X,LI B C,FAN L,et al.Palygorskite@Fe_3O_4@polyperfluoroalkylsilane nanocomposites for superoleophobic coatings and magnetic liquid marbles[J].J Mater Chem A,2016,4:5859-5868
[71]TIAN G Y,WANG W B,ZONG L,et al.From spent dye-loaded palygorskite to a multifunctional palygorskite/carbon/Ag nanocomposite[J].RSC Adv,2016(6):41696-41706
[72]MU B,WANG A Q.One-pot fabrication of multifunctional superparamagnetic attapulgite/Fe_3O_4/polyani line nanocomposites served as adsorbent and catalyst support[J].J Mater Chem A,2015,3(1):281-289.
[73]LU H L,WANG W B,WANG A Q.Ethanol-NaOH solidification method intensify chitosan/poly(vinyl alcohol)/attapulgite composite film[J].RSC Adv,2015(5):17775-17781.
[74]TANG J,MU B,ZONG L,et al.Fabrication of attapulgite/carbon composites from the spent bleaching earth for the efficient adsorption of methylene blue[J].RSC Adv,2015(5):38443-38451.
[75]谢晶晶,邢波波,陈天虎,等.不同矿石类型凹凸棒石黏土热处理后磷的吸附性能[J].硅酸盐学报,2014,42(5):683-687.XIE J J,XING B B,CHEN T H,et al.J Chin Ceram Soc,2014,42(5):683-687.
[76]陈天虎,汪嘉源,束松林,等.改性凹凸棒石粘土吸附低浓度磷的热力学研究[J].硅酸盐学报,2010,38(9):1816-1819.CHEN T H,WANG J Y,SU S L,et al.J Chin Ceram Soc,2010,38(9):1816-1819.
[77]石莹,陈天虎,张先龙,等.凹凸棒石黏土催化裂解生物质焦油[J].太阳能学报,2010,31(9):1092-1096.SHI Y,CHEN T H,ZHANG X L,et al.Acta Energiae Sol Sin(in Chinese),2010,31(9):1092-1096.
[78]BAO T,CHEN T H,QING C S,et al.Development and application of palygorskite porous ceramsite in a biological aerated filter(BAF)[J].Desalinat Water Treat,2016,57(4):1790-1803.
[79]GAN F Q,ZHOU J M,WANG H Y,et al.Removal of phosphate from aqueous solution by thermally treated natural palygorskite[J].Water Res,2009,43(11):2907-2915.
[80]LIU H B,CHEN T H,CHANG D Y,et al.Effect of palygorskite clay on catalytic pyrolysis of rape straw:an in-situ catalytic cracking study[J].J Colloid Interface Sci,2014,417(3):264-269.
[81]QIU G,XIE Q Q,LIU H B,et al.Removal of Cu(Ⅱ)from aqueous solution using dolomite-palygorskite clay:performance and removal mechanism[J].Appl Clay Sci,2015,118:107-115.
[82]XIE J J,CHEN T H,QING C S,et al.Adsorption of phosphate from aqueous solution onto thermal modified palygorskite[J].Environ Eng Manag J,2013 12(7):1393-1399.
[2]陈天虎,徐晓春,岳书仓.苏皖地区凹凸棒石黏土纳米矿物学及地球化学[M].北京:科学出版社,2004:77-78.
[3]孔德军,陈天虎,刘海波,等.煅烧凹凸棒石的水化处理对其结构和吸附NH3的影响[J].硅酸盐学报,2011,39(11):1867-1871.KONG D J,CHEN T H,LIU H B et al.J Chin Ceram Soc,2011,39(11):1867-1871.
[4]姚超,曾永斌,曹燕媛,等.聚苯胺/凹凸棒石纳米复合材料对甲基橙的吸附性能[J].硅酸盐学报,2010,38(4):671-677.YAO C,ZENG Y B,CAO Y Y,et al.J Chin Ceram Soc,2010,38(4):671-677.
[5]CHEN T H,LIU H B,LI J H,et al.Effect of thermal treatment onadsorption-desorption of ammonia and sulfur dioxide on palygorskite:Change of surface acid-alkali properties[J].Chem Eng J,2011,166(3):1017-1021.
[6]高东升,陈天虎,吴雪平,等.苏皖凹凸棒石粘土水悬浮液流变性能研究[J].岩石矿物学杂志,2009,28(6):665-669.GAO D S,CHEN T H,WU X P,et al.Acta Petrol Miner(in Chinese),2009,28(6):665-669.
