废旧锂电池正负极材料修复再生技术
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摘要
归纳总结了废旧锂电池中正极和负极材料回收、修复再生技术现状。从工艺流程、成本、产品质量等方面比较了各自优缺点。总的来看,目前对报废电池正负极材料的回收、修复技术不成熟不全面,工艺成本偏高。
The research status of recovery and regeneration of anode and cathode materials for lithium iron phosphate battery were introduced. The advantages and disadvantages of each method were compared from the aspects of process, cost and product quality. There are still problems in repair regeneration processes, such as the instability and high cost of battery source,also the research on recovery and regeneration of whole battery material recovery is not mature.
The research status of recovery and regeneration of anode and cathode materials for lithium iron phosphate battery were introduced. The advantages and disadvantages of each method were compared from the aspects of process, cost and product quality. There are still problems in repair regeneration processes, such as the instability and high cost of battery source,also the research on recovery and regeneration of whole battery material recovery is not mature.
引文
[1]梁立君.废旧锂离子电池正极材料LiFePO4的回收及合成的研究[D].大连:大连交通大学,2012.
[2]宾智勇,刘景槐,吴海国,等.废旧锂离子电池的综合利用试验研究[J].湖南有色金属,2008(5):27-31,80.
[3]谢英豪,余海军,欧彦楠,等.从废旧动力电池中回收制备磷酸铁锂[J].电源技术,2014,38(12):2239-2241,2257.
[4] SUN L, QIU K. Vacuum pyrolysis and hydrometallurgical process for the recovery of valuable metals from spent lithium-ion batteries[J]. Journal of Hazardous Materials, 2011, 194(11):378-384.
[5] HU Y Q, DOF M M, KOSTEEKI R, et al. Electrochemical performance of sol-gel synthesized LiFePO4in lithium batteries[J]. Journal of the Electrochemical Society, 2004, 51(8):1279-1285.
[6]赵新兵,周斌,曹高劭,等.一种从磷酸铁锂废旧电池中回收制备磷酸铁锂的方法:CN102751548A[P]. 2012-10-24.
[7]谢英豪,余海军,欧彦楠,等.从废旧动力电池中回收制备磷酸铁锂[J].电源技术,2014,38(12):2239-2241,2257.
[8]吴越,裴锋,贾蕗路,等.从废旧磷酸铁锂电池中回收铝、铁和锂[J].电源技术,2014,38(4):629-631.
[9]李荐,王利华.一种从废旧磷酸铁锂正极料中制备磷酸铁和锂的磷酸盐的方法:CN106997973A[P]. 2017-08-01.
[10]晏荦.一种报废锂离子电池石墨负极片的回收利用方法:CN10-5304967A[P]. 2016-02-03.
[11]万传云,邹学彬,何赛燕,等.一种从废旧锂离子电池中回收高纯碳材料的方法:CN102709621A[P]. 2012-10-03.
[12]周顺,周汉章,谭静进,等.石墨体系的不合格锂离子电池中负极材料再生利用方法:CN104241723A[P]. 2014-12-24.
[13]杨全红,张辰,游从辉,等.一种废旧锂离子电池回收再生石墨烯的方法:CN103259062A[P]. 2013-08-21.
[2]宾智勇,刘景槐,吴海国,等.废旧锂离子电池的综合利用试验研究[J].湖南有色金属,2008(5):27-31,80.
[3]谢英豪,余海军,欧彦楠,等.从废旧动力电池中回收制备磷酸铁锂[J].电源技术,2014,38(12):2239-2241,2257.
[4] SUN L, QIU K. Vacuum pyrolysis and hydrometallurgical process for the recovery of valuable metals from spent lithium-ion batteries[J]. Journal of Hazardous Materials, 2011, 194(11):378-384.
[5] HU Y Q, DOF M M, KOSTEEKI R, et al. Electrochemical performance of sol-gel synthesized LiFePO4in lithium batteries[J]. Journal of the Electrochemical Society, 2004, 51(8):1279-1285.
[6]赵新兵,周斌,曹高劭,等.一种从磷酸铁锂废旧电池中回收制备磷酸铁锂的方法:CN102751548A[P]. 2012-10-24.
[7]谢英豪,余海军,欧彦楠,等.从废旧动力电池中回收制备磷酸铁锂[J].电源技术,2014,38(12):2239-2241,2257.
[8]吴越,裴锋,贾蕗路,等.从废旧磷酸铁锂电池中回收铝、铁和锂[J].电源技术,2014,38(4):629-631.
[9]李荐,王利华.一种从废旧磷酸铁锂正极料中制备磷酸铁和锂的磷酸盐的方法:CN106997973A[P]. 2017-08-01.
[10]晏荦.一种报废锂离子电池石墨负极片的回收利用方法:CN10-5304967A[P]. 2016-02-03.
[11]万传云,邹学彬,何赛燕,等.一种从废旧锂离子电池中回收高纯碳材料的方法:CN102709621A[P]. 2012-10-03.
[12]周顺,周汉章,谭静进,等.石墨体系的不合格锂离子电池中负极材料再生利用方法:CN104241723A[P]. 2014-12-24.
[13]杨全红,张辰,游从辉,等.一种废旧锂离子电池回收再生石墨烯的方法:CN103259062A[P]. 2013-08-21.