完全可生物降解淀粉塑料研究进展
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摘要
依据生物降解性能的不同,淀粉塑料可分为部分可降解和完全可降解两大类。本文重点阐述了完全可降解淀粉塑料的概念和范畴,并将其分为三大类;系统归纳了近年来国内外不同类型完全可降解淀粉塑料的研究现状及进展,并对今后的发展趋势进行了展望。
In this paper, based on the difference in biodegradability, starch plastics are divided into two categories, partially degradable and completely degradable starch plastics. The concept and scope of completely degradable starch plastics are mainly described, and divided it into three categories. The research status and progress of different types of completely degradable starch plastics reported at home and abroad in recent years have been systematically summarized, and the future development trend is prospected.
In this paper, based on the difference in biodegradability, starch plastics are divided into two categories, partially degradable and completely degradable starch plastics. The concept and scope of completely degradable starch plastics are mainly described, and divided it into three categories. The research status and progress of different types of completely degradable starch plastics reported at home and abroad in recent years have been systematically summarized, and the future development trend is prospected.
引文
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[10]Ivanic F,Jochec-Moskova D,Janigova I,et al.Physical properties of starch plasticized by a mixture of plasticizers[J].European Polymer Journal,2017,93:843-849.
[11]Dang K M,Yoksan R.Development of thermoplastic starch blown film by incorporating plasticized chitosan[J].Carbohydrate Polymers,2015,115:575-581.
[12]Dang K M,Yoksan R.Morphological characteristics and barrier properties of thermoplastic starch/chitosan blown lm[J].Carbohydrate Polymers,2016,150:40-47.
[13]Guo B,Zha D,Li B,et al.Polyvinyl alcohol microspheres reinforced thermoplastic starch composites[J].Materials,2018,DOI:10.3390/ma11040640.
[14]Yutaka T,Calabia B P,Ugwu C U,et al.Biodegradability of plastics[J].International Journal of Molecular Sciences,2009,10(9):3 722-3 742.
[15]Raghu N,Kale A,Raj A,et al.Mechanical and thermal properties of wood fibers reinforced poly(lactic acid)/thermoplasticized starch composites[J].Journal of Applied Polymer Science,2017,DOI:10.1002/app.46118.
[16]Yang Y,Tang Z,Xiong Z,et al.Preparation and characterization of thermoplastic starches and their blends with poly(lactic acid)[J].International Journal of Biological Macromolecules,2015,77(5):273-279.
[17]Zuo Y,Wu Y,Gu J,et al.The UV aging properties of maleic anhydride esteri ed starch/polylactic acid composites[J].Journal of Wuhan University of Technology,2017,32(4):971-977.
[18]Gutierrez T J,Alvarezl V A.Films made by blending poly(ε-caprolactone)with starch and our from sagu rhizome grown at the Venezuelan Amazons[J].Journal of Polymers&the Environment,2017,25(3):701-716.
[19]Ortega-Toro R,Munoz A,Talens P,et al.Improvement of properties of glycerol plasticized starch lms by blending with a low ratio of polycaprolactone and/or polyethylene glycol[J].Food Hydrocolloids,2016,56:9-19.
[20]Correa A C,Carmona V B,Simao J A,et al.Biodegradable blends of urea plasticized thermoplastic starch(UTPS)and poly(ε-caprolactone)(PCL):Morphological,rheological,thermal and mechanical properties[J].Carbohydrate Polymers,2017,167:177-184.
[21]Ninago M D,Lapez O V,Lencina M M,et al.Enhancement of thermoplastic starch nal properties by blending with poly(ε-caprolactone)[J].Carbohydrate Polymers,2015,134:205-212.
[22]王礼建,董亚强,郭斌,等.共混技术在淀粉塑料中的应用研究进展[J].材料导报,2015,29(5):78-82.
[23]Castilho L R,Mitchell D A,Freire D M G.Production of polyhydroxyalkanoates(PHAs)from waste materials and byproducts by submerged and solid-state fermentation[J].Bioresource Technology,2009,100(23):5 996-6 009.
[24]Thire R M S M,Ribeiro T A A,Andrade C T.Effect of starch addition on compression-molded poly(3-hydroxybutyrate)/starch blends[J].Journal of Applied Polymer Science,2010,100(6):4 338-4 347.
[25]Garrido-Miranda K A,Rivas B L,Perez M A.Poly(3-hydroxybutyrate)-thermoplastic starch-organoclay bionanocomposites:Surface properties[J].Journal of Applied Polymer Science,2017,DOI:10.1002/app.45217.
