聚丙烯的增韧改性研究进展
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摘要
从化学改性、物理改性技术方面介绍了国内外对聚丙烯(PP)进行增韧改性的研究进展。其中,化学改性技术包括共聚改性、接枝改性和交联改性;物理改性技术包括填充改性、共混改性和增强增韧改性。在PP增韧改性众多方法中,物理改性其成本低、效果快,成为应用广泛的增韧方法。PP的增韧改性仍有很大的潜力有待发掘,因此其发展前景受到人们的广泛关注。
In this review, the research progress toughening of polypropylene(PP) introduced chemical and physical modification at home and abroad. Chemical modification technology includes copolymerization, graft and cross-linking modification. Physical modification technology includes filling, blending and toughening modification. In the many methods of toughening of PP, physical modification had become a wide application of toughening method because of low cost and fast effect. The research of toughening modification of PP still has great potential to be explored, so it has been attracted much attention in recent years.
In this review, the research progress toughening of polypropylene(PP) introduced chemical and physical modification at home and abroad. Chemical modification technology includes copolymerization, graft and cross-linking modification. Physical modification technology includes filling, blending and toughening modification. In the many methods of toughening of PP, physical modification had become a wide application of toughening method because of low cost and fast effect. The research of toughening modification of PP still has great potential to be explored, so it has been attracted much attention in recent years.
引文
[1]Ning NY,Yin QJ,Luo F,Zhang Q,Du RN,Fu Q.Crystallization behavior and mechanical properties of polypropylene/halloysite composites[J].Polymers,2007,48:7374-7384.
[2]Zhang S.A review of flame retardant polypropylene fibres[J].Progress in Polymer Science,2003,28:1517-1538.
[3]Hong CH,Lee YB,Bae JW,Jho JY,Nam BU,Chang DH.Tensile properties and stress whitening of polypropylene/polyolefin elastomer/magnesium hydroxide flame retardant composites for cable insulating application[J].Appl Polym Sci,2005;97:2311–8.
[4]Liauw CM,Lees GC,Hurst SJ,Rothon CRN,Ali S.Effect of silane-based filler surface treatment formulation on the interfacial properties of impact modified polypropylene magnesium hydroxide composites[J].Compos Part A–Appl Sci,1998;29:1313–8.
[5]Yin J,Zhang Y,Zhang YX.Fracture behavior and deformation mechanism of polypropylene/ethylene–octane copolymer/magnesium hydroxide ternary phase composites[J].Appl Polym Sci,2005;98:957–67.
[6]Chen XL,Yu J,Guo SY.Structureand properties of polypropylene composites filled with magnesium hydroxide.[J]Appl Polym Sci,2006;102:4943–51.
[7]张立峰,郭宝华,张增民.双单体固相共聚改性聚丙烯技术及其机理研究[J].高等学校化学学报,2001,(08):1406-1409.
[8]王东波,田言,韩俐伟,聂玉梅,吴青,霍力超,冯玉杰.纳米Si O2表面接枝聚合改性及在PP中的分散[J].合成树脂及塑料,2008,11(01):32-34+39.
[9]蒋姗,李夏倩,王克敏等.丙烯酸甲酯/二乙烯基苯接枝交联共聚合改性聚丙烯隔膜[J].功能材料,2014,32(20):20020-20023.
[10]谢浩,杨隽,周立民,郭雅妮.PP/LDPE化学交联发泡的研究[J].应用化工,2012,21(07):1132-1134+1139.
[11]Yin J,Zhang Y,Zhang YX.Fracture behavior and deformation mechanism of polypropylene/ethylene–octane copolymer/magnesium hydroxide ternary phase composites[J].Appl Polym Sci,2005;98:957–67.
[12]郭红革,谢雁.橡胶改性PP共混体系的研究[J].塑料工业,2001,29(1):13-15.
[13]Hao GR,Huang WD,Yuan J,Tang NP,Xiao FP,Effect of aging on chemical and rheological properties of SBS modified asphalt with different compositions[J].Construction and Building Materials,2017;156:902-910.
[14]蔺海兰,李常青,蒋少强等.SBS和纳米Si O2协同增韧增强PP复合材料的研究[J].工程塑料应用,2014,44(11):11-16.
[15]杨继年,许爱琴.LDPE共混改性PP的结晶行为及模压发泡效果[J].塑料科技,2012,40(07):60-63.
