蒸汽裂解催化剂研究进展
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摘要
蒸汽裂解是指石油烃类如乙烷或石油馏分如石脑油、瓦斯油等在高温和水蒸气存在的条件下发生分子断裂和脱氢反应的过程,其主要目的是制备乙烯、副产丙烯、丁二烯等低分子烯烃产品。蒸汽裂解方法是为化学工业提供基础化学品的主要途径,其过程中所使用的催化剂对提高蒸汽裂解的效率起着至关重要的作用。本文对催化蒸汽裂解中所使用的催化剂进行了综述。
Steam cracking refers to a reaction which use hydrocarbon such as ethane or petroleum distillates such as naphtha,gas oil as reactant,and dehydrogenate,moleculars crack at high temperature and presence of water vapor,the process' s main purpose is to prepare ethylene,byproduct propylene,butadiene or other short chain olefin.Steam cracking is the main course to provide basic chemicals in chemical industry,the use of catalyst is of great importance to the increase of efficiency in steam cracking.The catalysts used in steam cracking were summarized.
Steam cracking refers to a reaction which use hydrocarbon such as ethane or petroleum distillates such as naphtha,gas oil as reactant,and dehydrogenate,moleculars crack at high temperature and presence of water vapor,the process' s main purpose is to prepare ethylene,byproduct propylene,butadiene or other short chain olefin.Steam cracking is the main course to provide basic chemicals in chemical industry,the use of catalyst is of great importance to the increase of efficiency in steam cracking.The catalysts used in steam cracking were summarized.
引文
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[4]中国石油化工股份有限公司/中国石油化工股份有限公司石油化工科学研究院.一种蒸汽裂解制丙烯的规整结构催化剂[P].CN103055919A,20130424.
[5]中国石油化工股份有限公司/中国石油化工股份有限公司石油化工科学研究院.一种制取低碳烯烃和芳烃的催化转化方法[P].CN101747928A,20100623.
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[10]H T YAN,R.Le Van Mao.Hybrid catalysts used in the Catalytic Steam Cracking process(CSC):Influence of the pore characteristics and the surface acidity properties of the ZSM-5 zeolite-based component on the overall catalytic performance[J].Applied Catalysis A:Genaral,2010,375(1):63-69.
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[12]Michael GOLOMBOK,Marcel Kornegoor,Peter van den Brink,et al.Surface-Enhanced Light Olefin Yields during Steam Cracking[J].Ind Eng Chem Res,2000,39:285-291.
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[14]Eri FUMOTO,Teruoki Tago,Takao Masuda.Recovery of Lighter Fuels by Cracking Heavy Oil with Zirconia-Alumina-Iron Oxide Catalysts in a Steam Atmosphere[J].Energy&Fuels,2009,23:1338-1341.
[15]Eri FUMOTO,Akimitsu Matsumura,Shinya Sato,et al.Kinetic Model for Catalytic Cracking of Heavy Oil with a Zirconia-Alumina-Iron Oxide Catalyst in a Steam Atmosphere[J].Energy&Fuels,2009,23:5308-5311.
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[20]LG化学株式会社.用于烃蒸汽裂化的催化剂、制备该催化剂的方法以及用该催化剂制备烯烃的方法[P].CN102008972A,20110413.
[21]中国石油化工股份有限公司中国石油化工股份有限公司石油化工科学研究院.一种蒸汽裂解制丙烯的规整结构催化剂及其应用[P].CN102451737A 20120516.
[22]SOC CHIMIQUE DE LA GRANDE PAROISSE A.Ethylene is prepared by re-forming hydrocarbons with steam in the presence of stable catalysts with little or no dehydrogenating metal and containing refractory[P].US3644557A,DW197212.
[23]中国石油化工股份有限公司中国石油化工股份有限公司石油化工科学研究院.一种规整催化剂及其在蒸汽裂解中的应用[P].CN1986745A,20070627.
[24]中国石油化工股份有限公司中国石油化工股份有限公司石油化工科学研究院.一种蒸汽裂解制丙烯的规整结构催化剂及其应用[P].CN102451738A,20120516.
[25]中国石油化工股份有限公司中国石油化工股份有限公司石油化工科学研究院.一种蒸汽裂解制丙烯的规整结构催化剂及其应用[P].CN102451739A,20120516.
[26]BRITISH PETROLEUM CO LTD.Olefins by steam cracking hydrocarbon residues-on manganese catalyst,giving high olefin yield and reducing coke deposition[P].US4087350A 19780502.
[27]PHILLIPS PETROLEUM CO.Catalysts contg.iron and lanthanide or niobium oxide-esp.for steam cracking of paraffin(s)to produce olefin(s)[P].US4829041A 19890509.
[2]LG化学株式会社.Thermal cracking of hydrocarbon,using tube type furnace,comprises packing hydrocarbon thermal-cracking catalyst comprising a metal oxide catalyst,in some or entire area of a tube placed in the radiation part of the tube type furnace[P].KR10-2009-0002996,20090109.
[3]中国石油化工股份有限公司/中国石油化工股份有限公司北京化工研究院.一种增产乙烯和丙烯的方法[P].CN102285851A,20111221.
