空心炭球应用研究进展
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摘要
空心炭球具有独特的结构和许多特殊的物理化学性质,使其在各个领域均表现出良好的应用前景。综述了空心炭球在吸附材料、电催化、锂离子电池负极材料、超级电容器电极材料、药物载体、储氢等领域的应用,展望了空心炭球的研究前景及应用方向。
Hollow carbon spheres with unique structure show many special physical and chemical properties and have good application prospect in various fields. The application fields of hollow carbon spheres were reviewed such as adsorbing material, electrocatalysis, anode material for lithium-ion battery, electrode materials for supercapacitor, drug carrier, and hydrogen storage material.The research prospect and application direction of hollow carbon spheres were also forecasted.
Hollow carbon spheres with unique structure show many special physical and chemical properties and have good application prospect in various fields. The application fields of hollow carbon spheres were reviewed such as adsorbing material, electrocatalysis, anode material for lithium-ion battery, electrode materials for supercapacitor, drug carrier, and hydrogen storage material.The research prospect and application direction of hollow carbon spheres were also forecasted.
引文
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[28]Wu X F,Tang W X,Jiao K J,et al.Preparation and Li+storage properties of hierarchical hollow porous carbon spheres[J].Particuology,2014,14(6):44-50.
[29]Zhang K L,Li X N,Liang J W,et al.Nitrogen-doped porous interconnected double-shelled hollow carbon spheres with high capacity for lithium ion batteries and sodium ion batteries[J].Electrochimica Acta,2015,155:174-182.
[30]Hao G,Liu C L,Yang L,et al.Mo O2-loaded porous carbon hollow spheres as anode materials for lithium-ion batteries[J].Materials Chemistry and Physics,2014,147(147):218-224.
[31]Liao Y,Gao L,Zhang X H,et al.Nitrogen-doped hollow carbon spheres with enhanced electrochemical capacitive properties[J].Materials Research Bulletin,2012,47(7):1625-1629.
[32]Han Y,Dong X T,Zhang C,et al.Hierarchical porous carbon hollow-spheres as a high performance electrical double-layer capacitor material[J].Journal of Power Sources,2012,211:92-96.
[33]Guo J X,Zhang H J,Geng H Y,et al.Efficient one-pot synthesis of peapod-like hollow carbon nanomaterials for utrahigh drug loading capacity[J].Journal of Colloid and Interface Science,2015,437:90-96.
[34]Wenelska K,Michalkiewicz B,Jiang Gong,et al.In situ deposition of Pd nanoparticles with controllable diameters in hollow carbon spheres for hydrogen storage[J].International Journal of Hydrogen Energy,2013,38(36):16179-16184.
[2]Xia Y D,Mokaya R.Ordered mesoporous carbon hollow spheres nanocast using mesoporous silica via chemical vapor deposition[J].Adv Mater,2004,16(11):886-891.
[3]Sun G H,Li K X,Wang J,et al.A novel approach for fabrication of hollow carbon spheres with large size and high specific surface area[J].Microporous and Mesoporous Materials,2011,139(1):207-210.
[4]Liu R,Mahurin S M,Li C,et al.Dopamine as a carbon source:The controlled synthesis of hollow carbon spheres and yolk-structured carbon nanocomposites[J].Angew Chem Int Ed,2011,50:6799-6802.
[5]Hu G,Ma D,Cheng M J,et al.Direct synthesis of uniform hollow carbon spheres by a self-assembly template approach[J].Chem Commun,2002,17(17):1948-1949.
[6]Liu J W,Shao M W,Tang Q,et al.A medial-reduction route to hollow carbon spheres[J].Carbon,2003,41(8):1682-1685.
[7]Niwase K,Homae T,Nakamura K G,et al.Generation of giant carbon hollow spheres from C60fullerene by shockcompression[J].Chemical Physics Letters,2002,362(1):47-50.
[8]Wang Z S,Li F S.Preparation of hollow carbon nanospheres via explosive detonation[J].Materials Letters,2009,63:58-60.
[9]Guo L M,Zhang L X,Zhang J M.Hollow mesoporous carbon spheres an excellent bilirubin adsorbent[J].Chemical Communications,2009,40(40):6071-6073.
[10]Valdes-Solias T,Valle-Vigon P,Sevilla M,et al.Encapsulation of nanosized catalysts in the hollow core of a mesoporous carbon capsule[J].Journal of Catalysis,2007,251(1):239-243.
[11]Tian Q H,Zhang Z X,Yang L,et al.Fabrication of mesoporous titanium dioxide/tin dioxide/carbon hollow microspheres as high performance anode for lithium-ion batteries[J].Journal of Power Sources,2015,279:528-532.
[12]Zhang C F,Wu H B,Yuan C Z,et al.Confining sulfur in double-shelled hollow carbon spheres for lithium-sulfur batteries[J].Angew Chem Int Ed,2012,51(2):9592-9595.
