超滤过程的膜污染和运行条件优化
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摘要
超滤是废水净化的最佳选择之一,然而不可避免的膜污染问题制约了超滤技术的进一步发展。通过阐述超滤膜污染过程和影响因素,精准认知污染类型和污染机制,不断优化膜运行条件,适当地改变操作参数,选择合适的清洗方式和清洗剂,以获得较高的污染物去除率和膜渗透率,降低超滤技术成本。
Ultrafiltration is one of the best choices for wastewater purification. However, the inevitable membrane fouling problem has restricted the further development of ultrafiltration technology. It was indicated that, by expounding the ultrafiltration membrane pollution process and the influencing factors, accurately understanding the type of pollution and the pollution mechanism, continuously optimizing the membrane operating conditions,appropriately changing the operating parameters, selecting proper cleaning method and cleaning agent, higher pollutant removal rate and membrane permeability could be obtained with lower ultrafiltration technology cost.
Ultrafiltration is one of the best choices for wastewater purification. However, the inevitable membrane fouling problem has restricted the further development of ultrafiltration technology. It was indicated that, by expounding the ultrafiltration membrane pollution process and the influencing factors, accurately understanding the type of pollution and the pollution mechanism, continuously optimizing the membrane operating conditions,appropriately changing the operating parameters, selecting proper cleaning method and cleaning agent, higher pollutant removal rate and membrane permeability could be obtained with lower ultrafiltration technology cost.
引文
[1]王旭亮,潘献辉,张艳萍,等.反渗透系统进水SDI测试技术的优化研究[J].工业用水与废水, 2013, 44(3):86-89.
[2]王旭亮,赵静红,李宗雨,等.离子效应对纳滤膜表面Zeta电位测定的影响[J].化学分析计量, 2018, 27(3):12-15.
[3]王旭亮,郑睿,赵静红,等.中空纤维膜表面Zeta电位检测技术[J].净水技术, 2017, 35(6):75-77.
[4]王旭亮,郑睿,张艳萍,等.测试滤膜和料液性质对SDI测试结果的影响分析[J].工业用水与废水, 2017, 48(1):82-86.
[5] ZARGAR M, HARTANTO Y, JIN B, et al. Understandingfunctionalized silica nanoparticles incorporation in thin filmcomposite membranes:Interactions and desalination performance[J]. Journal of Membrane Science, 2017, 521(1):53-64.
[6] LIAO Y, TIAN M, WANG R. A high-performance and robustmembrane with switchable super-wettability for oil/water separationunder ultralow pressure[J]. Journal of Membrane Science, 2017,543(12):123-132.
[7] WANG L, WANG X D, FUKUSHI K. Effects of operationalconditions on ultrafiltration membrane fouling[J].Desalination,2008, 229(1):181-191.
[8] GAO W, LIANG H, MA J, et al. Membrane fouling control inultrafiltration technology for drinking water production:A review[J]. Desalination, 2011, 272(1):1-8.
[9] SUTZKOVER-GUTMAN I, HASSON D, SEMIAT R. Humicsubstances fouling in ultrafiltration processes[J]. Desalination,2010, 261(3):218-231.
[10] ZHOU M, MENG F. Using UV-vis absorbance spectral parame-ters to characterize the fouling propensity of humic substances duringultrafiltration[J]. Water Research, 2015, 87(9):5043-5050.
[11] AHN W-Y, KALINICHEV A, CLARK M. Effects of backgroundcations on the fouling of polyethersulfone membranes by naturalorganic matter:experimental and molecular modelling study[J].Journal of Membrane Science, 2008, 309(1):128-140.
[12] SHOPARWE N F, OTITOJU T A, AHMAD A L. Foulingevaluation of polyethersulfone(PES)/sulfonated cation exchangeresin(SCER)membrane for BSA separation[J]. Journal of AppliedPolymer Science, 2018, 135:45854-45866.
[13] SHI X E, TAL G, NICHOLAS P, et al. Fouling and cleaning ofultrafiltration membranes:A review[J]. Journal of Water ProcessEngineering, 2014, 1:1685-1718.
