现代测试技术在水合物实物样品分析测试中的应用概述
摘要
天然气水合物是一种潜在可开发的清洁能源,水合物的研究在资源勘查、开采和环境上意义重大,受到高度关注。随着技术的发展,多种现代测试技术应用到水合物物性分析测试中。X射线衍射、拉曼光谱技术和核磁共振技术均可分析水合物的成分和结构,X射线衍射和拉曼光谱还能研究水合物的生成/分解动力学过程,不同的研究手段有其利弊,需在实际应用中选择最优方案。然而,现代测试技术在我国应用时间尚短,分析测试技术还有很大的发展空间。
引文
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[2]肖钢,等.天然气水合物综论[M].北京:高等教育出版社,2012.
[3]陈庆.基于X射线衍射法对天然气水合物测试分析研究概述[J].地质论评,2016,62(增刊):3-4.
[4]Udachin K A,Ratcliffe C I,Ripmeester J A.Structure,composition,and thermai expansion of CO2hydrate from single crystal X-ray diffraction measurements[J].The Journal of Physical Chemistry B,2001,105(19):4200-4204.
[5]Udachin K A,Ratcliffe C I,Ripmeester J A.Single crystal diffraction studies of structureⅠ,Ⅱ,H hydrates:Structure,cage occupancy and composition[J].Journal of Supramolecular Chemistry,2002,2(4):405-408.
[6]刘昌岭,孟国庆.X射线衍射法在天然气水合物研究中的应用[J].岩矿测试,2014,33(4):468-479.
[7]Collett T S,Lee M W.Reservoir characterization of marine and permafrost associated gas hydrate accumulations with downhole well logs[J].Annals of the New York Academy of Sciences,2000,912(1):51-64.
[8]Amadeu K S,Robert C B,Sloan E D.Measurement of Clathrate Hydrates via Raman Spectroscopy[J].Journal of Physical Chemistry B,1997,101(38):7371-7377.
[9]Peter Larkin.Infrared and Raman Spectroscopy:Principles and Spectral Interpretation[M].Elsevier,2011.
[10]Chazallon B,Champagnon B,Panczer G,et al.Micro-Raman analysis of synthetic air clathrates[J].European Journal of Mineralogy,1998,10(6):1125-1134.
[11]付娟,吴能友,卢海龙,等.激光拉曼光谱在气体水合物研究中的应用[J].光谱学与光谱分析,2015,35(11):2996-3002.
[12]Davies S R,Sloan E D,Sum K S,et al.In situ studies of the mass transfer mechanism across a methane hydrate film using HighResolution Confocal Raman Spectroscopy[J].Journal of Physical Chemistry C,2010,114(2):1173-1180.
[13]Subramanian S,Kini R A,Dec S F,et al.Microscopic Measurements and Modeling of Hydrate Formation Kinetics[J].Annals of the New York Academy of Sciences,2000,912(1):583-592.
[14]刘昌岭,孟庆国,业渝光.固体核磁共振技术在气体水合物研究中的应用[J].波谱学杂志,2012,29(3):465-474.