凹凸棒去除水环境中典型污染物的研究进展
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摘要
简要介绍了凹凸棒的结构特点及预处理方法,并重点论述了凹凸棒的有机与无机两大类改性方法以及国内外关于凹凸棒去除水环境中重金属和有机污染物的研究进展,针对当前凹凸棒在水污染物处理方面的应用,指出了凹凸棒的未来研究方向。
Not only the structure, characteristics and pretreatment methods of attapulgite were described in brief, but also the organic and inorganic modification methods were mainly reviewed. Furthermore, the domestic and foreign research progress of attapulgite on the removal of heavy metals and organic contaminants in water environment was summarized. In view of the application of attapulgite in wastewater treatment, the future research directions were pointed out.
Not only the structure, characteristics and pretreatment methods of attapulgite were described in brief, but also the organic and inorganic modification methods were mainly reviewed. Furthermore, the domestic and foreign research progress of attapulgite on the removal of heavy metals and organic contaminants in water environment was summarized. In view of the application of attapulgite in wastewater treatment, the future research directions were pointed out.
引文
[1]Zhang Y,Wang W B,Zhang J P,et al.A comparative study about adsorption of natural palygorskite for methylene blue[J].Chemical Engineering Journal,2015,262:390-398.
[2]孟庆森,石宗利,王顺花.凹凸棒表面改性及其在废水处理中的应用[J].硅酸盐学报,2008,27(5):996-999.
[3]Tao L,Li Y N,Zhao Y Q,et al.International conference on computer science and electronic technology[C].China:Atlantis Press,2015.
[4]谢兆歌,严子春,胡家玮.凹凸棒石的改性及在水处理中的应用[J].能源与环境,2009(4):12-14.
[5]Chi Y L,Chen Y T,Liu X,et al.Impact of environmental conditions on the sorption behavior of Pb(Ⅱ)onto attapulgite[J].Journal of Radioanalytical and Nuclear Chemistry,2013,295(2):1589-1596.
[6]Liu H B,Chen T H,Chang D Y,et al.Effect of rehydration on structure and surface properties of thermally treated palygorskite[J].Journal of Colloid and Interface Science,2013,393:87-91.
[7]Xavier K C M,Santos M S F,Santos M R M C,et al.Effects of acid treatment on the clay palygorskite:XRD,surface area morphological and chemical composition[J].Materials Research,2014,17:3-8.
[8]Deng Y,Wu F,Liu B,et al.Sorptive removal ofβ-blocker propranolol from aqueous solution by modified attapulgite:Effect factors and sorption mechanisms[J].Chemical Engineering Journal,2011,174(2):571-578.
[9]Wang W B,Wang F F,Kang Y R,et al.Enhanced adsorptive removal of methylene blue from aqueous solution by alkali-Activated palygorskite[J].Water Air Soil Pollution,2015,226:83.
[10]徐继香,康玉茹,王爱勤,等.油酸钠改性对凹凸棒黏土理化性能的影响[J].中国矿业,2011,20(9):102-105.
[11]Tai Y,Shi C,Wang C.Preparation and characterization of anion-cation organopalygorskite for 2-naphthol removal from aqueous solution[J].Journal of Molecular Liquids,2014,195:116-124.
[12]姚超,左士祥.凹凸棒石的表面改性及其在脲醛树脂中的应用[J].硅酸盐学报,2011,39(4):630-634.
[13]曾永斌,姚超.盐酸掺杂聚苯胺/凹凸棒纳米导电复合材料的研究[J].非金属矿,2008,31(4):53-56.
[14]Peng Y G,Chen D J,Ji J L,et al.Chitosan-modified palygorskite:Preparation,haracterization and reactive dye removal[J].Applied Clay Science,2013,74:81-86.
[15]Liang X F,Xu Y M,Tan X,et al.Heavy metal adsorbents mercapto and amino functionalized palygorskite:Preparation and characterization[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2013,426:98-105.
[16]Deng Y H,Gao Z Q,Liu B Z,et al.Selective removal of lead from aqueous solutions by ethylenediamine-modified attapulgite[J].Chemical Engineering Journal,2013,223:91-98.
[17]王红艳,张艳,周守勇,等.硫酸改性凹凸棒粘土的性能表征及吸附Pb(Ⅱ)工艺研究[J].淮阴师范学院学报,2005,4(1):47-50.
[18]郭春芳.凹凸棒对废水中Pb(Ⅱ)吸附的初步研究[J].印染助剂,2013,30(7):36-38.
