国内外汽柴油加氢催化剂的技术进展
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摘要
国内外催化剂科研单位院所和公司的汽柴油加氢处理催化剂主要是针对石油中硫含量、芳烃含量高的特点而研发,以Ni、Co、Mo的化合物为主要活性组分,如Co-Mo型、Ni-Mo型、Ni-W型、Ni-Mo-W型、Co-Mo-Ni型等。对比国内外汽柴油加氢催化剂的现状,其催化剂体系在钨组分上存在明显区别。结合中国国情,可从硫化型、纳米型以及杂多酸型催化剂等几个方面入手,开发出新型高效环保的汽柴油加氢催化剂,特别是可大力开发含钨的杂多酸型的纳米催化剂体系。
Through the investigation of domestic and foreign catalyst institutes and companies,we find that the gasoline and diesel hydrogenation catalysts are mainly developed for the sulfur content and aromatics content in petroleum. The Ni,Co and Mo compounds are the active components,and there are some types catalysts,such as Co-Mo type,Ni-Mo type,Ni-W type,Ni-Mo-W type,Co-Mo-Ni type. By comparing the domestic and foreign gasoline and diesel hydrogenation catalyst,there are obvious differences within tungsten components. Taking into account China's national conditions,we should develop a new efficient and environmentally friendly gasoline and diesel hydrogenation catalyst with the vulcanization,nano-type or heteropolyacid catalyst-type,especially the development of the containing tungsten nano-catalyst system with a heteropolyacid catalyst-type.
Through the investigation of domestic and foreign catalyst institutes and companies,we find that the gasoline and diesel hydrogenation catalysts are mainly developed for the sulfur content and aromatics content in petroleum. The Ni,Co and Mo compounds are the active components,and there are some types catalysts,such as Co-Mo type,Ni-Mo type,Ni-W type,Ni-Mo-W type,Co-Mo-Ni type. By comparing the domestic and foreign gasoline and diesel hydrogenation catalyst,there are obvious differences within tungsten components. Taking into account China's national conditions,we should develop a new efficient and environmentally friendly gasoline and diesel hydrogenation catalyst with the vulcanization,nano-type or heteropolyacid catalyst-type,especially the development of the containing tungsten nano-catalyst system with a heteropolyacid catalyst-type.
引文
[1]SUN X S,QIAN X K,JIANG X F.Review of China's oil&gas industry development in 2014 and outlook for2015[J].China Oil and Gas,2015(1):24-29.
[2]马艳秋,李宝忠,侯娜,等.炼油业大气污染物减排技术发展现状[J].当代石油石化,2012,20(5):14-17.
[3]张娟利,杨天华.甲醇汽油理化特性的检测分析与系统研究[J].当代化工,2014(2):174-177.
[4]于海霞,王松涛,杨雅仙.炼油厂尾气处理技术探讨[J].石油化工技术与经济,2016,32(4):59-62.
[5]ZHANG J X,ZHOU Y,XU Y,et al.Research and development of novel heavy oil catalytic cracking catalyst RCC-1[J].China Petroleum Processing&Petrochemical Technology,2014,16(4):7-11.
[6]张阳,崔发祥.催化重整化学反应研究[J].当代化工,2016,45(7):1599-1601.
[7]袁洪生.提高柴油加氢精制催化剂活性的方法[J].石化技术,2016,23(8):33-34.
[8]XU X J,LIU D X,WANG H T,et al.Preparation and commercial application of ZHC-01 hydrocracking catalyst[J].China Petroleum Processing&Petrochemical Technology,2007(2):43-47.
[9]WANG Y J,LI Y,ZHANG Y Y,et al.Catalytic performance of Mo O3-WO3/Ti O2-Si O2 catalyst for n-heptane isomerization[J].Acta Petrolei Sinica(Petroleum Processing Section),2012,28(1):127-132.
[10]GAO J,CHEN X,REN N,et al.Acylation desulfurization of oil via reactive adsorption[J].Aiche Journal,2013,59(8):2966-2976.
[11]徐伟池,倪术荣,刘明东.烯烃催化叠合生产合成油技术进展[J].化工中间体,2014(9):24-27.
[12]JIANG D H,ZHANG Y Y,HU Z H,et al.Medium-pressure hydro-upgrading(MHUG)technology for producing clean diesel fuel[J].China Petroleum Processing&Petrochemical Technology,2012,14(1):1-7.
[13]姚峰,詹书田,张新来.选择性加氢脱硫催化剂RSDS-1的应用[J].炼油技术与工程,2009,39(10):50-52.