[26]Ramsay B A,Langlade V,Carreau P J,et al.Biodegradability and mechanical properties of poly-(beta-hydroxybutyrateco-beta-hydroxyvalerate)-starch blends[J].Applied&Environmental Microbiology,1993,59(4):1 242-1 246.
[27]Pelicano M,Pachekoski W,Agnelli J A M.In uência da adi??o de amido de mandioca na biodegrada??o da blenda polimérica PHBV/Eco ex?[J].Polímeros,2009,19(3):212-217.
[28]Magalhaes N F,Andrade C T.Properties of melt-processed poly(hydroxybutyrate-co-hydroxyvalerate)/starch 1:1 blend nanocomposites[J].Polímeros,2013,23(3):366-372.
[29]He Y S,Zeng J B,Li S L,et al.Crystallization behavior of partially miscible biodegradable poly(butylene succinate)/poly(ethylene succinate)blends[J].Thermochimica Acta,2012,529(1):80-86.
[30]Li J,Luo X,Lin X,et al.Comparative study on the blends of PBS/thermoplastic starch prepared from waxy and normal corn starches[J].Starch-St?rke,2013,65(9-10):831-839.
[31]Zeng J B,Jiao L,Li Y D,et al.Bio-based blends of starch and poly(butylene succinate)with improved miscibility,mechanical properties,and reduced water absorption[J].Carbohydrate Polymers,2011,83(2):762-768.
[32]Wang W,Zhang H,Dai Y,et al.Effects of low poly(vinyl alcohol)content on properties of biodegradable blowing films based on two modified starches[J]. Journal of Thermoplastic Composite Materials, 2015, DOI:10.1177/0892705715614080.
[33]Tian H,Yan J,Rajulu A V,et al.Fabrication and properties of polyvinyl alcohol/starch blend lms:Effect of composition and humidity[J].Inter national Jour nal of Biological Macromolecules,2016,96:518-523.
[34]Abdullah Z W,Dong Y.Preparation and characterisation of poly(vinyl)alcohol(PVA)/starch(ST)/halloysite nanotube(HNT)nanocomposite films as renewable materials[J].Journal of Materials Science,2018,53(5):3 455-3 469.
[35]Ghanbari A,Tabarsa T,Ashori A,et al.Preparation and characterization of thermoplastic starch and cellulose nanofibers as green nanocomposites: Extrusion processing[J]. International Journal of Biological Macromolecules,2018,112:442-447.
[36]Babaee M,Jonoobi M,Hamzeh Y,et al.Biodegradability and mechanical properties of reinforced starch nanocomposites using cellulose nano bers[J].Carbohydrate Polymers,2015,132:1-8.
[37]Santana J S,Do Rosario J M,Pola C C,et al.Cassava starch-based nanocomposites reinforced with cellulose nano bers extracted from sisal[J].Journal of Applied Polymer Science,2016,DOI:10.1002/app.44637.
[38]Ciobanu C,Ungureanu M,Ignat L,et al.Properties of ligninpolyurethane lms prepared by casting method[J].Industrial Crops&Products,2004,20(2):231-241.
[39]Bhat R,Abdullah N,Din R H,et al.Producing novel sago starch based food packaging films by incorporating lignin isolated from oil palm black liquor waste[J].Journal of Food Engineering,2013,119(4):707-713.
[40]史瑞欣.一种碱木质素-淀粉膜的制备方法:中国,103146008B[P].2014-12-10.
[41]Lazaridou A,Biliaderis C G.Molecular aspects of cerealβ-glucan functionality:Physical properties,technological applications and physiological effects[J].Journal of Cereal Science,2007,46(2):101-118.
[42]Sagnelli D,Kirkensgaard J J K,Giosafatto C V L,et al.Allnatural bio-plastics using starch-betaglucan composites[J].Carbohydrate Polymers,2017,172:237-245.
[43]Qin Y,Zhang S,Yu J,et al.Effects of chitin nano-whiskers on the antibacterial and physicochemical properties of maize starch lms[J].Carbohydrate Polymers,2016,147:372-378.
[44]Salaberria A M,Diaz R H,Labidi J,et al.Role of chitin nanocrystals and nanofibers on physical,mechanical and functional properties in thermoplastic starch films[J].Food Hydrocolloids,2015,46:93-102.
[2]郭斌,韩梓军,薛灿,等.当今世界淀粉塑料行业的发展现状--北美[J].塑料科技,2018,46(3):140-143.
