钙钛矿太阳能电池的研究进展
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摘要
钙钛矿太阳能电池因其本身具有太阳光的转化能力强,全色光吸收和双极性(既能传输电子又能传输空穴)等优点,而成为研究的重点。主要介绍了钙钛矿太阳能电池的分类,阐述了钙钛矿太阳能电池发展历程与工作原理。提出今后应进行以下几个方面研究:电池的稳定性,寻找铅元素替代元素等;优化电池结构,增加阻挡层,减少电子复合;注重理论研究与机理研究,加强理论计算;开发新材料等。
The perovskite solar cells have become the focus ofthe research because oftheir strongtransformation abilityofsun light, full light absorption and bipolar(both transmission of electron and transmission electron hole)etc. The classification of perovskite solar cells was mainly introduced, the development history and working principle of perovskite solar cells were described. The followingaspects should be put forward in the future: studying the stability of the battery, searching for alternative elements of lead; optimizing battery structure, increasing the barrier layer, reducing the electron recombination; paying great attention tothe research oftheoryand mechanism, strengtheningthe theorycalculation, and developingnewmaterials etc..
The perovskite solar cells have become the focus ofthe research because oftheir strongtransformation abilityofsun light, full light absorption and bipolar(both transmission of electron and transmission electron hole)etc. The classification of perovskite solar cells was mainly introduced, the development history and working principle of perovskite solar cells were described. The followingaspects should be put forward in the future: studying the stability of the battery, searching for alternative elements of lead; optimizing battery structure, increasing the barrier layer, reducing the electron recombination; paying great attention tothe research oftheoryand mechanism, strengtheningthe theorycalculation, and developingnewmaterials etc..
引文
[1]Kojima A,Teshima K,Shirai Y,et al.Organometal halide perovs-kites as visible-light sensitizers for photovoltaic cells[J].J Am Chem Soc,2009,131:6 050-6 051.
[2]Samrana Kazim,Mohammad Khaja Nazeeruddin,Michael Gratzel,et al.Perovskite as Light Harvester:A Game Changer in Photovolta-ics[J].Angew Chem Int Ed,2014,53:2-15.
[3]Anyi Mei,Xiong Li,Michael Gratzel,et al.A hole-conductorfree,fully printable mesoscopic perovskite solar cell with high stability[J].Science,2014:295-297,345.
[4]Tsutomu Miyasaka.Perovskite Photovoltaics:Rare Functions of Organo Lead Halide in Solar Cells and Optoelectronic Devices[J].Chem Lett,2015,44:720-729.
[5]Akihiro Kojima.Kenjiro Teshima.Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J].J AM CHEM SOC,2009,131:6 050-6 051.
[6]Michael Gratzel.Recent Advances in Sensitized Mesoscopic Solar Cells[J].Accounts Chem Res,2009,42(11):1 788-1 798.
[7]Jeong-Hyeok Im,Sang-Won Park,Nam-Gyu Park.6.5%Efficient perovskite quantum-dot-sensitized solar cell[J].Nanoscale,2011(3):4 088-4 093.
[8]Lioz Etgar,Michael Gratzel.Mesoscopic CH3NH3Pb I3/Ti O2Heterojunction Solar Cells[J].J Am Chem Soc,2012,134(42):17 396-17 399.
[9]Michael M Lee,Joel Teuscher,Henry J Snaith.Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites[J].Science,2012,338(2):643-646.
[10]Ying Yang,Hongwei Han.Size effect of Ti O2nanoparticles on the printable mesoscopic perovskite solar cell[J].Journal of Materials Chemistry A,2015(3):9 165-9 170.
[11]Jianhang Qiu,Shihe Yang.All-solid-state hybrid solar cells based on a new organometal halide perovskite sensitizer anone-dimensional Ti O2nanowire arrays[J].Nanoscale,2013(5):3 245.
[12]Xiong Yin,Meng He,Bin Liu.Performance enhancement of perovskite-sensitized mesoscopic solar cells using Nb-doped Ti O2compact layer[J].Nano Research,2015,8(6):1 997-2 003.
[13]Dongqin Bi,Erik M,J Johansson.Effect of Different Hole Tran-sport Materials on Recombination in CH3NH3Pb I3Perovskite-Sensi-tized Mesoscopic Solar Cells[J].J Phys Chem Lett,2013(4):1 532-1 536.