[7]LIU H B,CHEN T H,CHANG D Y,et al.The difference of thermal stability between Fe-substituted palygorskite and Al-rich palygorskite[J].J Thermal Anal Calorim,2013,111(1):409-415.
[8]陈天虎,王健,庆承松,等.凹凸棒石热处理结构、形貌和表面性质变化[J].硅酸盐学报,2006,34(11):1406-1410.CHEN T H,WAGN J,QING C S,et al.J Chin Ceram Soc,2006,34(11):1406-1410.
[9]谢品晶,陈天虎,庆承松,等.热处理凹凸棒石结构演化[J].地学前缘,2014,21(5):338-345.XIE Jingjing,CHEN Tianhu,QING Chengsong,et al.Earth Sci Front(in Chinese),2014,21(5):338-345.
[10]HUO C L,YANG H M.Preparation and enhanced photocatalytic activity of Pd-CuO/palygorskite nanocomposites[J].Appl Clay Sci,2013,74(74):87-94.
[11]高薇,陈天虎,庆承松,等.坡缕石/磁性铁氧化物/Ti02复合光催化剂性能实验研究[J].岩石矿物学杂志,2009,28(2):185-190.GAO W,CHEN T H,QING C S,et al.Acta Petrologica et Mineralogica Acta Petrol Miner(in Chinese),2009,28(2):185-190.
[12]潘敏,陈天虎,黄晓鸣,等.凹凸棒石/氢氧化物纳米复合材料对磷的吸附热力学[J].硅酸盐学报,2009,37(10):1673-1677.PAN M,CHEN T H,HUANG X M,et al.J Chin Ceram Soc,2009,37(10):1673-1677.
[13]陈天虎,冯有亮,史晓莉.凹凸棒石与酸反应纳米尺度研究:产物和结构演化[J].硅酸盐学报,2003,31(10):959-964.CHEN T H,FENG Y L,SHI X L,et al.J Chin Ceram Soc,2003,31(10):959-964.
[14]彭书传,宋磊,马步春,等.棒状活性二氧化硅补强橡胶[J].硅酸盐学报,2009,37(1):103-106.PENG S C,SONG L,MA B C,et al.J Chin Ceram Soc,2006,34(11):1406-1410.
[15]姚超,左士祥,杜郢,等.凹凸棒石的表面改性及其在脲醛树脂中的应用[J].硅酸盐学报,2011,39(4):630-634.YAO C,ZUO S X,DU Y,et al.J Chin Ceram Soc,2006,34(11):1406-1410.
[16]王海洋,邵佳敏,唐颂超.PET/纳米凹凸棒母料复合材料性能与结构研究[J].工程塑料应用,2008,36(1):17-19.WANG H Y,SHAO J M,TANG S C.Eng Plastic Appl(in Chinese),2006,34(11):1406-1410.
[17]CHEN T H,LIU H B,SHI P C,et al.CO_2 reforming of toluene as model compound of biomass tar on Ni/Palygorskite[J].Fuel,2013,107:699-705.
[18]SONG L,CHEN T H,XIE J J,et al.Catalytic decomposition of toluene over La_(1-x)SrMnO_3/palygorskite synthesized catalysts[J].Chem Eng Technol,2013,39(3):31-42.
[19]LIU H B,CHEN T H,CHANG D Y,et al.Effect of preparation method of palygorskite-supported Fe and Ni catalysts on catalytic cracking of biomass tar[J].Chem Eng J,2012,188:108-112.
[20]LIU H B,CHEN T H,CHEN D,et al.Catalytic cracking biomass tar derived from rice hull gasification with palygorskite-supported Ni and Fe[J].J Mol Catal A:2012,363-364:304-310.
[21]ZOU X H,CHEN T H,LIU H B,et al.An insight into the effect of calcination conditions on catalytic cracking:of toluene over3Fe8Ni/palygorskite:Catalysts characterization and performance[J].Fuel,2017,190:47-57.
[22]LIU H B,CHEN T H,CHANG D Y,et al.Effect of rehydration on structure and surface property of thermally treated palygorskite[J].J Colloid Interface Sci,2013,393:87-91.
[23]颜文昌,袁鹏,谭道永,等.富镁与贫镁坡缕石的红外光谱[J].硅酸盐学报,2013,41(1):89-95.YANG W C,YANG P,TANG D Y,et al.J Chin Ceram Soc,2013,41(1):89-95.
[24]谢晶晶,陈天虎,陈冬,等.~(27)Al魔角旋转核磁共振研究热处理凹凸棒石结构中Al配位变化[J].硅酸盐学报,2014,41(2):235-239.XIE J J,CHEN T H,CHEN D,et al.J Chin Ceram Soc,2014,41(2):235-239.
