电极材料对微生物燃料电池处理老龄垃圾渗滤液性能的影响
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摘要
以碳毡和碳布为电极材料,老龄垃圾渗滤液为阳极底物构建生物阴极型微生物燃料电池(MFC),考察碳毡和碳布分别作为阴极和阳极材料时对MFC明在阳极材料相同时,碳毡阴极MFC料相同时,碳布阳极MFC输出电压和功率密度最大(分别为294 mV、95.31 mW/m~3)、化学需氧量和氨氮去除率最大(分别为58.78%、74.38%);阳极、阴极均为碳布的MFC内阻最小(308Ω),阳极、阴极均为碳毡的MFC内阻最大(347Ω)。
Bio-cathode microbial fuel cell(MFC)using carbon felt and carbon cloth as electrode materials and treatedaging landfill leachate as anolyte were investigated for their electricity production and treatment performance. As the anode materials are same,the electricity production and treatment performance of the MFC using carbon felt as cathode materials are both better than those of the MFC using carbon cloth as cathode materials. Meanwhile,the electricity production and treatment performance of the MFC using carbon cloth as anode materials are better than those of the MFCs using carbon felt-cathode MFC when the cathode materials are same. The MFC,used carbon cloth as anode material and carbon felt as cathode material,harvests maximum voltage and power density(294 mV,95.31 mW/m~3),and the highest chemical oxygen demand and ammonia removal rate(58.78%,74.38%). The minimum internal resistance is 308 Ω as carbon cloth is used as electrodes,while the maximum internal resistance is 347 Ω,when carbon felt is used as electrodes.
Bio-cathode microbial fuel cell(MFC)using carbon felt and carbon cloth as electrode materials and treatedaging landfill leachate as anolyte were investigated for their electricity production and treatment performance. As the anode materials are same,the electricity production and treatment performance of the MFC using carbon felt as cathode materials are both better than those of the MFC using carbon cloth as cathode materials. Meanwhile,the electricity production and treatment performance of the MFC using carbon cloth as anode materials are better than those of the MFCs using carbon felt-cathode MFC when the cathode materials are same. The MFC,used carbon cloth as anode material and carbon felt as cathode material,harvests maximum voltage and power density(294 mV,95.31 mW/m~3),and the highest chemical oxygen demand and ammonia removal rate(58.78%,74.38%). The minimum internal resistance is 308 Ω as carbon cloth is used as electrodes,while the maximum internal resistance is 347 Ω,when carbon felt is used as electrodes.
引文
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[24]曹琳,雍晓雨,周俊,等.以沼液为原料的微生物燃料电池产电降解特性[J].化工学报,2014,65(5):1900-1905.[24]Cao Lin,Yong Xiaoyu,Zhou Jun,et al.Electrical and degradation characteristics of microbial fuel cell using biogas slurry as substrate[J].CIESC Journal,2014,65(5):1900-1905.
[25]卢娜,周顺桂,倪晋仁.微生物燃料电池的产电机制[J].化学进展,2008,20(7/8):1233-1240.[25]Lu Na,Zhou Shungui,Ni Jinren.Mechanism of energy generation of microbial fuel cell[J].Progress in Chemistry,2008,20(7/8):1233-1240.
[26]Logan B E.Exoelectrogenic bacteria that power microbial fuel cells[J].Nature Reviews Microbiology,2009,7(5):375-381.
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[28]周少奇.氨氮厌氧氧化的微生物反应机理[J].华南理工大学学报:自然科学版,2000,28(11):16-19.[28]Zhou Shaoqi.Microbial biochemical reactions of anaerobic oxidation of ammonium[J].Journal of South China University of Technology:Natural Science Edition,2000,28(11):16-19.
[2]Logan B E,Hamelers B,Rozendal R,et al.Microbial fuel cells:Methodology and technology[J].Environmental Science and Technology,2006,40(17):5181-5192.
[3]Li Zhuang,Yu Zheng,Zhou Shungui,et al.Scalable microbial fuel cell(MFC)stack for continuous real wastewater treatment[J].Bioresource Technology,2011,106:82-88.
[4]Oh S E,Logan B E.Hydrogen and electricity production from a food processing wastewater using fermentation and microbial fuel cell technology[J].Water Research,2005,39(19):4673-4682.
[5]Min Booki,Kim Jung-Rae,Oh Sang-Eun,et al.Electricity generation from swine wastewater using microbial fuel cells[J].Water Research,2005,39(20):4961-4968.
[6]王鑫,冯玉杰,曲友鹏,等.温度对啤酒废水微生物燃料电池产电性能的影响[J].环境科学,2008,29(11):3128-3132.[6]Wang Xin,Feng Yujie,Qu Youpeng,et al.Effect of temperature on performance of microbial fuel cell using beer wastewater[J].Environmental Science,2008,29(11):3128-3132.
[7]卢娜,周奔,邓丽芳,等.MnO2为阴极催化剂的微生物燃料电池处理淀粉废水研究[J].应用基础与工程科学学报,2009,17:65-72.[7]Lu Na,Zhou Ben,Deng Lifang,et al.Starch processing wastewater treatment using a continuous microbial fuel cell with MnO2cathodic catalyst[J].Journal of Basic Science and Engineering,2009,17:65-72.
[8]Katuri K P,Enright A M,Flaherty V,et al.Microbial analysis of anodic biofilm in a microbial fuel cell using slaughter house wastewater[J].Bioelectro Chemistry,2010,87:164-171.
