基于复合电极材料的超级电容器研究进展
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摘要
综述了基于复合电极材料作超级电容器电极材料的研究现状,总结了近几年来在开发超级电容器电极材料领域中将炭材料、金属氧化物、导电聚合物三者复合得到的二元、三元复合电极材料的研究进展以及现状,并探讨了超级电容器复合电极材料的发展方向和研究重点。
This paper summarized the progress of supercapacitors electrode materials based on hybrid electrode materials.Research progress and present status are summarized such as the binary complex and ternary complex of activated carbon materials, metal oxide materials, conducting polymers. In the end, the development direction and research emphases are discussed.
This paper summarized the progress of supercapacitors electrode materials based on hybrid electrode materials.Research progress and present status are summarized such as the binary complex and ternary complex of activated carbon materials, metal oxide materials, conducting polymers. In the end, the development direction and research emphases are discussed.
引文
[1]Zhang H,Wang K,Zhang X,et al.Self-generating graphene and porous nanocarbon composites for capacitive energy storage[J].Journal of Materials Chemistry A,2015,3(21):11277-11286.
[2]Yan J,Wei T,Shao B,et al.Electrochemical properties of graphene nanosheet/carbon black composites as electrodes for supercapacitors[J].Carbon,2010,48(6):1731-1737.
[3]Sun M,Wang G,Li X,et al.Irradiation preparation of reduced graphene oxide/carbon nanotube composites for high-performance supercapacitors[J].Journal of Power Sources,2014,245(1):436-444.
[4]Zhang H,Zhang X,Lin H,et al.Graphene and maghemite composites based supercapacitors delivering high volumetric capacitance and extraordinary cycling stability[J].Electrochimica Acta,2015,156:70-76.
[5]Wu Z,Wang D,Ren W,et al.Anchoring hydrous Ru O2 on graphene sheets for high‐performance electrochemical capacitors[J].Advanced Functional Materials,2010,20(20):3595-3602.
[6]Dong X C,Xu H,Wang X W,et al.3D Graphene–cobalt oxide electrode for high-performance supercapacitor and enzymeless glucose detection[J].Acs Nano,2012,6(4):3206.
[7]邱照远,林建明,玉富达,等.氧化镍/碳纳米管复合材料的合成及其在超级电容器上的应用[J].化学工程与装备,2013(7):7-11.
[8]付蓉蓉,罗民,马永华,等.Ni3(HCOO)6/还原氧化石墨烯复合电极材料的制备及电容性能[J].高等学校化学学报,2016,37(8):1485-1490.
[9]However,Example F.Supercapacitors based on nickel oxide/carbon materials composites[J].International Journal of Electrochemistry,2011,2011.
[10]蔡敏,崔李三,李庆余,等.Mn O2/AMCMB复合电极材料的制备及超电容性能的研究[J].电源技术,2016,40(4):796-798.
[11]袁磊,付志兵,常丽娟,等.Mn O2/石墨烯复合电极材料的制备与储能性能[J].强激光与粒子束,2014,26(11):210-215.
[12]王超飞,鲁双,陈慧龙,等.一步合成Mn3O4@RGO复合材料及其非对称超级电容器的应用[J].无机材料学报,2016,31(6):581-587.
[13]Li G R,Feng Z P,Ou Y N,et al.Mesoporous Mn O2/carbon aerogel composites as promising electrode materials for high-performance supercapacitors[J].Langmuir,2012,26(4):2209-2213.
[14]Ren S,Yang Y,Xu M,et al.Hollow Sn O2 microspheres and their carbon-coated composites for supercapacitors[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2014,444(4):26-32.
[15]Li J,Wang X,Huang Q,et al.Preparation and characterization of Ru O2·x H2O/carbon aerogel composites for supercapacitors[J].Journal of Applied Electrochemistry,2007,37(10):1129-1135.
[16]Yilmaz G,Guo C X,Lu X.High‐Performance Solid‐State Supercapacitors Based on V2O5/Carbon Nanotube Composites[J].Chemelectrochem,2016,3(1):158-164.
[17]Yang Y,Yang F,Hu H,et al.Dilute Ni O/carbon nanofiber composites derived from metal organic framework fibers as electrode materials for supercapacitors[J].Chemical Engineering Journal,2016,307:583-592.
[18]吴娟,吴雪艳,魏霄,等.聚苯胺/介孔碳纳米线复合电极材料的制备和性能[J].高等学校化学学报,2012,33(7):1540-1544.
