阻燃型聚氨酯的研究进展
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摘要
主要介绍了聚氨酯材料在阻燃方面的研究的必要性;根据在聚氨酯材料中的存在形式不同,阻燃剂可以分为添加型阻燃剂、反应型阻燃剂和纳米复合型阻燃剂,同时介绍了不同类型阻燃剂的作用机理。
This paper mainly introduces the research necessity of polyurethane material with the flame retardant properties.According to the existing form in polyurethane,flame retardant can be divided into additive flame retardant,reactive flame retardant and nano composite flame retardant,meanwhile we have introduced the mechanism of different types of flame retardants.
This paper mainly introduces the research necessity of polyurethane material with the flame retardant properties.According to the existing form in polyurethane,flame retardant can be divided into additive flame retardant,reactive flame retardant and nano composite flame retardant,meanwhile we have introduced the mechanism of different types of flame retardants.
引文
[1]朱吕民,刘益军,等.聚氨酯泡沫材料[M].北京:化学工业出版社,2005.
[2]赵治安,鲁广斌,鲁健.聚氨酯泡沫塑料火灾危险性分析及其防火措施[J].合肥工业大学学报:社会科学版,2002,16(5):143-146.
[3]袁开军,江治,李疏芬,等.聚氨酯的阻燃性机理研究进展[J].高分子材料科学与工程,2006,22(5):1-4.
[4]李跃文,陈兴华.聚氨酯阻燃改性研究进展[J].现代塑料加工应用,2014,26(5):53-56.
[5]史以俊,罗振扬,何明,等.含磷阻燃剂对聚氨酯硬泡燃烧特性影响的研究[J].聚氨酯工业,2009,24(5):23-25.
[6]韩海军,王新峰,李红英.阻燃型喷涂硬质聚氨酯泡沫塑料的制备及性能研究[J].新型建筑材料,2014(1):67-71.
[7]钟柳,刘治国,欧育湘.一种新型含氯的磷-膦酸酯阻燃聚氨酯的阻燃性能[J].阻燃材料与技术,2007(4):9-12.
[8]王学川,王莉,强涛涛,等.阻燃聚氨酯的研究进展[J].材料导报A:综述篇,2013,27(2):90-94.
[9]Sabyasachi Gaan,Shuyu Liang,Henri Mispreuve,et al.Flame retardant flexible polyurethane foams from novel DOPO-phosphonamidate additives[J].Polymer Degradation and Stability,2015,113:180-188.
[10]王紫潇,文庆珍,朱金华.用于聚氨酯材料的无卤添加型阻燃剂研究进展[J].聚氨酯工业,2015,30(3):31-34.
[11]黄福林,赵乘寿,王德义,等.软质聚氨酯泡沫塑料用无卤阻燃剂的研究[J].化学研究与应用,2008,20(7):840-843.
[12]Matthias N Neisius,Shuyu Liang,Henri Mispreuve,et al.Recent Developments in Flame Retardancy of Flexible Polyurethane Foams[C]∥Morgan,et al.Fire and Polymers VI:New Advances in Flame Retardant Chemistry and Science,American Chemical Society:Washington,DC,2012.
[13]王方超,魏徵,王源升,等.添加型阻燃聚氨酯泡沫的研究进展[J].聚氨酯工业,2016,31(3):1-4.
[14]许晓光,许乃迪.无机添加型阻燃剂对聚氨酯阻燃涂料性能的影响[J].塑料制造,2012(8):81-84.
[15]Wenzong Xu,Baolin Xu,Aijiao Li,et al.Flame Retardancy and Smoke Suppression of Mg Al Layered Double Hydroxides Containing P and Si in Polyurethane Elastomer[J].Industrial&Engineering Chemistry Research,2016,55(42):11175-11185.
[16]许晶晶,肖卫东,郝惠军,等.膨胀型阻燃剂的研究与应用[J].塑料工业,2005,33:210-214.
[17]张晓光,王列平,宁斌科,等.聚氨酯泡沫塑料无卤阻燃技术的研究进展[J].化工进展,2012,31(7):1521-1527.
[18]常海洲,彭云,江霜英,等.氮磷膨胀型阻燃剂对聚氨酯阻燃性的影响[J].皮革与化工,2015,32(1):1-4.
[19]张志毅,孙付宇,刘亚青.新型磷-氮膨胀型阻燃剂的合成及其在硬质聚氨酯泡沫中的应用[J].合成化学,2014,22(1):20-23.
[20]李跃文,陈兴华.聚氨酯阻燃改性研究进展[J].现代塑料加工应用,2014,26(5):53-56.
[21]Wang Xi,Lijun Qian,Yajun Chen,et al.Addition flame-retardant behaviors of expandable graphite and[bis(2-hydroxyethyl)amino]-methyl-phosphonic acid dimethyl ester in rigid polyurethane foams[J].Polymer Degradation and Stability,2015,122:36-43.
[22]Modesti M,Lorenzetti A,Simioni F,et al.Expandable graphite as an intumescent flame retardant in polyisocyanurate-polyurethane foams[J].Polymer Degradation and Stability,2002,77:195-202.
