4'-(4-(4-羧基苯氧基)苯基-4,2'6',4″-三联吡啶的合成、晶体结构及性质研究
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摘要
以4-乙酰基吡啶及对氯苯甲醛为原料合成了一例新的化合物4'-(4-(4-羧基苯氧基)苯基-4,2'6',4″-三联吡啶,用元素分析、红外光谱、紫外光谱、X射线单晶衍射对此化合物进行了表征,结果表明,该化合物属于P2(1)/c空间群,晶胞参数为:a=1.4405(5)nm,b=0.7708(2)nm,c=2.0567(7)nm,β=107.699(6)°。
A compound 4'-( 4-( 4-carboxyl phenoxy) phenyl)-4,2'6',4″-Terpyridine was synthesized by reacting with 4-acetylpyridine and p-chlorobenzaldehyde. The compound was structurally characterized by elemental analyses,IR,Uv-vis and single crystal X-ray diffraction,and the result shows that the complex is crystallized in Monoclinic system with Cc space group. The cell parameters are as follows: a = 1. 4405( 5) nm,b = 0. 7708( 2) nm,c = 2. 0567( 7) nm,β = 107. 699( 6) °.
A compound 4'-( 4-( 4-carboxyl phenoxy) phenyl)-4,2'6',4″-Terpyridine was synthesized by reacting with 4-acetylpyridine and p-chlorobenzaldehyde. The compound was structurally characterized by elemental analyses,IR,Uv-vis and single crystal X-ray diffraction,and the result shows that the complex is crystallized in Monoclinic system with Cc space group. The cell parameters are as follows: a = 1. 4405( 5) nm,b = 0. 7708( 2) nm,c = 2. 0567( 7) nm,β = 107. 699( 6) °.
引文
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[3]Xu B,Xie J,Hu H M,et al.Synthesis,Crystal Structure,and Luminescence if Zn/Cd Coordination Polymers with a New Fuctionalized Terpyridyl Carboxylate Ligand[J].Cryst.Growth Des,2014,14:1629-1641.
[4]宋娟,葛红光.二维锰(Ⅱ)配位聚合物[Mn2(bppc)4(H2O)]n·2n H2O的合成、晶体结构及热稳定性研究[J].人工晶体学报,2017,46(6):1170-1174.
[5]张高宾,刘杰,潘扬,等.功能化三联吡啶衍生物的合成及其对Fe2+识别研究[J].无机化学学报,2014,30(12):2699-2705.
[6]Dehaudt J,Husson J,Guyard L,et al.A More Efficient Synthesis of 4,4',4″-tricarboxy-2,2':6',2″-terpyridine[J].Green Chem,2011,V13:3337-3340.
[7]Liu D,Liu Q,Li Y,etal.A Tpy Ru2+-base Bismetallopolymer and its Performance in Catalytic Water Oxidation(Tpy=4-(p-methoxyphenyl)-2,2':6',2″-terpyridine[J].Dalton Transactions,2015,44(25):11269-11273.
[8]Jiao S Y,Li K,Zhang W,et al.Cd(Ⅱ)-terpyridine-based Complex as a Ratiometric Fluorescent probe for Pyrophosphate Detection in Solution and as an Imaging Agent in Living cells[J].Dalton Transactions,2015,44(3):1358-1365.
[9]戴立信.Ullmann反应百年纪念及近期复兴-兼及碳-杂原子键的形成[J].化学进展,2018,30(9):1257-1297.