处理含酚废水的研究进展
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摘要
阐述了处理含酚废水的研究进展。根据处理方法的不同,大致分为物理法、化学法、生物法3大类,其中物理法包括吸附法、溶剂萃取法和液膜法;化学法包括氧化法、沉淀法、光催化法;生物法包括活性污泥法、酶处理技术以及固定化微生物技术。比较了3类含酚废水处理方法的优缺点,并对将来处理工业含酚废水的研究进行了展望。
As the main pollution sources,the wastewater containing phenol brings great harm to the environment and human health. The research progress of dealing with wastewater containing phenol is discussed. The wastewater treatment processes can be divided into physical,chemical and biological methods. The physical methods consist of adsorption,extraction and liquid membrane treatment processes. The chemical methods include oxidation,precipitation and photocatalytic treatment processes. The biological methods contain activated sludge process,immobilized microorganism technology and enzyme treatment technology. The advantages and disadvantages of these treatment processes are compared. The development direction of wastewater containing phenol in the future is proposed as well.
As the main pollution sources,the wastewater containing phenol brings great harm to the environment and human health. The research progress of dealing with wastewater containing phenol is discussed. The wastewater treatment processes can be divided into physical,chemical and biological methods. The physical methods consist of adsorption,extraction and liquid membrane treatment processes. The chemical methods include oxidation,precipitation and photocatalytic treatment processes. The biological methods contain activated sludge process,immobilized microorganism technology and enzyme treatment technology. The advantages and disadvantages of these treatment processes are compared. The development direction of wastewater containing phenol in the future is proposed as well.
引文
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[25]王亚玲,习霞,杨宇民,等.丝素/Si O2杂化膜固定化多酚氧化酶处理模拟含酚废水[J].环境污染与防治,2009,31(3):21-23.
[26]Zhang Yu,Zeng Zhuotong,Zeng Guangming,et al.Effect of triton X-100 on the removal of aqueous phenol by laccase analyzed with a combined approach of experiments and molecular docking[J].Colloids and Surfaces B:Biointerfaces,2012,97:7-12.
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[28]Jiang Yanjun,Cui Cuicui,Zhou Liya,et al.Preparation and characterization of porous horseradish peroxidase microspheres for the removal of phenolic compound and dye[J].Industrial&Engineering Chemistry Research,2014,53(18):7591-7597.
[29]魏远隆,安春江,席淑琪,等.固定化微生物法处理含酚废水的研究[J].南京理工大学学报:自然科学版,2005,29(3):326-329.
[30]Brbara Safont,Ana Isabel Vitas,Francisco Javier Peas.Isolation and characterization of phenol degrading bacteria immobilized onto cyclodextrin-hydrogel particles within a draft tube spouted bed bioreactor[J].Biochemical Engineering Journal,2012,64(5):69-75.
[2]Bizerea Spiridon O,Preda E,Botez A,et al.Phenol removal from wastewater by adsorption on zeolitic composite[J].Environmental Science and Pollution Research,2013,20:6367-6381.
[3]张萌,尹连庆,李若征,等.特种活性炭处理含酚废水的实验研究[J].煤炭工程,2010,(6):82-84.
[4]Guo Xiali,Wang Jing,Wang Yan,et al.Research of phenols adsorption from simulated coal-gasification wastewater by resin[J].Procedia Environmental Sciences:Part A,2012,12:152-158.
[5]Liliana Giraldo,Juan Carlos Moreno-Pirajn.Study of adsorption of phenol on activated carbons obtained from eggshells[J].Journal of Analytical and Applied Pyrolysis,2014,106:41-47.
[6]Yang Chufen,Shiying Yang,Qian Yu,et al.Simulation and operation cost estimate for phenol extraction and solvent recovery process of coal-gasification wastewater[J].Industrial&Engineering Chemistry Research,2013,52(34):12108-12115.
[7]Xu Hang,Zhou Quan,Wang Jinfu.Treatment of sebacic acid industrial wastewater by extraction process using castor oil acid as extractant[J].Chinese Journal of Chemical Engineering,2013,21(9):967-973.
[8]Moamer Ehtash,Marie-Christine Fournier-Salaün,Krasimir Dimitrov,et al.Phenol removal from aqueous media by pertraction using vegetable oil as a liquid membrane[J].Chemical Engineering Journal,2014,250(15):42-47.
[9]Pezhman Kazemi,Mohammad Peydayesh,Alireza Bandegi,et al.Stability and extraction study of phenolic wastewater treatment by supported liquid membrane using tributyl phosphate and sesame oil as liquid membrane[J].Chemical Engineering Research and Design,2014,92(2):375-383.
[10]Chiraz Zidi,Rafik Tayeb,Mahmoud Dhahbi.Extraction of phenol from aqueous solutions by means of supported liquid membrane(MLS)containing tri-n-octyl phosphine oxide(TOPO)[J].Journal of Hazardous Materials,2011,194:62-68.