[14]黄婷婷.高负载量Ni Mo S柴油加氢催化剂的制备方法与性能评价[D].青岛:中国石油大学(华东),2014.
[15]陈姣,张爱民,李建伟,等.国产催化剂在柴油加氢装置中的应用[J].化工管理,2016(3):116.
[16]文国民,黄莉,南晓钟,等.DN3110催化剂在连续重整预加氢装置上的工业应用[J].科学技术与工程,2012,12(2):428-430.
[17]冯保杰.高标准柴油加氢技术进展[J].当代化工,2015(2):343-346.
[18]贾云刚,张铁珍,高善彬,等.柴油加氢精制催化剂研究进展[C]//第八届全国工业催化技术及应用年会,西安:中国化工学会,全国工业催化信息站,2011:43-45.
[19]张斌,程海,李吉春,等.催化裂化汽油加氢脱硫技术研究[J].化工技术与开发,2014,38(7):30-35.
[20]董大清.国外清洁柴油加氢催化剂技术进展[J].化工科技市场,2010,33(7):1-4.
[21]胡俊利,王高杰.催化柴油加氢改质技术研究进展[J].石化技术与应用,2016,34(4):346-348.
[22]王福军,韩建新.清洁燃料生产[J].当代化工,2009,38(2):134-137.
[23]吕恩静,徐永强,刘晨光.FCC汽油选择性加氢脱硫催化剂Ru/Al2O3的研究[J].工业催化,2010,18(5):40-43.
[24]孟欣欣.Ni-W/γ-Al2O3催化剂对煤焦油加氢脱硫脱氮性能的研究[D].太原:太原理工大学,2016.
[25]许驰.柴油加氢催化剂研究进展[J].辽宁化工,2014(8):1052-1054.
[26]张鹏.硫化型催化剂NMS/γ-Al2O3的催化加氢性能研究[J].炼油技术与工程,2014,44(12):45-48.
[27]BELLUSSI G,RISPOLI G,MOLINARI D,et al.The role of Mo S2 nano-slabs in the protection of solid cracking catalysts for the total conversion of heavy oils to good quality distillates[J].Catalysis Science&Technology,2013,3(1):176-182.
[28]马玲,李磊,地力拜·马力克,等.纳米加氢催化剂研究进展[J].炼油与化工,2013(6):1-3.
[29]KUMAR S,SRIVASTAVA V C,BADONI R P.Oxidative desulfurization by chromium promotedsulfated zirconia[J].Fuel Processing Technology,2012,93(1):18-25.
[30]张伟伟,王建强,韩淑利,等.杂多酸催化剂在石油炼制中的应用研究进展[J].精细石油化工进展,2015(3):42-46.
[31]陈立东,于博浩,李传鹏,等.磷钼钒多酸基固体酸催化剂高效加氢精制FCC汽油[J].辽宁师范大学学报(自然科学版),2014(3):385-388.
[32]傅欲生.催化剂及助剂在催化裂化中的应用[D].济南:山东大学,2008.
[33]BESENBACHER F,BRORSON M,CLAUSEN B S,et al.Recent STM,DFT and HAADF-STEM studies of sulfide-based hydrotreating catalysts:insight into mechanistic,structural and particle size effects[J].Catalysis Today,2008,130(1):86-96.
[34]HAO L,XIONG G,LIU L,et al.Preparation of highly dispersed desulfurization catalysts and their catalytic performance in hydrodesulfurization of dibenzothiophene[J].Chinese Journal of Catalysis,2016,37(3):412-419.
[2]马艳秋,李宝忠,侯娜,等.炼油业大气污染物减排技术发展现状[J].当代石油石化,2012,20(5):14-17.
[3]张娟利,杨天华.甲醇汽油理化特性的检测分析与系统研究[J].当代化工,2014(2):174-177.
[4]于海霞,王松涛,杨雅仙.炼油厂尾气处理技术探讨[J].石油化工技术与经济,2016,32(4):59-62.
[5]ZHANG J X,ZHOU Y,XU Y,et al.Research and development of novel heavy oil catalytic cracking catalyst RCC-1[J].China Petroleum Processing&Petrochemical Technology,2014,16(4):7-11.
[6]张阳,崔发祥.催化重整化学反应研究[J].当代化工,2016,45(7):1599-1601.
[7]袁洪生.提高柴油加氢精制催化剂活性的方法[J].石化技术,2016,23(8):33-34.
[8]XU X J,LIU D X,WANG H T,et al.Preparation and commercial application of ZHC-01 hydrocracking catalyst[J].China Petroleum Processing&Petrochemical Technology,2007(2):43-47.