[19]蔡敏,杨桂芬,王红强,等.超级电容器聚苯胺/活性中间相炭微球复合电极材料的研究[J].功能材料与器件学报,2011,17(2):168-172.
[20]王春晓,任鹏刚,刘蓬,等.聚吡咯/石墨烯复合导电材料的制备及性能表征[J].功能材料,2012,43(16):2150-2152.
[21]Zhang D,Xiong Z,Yao C,et al.Enhanced capacitance and rate capability of graphene/polypyrrole composite as electrode material for supercapacitors[J].Journal of Power Sources,2011,196(14):5990-5996.
[22]王浩,任鹏刚.纳米石墨片/聚吡咯复合材料的制备方法[J].化工新型材料,2013,41(10):65-67.
[23]杨文耀,邱永龙,夏双,等.聚3,4-乙烯二氧噻吩/活性炭扣式复合电极的制备及其性能研究[J].材料导报,2015,29(6):1-5.
[24]Sun X,Gan M,Ma L,et al.Fabrication of PANI-coated honeycomb-like Mn O2 nanospheres with enhanced electrochemical performance for energy storage[J].Electrochimica Acta,2015,180:977-982.
[25]Jianfeng Zang,Xiaodong Li.synthesis of ultrafineβ-Mn O/polypyrrole nanorod composites for high-performance supercapacitors[J].Journal of Materials Chemistry,2011,21(29):10965-10969.
[26]Han G,Liu Y,Kan E,et al.Sandwich-structured Mn O2/polypyrrole/reduced graphene oxide hybrid composites for high-performance supercapacitors[J].Rsc Advances,2014,4(20):9898.
[27]Tao J,Liu N,Li L,et al.Hierarchical nanostructures of polypyrrole@Mn O2 composite electrodes for high performance solid-state asymmetric supercapacitors[J].Nanoscale,2014,6(5):2922-8.
[28]Zhang Z,Chi K,Xiao F,et al.Advanced solid-state asymmetric supercapacitors based on 3D graphene/Mn O2and graphene/polypyrrole hybrid architectures[J].Journal of Materials Chemistry A,2015,3(24):12828-12835.
[29]Lin H,Huang Q,Wang J,et al.Self-Assembled Graphene/Polyaniline/Co3O4 Ternary Hybrid Aerogels for Supercapacitors[J].Electrochimica Acta,2016,191:444-451.
[30]孙万虹,周艳青,孙豫,等.用于超级电容器的纳米氧化镍/石墨薄片/银复合电极材料的超声法合成及性能[J].材料导报,2016,30(22):36-42.
[31]Tao J,Liu N,Ma W,et al.Solid-state high performance flexible supercapacitors based on polypyrrole-Mn O2-carbon fiber hybrid structure.[J].Scientific Reports,2013,3(7459):2286.
[2]Yan J,Wei T,Shao B,et al.Electrochemical properties of graphene nanosheet/carbon black composites as electrodes for supercapacitors[J].Carbon,2010,48(6):1731-1737.
[3]Sun M,Wang G,Li X,et al.Irradiation preparation of reduced graphene oxide/carbon nanotube composites for high-performance supercapacitors[J].Journal of Power Sources,2014,245(1):436-444.
[4]Zhang H,Zhang X,Lin H,et al.Graphene and maghemite composites based supercapacitors delivering high volumetric capacitance and extraordinary cycling stability[J].Electrochimica Acta,2015,156:70-76.
[5]Wu Z,Wang D,Ren W,et al.Anchoring hydrous Ru O2 on graphene sheets for high‐performance electrochemical capacitors[J].Advanced Functional Materials,2010,20(20):3595-3602.
[6]Dong X C,Xu H,Wang X W,et al.3D Graphene–cobalt oxide electrode for high-performance supercapacitor and enzymeless glucose detection[J].Acs Nano,2012,6(4):3206.
[7]邱照远,林建明,玉富达,等.氧化镍/碳纳米管复合材料的合成及其在超级电容器上的应用[J].化学工程与装备,2013(7):7-11.
[8]付蓉蓉,罗民,马永华,等.Ni3(HCOO)6/还原氧化石墨烯复合电极材料的制备及电容性能[J].高等学校化学学报,2016,37(8):1485-1490.
[9]However,Example F.Supercapacitors based on nickel oxide/carbon materials composites[J].International Journal of Electrochemistry,2011,2011.
[10]蔡敏,崔李三,李庆余,等.Mn O2/AMCMB复合电极材料的制备及超电容性能的研究[J].电源技术,2016,40(4):796-798.