[25]陈天虎,彭书传,黄川徽,等.从苏皖凹凸棒石粘土制备纯凹凸棒石[J].硅酸盐学报,2004,32(8):965-969.CHEN T H,PENG S C,HUANG C H,et al.J Chin Ceram Soc,2004,32(8):965-969.
[26]王礼君,惠剑,陈权,等.基于异丙醉蒸汽爆破的凹凸棒石黏土微纳米化及晶束解离[J].硅酸盐学报,2015,43(8):1156-1161.WANG L J,HUI J,CHEN Q,et al.J Chin Ceram Soc,2015,43(8):1156-1161.
[27]WANG W B,WANG A Q.Recent progress in dispersion of palygorskite crystal bundles for nanocomposites[J].Appl Clay Sci,2016,119:18-30.
[28]XU J X,WANG W B.Effects of solvent treatment and high-pressure homogenization process on dispersion properties of palygorskite[J].Powder Technol,2013,652-660.
[29]XU J X,WANG W B,Wang Aiqin.Enhanced microscopic structure and properties of palygorskite by associated extrusion and high-pressure homogenization process[J].Appl Clay Sci,2014,95:365-370.
[30]WANG Qin,ZHANG Junping,WANG A Q.Freeze-drying:A versatile method to overcome re-aggregation and improve dispersion stability of palygorskite for sustained release of ofloxacin[J].Appl Clay Sci,2014,87:7-13.
[31]WANG W B,WANG F F,KANG Y R,et al.Nanoscale dispersion crystal bundles of palygorskite by associated modification with phytic acid and high-pressure homogenization for enhanced colloidal properties[J].Powder Technol,2015,269:85-92.
[32]刘悦,刘元法,王兴国,等.凹凸棒石脱色大豆油的热力学研究[J].食品科学,2008,29(12):164-167.LIU Y,LIU Y F,WANG X G,et al.Food Sci(in Chinese),2008,29(12):164-167.
[33]CAI D Q,WU Z Y,JIANG J,et al.Controlling nitrogen migration through micro-nano networks[J].Sci Rep,2014,4(2):3665.
[34]CAI D Q,WU Z Y,JIANG J,et al.A unique technology to transform inorganic nanorods into nano-networks[J].Nanotechnology,2009,20(25):255302.
[35]YANG H M,TANG A D,OUYANG J,et al.From natural attapulgite to mesoporous materials:methodology,characterization and structural evolution[J].J Phys Chem B,2010,114(7):2390-2398.
[36]HE X,FU I J,YANG H M.Insight into the nature of Au-Au_2O_3functionalized palygorskite[J].Appl Clay Sci,2014,100(2):118-122.
[37]HE X,WANG J J,SHU Z,et al.Y_2O_3 functionalized natural palygorskite as an adsorbent for methyl blue removal[J].RSC Adv,2016,6(48):41765-41771.
[38]HE X,YANG H M.Au nanoparticles assembled on palygorskite:Au-Au_2O_3 coexistence and enhanced catalytic property[J].J Mol Catal A:Chem,2013,379(1):219-224.
[39]HUO C L,YANG H M.Attachment of nickel oxide nanoparticles on the surface of palygorskite nanofibers[J].J Colloid Interface Sci,2012,384(1):55-60.
[40]HUO C L,YANG H M.Synthesis and characterization of ZnO/palygorskite[J].Appl Clay Sci,2015,50(3):362-366.
[41]KONG Y,WEI J X,WANG Z L.Heavy Metals Removal from Solution by Polyaniline/Palygorskite Composite[J].J Appl Polym Sci,2011,122(3):2054-2059.
[42]LIANG X F,HAN J,XU Y M.In situ field-scale remediation of Cd polluted paddy soil using sepiolite and palygorskite[J].Geoderma,2014,S235-236(4):9-18.
[43]LIANG X F,XU Y M,TAN X.Heavy metal adsorbents mercapto and amino functionalized palygorskite:Preparation and characterization[J].Colloids Surf A:Physicochem Eng Aspects,2013,426(21):98-105.
[44]HAN J XU Y M,LIANG X F.Sorption stability and mechanism exploration of palygorskite as immobilization agent for Cd in polluted soil[J].Water Air Soil Pollut,2014,225(10):2160-2172.
[45]ZHANG J P,WANG A Q.Adsorption of Pb(II)from aqueous solution by chitosan-g-poly/attapulgite/sodium humate composite hydrogels[J].J Chem Eng Data,2010,55(7):2379-2384.
