过硫酸氢钾在水处理中的应用研究进展
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摘要
介绍了过硫酸氢钾的主要活化方式及活化机理,阐述了硫酸根自由基进攻有机物的3种主要机理,综述了过硫酸氢钾在水处理中的应用进展,指出了目前过硫酸氢钾在水处理领域应用中存在的问题,并对其应用前景进行了展望。
We introduce the activation methods and activation mechanisms of peroxymonosulfate(PMS),and demonstrate three main mechanisms of the degradation of organic compounds by sulfate free radicals.Furthermore,we review the application progress of PMS in water treatment,point out the problems existing in current application of PMS in water treatment,and put forward its application prospect.
We introduce the activation methods and activation mechanisms of peroxymonosulfate(PMS),and demonstrate three main mechanisms of the degradation of organic compounds by sulfate free radicals.Furthermore,we review the application progress of PMS in water treatment,point out the problems existing in current application of PMS in water treatment,and put forward its application prospect.
引文
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[8]JI Y F,DONG C X,KONG D Y,et al.New insights into atrazine degradation by cobalt catalyzed peroxymonosulfate oxidation:kinetics,reaction products and transformation mechanisms[J].Journal of Hazardous Materials,2015,285:491-500.
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[10]MORADI M,GHANBARI F.Application of response surface method for coagulation process in leachate treatment as pretreatment for Fenton process:biodegradability improvement[J].Journal of Water Process Engineering,2014,4:67-73.
[11]MORADI M,GHANBARI F,TABRIZI E M.Removal of Acid Yellow 36using Box-Behnken designed photoelectro-Fenton:a study on removal mechanisms[J].Toxicological&Environmental Chemistry,2015,97(6):700-709.
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[18]LIN K Y A,ZHANG Z Y.Metal-free activation of Oxone using one-step prepared sulfur-doped carbon nitride under visible light irradiation[J].Separation&Purification Technology,2017,173:72-79.
[19]ANDERSEN J,PELAEZ M,GUAY L,et al.NF-TiO2photocatalysis of amitrole and atrazine with addition of oxidants under simulated solar light:emerging synergies,degradation intermediates,and reusable attributes[J].Journal of Hazardous Materials,2013,260:569-575.
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[21]DUAN X G,AO Z M,LI D G,et al.Surface-tailored nanodiamonds as excellent metal-free catalysts for organic oxidation[J].Carbon,2016,103:404-411.
[22]LIN K Y A,CHEN Y C.Accelerated decomposition of Oxone using graphene-like carbon nitride with visible light irradiation for enhanced decolorization in water[J].Journal of the Taiwan Institute of Chemical Engineers,2016,60(1):423-429.
[23]DUAN X G,SUN H Q,AO Z M,et al.Unveiling the active sites of graphene-catalyzed peroxymonosulfate activation[J].Carbon,2016,107:371-378.
[24]YANG S Y,XIAO T,ZHANG J,et al.Activated carbon fiber as heterogeneous catalyst of peroxymonosulfate activation for efficient degradation of Acid Orange 7in aqueous solution[J].Separation&Purification Technology,2015,143:19-26.
[25]ZHANG J,SHAO X T,CHAO S,et al.Decolorization of Acid Orange 7with peroxymonosulfate oxidation catalyzed by granular activated carbon[J].Chemical Engineering Journal,2013,232(10):259-265.
[26]DONG H J,WEI M Y,LI J,et al.Catalytic performance of supported g-C3N4on MCM-41in organic dye degradation with peroxymonosulfate[J].RSC Advances,2016,6(75):70747-70755.
[27]WEI M Y,GAO L,LI J,et al.Activation of peroxymonosulfate by graphitic carbon nitride loaded on activated carbon for organic pollutants degradation[J].Journal of Hazardous Materials,2016,316:60-68.
[28]LIN H,WU J,ZHANG H.Degradation of clofibric acid in aqueous solution by an EC/Fe3+/PMS process[J].Chemical Engineering Journal,2014,244(1):514-521.