[11]袁磊,付志兵,常丽娟,等.Mn O2/石墨烯复合电极材料的制备与储能性能[J].强激光与粒子束,2014,26(11):210-215.
[12]王超飞,鲁双,陈慧龙,等.一步合成Mn3O4@RGO复合材料及其非对称超级电容器的应用[J].无机材料学报,2016,31(6):581-587.
[13]Li G R,Feng Z P,Ou Y N,et al.Mesoporous Mn O2/carbon aerogel composites as promising electrode materials for high-performance supercapacitors[J].Langmuir,2012,26(4):2209-2213.
[14]Ren S,Yang Y,Xu M,et al.Hollow Sn O2 microspheres and their carbon-coated composites for supercapacitors[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2014,444(4):26-32.
[15]Li J,Wang X,Huang Q,et al.Preparation and characterization of Ru O2·x H2O/carbon aerogel composites for supercapacitors[J].Journal of Applied Electrochemistry,2007,37(10):1129-1135.
[16]Yilmaz G,Guo C X,Lu X.High‐Performance Solid‐State Supercapacitors Based on V2O5/Carbon Nanotube Composites[J].Chemelectrochem,2016,3(1):158-164.
[17]Yang Y,Yang F,Hu H,et al.Dilute Ni O/carbon nanofiber composites derived from metal organic framework fibers as electrode materials for supercapacitors[J].Chemical Engineering Journal,2016,307:583-592.
[18]吴娟,吴雪艳,魏霄,等.聚苯胺/介孔碳纳米线复合电极材料的制备和性能[J].高等学校化学学报,2012,33(7):1540-1544.
[19]蔡敏,杨桂芬,王红强,等.超级电容器聚苯胺/活性中间相炭微球复合电极材料的研究[J].功能材料与器件学报,2011,17(2):168-172.
[20]王春晓,任鹏刚,刘蓬,等.聚吡咯/石墨烯复合导电材料的制备及性能表征[J].功能材料,2012,43(16):2150-2152.
[21]Zhang D,Xiong Z,Yao C,et al.Enhanced capacitance and rate capability of graphene/polypyrrole composite as electrode material for supercapacitors[J].Journal of Power Sources,2011,196(14):5990-5996.
[22]王浩,任鹏刚.纳米石墨片/聚吡咯复合材料的制备方法[J].化工新型材料,2013,41(10):65-67.
[23]杨文耀,邱永龙,夏双,等.聚3,4-乙烯二氧噻吩/活性炭扣式复合电极的制备及其性能研究[J].材料导报,2015,29(6):1-5.
[24]Sun X,Gan M,Ma L,et al.Fabrication of PANI-coated honeycomb-like Mn O2 nanospheres with enhanced electrochemical performance for energy storage[J].Electrochimica Acta,2015,180:977-982.
[25]Jianfeng Zang,Xiaodong Li.synthesis of ultrafineβ-Mn O/polypyrrole nanorod composites for high-performance supercapacitors[J].Journal of Materials Chemistry,2011,21(29):10965-10969.
[26]Han G,Liu Y,Kan E,et al.Sandwich-structured Mn O2/polypyrrole/reduced graphene oxide hybrid composites for high-performance supercapacitors[J].Rsc Advances,2014,4(20):9898.
[27]Tao J,Liu N,Li L,et al.Hierarchical nanostructures of polypyrrole@Mn O2 composite electrodes for high performance solid-state asymmetric supercapacitors[J].Nanoscale,2014,6(5):2922-8.
[28]Zhang Z,Chi K,Xiao F,et al.Advanced solid-state asymmetric supercapacitors based on 3D graphene/Mn O2and graphene/polypyrrole hybrid architectures[J].Journal of Materials Chemistry A,2015,3(24):12828-12835.
[29]Lin H,Huang Q,Wang J,et al.Self-Assembled Graphene/Polyaniline/Co3O4 Ternary Hybrid Aerogels for Supercapacitors[J].Electrochimica Acta,2016,191:444-451.
[30]孙万虹,周艳青,孙豫,等.用于超级电容器的纳米氧化镍/石墨薄片/银复合电极材料的超声法合成及性能[J].材料导报,2016,30(22):36-42.
[31]Tao J,Liu N,Ma W,et al.Solid-state high performance flexible supercapacitors based on polypyrrole-Mn O2-carbon fiber hybrid structure.[J].Scientific Reports,2013,3(7459):2286.