[46]ZHOU S Y,XUE A L,ZHAO Y J.Competitive adsorption of Hg~(2+),Pb~(2+)and Co~(2+)ions on polyacrylamide/attapulgite[J].Desalination,2011,270(1-3):269-274.
[47]MU B,WANG AQ.Adsorption of dyes onto palygorskite and its composites:A review[J].J Environ Chem Eng,2016,(4):1274-1294.
[48]ZHANG Y J,ZANG J P,WANG A Q.From Maya Blue to biomimetic pigments:Durable biomimetic pigments with self-cleaning property[J].J Mater Chem A,2016,(4):901-907.
[49]TIAN G Y,WANG W B,WANG D D,et al.Novel environment friendly inorganic red pigments based on attapulgite[J].Powder Technol,2017,315:60-67.
[50]XU J X,WANG W B,WANG A Q.Stable formamide/palygorskite nanostructure hybrid material fortified by high-pressure homogenization[J].Powder Technol,2017,318:1-7.
[51]WANG Q,MU B,ZHANG Y,et al.Palygorskite-based hybrid fluorescent pigment:preparation,spectroscopic characterization and environmental stability[J].Micropor Mesopor Mater,2016,224:107-115.
[52]ZHANG Y J,FAN L,CHEN H,et al.Learning from ancient Maya:Preparation of stable palygorskite/methylene blue@SiO_2 Maya Blue-like pigment[J].Micropor Mesopor Mater,2015,211:124-133.
[53]牟斌,汪琴,王爱勤.CoAl2O_4/凹凸棒石杂化颜料的制备.吉林大学学报(地球科学版),2015,45:1501.MOU B,WANG Q,WANG A Q.J Jilin Unv:Earth Sci Ed(in Chinese),2015,45:1501.
[54]MU B,KANG Y R,WANG A Q.Preparation of a polyelectrolytecoated magnetic attapulgite composite for the adsorption of precious metals[J].J Mater Chem A,2013,1(15):4804-4811.
[55]MU B,ZHANG W B,SHAO S J,et al.Glycol assisted synthesis of graphene/MnO_2/polyaniline ternary composites for high performance supercapacitor electrodes[J].Phys Chem Chem Phys,2014,16(17):7872-7880.
[56]赵晓兵,张作松,李霞章,等.g-C_3N_4-CeO_2/ATP复合材料的制备及可见光催化性能[J].硅酸盐学报,2015,43(11):1650-1655.ZHAO X B,ZHANG Z S,LI Z X,et al.J Chin Ceram Soc,2015,43(11):1650-1655.
[57]姚超,王文娟,陈志刚,等.聚吡咯/凹凸棒石纳米复合材料的制备及导电性能[J].硅酸盐学报,2009,37(12):2031-2036.YAO C,WANG W J,CHEN Z G,et al.J Chin Ceram Soc,2009,37(12):2031-2036.
[58]姚超,曾永斌,曹燕媛,等.聚苯胺/凹凸棒石纳米复合材料对甲基橙的吸附性能[J].硅酸盐学报,2010,38(4):671-676.YAO C,ZENG Y B,CAO Y Y,et al.J Chin Ceram Soc,2010,38(4):671-676.
[59]李霞章,姚超,陈志刚.凹凸棒石/Ce_(1-x)Zr_xO_2纳米复合材料的制备及其催化氧化性能[J].硅酸盐学报,2011,39(8):1307-1310.LI X Z,YAO C,CHEN Z G,et al.J Chin Ceram Soc,2011,39(8):1307-1310.
[60]李金虎,张先龙,陈天虎,等.凹凸棒石负载锰氧化物低温SCR催化剂表征及对氨的吸脱附[J].催化学报,2010,31(4):454-460.LI J H,ZHANG X L,CHEN T H,et al.Chin J Catal(in Chinese),2010,31(4):454-460.
[61]施培超,陈天虎,张先龙,等.生物质焦油组分甲苯在Ni/凹凸棒石上的CO_2催化重整[J].催化学报,2010,31(10):1281-1285.SHI P C,CHEN T H,ZHANG X L,et al.Chin J Catal(in Chinese),2010,31(10):1281-1285.
[62]刘海波,陈天虎,石莹,等.凹凸棒石粘土负载Ni催化裂解生物质焦油[J].硅酸盐学报,2011,39(4):590-595.LIU H B,CHEN T H,SHI Y,et al.J Chin Ceram Soc,2011,39(4):590-595.
[63]MA J Z,ZHU C Z,LU J,et al.Catalytic degradation of gaseous benzene by using TiO_2/goethite immobilized on palygorskite:Preparation,characterization,mechanism and kinetics[J].Solid State Sci,2015,49:1-7.