[4]中国石油化工股份有限公司/中国石油化工股份有限公司石油化工科学研究院.一种蒸汽裂解制丙烯的规整结构催化剂[P].CN103055919A,20130424.
[5]中国石油化工股份有限公司/中国石油化工股份有限公司石油化工科学研究院.一种制取低碳烯烃和芳烃的催化转化方法[P].CN101747928A,20100623.
[6]中国石油化工股份有限公司/中国石油化工股份有限公司石油化工科学研究院.一种由含烯烃汽油催化裂解制丙烯的方法[P].CN1903808A,20070131.
[7]董家禄,张伟峰,须沁华.正已烷在酸性沸石催化剂上的蒸汽裂解反应[J].南京大学学报,1996,32(3):446-453.
[8]Avelino CORMA,Jesús Mengual,Pablo J.Miguel.Steam catalytic cracking of naphtha over ZSM-5 zeolite for production of propene and ethene:Micro and macroscopic implications of the presence of steam[J].Applied Catalysis A:General,2012,417-418(1):220-235.
[9]Avelino CORMA,Jesús Mengual,Pablo J.Miguel.Stabilization of ZSM-5 zeolite catalysts for steam catalytic cracking of naphtha for production of propene and ethene[J].Applied Catalysis A:General,2012,421-422(8):121-134.
[10]H T YAN,R.Le Van Mao.Hybrid catalysts used in the Catalytic Steam Cracking process(CSC):Influence of the pore characteristics and the surface acidity properties of the ZSM-5 zeolite-based component on the overall catalytic performance[J].Applied Catalysis A:Genaral,2010,375(1):63-69.
[11]A A LEMONIDOU,I A Vasalos.Preparation and Evaluation of Catalysts for the Production of Ethylene via Steam Cracking Effect of Operating Conditions on the Performance of 12Ca O-7Al2O3Catalyst[J].Applied Catalysis,1998,54(1):119-138.
[12]Michael GOLOMBOK,Marcel Kornegoor,Peter van den Brink,et al.Surface-Enhanced Light Olefin Yields during Steam Cracking[J].Ind Eng Chem Res,2000,39:285-291.
[13]Jafar TOWFIGHI,Heinz Zimmermann,Ramin Karimzadeh,et al.Steam Cracking of Naphtha in Packed Bed Reactors[J].Ind Eng Chem Res,2002,41:1419-1424.
[14]Eri FUMOTO,Teruoki Tago,Takao Masuda.Recovery of Lighter Fuels by Cracking Heavy Oil with Zirconia-Alumina-Iron Oxide Catalysts in a Steam Atmosphere[J].Energy&Fuels,2009,23:1338-1341.
[15]Eri FUMOTO,Akimitsu Matsumura,Shinya Sato,et al.Kinetic Model for Catalytic Cracking of Heavy Oil with a Zirconia-Alumina-Iron Oxide Catalyst in a Steam Atmosphere[J].Energy&Fuels,2009,23:5308-5311.
[16]恩尼彻姆公司埃尼里塞奇公司.用于蒸汽裂解反应的催化剂和相关制备方法[P].CN1317546A,20011017.
[17]中国石油化工股份有限公司中国石油化工股份有限公司石油化工科学研究院.一种蒸汽裂解催化剂及其制备方法和应用[P].CN101314126A,20081203.
[18]LG化学株式会社.烃的热裂解方法[P].CN101353590A,20090128.
[19]LG化学株式会社LG石油化学株式会社.用于烃蒸气裂解的氧化物催化剂和含磷氧化物催化剂、其制备方法和使用其制备烯烃的方法[P].CN101516499A,20090826.
[20]LG化学株式会社.用于烃蒸汽裂化的催化剂、制备该催化剂的方法以及用该催化剂制备烯烃的方法[P].CN102008972A,20110413.
[21]中国石油化工股份有限公司中国石油化工股份有限公司石油化工科学研究院.一种蒸汽裂解制丙烯的规整结构催化剂及其应用[P].CN102451737A 20120516.
[22]SOC CHIMIQUE DE LA GRANDE PAROISSE A.Ethylene is prepared by re-forming hydrocarbons with steam in the presence of stable catalysts with little or no dehydrogenating metal and containing refractory[P].US3644557A,DW197212.
[23]中国石油化工股份有限公司中国石油化工股份有限公司石油化工科学研究院.一种规整催化剂及其在蒸汽裂解中的应用[P].CN1986745A,20070627.
[24]中国石油化工股份有限公司中国石油化工股份有限公司石油化工科学研究院.一种蒸汽裂解制丙烯的规整结构催化剂及其应用[P].CN102451738A,20120516.
[25]中国石油化工股份有限公司中国石油化工股份有限公司石油化工科学研究院.一种蒸汽裂解制丙烯的规整结构催化剂及其应用[P].CN102451739A,20120516.
[26]BRITISH PETROLEUM CO LTD.Olefins by steam cracking hydrocarbon residues-on manganese catalyst,giving high olefin yield and reducing coke deposition[P].US4087350A 19780502.
[27]PHILLIPS PETROLEUM CO.Catalysts contg.iron and lanthanide or niobium oxide-esp.for steam cracking of paraffin(s)to produce olefin(s)[P].US4829041A 19890509.