抗菌不锈钢的研究进展
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摘要
抗菌不锈钢结合了不锈钢稳定的加工性能和抗菌元素良好的抗菌性能,因而广泛的应用于医疗器械、厨房用餐具、刀具、洗衣机等领域。本文综述了抗菌不锈钢国内外的研究与发展,介绍了抗菌不锈钢的概念、分类及其制备工艺,分析了抗菌不锈钢的抗菌机制,最后指出了抗菌不锈钢制备工艺仍存在的问题,并就这些问题提出了解决办法以及对其未来发展提出了展望。
Antibacterial stainless steel combines stable processing performance of stainless steel with good antibacterial properties of antibacterial element, which is widely used in medical equipment, kitchen utensils, cutlery, washing machine and other fields. In this paper, the research and development of antibacterial stainless steel at home and abroad were reviewed. The concept, classification and preparation process of antibacterial stainless steel were introduced. Antibacterial mechanism of antibacterial stainless steel was analyzed. Finally, the problems of antibacterial stainless steel in preparation were pointed out, and the solutions to these problems were put forward and the prospect of its future development was put forward.
Antibacterial stainless steel combines stable processing performance of stainless steel with good antibacterial properties of antibacterial element, which is widely used in medical equipment, kitchen utensils, cutlery, washing machine and other fields. In this paper, the research and development of antibacterial stainless steel at home and abroad were reviewed. The concept, classification and preparation process of antibacterial stainless steel were introduced. Antibacterial mechanism of antibacterial stainless steel was analyzed. Finally, the problems of antibacterial stainless steel in preparation were pointed out, and the solutions to these problems were put forward and the prospect of its future development was put forward.
引文
[1]张文毓.抗菌不锈钢的开发与应用[J].新材料产业,2009(7):32.
[2]铃木聪,石井滕己,平松植人,等.高加工用才-ステナイト系抗菌ステンレス钢NSSAM-4の开发[J].日新制钢技报,2001(81):21.
[3]邱庆忠,张中秋,宋景颜.抗菌不锈钢的研究与发展现状[J].材料研究与应用,2011,12,5(4):239-242.
[4]吕曼祺,陈四红,董加胜,等.铁素体抗菌不锈钢杀菌过程与机理初探[J].金属功能材料,2005(6):10-13.
[5]杨柯,陈四红,董加胜,等.铁素体抗菌不锈钢的抗菌特性[J].金属功能材料,2005,12(6):6-9.
[6]陈四红,吕曼祺,张敬党,等.含Cu抗菌不锈钢的微观组织及其抗菌性能[J].金属学报,2004(3):314-318.
[7]杨柯,董加胜,陈四红,等.含Cu抗菌不锈钢的工艺与耐蚀性能[J].材料研究学报,2006,20(5):523-527.
[8]刘永前,等.时效处理对含铜马氏体抗菌不锈钢抗菌性能的影响[J〕.功能材料,2007,38(增刊):3419.
[9]倪红卫,詹玮婷,陈荣生.Ag/Cu共渗不锈钢表面的微观结构及抗菌性能研究[J].2011,4,25(4):27-29.
[10]CHEN Li-mei.Chemical Assembly of Silver Nanoparticles on Stainless Steel for Antimicrobial Applications[J].Surface and Coatings Technology,2010(204):3871.
[11]敬和民,陈四红,董加胜,等.抗菌不锈钢材料及其发展现状[J].材料保护,2003(10):10.
[12]Wilks S A,Michels H.The survival of Escherichia coli O157 on a range of metal surfaces[J].Int J Food Microbiol,2005,105(3):445.
[13]杨志勇,李文辉,林师焱.抗菌不锈钢材料的开发[J].金属功能材料,2000(4):1.
[14]DONG Y.Towards Long-Lasting Antibacterial Stainless Steel Surfaces by Combining Double Glow Plasma Silvering With Active Screen Plasma Nitriding[J].Acta Biomaterialia,2011(7):447.
[15]DAN Z G.Microstructure and Antibacterial Properties of AISI420Stainless Steel Implantedby Copper Ions[J].Thin Solid Films,2005(492):93.
[16]李金刚,汪振福,时海芳,等.渗铜法制备抗菌不锈钢的抗菌性和耐蚀性[J].腐蚀与防护,2008,29(5):253.
[17]詹玮婷,倪红卫,陈荣生,等.Ag/Zn双元离子注入不锈钢的研制与抗菌性能研究[J].功能材料,2010,41(9):1635-1638.
