动车用环保水性清洗剂的研制及其性能
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摘要
通过正交试验得到一种适用于高速动车组的环保型水性清洗剂:阴离子表面活性剂Y-421 5.0%(均为质量分数),十二烷基葡萄糖苷(APG)4.0%,十二烷基硫酸钠0.5%,曲拉通X-100 1.5%,硅酸钠1.0%,柠檬酸钠1.0%,异丙醇10.0%,去离子水余量。与常用的两种清洗剂相比,自制清洗剂稳定,腐蚀性弱,洗净力较强,生物降解性好,对人体伤害小。该清洗剂对动车组较难清洗的橡胶外风挡和头车挡风玻璃部位均具有良好的去污能力。
An environment-friendly water-based cleaner comprising anionic surfactant Y-421 5.0 wt.%, dodecyl glucoside 4.0 wt.%, sodium dodecyl sulfate 0.5 wt.%, Triton X-100 1.5 wt.%, sodium silicate 1.0 wt.%, sodium citrate 1.0 wt.%, isopropanol 10.0 wt.%, and deionized water balance was obtained by orthogonal test for high-speed motor train. As compared with two commercial cleaners, the developed cleaner has better stability, weaker corrosiveness, higher detergency, superior biodegradability, and less harm to users. It has good detergency for the exterior rubber vestibule diaphragm and the windshield of head car, which are difficult to be cleaned.
An environment-friendly water-based cleaner comprising anionic surfactant Y-421 5.0 wt.%, dodecyl glucoside 4.0 wt.%, sodium dodecyl sulfate 0.5 wt.%, Triton X-100 1.5 wt.%, sodium silicate 1.0 wt.%, sodium citrate 1.0 wt.%, isopropanol 10.0 wt.%, and deionized water balance was obtained by orthogonal test for high-speed motor train. As compared with two commercial cleaners, the developed cleaner has better stability, weaker corrosiveness, higher detergency, superior biodegradability, and less harm to users. It has good detergency for the exterior rubber vestibule diaphragm and the windshield of head car, which are difficult to be cleaned.
引文
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[2]中国铁道科学研究院金属及化学研究所.动车组清洗作业专用清洗剂[J].现代城市轨道交通,2008(3):71-72.
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[10]魏铭,朱焱.无磷水基金属清洗剂的研制[J].材料保护,2007,40(4):30-31,38.
[11]李玉军,蔡卫权,宋素娟,等.高效油烟机重油垢环保型水基清洗剂的研制[J].化工进展,2013,32(8):1898-1901.
[12]古蒙蒙,涂文辉,桂绍庸,等.环保型高效稠油垢弱酸性水基清洗剂的研制[J].化工进展,2014,33(6):1563-1566.
[13]古蒙蒙,蔡卫权.高效绿色多功能水基清洗剂的研制[J].化工进展,2016,35(10):3301-3305.
[14]罗胜铁,沈丽,魏利滨,等.一种环境友好型水基多功能油污清洗剂的研制[J].清洗世界,2009,25(3):11-16.
[15]邹其超,方光荣,彭顺金.新型无磷除油锈水基金属清洗剂HD的研制[J].精细化工,1999,16(增刊):223-225.
[2]中国铁道科学研究院金属及化学研究所.动车组清洗作业专用清洗剂[J].现代城市轨道交通,2008(3):71-72.
[3]胡小强,王双田,白剑利,等.汽车挡风玻璃清洗剂市场现状与发展趋势[J].清洗世界,2016,32(9):44-47.
[4]钱国坻,桂玉梅.表面活性剂复配原理及其在纺织印染工业中的应用[J].日用化学工业,1999,21(2):19-25.
[5]袁寅力,龚红梅.表面活性剂在水基金属清洗剂中的应用[J].日用化学品科学,2016,39(10):29-32.
[6]王世荣.表面活性剂化学[M].2版.北京:化学工业出版社,2010:200-215.
[7]KABASHIMA K,KATO K,MATSUMOTO S,et al.Cleaning agent,cleaning method and cleaning apparatus:US20030168079A1[P].2003–09–11.
[8]JESCHKE R,SCHIEFERSTEIN L,BOCARAC K,et al.Cleaning agent for hard surfaces based on cationic polymer soil-release compounds:US6251849B1[P].2001–06–26.
[9]PICHOT R,SPYROPOULOS F,NORTON I T.O/W emulsions stabilised by both low molecular weight surfactants and colloidal particles:the effect of surfactant type and concentration[J].Journal of Colloid and Interface Science,2010,352(1):128-135.
[10]魏铭,朱焱.无磷水基金属清洗剂的研制[J].材料保护,2007,40(4):30-31,38.
[11]李玉军,蔡卫权,宋素娟,等.高效油烟机重油垢环保型水基清洗剂的研制[J].化工进展,2013,32(8):1898-1901.
[12]古蒙蒙,涂文辉,桂绍庸,等.环保型高效稠油垢弱酸性水基清洗剂的研制[J].化工进展,2014,33(6):1563-1566.
[13]古蒙蒙,蔡卫权.高效绿色多功能水基清洗剂的研制[J].化工进展,2016,35(10):3301-3305.
[14]罗胜铁,沈丽,魏利滨,等.一种环境友好型水基多功能油污清洗剂的研制[J].清洗世界,2009,25(3):11-16.
[15]邹其超,方光荣,彭顺金.新型无磷除油锈水基金属清洗剂HD的研制[J].精细化工,1999,16(增刊):223-225.