热塑性淀粉耐水性的化学与物理作用机制
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摘要
石油资源的短缺以及减轻石油基聚合物所产生的环境负担的必要性,推动了生物可降解材料的开发和生产。近几十年来天然聚合物由于无毒性、可生物降解性和生物相容性正在某些领域取代目前的合成聚合物。淀粉由于其可再生性、可生物降解性、低成本和易获得性已经被广泛研究用于制造可生物降解的复合材料,应用于农业、食品、医药和包装行业。但淀粉的多羟基结构赋予其很强的亲水性,这种湿度敏感性限制了它们的机械性能并影响到其应用。本文主要从提高热塑性淀粉耐水性的物理与化学作用机理的角度出发,总结和归纳了近年来国内外以提高热塑性淀粉材料的耐水性能和降低其对环境湿度敏感性为目的的研究工作,介绍了影响耐水性能的相关因素以及改善方法,并指出今后研究工作的发展方向。
The shortage of oil resources and the need to reduce the environmental burden caused by petroleum-based polymers have driven the development and production of biodegradable materials. In recent decades, natural polymers have replaced current synthetic polymers due to their non-toxicity, biodegradability, and biocompatibility. Starch has been extensively studied for the manufacture of biodegradable composites due to its reproducibility, biodegradability, low cost, and availability, which has been widely used for applications in agriculture, alimentary, medicine and packaging industry. However, the polyhydroxyl structure of starch gives it strong hydrophilicity, and the moisture sensitivity limits their mechanical properties and affects their application. In this paper, mainly from the perspective of improving the physical and chemical effects of thermoplastic starch, the research works in recent years on improving the water resistance of thermoplastic starch material and reducing its sensitivity to environmental humidity are summarized. The related factors affecting the water resistance and the methods of improvement are introduced, and the research trend in this field is also proposed.
The shortage of oil resources and the need to reduce the environmental burden caused by petroleum-based polymers have driven the development and production of biodegradable materials. In recent decades, natural polymers have replaced current synthetic polymers due to their non-toxicity, biodegradability, and biocompatibility. Starch has been extensively studied for the manufacture of biodegradable composites due to its reproducibility, biodegradability, low cost, and availability, which has been widely used for applications in agriculture, alimentary, medicine and packaging industry. However, the polyhydroxyl structure of starch gives it strong hydrophilicity, and the moisture sensitivity limits their mechanical properties and affects their application. In this paper, mainly from the perspective of improving the physical and chemical effects of thermoplastic starch, the research works in recent years on improving the water resistance of thermoplastic starch material and reducing its sensitivity to environmental humidity are summarized. The related factors affecting the water resistance and the methods of improvement are introduced, and the research trend in this field is also proposed.
引文
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