[14]Norman Pellet,Peng Gao,Michael Gratzel,et al.Mixed-OrganicCation Perovskite Photovoltaics for Enhanced Solar-Light Harvest-ing[J].Angew Chem Int Ed,2014,53:3 151-3 157.
[15]Eran Edri,David Cahen,Gary Hodes.High Open-Circuit Voltage Solar Cells Based on Organic Inorganic Lead Bromide Perovskite[J].J Phys Chem Lett,2013(4):897-902.
[16]Dianyi Liu,Timothy L.Kelly Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques[J].Nature,Photonics,2014,8(2):133-138.
[17]Yani Chen,Yixin Zhao,Ziqi Liang.Non-Thermal Annealing Fabrication of Efficient Planar Perovskite Solar Cells with Inclusion of NH4Cl[J].Chem Mater,2015,27:1 448-1 451.
[18]Nam Joong Jeon,Jun Hong Noh,Sang II Seok.Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells[J].Nature,Materials,2014(3):897-903.
[19]Sonia R Raga,Yabing Qi.Influence of Air Annealing on High Efficiency Planar Structure Perovskite Solar Cells[J].Chem Mater,2015,27:1 597-1 603.
[20]Chun-yu Chang,Cheng-ya Chu,Wei-fang Su.Tuning Perovskite Morphology by Polymer Additive for High Efficiency Solar Cell[J].ACS Appl Mater Interface,2015(7):4 955-4 961.
[21]Jun-Seok Yeo,Rira Kang,Sehyun Lee,et al.Highly efficient and stable planar perovskite solar cells with reduced graphene oxide nanosheets as electrode interlayer[J].Nano Energy,2015(12):96-104.
[22]Weiwei Wang,Jianyu Yuan,Hai-Qiao Wang,et al.Inverted Planar Heterojunction Perovskite Solar Cells Employing Polymer as the Electron Conductor[J].ACS Appl Mater Interfaces,2015(7):3 994-3 999.
[23]Pablo Docampo1,James M Ball,Henry J Snaith.Efficient organo-metal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates[J].Nature Communications,2013,4(7):657-678.
[24]Jingbi You,Ziruo Hong,Yang Yang.Low-Temperature Solution-Processed Perovskite Solar Cells with High Efficiency and Flexibility[J].ACS nano,2014,8(2):1 674-1 680.
[25]Byeong Jo Kim,Dong Hoe Kim,Yoo-Yong Lee,et al.Highly efficient and bending durable perovskite solar cells:toward a wearable power source[J].Energy Environ Sci,2015(8):916-921.
[26]宋志浩,王世荣,肖殷,等.新型空穴传输材料在钙钛矿太阳能电池中的研究进展[J].物理学报,2015(3):33301-033301.
[27]杨林,左智翔,于凤琴,等.钙钛矿太阳能电池的研究进展[J].化工技术与开发,2015(9):40-45.
[28]陈建清,杨东辉,江静华,等.复合钙钛矿太阳能电池电荷传输层材料研究进展[J].材料导报,2015,29(5):1-7.
[29]丁雄傑,倪露,马圣博,等.钙钛矿太阳能电池中电子传输材料的研究进展[J].物理学报,2015(3):38 802-038 802.
[30]郭旭东,牛广达,王立铎.高效率钙钛矿型太阳能电池的化学稳定性及其研究进展[J].化学学报,2015,73(3):211-218.
[31]李明军,李旭,韦志仁,等.有机金属卤化物钙钛矿太阳能电池的研究进展[J].科学通报,2015,60(7):581-592.
[32]梁栋,贾瑞龙,简选,等.钙钛矿太阳能电池的研究进展[J].现代化工,2015(9):16-20.
[33]曹久朋,刘德鹤,覃耀慰,等.钙钛矿太阳能电池的研究进展[J].齐鲁工业大学学报:自然科学版,2015(1):7-10.
[34]张太阳,赵一新.铅卤钙钛矿敏化型太阳能电池的研究进展[J].化学学报,2015,73(3):202-210.