[29]陈晓旸.基于硫酸自由基的高级氧化技术降解水中典型有机污染物研究[D].大连:大连理工大学,2007.CHEN X Y.Degradation of typical organic pollutants in aqueous solution with advanced oxidation technology based on sulfate radicals[D].Dalian:Dalian University of Technology,2007.
[30]SHARMA J,MISHRA I M,DIONYSIOU D D,et al.Oxidative removal of Bisphenol A by UV-C/peroxymonosulfate(PMS):kinetics,influence of co-existing chemicals and degradation pathway[J].Chemical Engineering Journal,2015,276:193-204.
[31]NETA P,MADHAVAN V,ZEMEL H,et al.Rate constants and mechanism of reaction of sulfate radical anion with aromatic compounds[J].Journal of the American Chemical Society,1977,99(1):163-164.
[32]陈晓旸,薛智勇,吴丹,等.基于硫酸自由基的高级氧化技术及其在水处理中的应用[J].水处理技术,2009,35(5):16-20.CHEN X Y,XUE Z Y,WU D,et al.The advanced oxidation technology based on sulfate radical and application in water treatment[J].Technology of Water Treatment,2009,35(5):16-20.
[33]PADMAJA S,ALFASSI Z B,NETA P,et al.Rate constants for reactions of SO-4·radicals in acetonitrile[J].International Journal of Chemical Kinetics,1993,25(3):193-198.
[34]GEORGE C,RASSY H E,CHOVELONJM.Reactivity of selected volatile organic compounds(VOCs)toward the sulfate radical(SO-4·)[J].International Journal of Chemical Kinetics,2001,33(9):539-547.
[35]VERMA S,NAKAMURA S,SILLANP M.Application of UV-C LED activated PMS for the degradation of anatoxin-a[J].Chemical Engineering Journal,2016,284:122-129.
[36]MALATO S,BLANCO J,RICHTER C,et al.Enhancement of the rate of solar photocatalytic mineralization of organic pollutants by inorganic oxidizing species[J].Applied Catalysis B:Environmental,1998,17(4):347-356.
[37]时鹏辉.非均相Co3O4/GO/PMS体系催化氧化降解染料废水的研究[D].上海:东华大学,2013.SHI P H.Study on the degradation of dye wastewater by heterogeneous Co3O4/GO/PMS system[D].Shanghai:Donghua University,2013.
[38]伊玉.可回收磁性材料CoFe2O4/GO催化PMS降解染料废水的性能研究[D].上海:东华大学,2014.YI Y.The research on the degradation of dye wastewater using PMS activation by CoFe2O4immobilized on GO[D].Shanghai:Donghua University,2014.
[39]明翠香,田凯勋,陆主,等.芬顿试剂预处理杀螟丹农药废水[J].环境工程学报,2014(12):5135-5140.MING C X,TIAN K X,LU Z,et al.Pretreatment of cartap pesticide wastewater by Fenton reagent[J].Chinese Journal of Environmental Engineering,2014(12):5135-5140.
[40]张跃华,赵永勋.过硫酸氢钾复合盐消毒作用实验研究[J].中国卫生检验杂志,2005,15(1):40-41.ZHANG Y H,ZHAO Y X.Experimental observation on germicidal efficacy of potassium monopersulfate[J].Chinese Journal of Health Laboratory Technology,2005,15(1):40-41.
[41]严志弦.电极电位和氧化电位[J].化学通报,1966(4):63-66.YAN Z X.Electrode potential and oxidation potential[J].Chemistry Bulletin,1966(4):63-66.
[42]龙光斗,谢子卓,李训生,等.氟气在有机精细化工中的应用[J].有机氟工业,2010(3):43-44.LONG G D,XIE Z Z,LI X S,et al.Application of fluorine gas in organic fine chemistry industry[J].Organo-Fluorine Industry,2010(3):43-44.
[43]徐飞飞,高乃云,李聪,等.新型消毒剂用于饮用水消毒的效果研究[J].给水排水,2008(S1):189-190.XU F F,GAO N Y,LI C,et al.Applieation of new disinfectant in drinking water disinfection[J].Water&Wastewater Engineering,2008(S1):189-190.