[18]倪红卫,詹玮婷,陈荣生.不锈钢表面Cu/Zn共渗层的微观结构及抗菌性能[J].材料保护,2011,44(9):25-27.
[19]倪红卫,詹玮婷,陈荣生.Ag/Cu共渗不锈钢表面的微观结构及抗菌性能研究[J].材料导报,2011,25(4):27-29.
[20]王岩,徐晋勇,高成,等.304不锈钢双辉渗铜铈渗层结构分析及其抗菌性能[J].稀有金属材料与工程,2013,42(6):1254-1257.
[21]吴明,徐晋勇,高波,等.渗铜铈法制作抗菌不锈钢的耐蚀性能研究[J].大众科技,2012,14(159):83-84.
[22]YANG Ke.Antibacterial Properties of Austenitic Antibacterial Stainless Steel and its Security for Human Boby[J].Mater Sci Technol,2007,23(3):333.
[23]XU Zhong.Method and apparatus for introducing normally solid materials into substrate surfaces:US,452202685[P].1985-05-28.
[24]高原,徐重.双层辉光离子渗金属技术的效果及应用[J].中国表面工程,2006,19(4):1-7.
[25]蒋立,张翔宇,黄晓波,等.等离子表面合金化制备抗菌不锈钢及其组织与性能[J].机械工程材料,2012,36(11):54-57.
[26]LI Nan.Antibacterial mechanism of copper-bearing antibacterial stainless steel against E:Coli[J].Mater Sci Technol,2008,24(2):197.
[27]HONG I T,Koo C H.Antibacterial Properties,Corrosion Resistance and Mechanical Properties of Cu-Modified SUS 304 Stainless Steel[J].Materials Science and Engineering,2005(393A):213.
[28]时均增,冯旺军,耿丹,等.含铜奥氏体抗菌不锈钢组织与性能研究[J].新技术新工艺,2010(8):74.
[29]胡文全,胡世菊,张伟强.铜对低碳马氏体不锈钢抗菌性和力学性能的影响[J].材料热处理技术,2009,38(2):32-34.
[30]许松梅.铜对马氏体不锈钢抗菌性的影响[C].//中国金属学会.第七届(2009)中国钢铁年会大会论文集(中).2009.
[31]张安峰,李利军,乔继英,等.马氏体抗菌不锈钢的微观组织及其抗菌性能[J].铸造技术,2009,30(7):860-863.
[32]刘永前,南黎,陈德敏,等.含铜马氏体抗菌不锈钢的研究[J].稀有金属材料与工程,2008,37(8):1380-1382.
[33]林刚,沈继程,王如萌.铜对铁素体抗菌不锈钢性能的影响[J].功能材料,2011,42:549-554.
[34]张志霞,林刚,徐洲.含铜铁素体抗菌不锈钢中抗菌相的析出行为[J].材料热处理学报,2008,29(5):93-96.
[35]邱文军,林刚,江来珠,等.铜对奥氏体抗菌不锈钢性能的影响[J].钢铁,2009,44(3):82-84.
[36]杨伟超,南黎,李慧,等.含铜抗菌不锈钢的抗菌性能研究[J].微生物学杂志,2009,29(3):1-5.
[37]魏莉,罗洪杰,姚广春,等.粉末冶金制备泡沫铝研究进展[J].轻金属,2003,(11):59-62.
[38]刘斌.泡沫铝粉末冶金法制备工艺改进及其孔结构控制研究[D].南京:东南大学材料系,2005.
[39]沈骏.固相颗粒对粉末冶金泡沫铝孔结构及其力学性能影响机制研究[D].南京:东南大学材料系,2006.
[40]刘菊芬,刘荣佩,史庆南,等.新型泡沫铝制备工艺研究[J].材料导报,2002,(8):65-68.
[41]凤仪,郑海务,朱震刚,等.闭孔泡沫铝的电磁屏蔽性能[J].中国有色金属学报,2004,(1):33-35.
[42]川崎制铁株式会社.抗菌性良好的不锈钢材及其制造方法:中国,CN1256716A[P].2000.
[43]徐光宪.稀土[M].北京:冶金工业出版社,1995.591.
[44]高锦章,龙全江,杨韬.中国稀土药物研究进展[J].西北师范大学学报,2002,38(1):108.
[45]Evans C H.Biochemistry of the Lanthanides[M].New York:Plenum Press,1990.
