镍-钴合金镀层研究进展
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摘要
镍-钴合金镀层由于其性能优异,被广泛用于零部件的表面装饰与防护。近年来在纳米复合技术发展的基础上,镍-钴合金镀层获得了新的研究和应用。简述了电沉积镍-钴合金的沉积原理,重点综述了镍-钴合金镀层主流镀液体系、镀层性能和镀层的最新进展,并对镍-钴纳米复合镀层的发展进行了展望。
Nickel-cobalt alloy coating is widely used for surface finishing and protection because of its excellent performance. In the recent years,Nickel-cobalt nano-composite coating has been widely researched and applied on the basis of the development of nano-composite technology. In this paper,the electrodeposition principle of nickel-cobalt alloy was briefly introduced,the main bath system,coating performance and the latest research development of nickel-cobalt alloy coatings were summarized. The development of nickel-cobalt nano-composite coatings was prospected.
Nickel-cobalt alloy coating is widely used for surface finishing and protection because of its excellent performance. In the recent years,Nickel-cobalt nano-composite coating has been widely researched and applied on the basis of the development of nano-composite technology. In this paper,the electrodeposition principle of nickel-cobalt alloy was briefly introduced,the main bath system,coating performance and the latest research development of nickel-cobalt alloy coatings were summarized. The development of nickel-cobalt nano-composite coatings was prospected.
引文
[1]Zhou Ke-chao,MA Li,LI Zhi-you.Oxidation behaviors of electrodeposited nickel-cobalt coatings in air at 960℃[J].Transaction of Nonferrous Metals Society of China,2011,21:1052-1060.
[2]王伊卿,赵文轸,唐一平,等.Ni-Co合金电铸工艺及性能研究[J].兵器材料科学与工程,2000,23(3):39-43.
[3]武刚,李宁,周德瑞.氨基磺酸体系Co-Ni合金电化学共沉积行为及动力学机理[J].高校化学工程学报,2005,19(1):48-53.
[4]Wu Z W,Lei Y P,Wang Y,et al.Effect of cobalt content on microstructure and property of electroplated nickel-cobalt alloy coatings[J].Mat.-wiss.u.Werkstofftech,2013,44(7):593-600.
[5]三谷和久,桥田和夫,周康.改善连铸铜板耐磨性能的Ni-Co合金的特性[J].连铸,1999,(6):35-36
[6]Babak Bakhit,Alireza Akbari,Farzad Nasirpouri,et al.Corrosion resistance of Ni-Co alloy and Ni-Co/Si C nanocompositecoatings electrodeposited by sediment codeposition technique[J].Applied Surface Science,2014,307:351-359.
[7]牟培兴.手表零件镀镍钴工艺[J].电镀与环保,1989,10(4):36-37.
[8]Burzyn'ska L,Rudnik E.The influence of electrolysis parameters on the composition and morphology of Co-Ni alloys[J].Hydromet-allurgy,2000,54:133-149.
[9]Gomez E,Ramirez J,Valles E.Electrodeposition of Co-Ni alloys[J].J Appl Electrochem,1998,28(3):71-76.
[10]Zamani,Amadeh,Laribaghal S M.Effect of Co content on electrodeposition mechanism and mechanical properties of electrodeposited Ni-Co alloy[J].Trans.Nonferrous Met.Soc.China,2016,26:484-491.
[11]王蓓蓓.用于结晶器内镀层的高钴低镍钴镍合金电铸工艺的研究[D].哈尔滨:哈尔滨工业大学,2012.
[12]裴和中,李雪,黄攀,等.镍钴合金电铸精密薄壁件的研究现状及展望[J].热加工工艺,2013,42(21):13-15.
[13]Sung Hoon Honga,Sang Hyun Ahnb,Insoo Choib,et al.Fabrication and evaluation of nickel cobalt alloy electrocatalysts foralkaline water[J].Applied Surface Science,2014,307:146-152.
[14]姚素薇,刘冰,张卫国,等.电沉积Ni-Co合金及其结构研究[J].电镀与精饰,1996,18(5):7-10.
[15]迟玉中,刘雁红,王新庄.电沉积镍钴纳米合金的制备及性能[J].天津科技大学学报,2007,22(3):40-43.
[16]Goldbach S,Kermadec R,Lapicque F.Electrodeposition of Ni-Co alloys from sulfamate baths[J].J Appl Electrochem,2000,30(2):277-284.