[44]宋莹莹.基于硫酸根自由基的单过硫酸氢盐高级氧化消毒技术[C]//《中国给水排水》杂志社第十一届年会暨水处理热点技术高峰论坛.西安:《中国给水排水》杂志社,2014.SONG Y Y.Peroxymonosulfate advanced oxidation disinfection technology based on sulfate radicals[C]//The 11th annual meeting of China Water and Wastewater and the Forum on water treatment.Xi′an:China Water and Wastewater,2014.
[45]汪一品.基于单过硫酸氢钾复合粉的饮用水消毒研究[D].长沙:湖南大学,2015.WANG Y P.Drinking water disinfection using potassium monopersulfate based compound[D].Changsha:Hunan University,2015.
[2]林丽,何婷,刘玉明,等.单过硫酸氢钾消毒粉在饮用水消毒中的应用[J].给水排水,2015(S1):14-15.LIN L,HE T,LIU Y M,et al.Application of potassium monopersulfate compound disinfectant in drinking water disinfection[J].Water&Wastewater Engineering,2015(S1):14-15.
[3]GOVINDAN K,RAJA M,NOEL M,et al.Degradation of pentachlorophenol by hydroxyl radicals and sulfate radicals using electrochemical activation of peroxomonosulfate,peroxodisulfate and hydrogen peroxide[J].Journal of Hazardous Materials,2014,272:42-51.
[4]SHARMA J,MISHRA I M,DIONYSIOU D D,et al.Oxidative removal of bisphenol A by UV-C/peroxymonosulfate(PMS):kinetics,influence of co-existing chemicals and degradation pathway[J].Chemical Engineering Journal,2015,276:193-204.
[5]BALL D L,EDWARDS J O.The kinetics and mechanism of the decomposition of Caro′s Acid.Ⅰ[J].Journal of the American Chemical Society,1956,78(6):1125-1129.
[6]ANIPSITAKIS G P,DIONYSIOU D D.Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of peroxymonosulfate with cobalt[J].Environmental Science&Technology,2003,37(20):4790-4797.
[7]CHEN X Y,QIAO X L,WANG D G,et al.Kinetics of oxidative decolorization and mineralization of Acid Orange 7by dark and photoassisted Co2+-catalyzed peroxymonosulfate system[J].Chemosphere,2007,67(4):802-808.
[8]JI Y F,DONG C X,KONG D Y,et al.New insights into atrazine degradation by cobalt catalyzed peroxymonosulfate oxidation:kinetics,reaction products and transformation mechanisms[J].Journal of Hazardous Materials,2015,285:491-500.
[9]ZHANG B T,ZHANG Y,TENG Y G,et al.Sulfate radical and its application in decontamination technologies[J].Critical Reviews in Environmental Science and Technology,2015,45(16):1756-1800.
[10]MORADI M,GHANBARI F.Application of response surface method for coagulation process in leachate treatment as pretreatment for Fenton process:biodegradability improvement[J].Journal of Water Process Engineering,2014,4:67-73.
[11]MORADI M,GHANBARI F,TABRIZI E M.Removal of Acid Yellow 36using Box-Behnken designed photoelectro-Fenton:a study on removal mechanisms[J].Toxicological&Environmental Chemistry,2015,97(6):700-709.
[12]SINDELAR H R,BROWN M T,BOYER T H.Evaluating UV/H2O2,UV/percarbonate,and UV/perborate for natural organic matter reduction from alternative water sources[J].Chemosphere,2014,105:112-118.
[13]MATZEK L W,CARTER K E.Activated persulfate for organic chemical degradation:a review[J].Chemosphere,2016,151:178-188.
[14]GUO W L,SU S N,YI C L,et al.Degradation of antibiotics amoxicillin by Co3O4-catalyzed peroxymonosulfate system[J].Environmental Progress&Sustainable Energy,2013,32(2):193-197.
[15]SU S N,GUO W L,YI C L,et al.Degradation of amoxicillin in aqueous solution using sulphate radicals under ultrasound irradiation[J].Ultrasonics Sonochemistry,2012,19(3):469-474.