[14]王旭亮,赵静红,李宗雨,等.基于Zeta电位法研究腐殖酸对超滤膜的污染[J].中国给水排水, 2018, 34(17):48-51.
[15] GUO X Y, ZHANG Z J, LIN F, et al. Study on ultrafiltration forsurface water by a polyvinylchloride hollow fiber membrane[J].Desalination, 2009, 238(1):183-191.
[16] LEE E K, CHEN V, FANE A G. Natural organic matter(NOM)fouling in low pressure membrane filtration-effect of membranesand operation modes[J]. Desalination, 2008, 218(1):257-270.
[17] LIPP P, BALDAUF G, SCHMITT A, et al. Long-term behaviourof UF membranes treating surface water[J]. Water Science andTechnology, 2003, 3(5):31-37.
[18] KHOUNA K M. The potable water production using glass coverdouble slope solar still with a different heat absorption materials[J].International Journal of Clinical Pharmacology&Therapeu-tics,2015, 34(7):277-81.
[19] QU F S, DU X, LIN B, et al. Control of ultra-filtration membranefouling caused by Microcystis cells with permanganatepreoxidation:Significance of in situ formed manganese dioxide[J].Chemical Engineering Journal, 2015, 279:56-65.
[20] KATSOUFIDOU K, YIANTSIOS S G, KARABELAS A J. Anexperimental study of UF membrane fouling by humic acid andsodium alginate solutions:the effect of backwashing on fluxrecovery[J]. Desalination, 2008, 220(1):214-227.
[21] KIMURA K, HANE Y, WATANABE Y. Effect of pre-coagulation on mitigating irreversible fouling during ultrafiltration ofa surface water[J]. Water Science and Technology, 2005, 51(6):93-100.
[22] LEE N, AMY G, CROUPE J P. Low-pressure membrane(MF/UF)fouling associated with allochthonous versus autochthonousnatural organic matter[J]. Water Research, 2006, 40(12):2357-2368.
[23] WIBISONO Y, CORNELISSEN ER, KEMPERMAN AJB, et al.Two-phase flow in membrane processes:A technology with a future[J]. Journal of Membrane Science, 2014, 453(3):566-602.
[24] PSOCH O, SCHIEWER S. Direct filtration of natural and simulatedriver water with air sparging and sponge ball application for foulingcontrol[J]. Desalination, 2006, 197(1):190-204.
[25] REGULA C, CARRETIER E, WYART Y, et al. Chemicalcleaning/disinfection and ageing of organic UF membranes:areview[J]. Water Research, 2014, 56(6):325-365.
[26] BREPOLS C, DRENSLA K, JANOT A, et al. Strategies forchemical cleaning in large scale membrane bioreactors[J]. WaterScience and Technology, 2008, 57(3):457-463.
[27] MENG F, ZHANG S, OH Y, et al. Fouling in membrane biore-actors:An updated review[J]. Water Research, 2017, 114(2):151-180.
[2]王旭亮,赵静红,李宗雨,等.离子效应对纳滤膜表面Zeta电位测定的影响[J].化学分析计量, 2018, 27(3):12-15.
[3]王旭亮,郑睿,赵静红,等.中空纤维膜表面Zeta电位检测技术[J].净水技术, 2017, 35(6):75-77.
[4]王旭亮,郑睿,张艳萍,等.测试滤膜和料液性质对SDI测试结果的影响分析[J].工业用水与废水, 2017, 48(1):82-86.
[5] ZARGAR M, HARTANTO Y, JIN B, et al. Understandingfunctionalized silica nanoparticles incorporation in thin filmcomposite membranes:Interactions and desalination performance[J]. Journal of Membrane Science, 2017, 521(1):53-64.
[6] LIAO Y, TIAN M, WANG R. A high-performance and robustmembrane with switchable super-wettability for oil/water separationunder ultralow pressure[J]. Journal of Membrane Science, 2017,543(12):123-132.
[7] WANG L, WANG X D, FUKUSHI K. Effects of operationalconditions on ultrafiltration membrane fouling[J].Desalination,2008, 229(1):181-191.
[8] GAO W, LIANG H, MA J, et al. Membrane fouling control inultrafiltration technology for drinking water production:A review[J]. Desalination, 2011, 272(1):1-8.