[17]封万起,王建,张义成,等.由氨基磺酸盐和硫酸盐电解液电沉积Ni-Co合金的对比研究[J].电镀与精饰,1996,18(2):4-8.
[18]武钢,李宁,杜明华,等.电沉积Ni-Co合金镀层结构及硬度的研究[J].材料科学与工艺,2002,10(4):419-423.
[19]张义成,封万启,王建宇,等.电沉积Ni-Co合金的研究[J].电镀与精饰,1995,17(6):4-7.
[20]邢乐红.硫酸型镍铁合金镀液中亚铁离子的补加与稳定性研究[D].哈尔滨:哈尔滨工业大学,2008.
[21]Meenu Srivastava,Ezhil Selvi V,William Grips V K,et al.Corrosion resistance and microstructure of electrodeposited nickel-cobalt alloy coatings[J].Surface&Coatings Technology,2006,201:3051-3060.
[22]潘秉锁,史冬梅,杨凯华.稀土元素对镍及镍钴合金镀层性能的影响[J].材料保护,2002,35(6):21-22.
[23]尤益辉.深共熔溶剂中金属镀层的电沉积制备及性能[D].浙江:浙江大学,2013.
[24]王丹,高吉成,张骥群,等.沉积参数对Ni-Co镀层成分及微观结构影响[J].四川大学学报(自然科学版),2013,50(1):118-124.
[25]牛丽媛,张洁.高硬度纳米镍钴合金镀层的制备与表征[J].材料热处理技术,2008,28(14):42-44.
[26]汪笑鹤,徐滨士,胡振峰,等.电刷镀n-Al2O3/Ni-Co镀层组织与性能的研究[J].电镀与环保2010,30(6):13-16.
[27]郑炜铭,庄哲峰,戴品强,等.电刷镀纳米晶Ni-Co合金镀层组织结构与性能的研究[J].福州大学学报,2010,28(1):90-94.
[28]耿哲,刘阳,张宏杰,等.结晶器铜板Ni-Co电镀层的耐磨性性[J].中国表面工程,2013,26(6):93-99.
[29]王立平,高燕,刘惠文,等.相结构对Ni-Co合金镀层摩擦磨损性能的影响[J].电镀与环保,2005,25(2):14-16.
[30]王立平,高燕,刘惠文,等.电沉积梯度Ni-Co纳米合金镀层的研究[J].电镀与涂饰,2004,23(6):5-7.
[31]刘学武,许韵华,胡芃,等.高频脉冲电镀镍钴合金镀层的耐磨性[J].电镀与涂饰,2013,32(9):18-22.
[32]朱龙章,张庆元,陈宇飞,等.镍钻合金镀层的电沉积及其耐蚀性的研究[J].材料保护,1997,30(5):4-6.
[33]屈新鑫,葛文,杨倩,等.糖精浓度和镀液温度对纳米晶镍钴合金电镀层组织结构和耐蚀性的影响[J].材料保护,2013,46(10):4-8.
[34]梁燕,许韵华,范爽,等.高频脉冲电沉积镍-钴合金镀层的耐蚀性[J].电镀与精饰,2009,30(9):32-35.
[35]Khorsanda,Raeissia K,Ashrafizadeha F,et al.Corrosion behaviour of super-hydrophobic electrodeposited nickelcobalt alloy film[J].Applied Surface Science,2016,364:349-357.
[36]刘向平,向永华,姚巨坤.纳米电刷镀—再制造关键技术之一[J].新技术新工艺,2005,(2):25-26.
[37]朱胜,姚巨坤.电刷镀再制造工艺技术[J].新技术新工艺,2009,(6):1-3.
[38]张叶成,孙智富,张津.纳米复合电刷镀镀层性能的研究现状[J].重庆工学院学报,2007,21(10):47-50.
[39]Ramazan Karslioglu,Hatem Akbulut.Comparison microstructure and sliding wear properties of nickel-cobalt/CNT composite coatings by DC,PC and PRC current electrodeposition[J].Applied Surface Science,2015,353:615-627.
[40]Wang Xiaohe,LüBiao,Hu Zhenfeng,et al.Effects of nAl2O3Particles Content on Structure and Performance of Electro-Brush Plating Ni-Co Alloy Composite Coatings[J].Rare Metal Materials and Engineering,2016,45(1):36-41.
[41]许伟长,戴品强,郑耀东.钴含量对电沉积纳米晶镍钴合金组织与力学性能的影响[J].中国有色金属学报,2010,20(1):92-99.