[19]吴云.凹凸棒和硅胶分离富集重金属及其应用研究[D].鞍山:辽宁科技大学,2012.
[20]Zhou S Y,Xue A,Zhang Y,et al.Novel polyamidoamine dendrimer-functionalized palygorskite adsorbents with high adsorption capacity for Pb2+and reactive dyes[J].Applied Clay Science,2015,107:220-229.
[21]Cui H,Qian Y,Li Q,et al.Fast removal of Hg(II)ions from aqueous solution by amine-modified attapulgite[J].Applied Clay Science,2013,72:84-90.
[22]陈冬梅,熊飞.碳化改性凹凸棒石处理含铬(Cr6+)废水[J].武汉理工大学学报,2008,30(7):88-90
[23]Kong Y,Wei J X,Wang Z L,et al.Heavy metals removal from solution by polyaniline/palygorskite composite[J].Journal of Applied Polymer Science,2011,122:2054-2059.
[24]Quan G X,Zhang Q J,Guo J,et al.Removal of Cr(VI)from aqueous solution by nanoscale zero-valent iron grafted on acid-activated attapulgite[J].Water Air Soil Pollution,2014:225-1979.
[25]张兴儒,郭会宾,崔明鑫,等.西宁盆地坡缕石粘土对Cd2+吸附性能研究[J].中国非金属矿工业导刊,2011,2:42-45,55.
[26]Frini-Srasra N,Srasra E.Acid treatment of south Tunisian palygorskite:Removal of Cd(II)from aqueous and phosphoric acid solutions[J].Desalination,2010,250:26-34.
[27]Liang X F,Han J,Xu Y M,et al.Sorption of Cd2+on mercapto and amino functionalized palygorskite[J].Applied Surface Science,2014,322:194-201.
[28]吴强,方旭波.余辉,等.凹凸棒负载壳聚糖去除鱼油重金属的试验研究[J].粮食食品科技,2012,20(3):26-30.
[29]Chen L F,Liang H W,Lu Y,et al.Synthesis of an attapulgite clay@carbon nanocomposite adsorbent by a hydrothermal carbonization process and their application in the removal of toxic metal Ions from water[J].Langmuir,2011,27,8998-9004.
[30]罗士平,谢爱娟.凹凸棒的改性及其吸附2,2′二硝基联苄废水的研究[J].工业用水与废水,2012,43(4):51-53,79.
[31]李天昕,矫媛媛,杨雯雯,等.凹凸棒石在造纸废水处理中的应用研究[J].水处理技术,2014,40(10):67-69.
[32]王翠,汪茜,王春杏,等.SDS/凹凸棒对水中碱性嫩黄的吸附及性能[J].环境科学与技术,2014,37(6):49-54.
[33]Liu Y,Wang W B,Jin Y L,et al.Adsorption behavior of methylene blue from aqueous solution by the hydrogel composites based on attapulgite[J].Separation Science and Technology,2011,46:5,858-868.
[34]Zhang J,Cai D Q,Zhang G L,et al.Adsorption of methylene bule from aqueous solution onto multiporous palygorskite modified by ion beam bombardment:effect of contact time,temperature,pH and ionic strength[J].Appied Clay Science,2013,(83-84):137-143.
[35]Zhang Z F,Wang W B,Wang A Q.Highly effective removal of methylene blue using functionalized attapulgite via hydrothermal process[J].Journal of Environmental Sciences,2015,33:106-115.
[36]Xi Y F,Mallavarapu M,Naidu R.Adsorption of the herbicide 2,4-D on organo-palygorskite[J].Applied Clay Science,2010,49(3):255-261.
[37]刘总堂,许敏,卢再亮,等.HDTMA-凹凸棒的制备表征及其对HCH的吸附研究[J].中国环境科学,2010,30(12):1602-1607.
[38]谢刚,韩志勇,赵霞.Fenton/活化凹凸棒石工艺去除微污染水中的苯酚[J].中国给水排水,2008,24(19):58-61.
[39]王素青,陈静,陈田田,等.改性凹凸棒处理含苯酚水的技术[J].工业水处理,2012,32(4):55-58.
[40]孙玉凤,刘总堂,费正皓,等.有机凹凸棒对二氯苯酚的吸附研究[J].化学研究与应用,2012,24(6):854-859.