[35]荣耀光,梅安意,刘林峰,等.全固态介观太阳能电池:从染料敏化到钙钛矿[J].化学学报,2015,73(3):237-251.
[36]白晓功,史彦涛,王开,等.少铅钙钛矿CH3NH3Srx Pb(1-x)I3的合成及其在全固态薄膜太阳能电池中的应用[J].物理化学学报,2015(2):285-290.
[37]张晓婷.钙钛矿太阳能电池的研究进展[J].科技风,2015(16):46-47.
[38]GUAN Li,LI Mingjun,LI Xu.有机金属卤化物钙钛矿太阳能电池的研究进展[J].科学通报,2015(7):581-592.
[39]邓林龙,谢素原,黄荣彬,等.钙钛矿太阳能电池材料和器件的研究进展[J].厦门大学学报:自然科学版,2015,54(5):619-629.
[40]张太阳,赵一新.铅卤钙钛矿敏化型太阳能电池的研究进展[J].化学学报,2015,73(3):202-210.
[2]Samrana Kazim,Mohammad Khaja Nazeeruddin,Michael Gratzel,et al.Perovskite as Light Harvester:A Game Changer in Photovolta-ics[J].Angew Chem Int Ed,2014,53:2-15.
[3]Anyi Mei,Xiong Li,Michael Gratzel,et al.A hole-conductorfree,fully printable mesoscopic perovskite solar cell with high stability[J].Science,2014:295-297,345.
[4]Tsutomu Miyasaka.Perovskite Photovoltaics:Rare Functions of Organo Lead Halide in Solar Cells and Optoelectronic Devices[J].Chem Lett,2015,44:720-729.
[5]Akihiro Kojima.Kenjiro Teshima.Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J].J AM CHEM SOC,2009,131:6 050-6 051.
[6]Michael Gratzel.Recent Advances in Sensitized Mesoscopic Solar Cells[J].Accounts Chem Res,2009,42(11):1 788-1 798.
[7]Jeong-Hyeok Im,Sang-Won Park,Nam-Gyu Park.6.5%Efficient perovskite quantum-dot-sensitized solar cell[J].Nanoscale,2011(3):4 088-4 093.
[8]Lioz Etgar,Michael Gratzel.Mesoscopic CH3NH3Pb I3/Ti O2Heterojunction Solar Cells[J].J Am Chem Soc,2012,134(42):17 396-17 399.
[9]Michael M Lee,Joel Teuscher,Henry J Snaith.Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites[J].Science,2012,338(2):643-646.
[10]Ying Yang,Hongwei Han.Size effect of Ti O2nanoparticles on the printable mesoscopic perovskite solar cell[J].Journal of Materials Chemistry A,2015(3):9 165-9 170.
[11]Jianhang Qiu,Shihe Yang.All-solid-state hybrid solar cells based on a new organometal halide perovskite sensitizer anone-dimensional Ti O2nanowire arrays[J].Nanoscale,2013(5):3 245.
[12]Xiong Yin,Meng He,Bin Liu.Performance enhancement of perovskite-sensitized mesoscopic solar cells using Nb-doped Ti O2compact layer[J].Nano Research,2015,8(6):1 997-2 003.
[13]Dongqin Bi,Erik M,J Johansson.Effect of Different Hole Tran-sport Materials on Recombination in CH3NH3Pb I3Perovskite-Sensi-tized Mesoscopic Solar Cells[J].J Phys Chem Lett,2013(4):1 532-1 536.
[14]Norman Pellet,Peng Gao,Michael Gratzel,et al.Mixed-OrganicCation Perovskite Photovoltaics for Enhanced Solar-Light Harvest-ing[J].Angew Chem Int Ed,2014,53:3 151-3 157.
[15]Eran Edri,David Cahen,Gary Hodes.High Open-Circuit Voltage Solar Cells Based on Organic Inorganic Lead Bromide Perovskite[J].J Phys Chem Lett,2013(4):897-902.
[16]Dianyi Liu,Timothy L.Kelly Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques[J].Nature,Photonics,2014,8(2):133-138.
[17]Yani Chen,Yixin Zhao,Ziqi Liang.Non-Thermal Annealing Fabrication of Efficient Planar Perovskite Solar Cells with Inclusion of NH4Cl[J].Chem Mater,2015,27:1 448-1 451.
