铜-硅基介孔材料的制备及应用现状
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摘要
铜-硅基介孔材料因其掺杂铜的氧化还原特性,赋予了纯硅介孔材料新的催化活性位,实现了介孔材料的多功能化,并在众多领域中展现出广阔的应用前景,受到了国内外研究学者的广泛关注。针对当前铜-硅基介孔材料的制备方法进行了详细介绍和分析,包括直接合成和合成后移植两类途径,并对不同合成方法存在的优缺点进行了比较。同时综述了近年来铜-硅基介孔材料在催化、吸附分离和其它领域的应用现状,并对其未来的研究进行了展望。
The copper-silica-based mesoporous materials have new catalytic active sites for the pure silica mesoporous materials due to the redox ability of the copper itself,thus realizing the multi-functionalization of the mesoporous materials,and have given wide attention by domestic and foreign scholars. In this paper,the fabrication methods of copper-silicon based mesoporous materials including direct synthesis and synthetic post-transplantation two classes of approaches are introduced and analyzed in detail,the advantages and disadvantages of different synthesis methods are compared. The application status of copper-silicon based mesoporous materials in catalysis,adsorption,separation,and other fields in recent years is reviewed and its application prospects are also prospected.
The copper-silica-based mesoporous materials have new catalytic active sites for the pure silica mesoporous materials due to the redox ability of the copper itself,thus realizing the multi-functionalization of the mesoporous materials,and have given wide attention by domestic and foreign scholars. In this paper,the fabrication methods of copper-silicon based mesoporous materials including direct synthesis and synthetic post-transplantation two classes of approaches are introduced and analyzed in detail,the advantages and disadvantages of different synthesis methods are compared. The application status of copper-silicon based mesoporous materials in catalysis,adsorption,separation,and other fields in recent years is reviewed and its application prospects are also prospected.
引文
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[3]ZHAO D Y,FENG J L,HUO Q S,et al.Science[J],1998,279(5350):548-552.
[4]TIAN W H,SUN L B,SONG X L,et al.Langmuir:the ACS Journal of Surfaces and Colloids[J],2010,26:17398-17404.
[5]CHANQUIA C M,SAPAG K,RODRGUEZCASTELLON E,et al.Journal of Physical Chemistry C[J],2010,114:1481-1490.
[6]CHANQUIA C M,CANEPA A L,BAZAN-AGUIRRE J,et al.Microporous and Mesoporous Materials[J],2012,151:2-12.
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[8]TENKYONG T,BACHAN N,RAJA J,et al.Materials Science-Poland[J],2015,33:826-834.
[9]DESHMANE V G,ABROKWAH R Y,KUILA D.International Journal of Hydrogen Energy[J],2015,40:10439-10452.
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[11]PATEL A,RUFFORD T E,RUDOLPH V,et al.Catalysis Today[J],2011,166:188-193.
[12]LIANG Z,ZHAO Z,SUN T,et al.Journal of Colloid and Interface Science[J],2017,485:192-200.
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[14]KOHLER M A,LEE J C,TRIMM D L,et al.Applied Catalysis[J],1987,31:309-321.
[15]YONEMITSU M,TANAKA Y,IWAMOTO M.Chemistry of Materials[J],1997,9:2679-2681.
[16]CHANQUIA C M,CANEPA A L,BAZAN-AGUIRRE J,et al.Microporous and Mesoporous Materials[J],2012,151:2-12.
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[18]VILARRASA-GARCIA E,CECILIA J A,BASTOS-NETO M,et al.Adsorption[J],2015,21:565-575.
[19]VASUDEVAN M,SAKARIA P L,BHATT A S,et al.Industrial&Engineering Chemistry Research[J],2011,50:11432-11439.
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[22]BERUBE F,KHADRAOUI A,FLOREK J,et al.Journal of Colloid and Interface Science[J],2015,449:102-114.
[23]WANG Y M,WU Z Y,SHI L Y,et al.Advanced Materials[J],2005,17:323-327.
[24]YIN Y,JIANG W J,LIU X Q,et al.Journal of Materials Chemistry[J],2012,22(35):18514-18521.
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[32]XIE F,WANG L,WANG K,et al.Catalysis Surveys from Asia[J],2016,20:74-81.
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[35]AMIRI T Y,MOGHADDAS J,KHAJEH S R.Journal of Sol-Gel Science and Technology[J],2015,77:627-635.
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