[16]AHMADI M,GHANBARI F,MORADI M.Photocatalysis assisted by peroxymonosulfate and persulfate for benzotriazole degradation:effect of pH on sulfate and hydroxyl radicals[J].Water Science&Technology:A Journal of the International Association on Water Pollution Research,2015,72(11):2095-2102.
[17]KURIECHEN S K,MURUGESAN S.Carbon-doped titanium dioxide nanoparticles mediated photocatalytic degradation of azo dyes under visible light[J].Water,Air,&Soil Pollution,2013,224(9):1671.
[18]LIN K Y A,ZHANG Z Y.Metal-free activation of Oxone using one-step prepared sulfur-doped carbon nitride under visible light irradiation[J].Separation&Purification Technology,2017,173:72-79.
[19]ANDERSEN J,PELAEZ M,GUAY L,et al.NF-TiO2photocatalysis of amitrole and atrazine with addition of oxidants under simulated solar light:emerging synergies,degradation intermediates,and reusable attributes[J].Journal of Hazardous Materials,2013,260:569-575.
[20]PUGAZHENTHIRAN N,MURUGESAN S,SATHISHKUMAR P,et al.Photocatalytic degradation of ceftiofur sodium in the presence of gold nanoparticles loaded TiO2 under UV-visible light[J].Chemical Engineering Journal,2014,241:401-409.
[21]DUAN X G,AO Z M,LI D G,et al.Surface-tailored nanodiamonds as excellent metal-free catalysts for organic oxidation[J].Carbon,2016,103:404-411.
[22]LIN K Y A,CHEN Y C.Accelerated decomposition of Oxone using graphene-like carbon nitride with visible light irradiation for enhanced decolorization in water[J].Journal of the Taiwan Institute of Chemical Engineers,2016,60(1):423-429.
[23]DUAN X G,SUN H Q,AO Z M,et al.Unveiling the active sites of graphene-catalyzed peroxymonosulfate activation[J].Carbon,2016,107:371-378.
[24]YANG S Y,XIAO T,ZHANG J,et al.Activated carbon fiber as heterogeneous catalyst of peroxymonosulfate activation for efficient degradation of Acid Orange 7in aqueous solution[J].Separation&Purification Technology,2015,143:19-26.
[25]ZHANG J,SHAO X T,CHAO S,et al.Decolorization of Acid Orange 7with peroxymonosulfate oxidation catalyzed by granular activated carbon[J].Chemical Engineering Journal,2013,232(10):259-265.
[26]DONG H J,WEI M Y,LI J,et al.Catalytic performance of supported g-C3N4on MCM-41in organic dye degradation with peroxymonosulfate[J].RSC Advances,2016,6(75):70747-70755.
[27]WEI M Y,GAO L,LI J,et al.Activation of peroxymonosulfate by graphitic carbon nitride loaded on activated carbon for organic pollutants degradation[J].Journal of Hazardous Materials,2016,316:60-68.
[28]LIN H,WU J,ZHANG H.Degradation of clofibric acid in aqueous solution by an EC/Fe3+/PMS process[J].Chemical Engineering Journal,2014,244(1):514-521.
[29]陈晓旸.基于硫酸自由基的高级氧化技术降解水中典型有机污染物研究[D].大连:大连理工大学,2007.CHEN X Y.Degradation of typical organic pollutants in aqueous solution with advanced oxidation technology based on sulfate radicals[D].Dalian:Dalian University of Technology,2007.
[30]SHARMA J,MISHRA I M,DIONYSIOU D D,et al.Oxidative removal of Bisphenol A by UV-C/peroxymonosulfate(PMS):kinetics,influence of co-existing chemicals and degradation pathway[J].Chemical Engineering Journal,2015,276:193-204.
[31]NETA P,MADHAVAN V,ZEMEL H,et al.Rate constants and mechanism of reaction of sulfate radical anion with aromatic compounds[J].Journal of the American Chemical Society,1977,99(1):163-164.
