不饱和橡胶的热氧老化研究进展
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摘要
简要介绍了不饱和橡胶热氧老化的分子机理,详细总结了近年来有关温度、分子链结构、硫化网构和填充体系等因素对热氧老化的影响规律,以及红外光谱、核磁共振波谱和电子自旋共振光谱等分析评价方法的研究进展,概述了橡胶防老化的研究现状,并对今后不饱和橡胶热氧老化研究的关键问题和方向做出展望。
The molecular mechanism of thermo-oxidative aging of unsaturated rubber was briefly introduced. The effects of temperature,chain structure,vulcanizing network forming and filler system etc on thermo-oxidative aging,as well as the research progress of analytical methods such as infrared spectroscopy,nuclear magnetic resonance spectroscopy and electron spin resonance spectroscopy were summarized in detail. Subsequently,recent research on anti-aging technology of rubber was generalized with 47 references. Finally,the prospect for the key points and future of thermo-oxidative aging of unsaturated rubber was provided.
The molecular mechanism of thermo-oxidative aging of unsaturated rubber was briefly introduced. The effects of temperature,chain structure,vulcanizing network forming and filler system etc on thermo-oxidative aging,as well as the research progress of analytical methods such as infrared spectroscopy,nuclear magnetic resonance spectroscopy and electron spin resonance spectroscopy were summarized in detail. Subsequently,recent research on anti-aging technology of rubber was generalized with 47 references. Finally,the prospect for the key points and future of thermo-oxidative aging of unsaturated rubber was provided.
引文
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[18]吴传营,赵菲,赵树高.硫化体系对丁腈橡胶NB 3305性能的影响[C]∥“诚信”杯2010年橡胶制品新技术交流暨信息发布会论文集.咸阳:《特种橡胶制品》编辑部,2011:154-157.
[19]李秀明.天然橡胶双硫化体系以及白炭黑/PDMS复合材料的研究[D].北京:北京化工大学,2016.
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[21] Liu M,Horrocks A R. Effect of carbon black on UV stability of LLDPE films under artificial weathering conditions[J]. Polymer Degradation&Stability,2002,75(3):485-499.
[22]张翠美.改性碱木质素在天然橡胶中的应用[D].青岛:青岛科技大学,2016.
[23]丁国新,程国君,李亭亭,等.木质纤维素/蒙脱土橡胶补强剂的制备及应用[J].化工新型材料,2017(2):219-221.
[24] Xue Xiaodong,Yin Qing,Jia Hongbing,et al. Enhancing mechanical and thermal properties of styrene-butadiene rubber/carboxylated acrylonitrile butadiene rubber blend by the usage of graphene oxide with diverse oxidation degrees[J]. Applied Surface Science,2017,423(30):584-591.
[25]奉林飞龙.石墨烯和富勒烯/橡胶纳米复合材料的制备与性能研究[D].北京:北京化工大学,2016.
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[27]王璐.基于多巴胺的橡胶/黏土纳米复合材料的界面设计及性能研究[D].北京:北京化工大学,2015.
[28] Zheng Wei,Zhao Xiuying,Li Qiangguo,et al. Compressive stress relaxation modeling of butadiene rubber under thermo-oxidative aging[J]. Journal of Applied Polymer Science,2017,134(11/12):doi:10. 1002/app. 44630.
[29] Poh B T,Lee K S. FTIR study of thermal oxidation of ENR[J]. European Polymer Journal,1994,30(1):17-23.
[30] Zhao Jiaohong,Yang Rui,Iervolino R,et al. Investigation of crosslinking in the thermo-oxidative aging of nitrile-butadiene rubber[J]. Journal of Applied Polymer Science,2015,132(3/4).
[31]李丹,苏晓声,孟运东,等.二维红外相关光谱的研究和应用[J].印制电路信息,2013(4):54-60.