[18]Nam Joong Jeon,Jun Hong Noh,Sang II Seok.Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells[J].Nature,Materials,2014(3):897-903.
[19]Sonia R Raga,Yabing Qi.Influence of Air Annealing on High Efficiency Planar Structure Perovskite Solar Cells[J].Chem Mater,2015,27:1 597-1 603.
[20]Chun-yu Chang,Cheng-ya Chu,Wei-fang Su.Tuning Perovskite Morphology by Polymer Additive for High Efficiency Solar Cell[J].ACS Appl Mater Interface,2015(7):4 955-4 961.
[21]Jun-Seok Yeo,Rira Kang,Sehyun Lee,et al.Highly efficient and stable planar perovskite solar cells with reduced graphene oxide nanosheets as electrode interlayer[J].Nano Energy,2015(12):96-104.
[22]Weiwei Wang,Jianyu Yuan,Hai-Qiao Wang,et al.Inverted Planar Heterojunction Perovskite Solar Cells Employing Polymer as the Electron Conductor[J].ACS Appl Mater Interfaces,2015(7):3 994-3 999.
[23]Pablo Docampo1,James M Ball,Henry J Snaith.Efficient organo-metal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates[J].Nature Communications,2013,4(7):657-678.
[24]Jingbi You,Ziruo Hong,Yang Yang.Low-Temperature Solution-Processed Perovskite Solar Cells with High Efficiency and Flexibility[J].ACS nano,2014,8(2):1 674-1 680.
[25]Byeong Jo Kim,Dong Hoe Kim,Yoo-Yong Lee,et al.Highly efficient and bending durable perovskite solar cells:toward a wearable power source[J].Energy Environ Sci,2015(8):916-921.
[26]宋志浩,王世荣,肖殷,等.新型空穴传输材料在钙钛矿太阳能电池中的研究进展[J].物理学报,2015(3):33301-033301.
[27]杨林,左智翔,于凤琴,等.钙钛矿太阳能电池的研究进展[J].化工技术与开发,2015(9):40-45.
[28]陈建清,杨东辉,江静华,等.复合钙钛矿太阳能电池电荷传输层材料研究进展[J].材料导报,2015,29(5):1-7.
[29]丁雄傑,倪露,马圣博,等.钙钛矿太阳能电池中电子传输材料的研究进展[J].物理学报,2015(3):38 802-038 802.
[30]郭旭东,牛广达,王立铎.高效率钙钛矿型太阳能电池的化学稳定性及其研究进展[J].化学学报,2015,73(3):211-218.
[31]李明军,李旭,韦志仁,等.有机金属卤化物钙钛矿太阳能电池的研究进展[J].科学通报,2015,60(7):581-592.
[32]梁栋,贾瑞龙,简选,等.钙钛矿太阳能电池的研究进展[J].现代化工,2015(9):16-20.
[33]曹久朋,刘德鹤,覃耀慰,等.钙钛矿太阳能电池的研究进展[J].齐鲁工业大学学报:自然科学版,2015(1):7-10.
[34]张太阳,赵一新.铅卤钙钛矿敏化型太阳能电池的研究进展[J].化学学报,2015,73(3):202-210.
[35]荣耀光,梅安意,刘林峰,等.全固态介观太阳能电池:从染料敏化到钙钛矿[J].化学学报,2015,73(3):237-251.
[36]白晓功,史彦涛,王开,等.少铅钙钛矿CH3NH3Srx Pb(1-x)I3的合成及其在全固态薄膜太阳能电池中的应用[J].物理化学学报,2015(2):285-290.
[37]张晓婷.钙钛矿太阳能电池的研究进展[J].科技风,2015(16):46-47.
[38]GUAN Li,LI Mingjun,LI Xu.有机金属卤化物钙钛矿太阳能电池的研究进展[J].科学通报,2015(7):581-592.
[39]邓林龙,谢素原,黄荣彬,等.钙钛矿太阳能电池材料和器件的研究进展[J].厦门大学学报:自然科学版,2015,54(5):619-629.
[40]张太阳,赵一新.铅卤钙钛矿敏化型太阳能电池的研究进展[J].化学学报,2015,73(3):202-210.