[64]ZHU C Z,WANG X H,HUANG Q,et al.Removal of gaseous carbon bisulfide using dielectric barrier discharge plasmas combined with Ti02coated attapulgite catalyst[J].Chem Eng J,2013,225(6):567-573.
[65]SONG L,CHEN T H,XIE J J,et al.Catalytic decomposition of toluene over La_(1-x)SrMnO_3/palygorskite synthesized catalysts[J].Chem Eng Technol,2013,39(3):31-42.
[66]ZHANG J H,ZHANG L L,HUANG J.A cost-effective magnetic photocatalyst palygorskite-TiO_2-Fe_xO_y with excellent performance for dye photodegredation under visible light[J].Nano,2014,9(6):20-28.
[67]ZHANG L L,LIU J Q,TANG C,et al.Palygorskite and SnO_2-TiO_2 for the photodegradation of phenol[J].Appli Clay Sci,2011,51(1/2):68-73.
[68]JIANG J L,XU Y,DUANMU C S.Preparation and catalytic properties of sulfonated carbon-palygorskite solid acid catalyst[J].Appl Clay Sci,2014,95(6):260-264.
[69]XIE J J,CHEN T H,XING B B,et al.The thermochemical activity ofdolomite occurred in dolomite-palygorskite clay[J].Appl Clay Sci,2016,119:42-48.
[70]LI L X,LI B C,FAN L,et al.Palygorskite@Fe_3O_4@polyperfluoroalkylsilane nanocomposites for superoleophobic coatings and magnetic liquid marbles[J].J Mater Chem A,2016,4:5859-5868
[71]TIAN G Y,WANG W B,ZONG L,et al.From spent dye-loaded palygorskite to a multifunctional palygorskite/carbon/Ag nanocomposite[J].RSC Adv,2016(6):41696-41706
[72]MU B,WANG A Q.One-pot fabrication of multifunctional superparamagnetic attapulgite/Fe_3O_4/polyani line nanocomposites served as adsorbent and catalyst support[J].J Mater Chem A,2015,3(1):281-289.
[73]LU H L,WANG W B,WANG A Q.Ethanol-NaOH solidification method intensify chitosan/poly(vinyl alcohol)/attapulgite composite film[J].RSC Adv,2015(5):17775-17781.
[74]TANG J,MU B,ZONG L,et al.Fabrication of attapulgite/carbon composites from the spent bleaching earth for the efficient adsorption of methylene blue[J].RSC Adv,2015(5):38443-38451.
[75]谢晶晶,邢波波,陈天虎,等.不同矿石类型凹凸棒石黏土热处理后磷的吸附性能[J].硅酸盐学报,2014,42(5):683-687.XIE J J,XING B B,CHEN T H,et al.J Chin Ceram Soc,2014,42(5):683-687.
[76]陈天虎,汪嘉源,束松林,等.改性凹凸棒石粘土吸附低浓度磷的热力学研究[J].硅酸盐学报,2010,38(9):1816-1819.CHEN T H,WANG J Y,SU S L,et al.J Chin Ceram Soc,2010,38(9):1816-1819.
[77]石莹,陈天虎,张先龙,等.凹凸棒石黏土催化裂解生物质焦油[J].太阳能学报,2010,31(9):1092-1096.SHI Y,CHEN T H,ZHANG X L,et al.Acta Energiae Sol Sin(in Chinese),2010,31(9):1092-1096.
[78]BAO T,CHEN T H,QING C S,et al.Development and application of palygorskite porous ceramsite in a biological aerated filter(BAF)[J].Desalinat Water Treat,2016,57(4):1790-1803.
[79]GAN F Q,ZHOU J M,WANG H Y,et al.Removal of phosphate from aqueous solution by thermally treated natural palygorskite[J].Water Res,2009,43(11):2907-2915.
[80]LIU H B,CHEN T H,CHANG D Y,et al.Effect of palygorskite clay on catalytic pyrolysis of rape straw:an in-situ catalytic cracking study[J].J Colloid Interface Sci,2014,417(3):264-269.
[81]QIU G,XIE Q Q,LIU H B,et al.Removal of Cu(Ⅱ)from aqueous solution using dolomite-palygorskite clay:performance and removal mechanism[J].Appl Clay Sci,2015,118:107-115.
[82]XIE J J,CHEN T H,QING C S,et al.Adsorption of phosphate from aqueous solution onto thermal modified palygorskite[J].Environ Eng Manag J,2013 12(7):1393-1399.