有机胺类化合物分析和治理技术研究进展
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摘要
有机胺类化合物是仅次于有机硫化物的恶臭污染物。近年来,有机胺类化合物在环境中的行为已引起了广泛关注。文章对有机胺类化合物的分析检测方法、治理技术及解离通道方面的研究进行了综述,着重阐述了水相和气相中有机胺类污染的治理方法和光解离通道。结合实际需要,预测了今后的研究方向和发展趋势。
Organic amine-containing compounds are malodorous pollutant only inferior to organic sulfur-containing compounds. In the last few decades,the behavior in environment has aroused extensive attention. The latest information available in the literature including detecting and analysis methods,treatment technologies and dissociation channels of organic amine-containing compounds were summarized. The removal methods and photodissociation channels in aqueous and gas phase were highlighted. Research orientation and development trend in the future were predicted as well.
Organic amine-containing compounds are malodorous pollutant only inferior to organic sulfur-containing compounds. In the last few decades,the behavior in environment has aroused extensive attention. The latest information available in the literature including detecting and analysis methods,treatment technologies and dissociation channels of organic amine-containing compounds were summarized. The removal methods and photodissociation channels in aqueous and gas phase were highlighted. Research orientation and development trend in the future were predicted as well.
引文
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[9]Martínez Y M,Hernández R H,FalcóP C.A microanalytical method for ammonium and short-chain primary aliphatic amines using precolumn derivatization and capillary liquid chromatography[J].Journal of Chromatography A,2007,1164(1/2):329-333.
[10]FalcóP C,Hernández R H,Andrés J V,et al.On-line determination of aliphatic amines in water using in-tube solid-phase microextraction-assisted derivatisation in invalve mode for processing large sample volumes in LC[J].Analytical Biochemistry,2009,394:557-565.
[11]杨磊,陈忠林,沈吉敏,等.对水中痕量二甲胺传统检测方法的改进[J].中国给水排水,2010,26(8):93-97.Yang Lei,Chen Zhonglin,Shen Jimin,et al.Improved method for determining trace dimethylamine in water by gas chromatography[J].China Water and Wastewater,2010,26(8):93-97(.inChinese)
[12]马兴华,韩润平,李捍东,等.环境水样中二甲胺和二乙胺的检测方法比较[J].分析化学,2010,38(5):731-734.Ma Xinghua,Han Runping,Li Handong,et al.Study on analysis methods for dimethylamine and diethylamine in ambient wsater[J].Chinese Journal of Analytic Chemistry,2010,38(5):731-734(.in Chinese)
[13]叶林静,关卫省,李宇亮.高级氧化技术降解双酚A的研究进展[J].化工进展,2013,32(4):909-918.Ye Linjing,Guan Weixing,Li Yuliang.Research advances in bisphenol A degraded by advanced oxidation process[J].Chemical Industry and Engineering Process,2013,32(4):909-918(.in Chinese)
[14]刘江红,潘洋,谷璟瑶,等.UASB和微生物固定化反应器降解含聚废水组合工艺[J].化工进展,2013,32(7):1701-1711.Liu Jianghong,Pan Yang,Gu Jingyao,et al.Degradation of HPAM-containing wastewater with integrated process of UASB and immobilized microorganism reactor[J].Chemical Industry and Engineering Process,2013,32(7):1701-1711.(inChinese)
[15]Kenneth M B,Phillip E S.Supercritical water oxidation of methylamine[J].Industrial and Engineering Chemistry Research,2005,44:5318-5324.
[16]Huerta F,Morallon E,Perez J M,et al.Oxidation of methylamine and ethylamine on Pt single crystal electrodes in acid medium[J].Journal of Electroanalytical Chemistry,1999,469(2):159-169.
[17]Helali S,Puzenat E,Perol N,et al.Mathylamine and dimethylamine photocatalytic degradation-adsorption isotherms and kinetics[J].Applied Catalysis A:General,2011,402:201-207.
[18]Helali S,Dappozze F,Horikoshi S,et al.Kinetics of the photocatalytic degradation of methylamine:influence of pH and UV-A/UV-B radiant fluxes[J].Journal of Photochemistry and Photobiology A,2013,255:50-57.
[19]Kim S,Choi W.Kinetics and mechanisms of photocatalytic degradation of(CH3)nNH+4-n(0≤n≤4)in TiO2suspension:the role of OH radicals[J].Environmental Science and Technology,2002,36:2019-2025.
[20]徐冰冰,陈忠林,齐飞,等.UV/O3对亚硝基二甲胺降解产物的控制研究[J].环境科学,2008,29(12):3421-3427.Xu Bingbing,Chen Zhonglin,Qi Fei,et al.Control on products of NDMA degradation by UV/O3[J].Environmental Science,2008,29(12):3421-3427(.in Chinese)
[21]Lee C H,Choi W Y,Yoon J Y.UV photolytic mechanism of N-nitrosodimethylamine in water:roles of dissolved oxygen and solution pH[J].Environmental Science and Technology,2005,39:9702-9709.
[22]曾帆,于萍,罗运柏.水体中二甲胺的吸附与氧化降解[J].环境科学与技术,2012,35(2):148-153.Zeng Fan,Yu Ping,Luo Yunbai.Dimethylamine in water adsorption and oxidative degradation[J].Environmental Science&Technology,2012,35(2):148-153(.in Chinese)
[23]Chung K H,Lee K Y.Removal of trimethylamine by adsorption over zeolite catalysts and deodorization of fish oil[J].Journal of Hazardous Materials,2009,172:922-927.
[24]胡芳,魏在山,叶蔚君.生物法净化含NH3、H2S和三甲胺的水产饲料恶臭废气的研究[J].环境工程,2007,25(3):41-44.Hu Fang,Wei Zaishan,Ye Weijun.The study on biopurification of NH3,H2S and trimethylamine containing odor from aquatic feed[J].Environmental Engineering,2007,25(3):41-44(.in Chinese)
[25]Chang C T,Chen B Y,Shiu I S,et al.Biofiltration of trimethylamine-containing waste gas by entrapped mixed microbial cells[J].Chemosphere,2004,55:751-756.
[26]Ho K L,Chung Y C,Tseng C P.Continuous deodorization and bacterial community analysis of a biofilter treating nitrogen-containing gases from swine waste storage pits[J].Bioresource Technology,2008,99:2757-2765.
[27]Xue N T,Wang Q H,Wang J,et al.Odorous composting gas abatement and microbial community diversity in a biotrickling filter[J].International Biodeterioration and Biodegradation,2013,82:73-80.
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