[32]陈晓旸,薛智勇,吴丹,等.基于硫酸自由基的高级氧化技术及其在水处理中的应用[J].水处理技术,2009,35(5):16-20.CHEN X Y,XUE Z Y,WU D,et al.The advanced oxidation technology based on sulfate radical and application in water treatment[J].Technology of Water Treatment,2009,35(5):16-20.
[33]PADMAJA S,ALFASSI Z B,NETA P,et al.Rate constants for reactions of SO-4·radicals in acetonitrile[J].International Journal of Chemical Kinetics,1993,25(3):193-198.
[34]GEORGE C,RASSY H E,CHOVELONJM.Reactivity of selected volatile organic compounds(VOCs)toward the sulfate radical(SO-4·)[J].International Journal of Chemical Kinetics,2001,33(9):539-547.
[35]VERMA S,NAKAMURA S,SILLANP M.Application of UV-C LED activated PMS for the degradation of anatoxin-a[J].Chemical Engineering Journal,2016,284:122-129.
[36]MALATO S,BLANCO J,RICHTER C,et al.Enhancement of the rate of solar photocatalytic mineralization of organic pollutants by inorganic oxidizing species[J].Applied Catalysis B:Environmental,1998,17(4):347-356.
[37]时鹏辉.非均相Co3O4/GO/PMS体系催化氧化降解染料废水的研究[D].上海:东华大学,2013.SHI P H.Study on the degradation of dye wastewater by heterogeneous Co3O4/GO/PMS system[D].Shanghai:Donghua University,2013.
[38]伊玉.可回收磁性材料CoFe2O4/GO催化PMS降解染料废水的性能研究[D].上海:东华大学,2014.YI Y.The research on the degradation of dye wastewater using PMS activation by CoFe2O4immobilized on GO[D].Shanghai:Donghua University,2014.
[39]明翠香,田凯勋,陆主,等.芬顿试剂预处理杀螟丹农药废水[J].环境工程学报,2014(12):5135-5140.MING C X,TIAN K X,LU Z,et al.Pretreatment of cartap pesticide wastewater by Fenton reagent[J].Chinese Journal of Environmental Engineering,2014(12):5135-5140.
[40]张跃华,赵永勋.过硫酸氢钾复合盐消毒作用实验研究[J].中国卫生检验杂志,2005,15(1):40-41.ZHANG Y H,ZHAO Y X.Experimental observation on germicidal efficacy of potassium monopersulfate[J].Chinese Journal of Health Laboratory Technology,2005,15(1):40-41.
[41]严志弦.电极电位和氧化电位[J].化学通报,1966(4):63-66.YAN Z X.Electrode potential and oxidation potential[J].Chemistry Bulletin,1966(4):63-66.
[42]龙光斗,谢子卓,李训生,等.氟气在有机精细化工中的应用[J].有机氟工业,2010(3):43-44.LONG G D,XIE Z Z,LI X S,et al.Application of fluorine gas in organic fine chemistry industry[J].Organo-Fluorine Industry,2010(3):43-44.
[43]徐飞飞,高乃云,李聪,等.新型消毒剂用于饮用水消毒的效果研究[J].给水排水,2008(S1):189-190.XU F F,GAO N Y,LI C,et al.Applieation of new disinfectant in drinking water disinfection[J].Water&Wastewater Engineering,2008(S1):189-190.
[44]宋莹莹.基于硫酸根自由基的单过硫酸氢盐高级氧化消毒技术[C]//《中国给水排水》杂志社第十一届年会暨水处理热点技术高峰论坛.西安:《中国给水排水》杂志社,2014.SONG Y Y.Peroxymonosulfate advanced oxidation disinfection technology based on sulfate radicals[C]//The 11th annual meeting of China Water and Wastewater and the Forum on water treatment.Xi′an:China Water and Wastewater,2014.
[45]汪一品.基于单过硫酸氢钾复合粉的饮用水消毒研究[D].长沙:湖南大学,2015.WANG Y P.Drinking water disinfection using potassium monopersulfate based compound[D].Changsha:Hunan University,2015.