纳米二氧化硅/丝素复配整理对粘胶织物性能影响
|
摘要
研究了纳米二氧化硅在丝素与纳米二氧化硅复配整理液最佳含量。通过观察、测试自制丝素与纳米二氧化硅复配整理液对粘胶织物整理后的微观形貌、湿润、折皱回复性、紫外线防护与力学性能变化,说明复配液整理对粘胶织物的性能影响。结果表明,当纳米二氧化硅含量在3.5%~4.5%之间时粘胶织物表面的纳米二氧化硅出现少量团聚现象,且此时粘胶织物的疏水、紫外线防护与力学性能得到很大程度的改善,唯有粘胶织物的折皱回复性能略有降低。总体而言,通过此种简单环保工艺极大提高了粘胶织物的防护性能,因此建议复配整理液中纳米二氧化硅的含量应控制在3.5%~4.5%。
Morphology, wet, wrinkle resilience angle, UV protection and mechanics properties of viscose fabrics finished by nano silicon dioxide/silk distribution were observed and tested to study properties changes of viscose fabrics after nano silicon dioxide/silk treatment to search for the optimum content of the nano silicon dioxide/silk distribution finishing liquor. Research showed that when the nano silicon dioxide content was between 3.5% and 4.5% of the nano silicon dioxide/silk distribution finishing liquor, small reunions were appeared on the viscose fabrics. Meanwhile, properties of wet, UV protection and mechanics were all improved greatly except wrinkle resilience angle. On the whole, it was suggested that the nano silicon dioxide content of nano silicon dioxide/silk distribution should be controlled between 3.5% and 4.5% that functionalities of viscose fabrics can be improved greatly by this simple environmental protection technology.
Morphology, wet, wrinkle resilience angle, UV protection and mechanics properties of viscose fabrics finished by nano silicon dioxide/silk distribution were observed and tested to study properties changes of viscose fabrics after nano silicon dioxide/silk treatment to search for the optimum content of the nano silicon dioxide/silk distribution finishing liquor. Research showed that when the nano silicon dioxide content was between 3.5% and 4.5% of the nano silicon dioxide/silk distribution finishing liquor, small reunions were appeared on the viscose fabrics. Meanwhile, properties of wet, UV protection and mechanics were all improved greatly except wrinkle resilience angle. On the whole, it was suggested that the nano silicon dioxide content of nano silicon dioxide/silk distribution should be controlled between 3.5% and 4.5% that functionalities of viscose fabrics can be improved greatly by this simple environmental protection technology.
引文
[1]李大为,何进,何凤利,等.丝素蛋白在骨组织工程中的应用研究进展[J].化学与生物工程,2017,34(9):1-6.
[2]吴惠英.脱胶工艺对蚕丝溶解及再生丝素蛋白纤维性能的影响[J].纺织学报,2017,38(8):75-80.
[3]解玉玲,林晓,王锐,等.壳聚糖-二氧化硅纳米多孔材料的制备及p H敏感性[J].广州化工,2017,45(18):57-59.
[4]陈博,陈学琴,任军,等.纳米二氧化硅表面改性研究进展[J].有机硅材料,2017,31(5):396-400.
[5]赵艳芹,于湖生,韦红莲,等.消臭粘胶纤维的制备与性能研究[J].上海纺织科技,2017,45(7):43-45.
[6]郑向华.抗菌除臭符合功能粘胶纤维的制备与研究[D].山东:青岛大学,2015.
[7]李继丰,杨震,彭凤霞,等.羧基化棉织物的丝素蛋白接枝改性[J].印染,2015(7):1-6.
[8]程洋,徐丽慧,李倩.棉织物的改性纳米二氧化硅超疏水整理[J].印染,2015(18):6-9.
[9]宋慧君,韩冰,张建丽,等.棉织物的免烫整理[J].纺织学报,2010,31(12):84-88.
[10]赵海洋.纳米氧化物对纯棉织物抗皱整理效果影响规律的研究[D].天津:天津工业大学,2007.
[11]阙永生,杨辉,汪海风,等.溶胶-凝胶法制备纳米二氧化硅及原位改性[J].无机盐工业,2015,47(9):13-16.
[12]王雪,王少凯,黄蕊,等.超疏水涂料的制备及性能研究[J].化学与黏合,2017,39(5):313-324.
[2]吴惠英.脱胶工艺对蚕丝溶解及再生丝素蛋白纤维性能的影响[J].纺织学报,2017,38(8):75-80.
[3]解玉玲,林晓,王锐,等.壳聚糖-二氧化硅纳米多孔材料的制备及p H敏感性[J].广州化工,2017,45(18):57-59.
[4]陈博,陈学琴,任军,等.纳米二氧化硅表面改性研究进展[J].有机硅材料,2017,31(5):396-400.
[5]赵艳芹,于湖生,韦红莲,等.消臭粘胶纤维的制备与性能研究[J].上海纺织科技,2017,45(7):43-45.
[6]郑向华.抗菌除臭符合功能粘胶纤维的制备与研究[D].山东:青岛大学,2015.
[7]李继丰,杨震,彭凤霞,等.羧基化棉织物的丝素蛋白接枝改性[J].印染,2015(7):1-6.
[8]程洋,徐丽慧,李倩.棉织物的改性纳米二氧化硅超疏水整理[J].印染,2015(18):6-9.
[9]宋慧君,韩冰,张建丽,等.棉织物的免烫整理[J].纺织学报,2010,31(12):84-88.
[10]赵海洋.纳米氧化物对纯棉织物抗皱整理效果影响规律的研究[D].天津:天津工业大学,2007.
[11]阙永生,杨辉,汪海风,等.溶胶-凝胶法制备纳米二氧化硅及原位改性[J].无机盐工业,2015,47(9):13-16.
[12]王雪,王少凯,黄蕊,等.超疏水涂料的制备及性能研究[J].化学与黏合,2017,39(5):313-324.