[41]韶晖,姚鹏飞,钟璟,等.凹凸棒的改性及其对二甲苯异构体的吸附性能[J].石油学报(石油加工),2014,30(6):1016-1021.
[42]凌慧诗,王志红,何晓梅,等.基于改性凹凸棒的强化混凝处理高藻低浊原水工艺[J].环境工程学报,2014,8(7):2765-2771.
[43]谭立强,蒋金龙,冯良东,等.等离子体法改性凹凸棒吸附多氯联苯研究[J].淮阴工学院学报,2013,22(5):1-6.
[44]徐灵舒.凹凸棒粘土/碳复合材料的制备及其水污染处理应用初步研究[D].扬州:扬州大学,2013.
[2]孟庆森,石宗利,王顺花.凹凸棒表面改性及其在废水处理中的应用[J].硅酸盐学报,2008,27(5):996-999.
[3]Tao L,Li Y N,Zhao Y Q,et al.International conference on computer science and electronic technology[C].China:Atlantis Press,2015.
[4]谢兆歌,严子春,胡家玮.凹凸棒石的改性及在水处理中的应用[J].能源与环境,2009(4):12-14.
[5]Chi Y L,Chen Y T,Liu X,et al.Impact of environmental conditions on the sorption behavior of Pb(Ⅱ)onto attapulgite[J].Journal of Radioanalytical and Nuclear Chemistry,2013,295(2):1589-1596.
[6]Liu H B,Chen T H,Chang D Y,et al.Effect of rehydration on structure and surface properties of thermally treated palygorskite[J].Journal of Colloid and Interface Science,2013,393:87-91.
[7]Xavier K C M,Santos M S F,Santos M R M C,et al.Effects of acid treatment on the clay palygorskite:XRD,surface area morphological and chemical composition[J].Materials Research,2014,17:3-8.
[8]Deng Y,Wu F,Liu B,et al.Sorptive removal ofβ-blocker propranolol from aqueous solution by modified attapulgite:Effect factors and sorption mechanisms[J].Chemical Engineering Journal,2011,174(2):571-578.
[9]Wang W B,Wang F F,Kang Y R,et al.Enhanced adsorptive removal of methylene blue from aqueous solution by alkali-Activated palygorskite[J].Water Air Soil Pollution,2015,226:83.
[10]徐继香,康玉茹,王爱勤,等.油酸钠改性对凹凸棒黏土理化性能的影响[J].中国矿业,2011,20(9):102-105.
[11]Tai Y,Shi C,Wang C.Preparation and characterization of anion-cation organopalygorskite for 2-naphthol removal from aqueous solution[J].Journal of Molecular Liquids,2014,195:116-124.
[12]姚超,左士祥.凹凸棒石的表面改性及其在脲醛树脂中的应用[J].硅酸盐学报,2011,39(4):630-634.
[13]曾永斌,姚超.盐酸掺杂聚苯胺/凹凸棒纳米导电复合材料的研究[J].非金属矿,2008,31(4):53-56.
[14]Peng Y G,Chen D J,Ji J L,et al.Chitosan-modified palygorskite:Preparation,haracterization and reactive dye removal[J].Applied Clay Science,2013,74:81-86.
[15]Liang X F,Xu Y M,Tan X,et al.Heavy metal adsorbents mercapto and amino functionalized palygorskite:Preparation and characterization[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2013,426:98-105.
[16]Deng Y H,Gao Z Q,Liu B Z,et al.Selective removal of lead from aqueous solutions by ethylenediamine-modified attapulgite[J].Chemical Engineering Journal,2013,223:91-98.
[17]王红艳,张艳,周守勇,等.硫酸改性凹凸棒粘土的性能表征及吸附Pb(Ⅱ)工艺研究[J].淮阴师范学院学报,2005,4(1):47-50.
[18]郭春芳.凹凸棒对废水中Pb(Ⅱ)吸附的初步研究[J].印染助剂,2013,30(7):36-38.
[19]吴云.凹凸棒和硅胶分离富集重金属及其应用研究[D].鞍山:辽宁科技大学,2012.
[20]Zhou S Y,Xue A,Zhang Y,et al.Novel polyamidoamine dendrimer-functionalized palygorskite adsorbents with high adsorption capacity for Pb2+and reactive dyes[J].Applied Clay Science,2015,107:220-229.
[21]Cui H,Qian Y,Li Q,et al.Fast removal of Hg(II)ions from aqueous solution by amine-modified attapulgite[J].Applied Clay Science,2013,72:84-90.