[3]Tang H,Jiang H,Guo B,et al.Effect of higher thermoplastic starch content on TPS/LDPE plastics[J].Advanced Material Research,2013,772:38-43.
[4]Guo B,Wang L J,Yin P,et al.Ultra-high molecular weight polyethylene fiber-reinforced thermoplastic corn starch composite[J].Journal of Thermoplastic Composite Materials,2017,30(4):564-577.
[5]韩梓军,薛灿,银鹏,等.国内淀粉塑料领域发明专利的现状分析研究[J].塑料科技,2018,46(1):126-131.
[6]王礼建,董亚强,郭斌,等.共混技术在淀粉塑料中的应用研究进展[J].材料导报,2015,29(5):78-82.
[7]唐皞,郭斌,薛岚,等.增塑剂在热塑性淀粉中的应用研究进展[J].塑料工业,2012,40(7):1-4.
[8]唐皞,郭斌,李本刚,等.热塑性淀粉的增强研究进展[J].塑料工业,2013,41(1):1-8.
[9]Niazi M B K,Zijlstra M,Broekhuis A A.In uence of plasticizer with different functional groups on thermoplastic starch[J].Journal of Applied Polymer Science,2015,DOI:10.1002/app.42012.
[10]Ivanic F,Jochec-Moskova D,Janigova I,et al.Physical properties of starch plasticized by a mixture of plasticizers[J].European Polymer Journal,2017,93:843-849.
[11]Dang K M,Yoksan R.Development of thermoplastic starch blown film by incorporating plasticized chitosan[J].Carbohydrate Polymers,2015,115:575-581.
[12]Dang K M,Yoksan R.Morphological characteristics and barrier properties of thermoplastic starch/chitosan blown lm[J].Carbohydrate Polymers,2016,150:40-47.
[13]Guo B,Zha D,Li B,et al.Polyvinyl alcohol microspheres reinforced thermoplastic starch composites[J].Materials,2018,DOI:10.3390/ma11040640.
[14]Yutaka T,Calabia B P,Ugwu C U,et al.Biodegradability of plastics[J].International Journal of Molecular Sciences,2009,10(9):3 722-3 742.
[15]Raghu N,Kale A,Raj A,et al.Mechanical and thermal properties of wood fibers reinforced poly(lactic acid)/thermoplasticized starch composites[J].Journal of Applied Polymer Science,2017,DOI:10.1002/app.46118.
[16]Yang Y,Tang Z,Xiong Z,et al.Preparation and characterization of thermoplastic starches and their blends with poly(lactic acid)[J].International Journal of Biological Macromolecules,2015,77(5):273-279.
[17]Zuo Y,Wu Y,Gu J,et al.The UV aging properties of maleic anhydride esteri ed starch/polylactic acid composites[J].Journal of Wuhan University of Technology,2017,32(4):971-977.
[18]Gutierrez T J,Alvarezl V A.Films made by blending poly(ε-caprolactone)with starch and our from sagu rhizome grown at the Venezuelan Amazons[J].Journal of Polymers&the Environment,2017,25(3):701-716.
[19]Ortega-Toro R,Munoz A,Talens P,et al.Improvement of properties of glycerol plasticized starch lms by blending with a low ratio of polycaprolactone and/or polyethylene glycol[J].Food Hydrocolloids,2016,56:9-19.
[20]Correa A C,Carmona V B,Simao J A,et al.Biodegradable blends of urea plasticized thermoplastic starch(UTPS)and poly(ε-caprolactone)(PCL):Morphological,rheological,thermal and mechanical properties[J].Carbohydrate Polymers,2017,167:177-184.
[21]Ninago M D,Lapez O V,Lencina M M,et al.Enhancement of thermoplastic starch nal properties by blending with poly(ε-caprolactone)[J].Carbohydrate Polymers,2015,134:205-212.
[22]王礼建,董亚强,郭斌,等.共混技术在淀粉塑料中的应用研究进展[J].材料导报,2015,29(5):78-82.
[23]Castilho L R,Mitchell D A,Freire D M G.Production of polyhydroxyalkanoates(PHAs)from waste materials and byproducts by submerged and solid-state fermentation[J].Bioresource Technology,2009,100(23):5 996-6 009.
[24]Thire R M S M,Ribeiro T A A,Andrade C T.Effect of starch addition on compression-molded poly(3-hydroxybutyrate)/starch blends[J].Journal of Applied Polymer Science,2010,100(6):4 338-4 347.