[23]刘超,金星龙,等.可膨胀石墨/磷酸三氯乙酯协同阻燃硬质聚氨酯泡沫塑料的研究[J].天津理工大学学报,2014,30(3):41-44.
[24]杨荣,乔红,胡文田,等.反应型磷氮阻燃剂/可膨胀石墨复配阻燃聚氨酯泡沫[J].化工学报,2016,67(5):2169-2175.
[25]郑敏睿,张猛,李书龙,等.阻燃型聚氨酯泡沫研究新进展[J].热固性树脂,2016,31(4):62-68.
[26]张晓光,王列平,宁斌科,等.聚氨酯泡沫塑料无卤阻燃技术的研究进展[J].化工进展,2012,31(7):1521-1527.
[27]丁思月,姚玥玮,等.反应型低聚有机膦酸酯阻燃剂的合成与应用[J].聚氨酯工业,2012,27(6):17-20.
[28]钱立军,冯发飞,许国志.两种磷系阻燃剂阻燃聚氨酯硬泡的对比研究[J].塑料工业,2013,41(8):100-103.
[29]周红欣,李建华,万小龙.含溴阻燃聚醚多元醇的合成及在聚氨酯硬泡中的应用研究[J].新型建筑材料,2014(8):68-71.
[30]贾润萍,魏路,等.三聚氰胺基结构阻燃聚醚多元醇的合成及其阻燃性能评价[J].功能材料,2015,46:156-160.
[31]吴一鸣.硬泡阻燃聚醚多元醇的合成及应用[J].能源化工,2015,36(3):62-66.
[32]孟玉刚,霍瑞亭,侯丽丽.聚氨酯纳米阻燃技术的研究进展[J].材料导报,2010,24(16):160-163.
[33]Meng Xue,Xian Zhang,Zhao-feng Wu,et al.Preparation and Flame Retardancy of Polyurethane/POSS Nanocomposites[J].Chinese Journal of Chemical Physics,2013,26(4):445-450.
[34]陈涛,胡爽,等.纳米金属氧化物对聚氨酯硬泡阻燃性能的影响[J].聚氨酯工业,2015,30(1):18-21.
[35]王荣涛,梁小平,王小会,等.纳米镁铝水滑石的制备及其对聚氨酯阻燃性能的影响[J].功能材料,2009,40(12):2119-2123.
[36]章培坤,范浩军,陈意,等.纳米硅溶胶改性水性聚氨酯及其阻燃性能[J].皮革科学与工程,2014,24(1):10-16.
[37]Wei Wang,Ying Pan,Haifeng Pan,et al.Synthesis and characterization of Mn O2nanosheets based multilayer coating and applications as a flame retardant for flexible polyurethane foam[J].Composites Science&Technology,2015,123:212-221.
[38]Wei Xu,Guojian Wang,Xiaorui Zhang.Research on highly flame-retardant rigid PU foams by combination of nanostructured additives and phosphorus flame retardants[J].Polymer Degradation and Stability,2015,111:142-150.
[2]赵治安,鲁广斌,鲁健.聚氨酯泡沫塑料火灾危险性分析及其防火措施[J].合肥工业大学学报:社会科学版,2002,16(5):143-146.
[3]袁开军,江治,李疏芬,等.聚氨酯的阻燃性机理研究进展[J].高分子材料科学与工程,2006,22(5):1-4.
[4]李跃文,陈兴华.聚氨酯阻燃改性研究进展[J].现代塑料加工应用,2014,26(5):53-56.
[5]史以俊,罗振扬,何明,等.含磷阻燃剂对聚氨酯硬泡燃烧特性影响的研究[J].聚氨酯工业,2009,24(5):23-25.
[6]韩海军,王新峰,李红英.阻燃型喷涂硬质聚氨酯泡沫塑料的制备及性能研究[J].新型建筑材料,2014(1):67-71.
[7]钟柳,刘治国,欧育湘.一种新型含氯的磷-膦酸酯阻燃聚氨酯的阻燃性能[J].阻燃材料与技术,2007(4):9-12.
[8]王学川,王莉,强涛涛,等.阻燃聚氨酯的研究进展[J].材料导报A:综述篇,2013,27(2):90-94.
[9]Sabyasachi Gaan,Shuyu Liang,Henri Mispreuve,et al.Flame retardant flexible polyurethane foams from novel DOPO-phosphonamidate additives[J].Polymer Degradation and Stability,2015,113:180-188.
[10]王紫潇,文庆珍,朱金华.用于聚氨酯材料的无卤添加型阻燃剂研究进展[J].聚氨酯工业,2015,30(3):31-34.
[11]黄福林,赵乘寿,王德义,等.软质聚氨酯泡沫塑料用无卤阻燃剂的研究[J].化学研究与应用,2008,20(7):840-843.
[12]Matthias N Neisius,Shuyu Liang,Henri Mispreuve,et al.Recent Developments in Flame Retardancy of Flexible Polyurethane Foams[C]∥Morgan,et al.Fire and Polymers VI:New Advances in Flame Retardant Chemistry and Science,American Chemical Society:Washington,DC,2012.