[42]黄志伟,王磊,王琳,等.电沉积纳米镍-钴合金在金刚石工具制备中的应用研究[J].金刚石与磨料磨具工程,2014,(34):40-43.
[43]Torabinejad V,Aliofkhazraei M,Sabour rouhaghdam A,et al.Tribological properties of Ni-Fe-Co multilayer coatings fabricaated by pulse electrodeposition[J].Tribology International,2017,106:34-40.
[44]杨添,彭成章,熊伟.Ni-Co-Cr合金共沉积工艺[J].湖南科技大学学报(自然科学版),2015,30(3):36-40.
[45]雷惊天.电沉积Fe-Co-W、Ni-Co-W非晶合金代铬镀层工艺及性能研究[D].湖南:湖南大学,2004.
[2]王伊卿,赵文轸,唐一平,等.Ni-Co合金电铸工艺及性能研究[J].兵器材料科学与工程,2000,23(3):39-43.
[3]武刚,李宁,周德瑞.氨基磺酸体系Co-Ni合金电化学共沉积行为及动力学机理[J].高校化学工程学报,2005,19(1):48-53.
[4]Wu Z W,Lei Y P,Wang Y,et al.Effect of cobalt content on microstructure and property of electroplated nickel-cobalt alloy coatings[J].Mat.-wiss.u.Werkstofftech,2013,44(7):593-600.
[5]三谷和久,桥田和夫,周康.改善连铸铜板耐磨性能的Ni-Co合金的特性[J].连铸,1999,(6):35-36
[6]Babak Bakhit,Alireza Akbari,Farzad Nasirpouri,et al.Corrosion resistance of Ni-Co alloy and Ni-Co/Si C nanocompositecoatings electrodeposited by sediment codeposition technique[J].Applied Surface Science,2014,307:351-359.
[7]牟培兴.手表零件镀镍钴工艺[J].电镀与环保,1989,10(4):36-37.
[8]Burzyn'ska L,Rudnik E.The influence of electrolysis parameters on the composition and morphology of Co-Ni alloys[J].Hydromet-allurgy,2000,54:133-149.
[9]Gomez E,Ramirez J,Valles E.Electrodeposition of Co-Ni alloys[J].J Appl Electrochem,1998,28(3):71-76.
[10]Zamani,Amadeh,Laribaghal S M.Effect of Co content on electrodeposition mechanism and mechanical properties of electrodeposited Ni-Co alloy[J].Trans.Nonferrous Met.Soc.China,2016,26:484-491.
[11]王蓓蓓.用于结晶器内镀层的高钴低镍钴镍合金电铸工艺的研究[D].哈尔滨:哈尔滨工业大学,2012.
[12]裴和中,李雪,黄攀,等.镍钴合金电铸精密薄壁件的研究现状及展望[J].热加工工艺,2013,42(21):13-15.
[13]Sung Hoon Honga,Sang Hyun Ahnb,Insoo Choib,et al.Fabrication and evaluation of nickel cobalt alloy electrocatalysts foralkaline water[J].Applied Surface Science,2014,307:146-152.
[14]姚素薇,刘冰,张卫国,等.电沉积Ni-Co合金及其结构研究[J].电镀与精饰,1996,18(5):7-10.
[15]迟玉中,刘雁红,王新庄.电沉积镍钴纳米合金的制备及性能[J].天津科技大学学报,2007,22(3):40-43.
[16]Goldbach S,Kermadec R,Lapicque F.Electrodeposition of Ni-Co alloys from sulfamate baths[J].J Appl Electrochem,2000,30(2):277-284.
[17]封万起,王建,张义成,等.由氨基磺酸盐和硫酸盐电解液电沉积Ni-Co合金的对比研究[J].电镀与精饰,1996,18(2):4-8.
[18]武钢,李宁,杜明华,等.电沉积Ni-Co合金镀层结构及硬度的研究[J].材料科学与工艺,2002,10(4):419-423.
[19]张义成,封万启,王建宇,等.电沉积Ni-Co合金的研究[J].电镀与精饰,1995,17(6):4-7.
[20]邢乐红.硫酸型镍铁合金镀液中亚铁离子的补加与稳定性研究[D].哈尔滨:哈尔滨工业大学,2008.
[21]Meenu Srivastava,Ezhil Selvi V,William Grips V K,et al.Corrosion resistance and microstructure of electrodeposited nickel-cobalt alloy coatings[J].Surface&Coatings Technology,2006,201:3051-3060.