[22]陈冬梅,熊飞.碳化改性凹凸棒石处理含铬(Cr6+)废水[J].武汉理工大学学报,2008,30(7):88-90
[23]Kong Y,Wei J X,Wang Z L,et al.Heavy metals removal from solution by polyaniline/palygorskite composite[J].Journal of Applied Polymer Science,2011,122:2054-2059.
[24]Quan G X,Zhang Q J,Guo J,et al.Removal of Cr(VI)from aqueous solution by nanoscale zero-valent iron grafted on acid-activated attapulgite[J].Water Air Soil Pollution,2014:225-1979.
[25]张兴儒,郭会宾,崔明鑫,等.西宁盆地坡缕石粘土对Cd2+吸附性能研究[J].中国非金属矿工业导刊,2011,2:42-45,55.
[26]Frini-Srasra N,Srasra E.Acid treatment of south Tunisian palygorskite:Removal of Cd(II)from aqueous and phosphoric acid solutions[J].Desalination,2010,250:26-34.
[27]Liang X F,Han J,Xu Y M,et al.Sorption of Cd2+on mercapto and amino functionalized palygorskite[J].Applied Surface Science,2014,322:194-201.
[28]吴强,方旭波.余辉,等.凹凸棒负载壳聚糖去除鱼油重金属的试验研究[J].粮食食品科技,2012,20(3):26-30.
[29]Chen L F,Liang H W,Lu Y,et al.Synthesis of an attapulgite clay@carbon nanocomposite adsorbent by a hydrothermal carbonization process and their application in the removal of toxic metal Ions from water[J].Langmuir,2011,27,8998-9004.
[30]罗士平,谢爱娟.凹凸棒的改性及其吸附2,2′二硝基联苄废水的研究[J].工业用水与废水,2012,43(4):51-53,79.
[31]李天昕,矫媛媛,杨雯雯,等.凹凸棒石在造纸废水处理中的应用研究[J].水处理技术,2014,40(10):67-69.
[32]王翠,汪茜,王春杏,等.SDS/凹凸棒对水中碱性嫩黄的吸附及性能[J].环境科学与技术,2014,37(6):49-54.
[33]Liu Y,Wang W B,Jin Y L,et al.Adsorption behavior of methylene blue from aqueous solution by the hydrogel composites based on attapulgite[J].Separation Science and Technology,2011,46:5,858-868.
[34]Zhang J,Cai D Q,Zhang G L,et al.Adsorption of methylene bule from aqueous solution onto multiporous palygorskite modified by ion beam bombardment:effect of contact time,temperature,pH and ionic strength[J].Appied Clay Science,2013,(83-84):137-143.
[35]Zhang Z F,Wang W B,Wang A Q.Highly effective removal of methylene blue using functionalized attapulgite via hydrothermal process[J].Journal of Environmental Sciences,2015,33:106-115.
[36]Xi Y F,Mallavarapu M,Naidu R.Adsorption of the herbicide 2,4-D on organo-palygorskite[J].Applied Clay Science,2010,49(3):255-261.
[37]刘总堂,许敏,卢再亮,等.HDTMA-凹凸棒的制备表征及其对HCH的吸附研究[J].中国环境科学,2010,30(12):1602-1607.
[38]谢刚,韩志勇,赵霞.Fenton/活化凹凸棒石工艺去除微污染水中的苯酚[J].中国给水排水,2008,24(19):58-61.
[39]王素青,陈静,陈田田,等.改性凹凸棒处理含苯酚水的技术[J].工业水处理,2012,32(4):55-58.
[40]孙玉凤,刘总堂,费正皓,等.有机凹凸棒对二氯苯酚的吸附研究[J].化学研究与应用,2012,24(6):854-859.
[41]韶晖,姚鹏飞,钟璟,等.凹凸棒的改性及其对二甲苯异构体的吸附性能[J].石油学报(石油加工),2014,30(6):1016-1021.
[42]凌慧诗,王志红,何晓梅,等.基于改性凹凸棒的强化混凝处理高藻低浊原水工艺[J].环境工程学报,2014,8(7):2765-2771.
[43]谭立强,蒋金龙,冯良东,等.等离子体法改性凹凸棒吸附多氯联苯研究[J].淮阴工学院学报,2013,22(5):1-6.
[44]徐灵舒.凹凸棒粘土/碳复合材料的制备及其水污染处理应用初步研究[D].扬州:扬州大学,2013.