[32] Harvey O R,Herbert B E,Kuo L J,et al. Generalized two-dimensional perturbation correlation infrared spectroscopy reveals mechanisms for the development of surface charge and recalcitrance in plant-derived biochars[J]. Environmental Science&Technology,2012,46(19):10641-10650.
[33]郑静,向科炜,黄光速.红外光谱研究丁基橡胶老化机理及寿命预测[J].宇航材料工艺,2013,43(1):89-92.
[34]贺经纬,赵秀英,郑玮,等.二维相关红外光谱法及标准线性固态模型对天然橡胶热氧老化机理的研究[J].高分子学报,2016(2):234-241.
[35] Kn9rgen M,Heuert U,Schneider H,et al. Spatially resolved and integral NMR investigation of the aging process of carbon black filled natural rubber[J]. Polymer Bulletin,1997,38(1):101-108.
[36]吴春红,卜少华,王足远,等.稀土异戊橡胶热老化研究[J].高分子通报,2012(11):76-81.
[37] Yang Changjin,Luo Yongyue,Chen Bangqian,et al. Effect of types of antioxidants on thermal and thermo-oxidative degradation of epoxidized natural rubber[J]. Advanced Materials Research,2014,1004/1005:245-248.
[38] Hu Dechao,Jia Zhixin,Zhong Bangchao,et al. A facile and green preparation of nanosilica-supported antioxidant and its reinforcement and antioxidation effect on styrene-butadiene rubber[J]. International Journal of Polymer Analysis&Characterization,2016,21(3):185-197.
[39]张守汉,高艳,于建,等.丁腈橡胶热氧老化与防护的研究进展及反应机理探讨[J].合成橡胶工业,2017,40(3):240-245.
[40] Fu Ye,Yang Chun,Lvov Y M,et al. Antioxidant sustained release from carbon nanotubes for preparation of highly aging resistant rubber[J]. Chemical Engineering Journal,2017,328:536-545.
[41]杨春.一维无机纳米管负载缓释防老剂制备高性能耐老化橡胶的研究[D].北京:北京化工大学,2017.
[42] Lvov Y,Wang Wencai,Zhang Liqun,et al. Halloysite clay nanotubes for loading and sustained release of functional compounds.[J]. Advanced Materials,2016,28(6):1227-1250.
[43]董前年,章于川,张芬红,等.纳米氮化硅的表面处理及其在丁腈橡胶中应用[J].功能材料,2007,38(A 09):3609-3613.
[44]邢冬华,王晓庆.新型防护蜡在胎侧配方中的耐天候老化试验研究[J].中国橡胶,2014,30(20):43-44.
[45]李永清,晏欣,郑淑贞.硫化橡胶防老化涂层的研制[J].合成材料老化与应用,2004,33(4):31-35.
[46]蒋洪罡,栗付平,王力,等.天然橡胶与合成聚异戊二烯的并用研究[J].特种橡胶制品,2008,29(5):20-23.
[47] Chen Mei,Wang Yongzhou,Lu Guang,et al. Effects of different drying methods on the microstructure and thermal oxidative aging resistance of natural rubber[J]. Journal of Applied Polymer Science,2012,126(6):1808-1813.
[2]张伟.如何自检轮胎,正确操作避免爆胎事故[J].汽车运用,2017(8):33-34.
[3] Bolland J L. Kinetic studies in the chemistry of rubber and related materials(I):The thermal oxidation of ethyl linoleate[J]. Transactions of the Faraday Society,1946,42(1005):218-236.
[4]李昂.橡胶的老化与寿命估算[J].橡胶参考资料,2009(3):2-77.
[5]李昂.橡胶的老化现象及其老化机理[J].特种橡胶制品,2009,30(5):56-67.
[6]卜少华.异戊橡胶的老化与防老化研究[D].北京:北京化工大学,2012.