[46]倪嘉缵.稀土生物无机化学(第二版)[M].北京:科学出版社,2002.
[47]马建方,倪嘉瓒.稀土羧酸配合物的结构[J].化学进展,1996,8(4):259.
[48]敬和民,吴欣强,刘永前,等.含铈不锈钢的抗菌性能[J].中国稀土学报,2006,24(2):223-226.
[49]杨晓龙,袁守谦,吴镇宇.抗菌不锈钢的研究进展[J].钢铁研究学报,2012,24(6):4-5.
[50]倪红卫,但智钢,高娟.抗菌不锈钢的制备与应用[J].武汉科技大学学报(自然科学版),2004,27(4):333.
[51]殷银锁,杨春光,王东辉.含铜抗菌不锈钢的抗菌机制及其应用[J].中国医学工程,2013,21(10):187-188.
[2]铃木聪,石井滕己,平松植人,等.高加工用才-ステナイト系抗菌ステンレス钢NSSAM-4の开发[J].日新制钢技报,2001(81):21.
[3]邱庆忠,张中秋,宋景颜.抗菌不锈钢的研究与发展现状[J].材料研究与应用,2011,12,5(4):239-242.
[4]吕曼祺,陈四红,董加胜,等.铁素体抗菌不锈钢杀菌过程与机理初探[J].金属功能材料,2005(6):10-13.
[5]杨柯,陈四红,董加胜,等.铁素体抗菌不锈钢的抗菌特性[J].金属功能材料,2005,12(6):6-9.
[6]陈四红,吕曼祺,张敬党,等.含Cu抗菌不锈钢的微观组织及其抗菌性能[J].金属学报,2004(3):314-318.
[7]杨柯,董加胜,陈四红,等.含Cu抗菌不锈钢的工艺与耐蚀性能[J].材料研究学报,2006,20(5):523-527.
[8]刘永前,等.时效处理对含铜马氏体抗菌不锈钢抗菌性能的影响[J〕.功能材料,2007,38(增刊):3419.
[9]倪红卫,詹玮婷,陈荣生.Ag/Cu共渗不锈钢表面的微观结构及抗菌性能研究[J].2011,4,25(4):27-29.
[10]CHEN Li-mei.Chemical Assembly of Silver Nanoparticles on Stainless Steel for Antimicrobial Applications[J].Surface and Coatings Technology,2010(204):3871.
[11]敬和民,陈四红,董加胜,等.抗菌不锈钢材料及其发展现状[J].材料保护,2003(10):10.
[12]Wilks S A,Michels H.The survival of Escherichia coli O157 on a range of metal surfaces[J].Int J Food Microbiol,2005,105(3):445.
[13]杨志勇,李文辉,林师焱.抗菌不锈钢材料的开发[J].金属功能材料,2000(4):1.
[14]DONG Y.Towards Long-Lasting Antibacterial Stainless Steel Surfaces by Combining Double Glow Plasma Silvering With Active Screen Plasma Nitriding[J].Acta Biomaterialia,2011(7):447.
[15]DAN Z G.Microstructure and Antibacterial Properties of AISI420Stainless Steel Implantedby Copper Ions[J].Thin Solid Films,2005(492):93.
[16]李金刚,汪振福,时海芳,等.渗铜法制备抗菌不锈钢的抗菌性和耐蚀性[J].腐蚀与防护,2008,29(5):253.
[17]詹玮婷,倪红卫,陈荣生,等.Ag/Zn双元离子注入不锈钢的研制与抗菌性能研究[J].功能材料,2010,41(9):1635-1638.
[18]倪红卫,詹玮婷,陈荣生.不锈钢表面Cu/Zn共渗层的微观结构及抗菌性能[J].材料保护,2011,44(9):25-27.
[19]倪红卫,詹玮婷,陈荣生.Ag/Cu共渗不锈钢表面的微观结构及抗菌性能研究[J].材料导报,2011,25(4):27-29.
[20]王岩,徐晋勇,高成,等.304不锈钢双辉渗铜铈渗层结构分析及其抗菌性能[J].稀有金属材料与工程,2013,42(6):1254-1257.
[21]吴明,徐晋勇,高波,等.渗铜铈法制作抗菌不锈钢的耐蚀性能研究[J].大众科技,2012,14(159):83-84.