[13]Chen X C,Kierzek K,Wenelska K,et al.Electrochemical characteristics of discrete,uniform,and monodispersed hollow mesoporous carbon spheres in double-layered supercapacitors[J].Chem Asian J,2013,8:2627-2633.
[14]Yan Z X,Meng H,Shen P K,et al.Effect of the templates on the synthesis of hollow carbon materials as electrocatalyst supports for direct alcohol fuel cells[J].International Journal of Hydrogen Energy,2012,37(5):4728-4736.
[15]Zhang C G,Li J J,Liu E Z,et al.Synthesis of hollow carbon nano-onions and their use for electrochemical hydrogen storage[J].Carbon,2012,50(10):3513-3521.
[16]Ganeshkumar M,Ponrasu T,Sathishkumar M,et al.Preparation of amphiphilic hollow carbon nanosphere loaded insulin for oral delivery[J].Colloids and Surfaces B Biointerfaces,2013,103(2):238-243.
[17]Konicki W,Cendrowski K,Chen X,et al.Application of hollow mesoporous carbon nanospheres as an high effective adsorbent for the fast removal of acid dyes from aqueous solutions[J].Chemical Engineering Journal,2013,228(28):824-833.
[18]Tripathi P K,Gan L,Liu M,et al.One-pot assembly of silica@two polymeric shells for synthesis of hollow carbon porous nanospheres:Adsorption of bisphenol A[J].Materials Letters,2014,120(4):108-110.
[19]Cui H J,Cai J K,Zhao H,et al.One step solvothermal synthesis of functional hybridγ-Fe2O3/carbon hollow spheres with superior capacities for heavy metal removal[J].J Colloid Interface Sci,2014,425:131-135.
[20]Zeng Y,Wang K,Yao J,et al.Hollow carbon beads fabricated by phase inversion method for efficient oil sorption[J].Carbon,2014,69(2):25-31.
[21]Wang H,Bo X J,Wang A,et al.Cobalt doped nanoporous hollow carbon spheres as novel non-precious metal oxygen reduction electrocatalysts[J].Electrochemistry Communications,2013,36:75-79.
[22]Wu J,Jin C,Yang Z R,et al.Synthesis of phosphorusdoped carbon hollow spheres as efficient metal-free electrocatalysts for oxygen reduction[J].Carbon,2015,82:562-571.
[23]Yan Z X,Xie J M,Zong S K,et al.Small-sized Pt particles on mesoporous hollow carbon spheres for highly stable oxygen reduction reaction[J].Electrochimica Acta,2013,109(11):256-261.
[24]Fan Y,Liu P F,Huang Z Y,et al.Porous hollow carbon spheres for electrode material of supercapacitors and support material of dendritic Pt electrocatalyst[J].Journal of Power Sources,2015,280:30-38.
[25]Song Y Y,Li Y,Xia X H.One-step pyrolysis process to synthesize dispersed Pt/carbon hollow nanospheres catalysts for electrocatalysis[J].Electrochemistry Communications,2007,9(2):201-205.
[26]Yan J,Meng H,Xie F Y,et al.Metal free nitrogen doped hollow mesoporous graphene-analogous spheres as effective electrocatalyst for oxygen reduction reaction[J].Journal of Power Sources,2014,245(1):772-778.
[27]Hu F P,Wang Z Y,Li Y L,et al.Improved performance of Pd electrocatalyst supported on ultrahigh surface area hollow carbon spheres for direct alcohol fuel cells[J].Journal of Power Sources,2008,177(1):61-66.
[28]Wu X F,Tang W X,Jiao K J,et al.Preparation and Li+storage properties of hierarchical hollow porous carbon spheres[J].Particuology,2014,14(6):44-50.
[29]Zhang K L,Li X N,Liang J W,et al.Nitrogen-doped porous interconnected double-shelled hollow carbon spheres with high capacity for lithium ion batteries and sodium ion batteries[J].Electrochimica Acta,2015,155:174-182.
[30]Hao G,Liu C L,Yang L,et al.Mo O2-loaded porous carbon hollow spheres as anode materials for lithium-ion batteries[J].Materials Chemistry and Physics,2014,147(147):218-224.
[31]Liao Y,Gao L,Zhang X H,et al.Nitrogen-doped hollow carbon spheres with enhanced electrochemical capacitive properties[J].Materials Research Bulletin,2012,47(7):1625-1629.
[32]Han Y,Dong X T,Zhang C,et al.Hierarchical porous carbon hollow-spheres as a high performance electrical double-layer capacitor material[J].Journal of Power Sources,2012,211:92-96.
[33]Guo J X,Zhang H J,Geng H Y,et al.Efficient one-pot synthesis of peapod-like hollow carbon nanomaterials for utrahigh drug loading capacity[J].Journal of Colloid and Interface Science,2015,437:90-96.
[34]Wenelska K,Michalkiewicz B,Jiang Gong,et al.In situ deposition of Pd nanoparticles with controllable diameters in hollow carbon spheres for hydrogen storage[J].International Journal of Hydrogen Energy,2013,38(36):16179-16184.