[9]樊立萍,苗晓慧.微生物燃料电池处理餐饮废水及同步发电性能研究[J].燃料化学学报,2014,42(12):1506-1512.[9]Fan Liping,Miao Xiaohui.Study on the performance of microbial fuel cell for restaurant wastewater treatment and simultaneous electricity generation[J].Journal of Fuel Chemistry and Technology,2014,42(12):1506-1512.
[10]You Shijie,Zhao Qingliang,Jiang Junqiu,et al.Sustainable approach for leachate treatment:Electricity generation in microbial fuel cell[J].Journal of Environmental Science and Health,Part A:Toxic Hazardous Substances&Envirnonental Engineering,2006,41(12):2721-2734.
[11]Greenman J,Gálvez A,Giusti L,et al.Electricity from landfill leachate using microbial fuel cells:Comparison with a biological aerated filter[J].Enzyme and Microbial Technology,2009,44(2):112-119.
[12]谢珊,梁鹏,李亮,等.两瓶型微生物燃料电池处理垃圾渗滤液的研究[J].中国给水排水,2011,27(15):16-20.[12]Xie Shan,Liang Peng,Li Liang,et al.Landfill leachate treatment with two-bottle H type microbial fuel cell[J].China Water and Wastewater,2011,27(15):16-20.
[13]?zkaya B,Cetinkaya A Y,Cakmkci M,et al.Electricity generation from young landfill leachate in a microbial fuel cell with a new electrode material[J].Bioprocessing and Biosystems Engineering,2013,36:399-405.
[14]严丰,黄少斌,许玫英,等.微生物燃料电池处理晚期垃圾渗滤液的特性研究[J].工业水处理,2013,33(1):52-55.[14]Yan Feng,Huang Shaobin,Xu Meiying,et al.Treatment of mature landfill leachate by microbial fuel cell[J].Industrial Water Treatment,2013,33(1):52-55.
[15]Li Yan,Lu Anhuai,Ding Hongrui,et al.Microbial fuel cells using natural pyrrhotite as the cathodic heterogeneous Fenton catalyst towards the degradation of biorefractory organics in landfill leachate[J].Electrochemistry Communications,2010,12(7):944-947.
[16]Kulikowska D,Klimiuk E.The effect of landfill age on municipal leachate composition[J].Bioresource Technology,2008,99(13):5981-5985.
[17]Khattabi H,Aleya L,Mania J.Changes in the quality of landfill leachates from recent and aged municipal solid waste[J].Waste Management and Research,2002,20(4):357-364.
[18]Kjeldsen P,Christophersen M.Composition of leachate from old landfills in Denmark[J].Waste Management and Research,2001,19(3):249-256.
[19]Zhou Minghua,Chi Meiling,Luo Jianmei,et al.An overview of electrode materials in microbial fuel cells[J].Journal of Power Sources,2011,196(10):4427-4435.
[20]张晓艳,腾洪辉.以垃圾渗滤液为燃料的微生物燃料电池产电性能[J].吉林大学学报,2011,49(6):1162-1166.[20]Zhang Xiaoyan,Teng Honghui.Electricity generation characteristics of microbial fuel cell with landfill leachate as fuel[J].Journal of Jilin University,2011,49(6):1162-1166.
[21]程李钰,徐龙君.电极面积对老龄垃圾渗滤液为底物的微生物燃料电池性能影响[J].燃料化学学报,2015,43(8):1011-1017.[21]Cheng Liyu,Xu Longjun.Effects of electrode surface area on the performance of microbial fuel cells with the aging landfill leachate as substrate[J].Journal of Fuel Chemistry and Technology,2015,43(8):1011-1017.
[22]周玲,李萍,颜幼平.微生物燃料电池阳极碳材料对产电性能的影响[J].安徽农业大学学报,2011,38(4):647-650.[22]Zhou Ling,Li Ping,Yan Youping.Effect of microbial fuel cell anode carbon material on MFC electrogenesis[J].Journal of Anhui Agricultural University,2011,38(4):647-650.
[23]Fan Liping,Miao Xiaohui.Study on the performance of microbial fuel cell for restaurant wastewater treatment and simultaneous electricity generation[J].Journal of Fuel Chemistry and Technology,2014,42(12):1506-1512.
[24]曹琳,雍晓雨,周俊,等.以沼液为原料的微生物燃料电池产电降解特性[J].化工学报,2014,65(5):1900-1905.[24]Cao Lin,Yong Xiaoyu,Zhou Jun,et al.Electrical and degradation characteristics of microbial fuel cell using biogas slurry as substrate[J].CIESC Journal,2014,65(5):1900-1905.
[25]卢娜,周顺桂,倪晋仁.微生物燃料电池的产电机制[J].化学进展,2008,20(7/8):1233-1240.[25]Lu Na,Zhou Shungui,Ni Jinren.Mechanism of energy generation of microbial fuel cell[J].Progress in Chemistry,2008,20(7/8):1233-1240.
[26]Logan B E.Exoelectrogenic bacteria that power microbial fuel cells[J].Nature Reviews Microbiology,2009,7(5):375-381.
[27]Fan Yanzhen,Sharbrough E,Liu Hong.Quantification of the internal resistance distribution of microbial fuel cells[J].Environmental Science and Technology,2008,42(21):8101-8107.
[28]周少奇.氨氮厌氧氧化的微生物反应机理[J].华南理工大学学报:自然科学版,2000,28(11):16-19.[28]Zhou Shaoqi.Microbial biochemical reactions of anaerobic oxidation of ammonium[J].Journal of South China University of Technology:Natural Science Edition,2000,28(11):16-19.