[9] SUTZKOVER-GUTMAN I, HASSON D, SEMIAT R. Humicsubstances fouling in ultrafiltration processes[J]. Desalination,2010, 261(3):218-231.
[10] ZHOU M, MENG F. Using UV-vis absorbance spectral parame-ters to characterize the fouling propensity of humic substances duringultrafiltration[J]. Water Research, 2015, 87(9):5043-5050.
[11] AHN W-Y, KALINICHEV A, CLARK M. Effects of backgroundcations on the fouling of polyethersulfone membranes by naturalorganic matter:experimental and molecular modelling study[J].Journal of Membrane Science, 2008, 309(1):128-140.
[12] SHOPARWE N F, OTITOJU T A, AHMAD A L. Foulingevaluation of polyethersulfone(PES)/sulfonated cation exchangeresin(SCER)membrane for BSA separation[J]. Journal of AppliedPolymer Science, 2018, 135:45854-45866.
[13] SHI X E, TAL G, NICHOLAS P, et al. Fouling and cleaning ofultrafiltration membranes:A review[J]. Journal of Water ProcessEngineering, 2014, 1:1685-1718.
[14]王旭亮,赵静红,李宗雨,等.基于Zeta电位法研究腐殖酸对超滤膜的污染[J].中国给水排水, 2018, 34(17):48-51.
[15] GUO X Y, ZHANG Z J, LIN F, et al. Study on ultrafiltration forsurface water by a polyvinylchloride hollow fiber membrane[J].Desalination, 2009, 238(1):183-191.
[16] LEE E K, CHEN V, FANE A G. Natural organic matter(NOM)fouling in low pressure membrane filtration-effect of membranesand operation modes[J]. Desalination, 2008, 218(1):257-270.
[17] LIPP P, BALDAUF G, SCHMITT A, et al. Long-term behaviourof UF membranes treating surface water[J]. Water Science andTechnology, 2003, 3(5):31-37.
[18] KHOUNA K M. The potable water production using glass coverdouble slope solar still with a different heat absorption materials[J].International Journal of Clinical Pharmacology&Therapeu-tics,2015, 34(7):277-81.
[19] QU F S, DU X, LIN B, et al. Control of ultra-filtration membranefouling caused by Microcystis cells with permanganatepreoxidation:Significance of in situ formed manganese dioxide[J].Chemical Engineering Journal, 2015, 279:56-65.
[20] KATSOUFIDOU K, YIANTSIOS S G, KARABELAS A J. Anexperimental study of UF membrane fouling by humic acid andsodium alginate solutions:the effect of backwashing on fluxrecovery[J]. Desalination, 2008, 220(1):214-227.
[21] KIMURA K, HANE Y, WATANABE Y. Effect of pre-coagulation on mitigating irreversible fouling during ultrafiltration ofa surface water[J]. Water Science and Technology, 2005, 51(6):93-100.
[22] LEE N, AMY G, CROUPE J P. Low-pressure membrane(MF/UF)fouling associated with allochthonous versus autochthonousnatural organic matter[J]. Water Research, 2006, 40(12):2357-2368.
[23] WIBISONO Y, CORNELISSEN ER, KEMPERMAN AJB, et al.Two-phase flow in membrane processes:A technology with a future[J]. Journal of Membrane Science, 2014, 453(3):566-602.
[24] PSOCH O, SCHIEWER S. Direct filtration of natural and simulatedriver water with air sparging and sponge ball application for foulingcontrol[J]. Desalination, 2006, 197(1):190-204.
[25] REGULA C, CARRETIER E, WYART Y, et al. Chemicalcleaning/disinfection and ageing of organic UF membranes:areview[J]. Water Research, 2014, 56(6):325-365.
[26] BREPOLS C, DRENSLA K, JANOT A, et al. Strategies forchemical cleaning in large scale membrane bioreactors[J]. WaterScience and Technology, 2008, 57(3):457-463.
[27] MENG F, ZHANG S, OH Y, et al. Fouling in membrane biore-actors:An updated review[J]. Water Research, 2017, 114(2):151-180.