[16]李国林,吴水珠,曾钫等.高模量高强度PP/PA6复合材料的制备与研究[J].塑料工业,2009,37(10):25-27,31.
[17]黄健,张云灿,左文京等.PP/EPDM/高岭土三元共混体系的脆韧转变[J].工程塑料应用,2000,28(10):6-9.
[18]朱德钦,生瑜,王剑峰等.PP/EPDM/Ca CO3三元复合材料的相结构及力学性能研究[J].高分子学报,2008,(11):1061-1067.
[19]羊海棠,杨瑞成,冯辉霞等.纳米二氧化硅粒子增韧聚丙烯的研究[J].甘肃工业大学学报,2003,29(2):34-36.
[20]赵红英.纳米Ca CO3粒子增韧PP及PP/SBS复合体系的研究[D].北京化工大学,2002.
[2]Zhang S.A review of flame retardant polypropylene fibres[J].Progress in Polymer Science,2003,28:1517-1538.
[3]Hong CH,Lee YB,Bae JW,Jho JY,Nam BU,Chang DH.Tensile properties and stress whitening of polypropylene/polyolefin elastomer/magnesium hydroxide flame retardant composites for cable insulating application[J].Appl Polym Sci,2005;97:2311–8.
[4]Liauw CM,Lees GC,Hurst SJ,Rothon CRN,Ali S.Effect of silane-based filler surface treatment formulation on the interfacial properties of impact modified polypropylene magnesium hydroxide composites[J].Compos Part A–Appl Sci,1998;29:1313–8.
[5]Yin J,Zhang Y,Zhang YX.Fracture behavior and deformation mechanism of polypropylene/ethylene–octane copolymer/magnesium hydroxide ternary phase composites[J].Appl Polym Sci,2005;98:957–67.
[6]Chen XL,Yu J,Guo SY.Structureand properties of polypropylene composites filled with magnesium hydroxide.[J]Appl Polym Sci,2006;102:4943–51.
[7]张立峰,郭宝华,张增民.双单体固相共聚改性聚丙烯技术及其机理研究[J].高等学校化学学报,2001,(08):1406-1409.
[8]王东波,田言,韩俐伟,聂玉梅,吴青,霍力超,冯玉杰.纳米Si O2表面接枝聚合改性及在PP中的分散[J].合成树脂及塑料,2008,11(01):32-34+39.
[9]蒋姗,李夏倩,王克敏等.丙烯酸甲酯/二乙烯基苯接枝交联共聚合改性聚丙烯隔膜[J].功能材料,2014,32(20):20020-20023.
[10]谢浩,杨隽,周立民,郭雅妮.PP/LDPE化学交联发泡的研究[J].应用化工,2012,21(07):1132-1134+1139.
[11]Yin J,Zhang Y,Zhang YX.Fracture behavior and deformation mechanism of polypropylene/ethylene–octane copolymer/magnesium hydroxide ternary phase composites[J].Appl Polym Sci,2005;98:957–67.
[12]郭红革,谢雁.橡胶改性PP共混体系的研究[J].塑料工业,2001,29(1):13-15.
[13]Hao GR,Huang WD,Yuan J,Tang NP,Xiao FP,Effect of aging on chemical and rheological properties of SBS modified asphalt with different compositions[J].Construction and Building Materials,2017;156:902-910.
[14]蔺海兰,李常青,蒋少强等.SBS和纳米Si O2协同增韧增强PP复合材料的研究[J].工程塑料应用,2014,44(11):11-16.
[15]杨继年,许爱琴.LDPE共混改性PP的结晶行为及模压发泡效果[J].塑料科技,2012,40(07):60-63.
[16]李国林,吴水珠,曾钫等.高模量高强度PP/PA6复合材料的制备与研究[J].塑料工业,2009,37(10):25-27,31.
[17]黄健,张云灿,左文京等.PP/EPDM/高岭土三元共混体系的脆韧转变[J].工程塑料应用,2000,28(10):6-9.
[18]朱德钦,生瑜,王剑峰等.PP/EPDM/Ca CO3三元复合材料的相结构及力学性能研究[J].高分子学报,2008,(11):1061-1067.
[19]羊海棠,杨瑞成,冯辉霞等.纳米二氧化硅粒子增韧聚丙烯的研究[J].甘肃工业大学学报,2003,29(2):34-36.
[20]赵红英.纳米Ca CO3粒子增韧PP及PP/SBS复合体系的研究[D].北京化工大学,2002.