环境激素酞酸酯类化合物检测的样品前处理技术研究进展
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摘要
酞酸酯类化合物(phthalate esters,PAEs)目前已成为地球上存在最广泛的环境污染物之一,如何快速准确地定性定量检测环境中的PAEs显得尤为重要。由于环境样品基质的复杂性,在检测酞酸类化合物时需要进行样品前处理,主要包括提取、分离、纯化、浓缩等技术,来最大限度地提取目标物、降低干扰、提高检测灵敏度。因此酞酸酯类化合物的样品前处理技术已成为研究的重点。本文综述了国内外主要的环境激素酞酸酯类化合物的样品前处理技术,对固相萃取、固相微萃取和液相微萃取3种主要富集纯化技术分别进行了详细的介绍,并对其发展趋势进行了展望。
Phthalate esters(PAEs) have become one of the most extensive environmental pollutants on the earth, so it is very important to determine PAEs in the environment quickly and accurately. Due to the complexity of environmental sample matrix, sample preparation is necessary when detecting the phthalate esters, including extraction, separation, purification and concentration, which can maximize the extraction of the targets, minimize the interference and improve the detection sensitivity. Therefore, sample preparation on phthalate esters has become a research focal point. This paper reviewed the sample preparation techniques for analysis of phthalate esters in environment, including introduction of solid-phase extraction(SPE), solid-phase microextraction(SPME) and liquid phase microextraction(LPME), and prospected the development about preparation techniques for analysis of phthalate esters in the future.
Phthalate esters(PAEs) have become one of the most extensive environmental pollutants on the earth, so it is very important to determine PAEs in the environment quickly and accurately. Due to the complexity of environmental sample matrix, sample preparation is necessary when detecting the phthalate esters, including extraction, separation, purification and concentration, which can maximize the extraction of the targets, minimize the interference and improve the detection sensitivity. Therefore, sample preparation on phthalate esters has become a research focal point. This paper reviewed the sample preparation techniques for analysis of phthalate esters in environment, including introduction of solid-phase extraction(SPE), solid-phase microextraction(SPME) and liquid phase microextraction(LPME), and prospected the development about preparation techniques for analysis of phthalate esters in the future.
引文
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[4]李锦,张占恩,陈鑫,等.超声提取-分散液相微萃取-气相色谱质谱法测定大气PM2.5种15种邻苯二甲酸酯[J].环境化学,2017,36(1):183-189.Li J,Zhang ZE,Chen X,et al.Determination of fifteen phthalate esters in air particulate matter(PM 2.5)by ultrasonic extraction-dispersive liquid-liquid microextraction combined with gas chromatography-mass spectrometry[J].Environ Chem,2017,36(1):183-189.
[5]林钦,石凤琼,柯常亮,等.水产品中邻苯二甲酸酯残留与健康风险评价研究进展[J].南方水产科学,2014,10(1):92-99.Lin Q,Shi FQ,Ke CL,et al.Residues of phthalic acid esters in aquatic products and their health risk assessment[J].South China Fish Sci,2014,10(1):92-99.
[6]张泽明,张洪海,李建龙,等.固相微萃取-气相色谱-质谱联用测定海水与沉积物中邻苯二甲酸酯类污染物[J].分析化学研究报告,2017,45(3):348-356.Zhang ZM,Zhang HH,Li JL,et al.Determination of phthalate esters in seawater and sediments by solid phase microextraction coupled with gas chromatography-mass spectrometry[J].Chin J Anal Chem,2017,45(3):348-356.
[7]杨健,施龙艳,祝艳,等.HF-LPME-HPLC法测定水中4种邻苯二甲酸酯[J].工业水处理,2018,38(5):94-97.Yang J,Shi LY,Zhu Y,et al.Determination of four phthalates in water by HF-LPME-HPLC[J].Ind Water Treat,2018,38(5):94-97.
[8]王成云,徐嵘,吴透明,等.微波辅助萃取-气相色谱-串联质谱法同时测定皮革制品中20种邻苯二甲酸酯含量[J].质谱学报,2013,34(1):45-50,64.Wang CY,Xu R,Wu TM,et al.Simultaneous determination of 20phthalates in leather products by microwave-assisted extraction coupled with gas chromatography-tandem mass spectrometry[J].J Chin Mass Spectr Soc,2013,34(1):45-50,64.
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[10]Zafra-Gomez A,Ballesteros O,Navalon A,et al.Determination of some endocrine disrupter chemicals in urban wastewater samples using liquid chromatography-mass spectrometry[J].Microchem J,2008,88(1):87-94.
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[12]Pietrogrande MC,Basaglia G,Dondi F.Signal processing to evaluate parameters affecting SPE for multi-residue analysis of personal care products[J].J Sep Sci,2009,32:1249-1261.
[13]Shen HY,Jiang HL,Mao HL,et al.Simultaneous determination of seven phthalates and four parabens in cosmetic products using HPLC-DAD and GC-MS methods[J].J Sep Sci,2007,30:48-54.
[14]戴树桂,张东梅,张仁江,等.固相萃取技术预富集环境水样中邻苯二甲酸酯[J].环境科学,2000,21:66-69.Dai SG,Zhang DM,Zhang RJ,et al.Isolation of phthalate esters in aquatic sample by C18 bonded-phase extraction column[J].Environ Sci,2000,21:66-69.
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