[7] Lu Xiang,Chen Xun,Wang Yashun,et al. Molecular dynamics simulation of gas transport in amorphous polyisoprene[J].Acta Physico-Chimica Sinica,2016,32(10):2523-2530.
[8]肖琰.天然橡胶硫化胶的热氧老化研究[D].西安:西北工业大学,2006.
[9]俞进涛,王占彬,范金娟,等.丁腈橡胶在液压油中的加速老化行为[J].机械工程材料,2017,41(4):103-105.
[10] Zhao Li,Zhang Weifang,Chen Yu,et al. NBR storage life prediction based on the accelerated life test[J]. Advanced Materials Research,2012,476/477/478:2260-2265.
[11]陈泽鹏,杨永民,张君禄,等.橡胶支座中橡胶板的寿命预测[J].合成橡胶工业,2015,38(1):62-65.
[12] Zhang Hongyan,Liu Kaikai. The synthesis of novel schiff base antioxidants to promote anti-thermal aging properties of natural rubber[J]. Chemical Papers,2017,71(8):1481-1489.
[13]王秀娟.二烯类橡胶及聚碳酸酯材料的老化性能分析及分子模拟研究[D].北京:北京化工大学,2016.
[14]王相鹏,杨慧,郑津,等.丁苯橡胶的紫外光老化和热氧老化机理[J].厦门大学学报(自然版),2016,55(6):815-822.
[15]刘莉,王炳昕,瞿永涛,等.丙烯腈含量对丁腈橡胶热降解性能的影响[J].高分子材料科学与工程,2013,29(3):103-106.
[16] Mostafa A,Abouel-Kasem A,Bayoumi M R,et al. The influence of CB loading on thermal aging resistance of SBR and NBR rubber compounds under different aging temperature[J].Materials&Design,2009,30(3):791-795.
[17] Shuhaimi N H H,Ishak N S,Othman N,et al. Effect of different types of vulcanization systems on the mechanical properties of natural rubber vulcanizates in the presence of oil palm leaves-based antioxidant[J]. Journal of Elastomers&Plastics,2014,46(8):747-764.
[18]吴传营,赵菲,赵树高.硫化体系对丁腈橡胶NB 3305性能的影响[C]∥“诚信”杯2010年橡胶制品新技术交流暨信息发布会论文集.咸阳:《特种橡胶制品》编辑部,2011:154-157.
[19]李秀明.天然橡胶双硫化体系以及白炭黑/PDMS复合材料的研究[D].北京:北京化工大学,2016.
[20]柴克鹏,沈惠玲.炭黑对橡胶耐热老化性能的影响[J].橡胶科技,2015,13(4):19-23.
[21] Liu M,Horrocks A R. Effect of carbon black on UV stability of LLDPE films under artificial weathering conditions[J]. Polymer Degradation&Stability,2002,75(3):485-499.
[22]张翠美.改性碱木质素在天然橡胶中的应用[D].青岛:青岛科技大学,2016.
[23]丁国新,程国君,李亭亭,等.木质纤维素/蒙脱土橡胶补强剂的制备及应用[J].化工新型材料,2017(2):219-221.
[24] Xue Xiaodong,Yin Qing,Jia Hongbing,et al. Enhancing mechanical and thermal properties of styrene-butadiene rubber/carboxylated acrylonitrile butadiene rubber blend by the usage of graphene oxide with diverse oxidation degrees[J]. Applied Surface Science,2017,423(30):584-591.
[25]奉林飞龙.石墨烯和富勒烯/橡胶纳米复合材料的制备与性能研究[D].北京:北京化工大学,2016.
[26]孙翠华.橡胶/层状硅酸盐纳米复合材料的制备及结构与性能的关系研究[D].青岛:青岛大学,2003.
[27]王璐.基于多巴胺的橡胶/黏土纳米复合材料的界面设计及性能研究[D].北京:北京化工大学,2015.