[9]WANG Y J,LI Y,ZHANG Y Y,et al.Catalytic performance of Mo O3-WO3/Ti O2-Si O2 catalyst for n-heptane isomerization[J].Acta Petrolei Sinica(Petroleum Processing Section),2012,28(1):127-132.
[10]GAO J,CHEN X,REN N,et al.Acylation desulfurization of oil via reactive adsorption[J].Aiche Journal,2013,59(8):2966-2976.
[11]徐伟池,倪术荣,刘明东.烯烃催化叠合生产合成油技术进展[J].化工中间体,2014(9):24-27.
[12]JIANG D H,ZHANG Y Y,HU Z H,et al.Medium-pressure hydro-upgrading(MHUG)technology for producing clean diesel fuel[J].China Petroleum Processing&Petrochemical Technology,2012,14(1):1-7.
[13]姚峰,詹书田,张新来.选择性加氢脱硫催化剂RSDS-1的应用[J].炼油技术与工程,2009,39(10):50-52.
[14]黄婷婷.高负载量Ni Mo S柴油加氢催化剂的制备方法与性能评价[D].青岛:中国石油大学(华东),2014.
[15]陈姣,张爱民,李建伟,等.国产催化剂在柴油加氢装置中的应用[J].化工管理,2016(3):116.
[16]文国民,黄莉,南晓钟,等.DN3110催化剂在连续重整预加氢装置上的工业应用[J].科学技术与工程,2012,12(2):428-430.
[17]冯保杰.高标准柴油加氢技术进展[J].当代化工,2015(2):343-346.
[18]贾云刚,张铁珍,高善彬,等.柴油加氢精制催化剂研究进展[C]//第八届全国工业催化技术及应用年会,西安:中国化工学会,全国工业催化信息站,2011:43-45.
[19]张斌,程海,李吉春,等.催化裂化汽油加氢脱硫技术研究[J].化工技术与开发,2014,38(7):30-35.
[20]董大清.国外清洁柴油加氢催化剂技术进展[J].化工科技市场,2010,33(7):1-4.
[21]胡俊利,王高杰.催化柴油加氢改质技术研究进展[J].石化技术与应用,2016,34(4):346-348.
[22]王福军,韩建新.清洁燃料生产[J].当代化工,2009,38(2):134-137.
[23]吕恩静,徐永强,刘晨光.FCC汽油选择性加氢脱硫催化剂Ru/Al2O3的研究[J].工业催化,2010,18(5):40-43.
[24]孟欣欣.Ni-W/γ-Al2O3催化剂对煤焦油加氢脱硫脱氮性能的研究[D].太原:太原理工大学,2016.
[25]许驰.柴油加氢催化剂研究进展[J].辽宁化工,2014(8):1052-1054.
[26]张鹏.硫化型催化剂NMS/γ-Al2O3的催化加氢性能研究[J].炼油技术与工程,2014,44(12):45-48.
[27]BELLUSSI G,RISPOLI G,MOLINARI D,et al.The role of Mo S2 nano-slabs in the protection of solid cracking catalysts for the total conversion of heavy oils to good quality distillates[J].Catalysis Science&Technology,2013,3(1):176-182.
[28]马玲,李磊,地力拜·马力克,等.纳米加氢催化剂研究进展[J].炼油与化工,2013(6):1-3.
[29]KUMAR S,SRIVASTAVA V C,BADONI R P.Oxidative desulfurization by chromium promotedsulfated zirconia[J].Fuel Processing Technology,2012,93(1):18-25.
[30]张伟伟,王建强,韩淑利,等.杂多酸催化剂在石油炼制中的应用研究进展[J].精细石油化工进展,2015(3):42-46.
[31]陈立东,于博浩,李传鹏,等.磷钼钒多酸基固体酸催化剂高效加氢精制FCC汽油[J].辽宁师范大学学报(自然科学版),2014(3):385-388.
[32]傅欲生.催化剂及助剂在催化裂化中的应用[D].济南:山东大学,2008.
[33]BESENBACHER F,BRORSON M,CLAUSEN B S,et al.Recent STM,DFT and HAADF-STEM studies of sulfide-based hydrotreating catalysts:insight into mechanistic,structural and particle size effects[J].Catalysis Today,2008,130(1):86-96.
[34]HAO L,XIONG G,LIU L,et al.Preparation of highly dispersed desulfurization catalysts and their catalytic performance in hydrodesulfurization of dibenzothiophene[J].Chinese Journal of Catalysis,2016,37(3):412-419.