[22]YANG Ke.Antibacterial Properties of Austenitic Antibacterial Stainless Steel and its Security for Human Boby[J].Mater Sci Technol,2007,23(3):333.
[23]XU Zhong.Method and apparatus for introducing normally solid materials into substrate surfaces:US,452202685[P].1985-05-28.
[24]高原,徐重.双层辉光离子渗金属技术的效果及应用[J].中国表面工程,2006,19(4):1-7.
[25]蒋立,张翔宇,黄晓波,等.等离子表面合金化制备抗菌不锈钢及其组织与性能[J].机械工程材料,2012,36(11):54-57.
[26]LI Nan.Antibacterial mechanism of copper-bearing antibacterial stainless steel against E:Coli[J].Mater Sci Technol,2008,24(2):197.
[27]HONG I T,Koo C H.Antibacterial Properties,Corrosion Resistance and Mechanical Properties of Cu-Modified SUS 304 Stainless Steel[J].Materials Science and Engineering,2005(393A):213.
[28]时均增,冯旺军,耿丹,等.含铜奥氏体抗菌不锈钢组织与性能研究[J].新技术新工艺,2010(8):74.
[29]胡文全,胡世菊,张伟强.铜对低碳马氏体不锈钢抗菌性和力学性能的影响[J].材料热处理技术,2009,38(2):32-34.
[30]许松梅.铜对马氏体不锈钢抗菌性的影响[C].//中国金属学会.第七届(2009)中国钢铁年会大会论文集(中).2009.
[31]张安峰,李利军,乔继英,等.马氏体抗菌不锈钢的微观组织及其抗菌性能[J].铸造技术,2009,30(7):860-863.
[32]刘永前,南黎,陈德敏,等.含铜马氏体抗菌不锈钢的研究[J].稀有金属材料与工程,2008,37(8):1380-1382.
[33]林刚,沈继程,王如萌.铜对铁素体抗菌不锈钢性能的影响[J].功能材料,2011,42:549-554.
[34]张志霞,林刚,徐洲.含铜铁素体抗菌不锈钢中抗菌相的析出行为[J].材料热处理学报,2008,29(5):93-96.
[35]邱文军,林刚,江来珠,等.铜对奥氏体抗菌不锈钢性能的影响[J].钢铁,2009,44(3):82-84.
[36]杨伟超,南黎,李慧,等.含铜抗菌不锈钢的抗菌性能研究[J].微生物学杂志,2009,29(3):1-5.
[37]魏莉,罗洪杰,姚广春,等.粉末冶金制备泡沫铝研究进展[J].轻金属,2003,(11):59-62.
[38]刘斌.泡沫铝粉末冶金法制备工艺改进及其孔结构控制研究[D].南京:东南大学材料系,2005.
[39]沈骏.固相颗粒对粉末冶金泡沫铝孔结构及其力学性能影响机制研究[D].南京:东南大学材料系,2006.
[40]刘菊芬,刘荣佩,史庆南,等.新型泡沫铝制备工艺研究[J].材料导报,2002,(8):65-68.
[41]凤仪,郑海务,朱震刚,等.闭孔泡沫铝的电磁屏蔽性能[J].中国有色金属学报,2004,(1):33-35.
[42]川崎制铁株式会社.抗菌性良好的不锈钢材及其制造方法:中国,CN1256716A[P].2000.
[43]徐光宪.稀土[M].北京:冶金工业出版社,1995.591.
[44]高锦章,龙全江,杨韬.中国稀土药物研究进展[J].西北师范大学学报,2002,38(1):108.
[45]Evans C H.Biochemistry of the Lanthanides[M].New York:Plenum Press,1990.
[46]倪嘉缵.稀土生物无机化学(第二版)[M].北京:科学出版社,2002.
[47]马建方,倪嘉瓒.稀土羧酸配合物的结构[J].化学进展,1996,8(4):259.
[48]敬和民,吴欣强,刘永前,等.含铈不锈钢的抗菌性能[J].中国稀土学报,2006,24(2):223-226.
[49]杨晓龙,袁守谦,吴镇宇.抗菌不锈钢的研究进展[J].钢铁研究学报,2012,24(6):4-5.
[50]倪红卫,但智钢,高娟.抗菌不锈钢的制备与应用[J].武汉科技大学学报(自然科学版),2004,27(4):333.
[51]殷银锁,杨春光,王东辉.含铜抗菌不锈钢的抗菌机制及其应用[J].中国医学工程,2013,21(10):187-188.