[13]王方超,魏徵,王源升,等.添加型阻燃聚氨酯泡沫的研究进展[J].聚氨酯工业,2016,31(3):1-4.
[14]许晓光,许乃迪.无机添加型阻燃剂对聚氨酯阻燃涂料性能的影响[J].塑料制造,2012(8):81-84.
[15]Wenzong Xu,Baolin Xu,Aijiao Li,et al.Flame Retardancy and Smoke Suppression of Mg Al Layered Double Hydroxides Containing P and Si in Polyurethane Elastomer[J].Industrial&Engineering Chemistry Research,2016,55(42):11175-11185.
[16]许晶晶,肖卫东,郝惠军,等.膨胀型阻燃剂的研究与应用[J].塑料工业,2005,33:210-214.
[17]张晓光,王列平,宁斌科,等.聚氨酯泡沫塑料无卤阻燃技术的研究进展[J].化工进展,2012,31(7):1521-1527.
[18]常海洲,彭云,江霜英,等.氮磷膨胀型阻燃剂对聚氨酯阻燃性的影响[J].皮革与化工,2015,32(1):1-4.
[19]张志毅,孙付宇,刘亚青.新型磷-氮膨胀型阻燃剂的合成及其在硬质聚氨酯泡沫中的应用[J].合成化学,2014,22(1):20-23.
[20]李跃文,陈兴华.聚氨酯阻燃改性研究进展[J].现代塑料加工应用,2014,26(5):53-56.
[21]Wang Xi,Lijun Qian,Yajun Chen,et al.Addition flame-retardant behaviors of expandable graphite and[bis(2-hydroxyethyl)amino]-methyl-phosphonic acid dimethyl ester in rigid polyurethane foams[J].Polymer Degradation and Stability,2015,122:36-43.
[22]Modesti M,Lorenzetti A,Simioni F,et al.Expandable graphite as an intumescent flame retardant in polyisocyanurate-polyurethane foams[J].Polymer Degradation and Stability,2002,77:195-202.
[23]刘超,金星龙,等.可膨胀石墨/磷酸三氯乙酯协同阻燃硬质聚氨酯泡沫塑料的研究[J].天津理工大学学报,2014,30(3):41-44.
[24]杨荣,乔红,胡文田,等.反应型磷氮阻燃剂/可膨胀石墨复配阻燃聚氨酯泡沫[J].化工学报,2016,67(5):2169-2175.
[25]郑敏睿,张猛,李书龙,等.阻燃型聚氨酯泡沫研究新进展[J].热固性树脂,2016,31(4):62-68.
[26]张晓光,王列平,宁斌科,等.聚氨酯泡沫塑料无卤阻燃技术的研究进展[J].化工进展,2012,31(7):1521-1527.
[27]丁思月,姚玥玮,等.反应型低聚有机膦酸酯阻燃剂的合成与应用[J].聚氨酯工业,2012,27(6):17-20.
[28]钱立军,冯发飞,许国志.两种磷系阻燃剂阻燃聚氨酯硬泡的对比研究[J].塑料工业,2013,41(8):100-103.
[29]周红欣,李建华,万小龙.含溴阻燃聚醚多元醇的合成及在聚氨酯硬泡中的应用研究[J].新型建筑材料,2014(8):68-71.
[30]贾润萍,魏路,等.三聚氰胺基结构阻燃聚醚多元醇的合成及其阻燃性能评价[J].功能材料,2015,46:156-160.
[31]吴一鸣.硬泡阻燃聚醚多元醇的合成及应用[J].能源化工,2015,36(3):62-66.
[32]孟玉刚,霍瑞亭,侯丽丽.聚氨酯纳米阻燃技术的研究进展[J].材料导报,2010,24(16):160-163.
[33]Meng Xue,Xian Zhang,Zhao-feng Wu,et al.Preparation and Flame Retardancy of Polyurethane/POSS Nanocomposites[J].Chinese Journal of Chemical Physics,2013,26(4):445-450.
[34]陈涛,胡爽,等.纳米金属氧化物对聚氨酯硬泡阻燃性能的影响[J].聚氨酯工业,2015,30(1):18-21.
[35]王荣涛,梁小平,王小会,等.纳米镁铝水滑石的制备及其对聚氨酯阻燃性能的影响[J].功能材料,2009,40(12):2119-2123.
[36]章培坤,范浩军,陈意,等.纳米硅溶胶改性水性聚氨酯及其阻燃性能[J].皮革科学与工程,2014,24(1):10-16.
[37]Wei Wang,Ying Pan,Haifeng Pan,et al.Synthesis and characterization of Mn O2nanosheets based multilayer coating and applications as a flame retardant for flexible polyurethane foam[J].Composites Science&Technology,2015,123:212-221.
[38]Wei Xu,Guojian Wang,Xiaorui Zhang.Research on highly flame-retardant rigid PU foams by combination of nanostructured additives and phosphorus flame retardants[J].Polymer Degradation and Stability,2015,111:142-150.