[25]Garrido-Miranda K A,Rivas B L,Perez M A.Poly(3-hydroxybutyrate)-thermoplastic starch-organoclay bionanocomposites:Surface properties[J].Journal of Applied Polymer Science,2017,DOI:10.1002/app.45217.
[26]Ramsay B A,Langlade V,Carreau P J,et al.Biodegradability and mechanical properties of poly-(beta-hydroxybutyrateco-beta-hydroxyvalerate)-starch blends[J].Applied&Environmental Microbiology,1993,59(4):1 242-1 246.
[27]Pelicano M,Pachekoski W,Agnelli J A M.In uência da adi??o de amido de mandioca na biodegrada??o da blenda polimérica PHBV/Eco ex?[J].Polímeros,2009,19(3):212-217.
[28]Magalhaes N F,Andrade C T.Properties of melt-processed poly(hydroxybutyrate-co-hydroxyvalerate)/starch 1:1 blend nanocomposites[J].Polímeros,2013,23(3):366-372.
[29]He Y S,Zeng J B,Li S L,et al.Crystallization behavior of partially miscible biodegradable poly(butylene succinate)/poly(ethylene succinate)blends[J].Thermochimica Acta,2012,529(1):80-86.
[30]Li J,Luo X,Lin X,et al.Comparative study on the blends of PBS/thermoplastic starch prepared from waxy and normal corn starches[J].Starch-St?rke,2013,65(9-10):831-839.
[31]Zeng J B,Jiao L,Li Y D,et al.Bio-based blends of starch and poly(butylene succinate)with improved miscibility,mechanical properties,and reduced water absorption[J].Carbohydrate Polymers,2011,83(2):762-768.
[32]Wang W,Zhang H,Dai Y,et al.Effects of low poly(vinyl alcohol)content on properties of biodegradable blowing films based on two modified starches[J]. Journal of Thermoplastic Composite Materials, 2015, DOI:10.1177/0892705715614080.
[33]Tian H,Yan J,Rajulu A V,et al.Fabrication and properties of polyvinyl alcohol/starch blend lms:Effect of composition and humidity[J].Inter national Jour nal of Biological Macromolecules,2016,96:518-523.
[34]Abdullah Z W,Dong Y.Preparation and characterisation of poly(vinyl)alcohol(PVA)/starch(ST)/halloysite nanotube(HNT)nanocomposite films as renewable materials[J].Journal of Materials Science,2018,53(5):3 455-3 469.
[35]Ghanbari A,Tabarsa T,Ashori A,et al.Preparation and characterization of thermoplastic starch and cellulose nanofibers as green nanocomposites: Extrusion processing[J]. International Journal of Biological Macromolecules,2018,112:442-447.
[36]Babaee M,Jonoobi M,Hamzeh Y,et al.Biodegradability and mechanical properties of reinforced starch nanocomposites using cellulose nano bers[J].Carbohydrate Polymers,2015,132:1-8.
[37]Santana J S,Do Rosario J M,Pola C C,et al.Cassava starch-based nanocomposites reinforced with cellulose nano bers extracted from sisal[J].Journal of Applied Polymer Science,2016,DOI:10.1002/app.44637.
[38]Ciobanu C,Ungureanu M,Ignat L,et al.Properties of ligninpolyurethane lms prepared by casting method[J].Industrial Crops&Products,2004,20(2):231-241.
[39]Bhat R,Abdullah N,Din R H,et al.Producing novel sago starch based food packaging films by incorporating lignin isolated from oil palm black liquor waste[J].Journal of Food Engineering,2013,119(4):707-713.
[40]史瑞欣.一种碱木质素-淀粉膜的制备方法:中国,103146008B[P].2014-12-10.
[41]Lazaridou A,Biliaderis C G.Molecular aspects of cerealβ-glucan functionality:Physical properties,technological applications and physiological effects[J].Journal of Cereal Science,2007,46(2):101-118.
[42]Sagnelli D,Kirkensgaard J J K,Giosafatto C V L,et al.Allnatural bio-plastics using starch-betaglucan composites[J].Carbohydrate Polymers,2017,172:237-245.
[43]Qin Y,Zhang S,Yu J,et al.Effects of chitin nano-whiskers on the antibacterial and physicochemical properties of maize starch lms[J].Carbohydrate Polymers,2016,147:372-378.
[44]Salaberria A M,Diaz R H,Labidi J,et al.Role of chitin nanocrystals and nanofibers on physical,mechanical and functional properties in thermoplastic starch films[J].Food Hydrocolloids,2015,46:93-102.