[11]Zhang Mingliang,Zhi Liang,Li Huaizhu,et al.Process integration of halogenation and oxidation for recovery and removal of phenols from high strength phenolic wastewater[J].Chemical Engineering Journal,2013,229:99-104.
[12]Haithem Bel Hadjltaief,Patrick Da Costa,Patricia Beaunier,et al.Fe-clay-plate as a heterogeneous catalyst in photo-Fenton oxidation of phenol as probe molecule for water treatment[J].Applied Clay Science,2014,91/92:46-54.
[13]Xia Min,Long Mingce,Yang Yudong,et al.A highly active bimetallic oxides catalyst supported on Al-containing MCM-41 for fenton oxidation of phenol solution[J].Applied Catalysis B:Environmental,2011,110:118-125.
[14]马艳然,韩玲芹,王雪涛.酚醛缩聚及吸附中和法处理含酚废水的研究[J].工业用水与废水,2003,34(2):38-39.
[15]Ayana Shimizu,Masahiro Tokumura,Koshiro Nakajima,et al.Phenol removal using zero-valent iron powder in the presence of dissolved oxygen:Roles of decomposition by the Fenton reaction and adsorption/precipitation[J].Journal of Hazardous Materials,2012,201/202:60-67.
[16]Manouchehr Nikazar,Mehriana Alizadeh,Reza Lalavi,et al.The optimum conditions for synthesis of Fe3O4/Zn O core/shell magnetic nanoparticles for photodegradation of phenol[J].Iranian Journal of Environmental Health Science&Engineering,2014,12:21.
[17]Fu Guokai,Xu Guanan,Chen Shuiping,et al.Ag3PO4/Bi2WO6hierarchical heterostructures with enhanced visible light photocatalytic activity for the degradation of phenol[J].Catalysis Communications,2013,40:120-124.
[18]Xu Jingjing.Synergy effect on a suspended mixture of ceria and activated carbon for the photocatalytic degradation of phenol[J].Powder Technology,2011,210(1):1-5.
[19]Sin Jin-chung,Lam Sze-mun,Lee Keat-teong,et al.Preparation of rare earth-doped Zn O hierarchical micro/nanospheres and their enhanced photocatalytic activity under visible light irradiation[J].Ceramics International,2014,40(4):5431-5440.
[20]Xu Chengwei,Liu Yuanyuan,Huang Baibiao,et al.Preparation,characterization,and photocatalytic properties of silver carbonate[J].Applied Surface Science,2011,257(20):8732-8736.
[21]贾海霞,胡瑞生,白雅琴,等.生物活性污泥法与化学光催化法对含酚废水处理的比较[J].现代化工,2009,29(s2):231-234.
[22]Marques R R N,Stüber F,Smith K M,et al.Graham sewage sludge based catalysts for catalytic wet air oxidation of phenol:Preparation,characterisation and catalytic performance[J].Applied Catalysis B:Environmental,2011,101:306-316.
[23]Leong M L,Lee K M,Lai S O,et al.Sludge characteristics and performances of the sequencing batch reactor at different influent phenol concentrations[J].Desalination,2011,270:181-187.
[24]Chérif Ben-youssef,Gabriela A.Vzquez-rodríguez.Model-based design of different fedbatch strategies for phenol degradation in acclimatized activated sludge cultures[J].Bioresource Technology,2011,102(4):3740-3747.
[25]王亚玲,习霞,杨宇民,等.丝素/Si O2杂化膜固定化多酚氧化酶处理模拟含酚废水[J].环境污染与防治,2009,31(3):21-23.
[26]Zhang Yu,Zeng Zhuotong,Zeng Guangming,et al.Effect of triton X-100 on the removal of aqueous phenol by laccase analyzed with a combined approach of experiments and molecular docking[J].Colloids and Surfaces B:Biointerfaces,2012,97:7-12.
[27]Aaron Steevensz,Sneha Madur,Wei Feng,et al.Crude soybean hull peroxidase treatment of phenol in synthetic and real wastewater:Enzyme economy enhanced by Triton X-100[J].Enzyme and Microbial Technology,2014,55:65-71.
[28]Jiang Yanjun,Cui Cuicui,Zhou Liya,et al.Preparation and characterization of porous horseradish peroxidase microspheres for the removal of phenolic compound and dye[J].Industrial&Engineering Chemistry Research,2014,53(18):7591-7597.
[29]魏远隆,安春江,席淑琪,等.固定化微生物法处理含酚废水的研究[J].南京理工大学学报:自然科学版,2005,29(3):326-329.
[30]Brbara Safont,Ana Isabel Vitas,Francisco Javier Peas.Isolation and characterization of phenol degrading bacteria immobilized onto cyclodextrin-hydrogel particles within a draft tube spouted bed bioreactor[J].Biochemical Engineering Journal,2012,64(5):69-75.