[28] Zheng Wei,Zhao Xiuying,Li Qiangguo,et al. Compressive stress relaxation modeling of butadiene rubber under thermo-oxidative aging[J]. Journal of Applied Polymer Science,2017,134(11/12):doi:10. 1002/app. 44630.
[29] Poh B T,Lee K S. FTIR study of thermal oxidation of ENR[J]. European Polymer Journal,1994,30(1):17-23.
[30] Zhao Jiaohong,Yang Rui,Iervolino R,et al. Investigation of crosslinking in the thermo-oxidative aging of nitrile-butadiene rubber[J]. Journal of Applied Polymer Science,2015,132(3/4).
[31]李丹,苏晓声,孟运东,等.二维红外相关光谱的研究和应用[J].印制电路信息,2013(4):54-60.
[32] Harvey O R,Herbert B E,Kuo L J,et al. Generalized two-dimensional perturbation correlation infrared spectroscopy reveals mechanisms for the development of surface charge and recalcitrance in plant-derived biochars[J]. Environmental Science&Technology,2012,46(19):10641-10650.
[33]郑静,向科炜,黄光速.红外光谱研究丁基橡胶老化机理及寿命预测[J].宇航材料工艺,2013,43(1):89-92.
[34]贺经纬,赵秀英,郑玮,等.二维相关红外光谱法及标准线性固态模型对天然橡胶热氧老化机理的研究[J].高分子学报,2016(2):234-241.
[35] Kn9rgen M,Heuert U,Schneider H,et al. Spatially resolved and integral NMR investigation of the aging process of carbon black filled natural rubber[J]. Polymer Bulletin,1997,38(1):101-108.
[36]吴春红,卜少华,王足远,等.稀土异戊橡胶热老化研究[J].高分子通报,2012(11):76-81.
[37] Yang Changjin,Luo Yongyue,Chen Bangqian,et al. Effect of types of antioxidants on thermal and thermo-oxidative degradation of epoxidized natural rubber[J]. Advanced Materials Research,2014,1004/1005:245-248.
[38] Hu Dechao,Jia Zhixin,Zhong Bangchao,et al. A facile and green preparation of nanosilica-supported antioxidant and its reinforcement and antioxidation effect on styrene-butadiene rubber[J]. International Journal of Polymer Analysis&Characterization,2016,21(3):185-197.
[39]张守汉,高艳,于建,等.丁腈橡胶热氧老化与防护的研究进展及反应机理探讨[J].合成橡胶工业,2017,40(3):240-245.
[40] Fu Ye,Yang Chun,Lvov Y M,et al. Antioxidant sustained release from carbon nanotubes for preparation of highly aging resistant rubber[J]. Chemical Engineering Journal,2017,328:536-545.
[41]杨春.一维无机纳米管负载缓释防老剂制备高性能耐老化橡胶的研究[D].北京:北京化工大学,2017.
[42] Lvov Y,Wang Wencai,Zhang Liqun,et al. Halloysite clay nanotubes for loading and sustained release of functional compounds.[J]. Advanced Materials,2016,28(6):1227-1250.
[43]董前年,章于川,张芬红,等.纳米氮化硅的表面处理及其在丁腈橡胶中应用[J].功能材料,2007,38(A 09):3609-3613.
[44]邢冬华,王晓庆.新型防护蜡在胎侧配方中的耐天候老化试验研究[J].中国橡胶,2014,30(20):43-44.
[45]李永清,晏欣,郑淑贞.硫化橡胶防老化涂层的研制[J].合成材料老化与应用,2004,33(4):31-35.
[46]蒋洪罡,栗付平,王力,等.天然橡胶与合成聚异戊二烯的并用研究[J].特种橡胶制品,2008,29(5):20-23.
[47] Chen Mei,Wang Yongzhou,Lu Guang,et al. Effects of different drying methods on the microstructure and thermal oxidative aging resistance of natural rubber[J]. Journal of Applied Polymer Science,2012,126(6):1808-1813.