[22]潘秉锁,史冬梅,杨凯华.稀土元素对镍及镍钴合金镀层性能的影响[J].材料保护,2002,35(6):21-22.
[23]尤益辉.深共熔溶剂中金属镀层的电沉积制备及性能[D].浙江:浙江大学,2013.
[24]王丹,高吉成,张骥群,等.沉积参数对Ni-Co镀层成分及微观结构影响[J].四川大学学报(自然科学版),2013,50(1):118-124.
[25]牛丽媛,张洁.高硬度纳米镍钴合金镀层的制备与表征[J].材料热处理技术,2008,28(14):42-44.
[26]汪笑鹤,徐滨士,胡振峰,等.电刷镀n-Al2O3/Ni-Co镀层组织与性能的研究[J].电镀与环保2010,30(6):13-16.
[27]郑炜铭,庄哲峰,戴品强,等.电刷镀纳米晶Ni-Co合金镀层组织结构与性能的研究[J].福州大学学报,2010,28(1):90-94.
[28]耿哲,刘阳,张宏杰,等.结晶器铜板Ni-Co电镀层的耐磨性性[J].中国表面工程,2013,26(6):93-99.
[29]王立平,高燕,刘惠文,等.相结构对Ni-Co合金镀层摩擦磨损性能的影响[J].电镀与环保,2005,25(2):14-16.
[30]王立平,高燕,刘惠文,等.电沉积梯度Ni-Co纳米合金镀层的研究[J].电镀与涂饰,2004,23(6):5-7.
[31]刘学武,许韵华,胡芃,等.高频脉冲电镀镍钴合金镀层的耐磨性[J].电镀与涂饰,2013,32(9):18-22.
[32]朱龙章,张庆元,陈宇飞,等.镍钻合金镀层的电沉积及其耐蚀性的研究[J].材料保护,1997,30(5):4-6.
[33]屈新鑫,葛文,杨倩,等.糖精浓度和镀液温度对纳米晶镍钴合金电镀层组织结构和耐蚀性的影响[J].材料保护,2013,46(10):4-8.
[34]梁燕,许韵华,范爽,等.高频脉冲电沉积镍-钴合金镀层的耐蚀性[J].电镀与精饰,2009,30(9):32-35.
[35]Khorsanda,Raeissia K,Ashrafizadeha F,et al.Corrosion behaviour of super-hydrophobic electrodeposited nickelcobalt alloy film[J].Applied Surface Science,2016,364:349-357.
[36]刘向平,向永华,姚巨坤.纳米电刷镀—再制造关键技术之一[J].新技术新工艺,2005,(2):25-26.
[37]朱胜,姚巨坤.电刷镀再制造工艺技术[J].新技术新工艺,2009,(6):1-3.
[38]张叶成,孙智富,张津.纳米复合电刷镀镀层性能的研究现状[J].重庆工学院学报,2007,21(10):47-50.
[39]Ramazan Karslioglu,Hatem Akbulut.Comparison microstructure and sliding wear properties of nickel-cobalt/CNT composite coatings by DC,PC and PRC current electrodeposition[J].Applied Surface Science,2015,353:615-627.
[40]Wang Xiaohe,LüBiao,Hu Zhenfeng,et al.Effects of nAl2O3Particles Content on Structure and Performance of Electro-Brush Plating Ni-Co Alloy Composite Coatings[J].Rare Metal Materials and Engineering,2016,45(1):36-41.
[41]许伟长,戴品强,郑耀东.钴含量对电沉积纳米晶镍钴合金组织与力学性能的影响[J].中国有色金属学报,2010,20(1):92-99.
[42]黄志伟,王磊,王琳,等.电沉积纳米镍-钴合金在金刚石工具制备中的应用研究[J].金刚石与磨料磨具工程,2014,(34):40-43.
[43]Torabinejad V,Aliofkhazraei M,Sabour rouhaghdam A,et al.Tribological properties of Ni-Fe-Co multilayer coatings fabricaated by pulse electrodeposition[J].Tribology International,2017,106:34-40.
[44]杨添,彭成章,熊伟.Ni-Co-Cr合金共沉积工艺[J].湖南科技大学学报(自然科学版),2015,30(3):36-40.
[45]雷惊天.电沉积Fe-Co-W、Ni-Co-W非晶合金代铬镀层工艺及性能研究[D].湖南:湖南大学,2004.