酞酸酯类增塑剂检测方法研究进展
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摘要
酞酸酯类增塑剂被广泛用于各种工商业产品中,可影响生物体的内分泌、致突变、致畸和癌细胞增殖。本文综述了酞酸酯类增塑剂样品前处理方法,包括超声波提取法、固相萃取法、索氏提取法、快速溶剂萃取法等,并对常用仪器方法,如气相色谱法、液相色谱法、色谱质谱联用法等研究进展进行了综述。
Phthalate ester plasticizers are widely used in various industrial and commercial products,which can affect the endocrine,mutagenic,teratogenic and cancer cell proliferation of organisms. This paper reviews the phthalic acid ester plasticizer pretreatment method,including ultrasonic extraction,solid phase extraction,Soxhlet extraction,accelerated solvent extraction,and the commonly used instrumental methods such as advances in gas chromatography,liquid chromatography,chromatography and mass spectrometry were reviewed.
Phthalate ester plasticizers are widely used in various industrial and commercial products,which can affect the endocrine,mutagenic,teratogenic and cancer cell proliferation of organisms. This paper reviews the phthalic acid ester plasticizer pretreatment method,including ultrasonic extraction,solid phase extraction,Soxhlet extraction,accelerated solvent extraction,and the commonly used instrumental methods such as advances in gas chromatography,liquid chromatography,chromatography and mass spectrometry were reviewed.
引文
[1]Blair J D,Ikonomou M G,Kelly B C,et al.[J].Environ Sci Technol,2009,43(16):6262-6268.
[2]Kickham Peter.Biodegradation of phthalate esters in False Creek sediments[D].Burnaby:Simon Fraser University,2010.
[3]Liu H,Liang H,Liang Y,et al.Distribution of phthalate esters in alluvial sediment:a case study at jiang han plain,Central China[J].Chemosphere,2010,78(4):382-388.
[4]Lin Z P,Ikonomou M G,Jing H,et al.Determination of phthalate ester congeners and mixtures by LC/ESI-MS in sediments and biota of an urbanized marine inlet[J].Environ Sci Technol,2003,37(10):2100-2108.
[5]Parkerton T F,Konkel W J.Application of quantitative structure---activity relationships for assessing the aquatic toxicity of phthalate esters[J].Ecotoxicol Environ Saf.2000,45(1):61-78.
[6]Wang P,Wang S L,Fan C Q.Atmospheric distribution of particulate-and gas-phase phthalic esters(PAEs)in a Metropolitan City,Nanjing,East China[J].Chemosphere,2008,72(10):1567-1572.
[7]Liang P,Zhao E H,Li F.Application of dispersive liquidliquid microextraction and high-performance liquid chromatography for the determination of three phthalate esters in water samples[J].Analytica Chimica Acta,2008,609(1):53-58.
[8]Zeng F,Cui K Y,Xie Z Y,et al.Phthalate esters(PAEs):Emerging organic contaminants in agricultural soils in periurban areas around Guangzhou,China[J].Environmental Pollution,2008,156(2):425-434.
[9]Bergh C,Torgrip R,Emenius G,et al.Organophosphate and phthalate esters in air and settled dust-a multi-location indoor study[J].2011,21(1):67-76.
[10]李拥军,熊文明,陈坚文,等.固相萃取/高效液相色谱-串联质谱罗非鱼中9种邻苯二甲酸酯[J].分析测试学报,2012,31(3):278-283.
[11]肖凯恩,莫测辉,蔡全英.珠江三角洲蔬菜基地蔬菜中邻苯二甲酸酯的含量特征[J].四川环境.2012,31(3):49-55.
[12]Ikonomou M G,Blair J D,Kelly B C,et al.Ultra-trace determination of phthalate ester metabolites in seawater,sediments,and biota from an urbanized marine inlet by LC/ESI-MS/MS[J].Environ Sci Technol,2009,43:6262-6268.上接第页
[13]Fromme H,Gruber L,Seckin E,et al.Phthalates and their metabolites in breast milk:results from the Bavarian Monitoring of Breast Milk(BAMBI)[J].Environment International,2011,37(4):715-722.
[14]CHEN Hui,WANG Ai,ZHU Ruo-hua.Analysis of phthalates in plastic food-packaging bags by thin layer chromatography[J].Chin J Chromatogr,2006,24(1):70
[15]张连波,荣会,于晓礼,等.气相色谱法测定植物纤维食品包装材料中邻苯二甲酸酯类增塑剂[J].中国卫生检验杂志,2012,22(3):450-452.
[16]王丽霞,邵蕾,王明林.超声波萃取-气相色谱法测定塑料袋袋装食品中邻苯二甲酸酯[J].粮食与油脂,2012(9):38-40.
[17]Carrillo J D,Salazar C,Moreta C,et al.Determination of phthalates in wine by headspace solidphasemicroextraction followed by gas chromatographymassspectrometry:fibre comparison and selection[J].Chromatography A,2007,1164(1/2):248-261.
[18]汪倩,赵意娜,莫非,等.茄子中邻苯二甲酸(2-乙基已基)酯提取方法的初步研究[J].现代农业科技,2012(18):293-294.
[19]肖道清,马明,曹国洲.ASE-GC/MS法测定EVA塑料消费品中的7种PAEs[J].塑料科技,2015,43(03):79-83.
[20]曹勇,华晓曼,郑明珠,等.气相色谱法测定白酒中5种增塑剂的残留量[J].食品与机械,2016,32(01):59-62.
[21]周佳,潘生林,丁友超,等.高效液相色谱法测定纺织品中的邻苯二甲酸酯[J].印染助剂,2015,32(12):48-52.
[22]方道赠,王宁,张亮,等.超高效液相色谱-串联质谱法测定水产品中22种邻苯二甲酸酯类环境激素[J].农产品加工,2018(20):46-49.
[23]姑丽巴哈尔·艾合买提,阿依古丽·塔西.同位素稀释-气相色谱-质谱法测定河蚌蚌肉中邻苯二甲酸酯类残留量[J].渔业研究,2018,40(01):60-65.
[2]Kickham Peter.Biodegradation of phthalate esters in False Creek sediments[D].Burnaby:Simon Fraser University,2010.
[3]Liu H,Liang H,Liang Y,et al.Distribution of phthalate esters in alluvial sediment:a case study at jiang han plain,Central China[J].Chemosphere,2010,78(4):382-388.
[4]Lin Z P,Ikonomou M G,Jing H,et al.Determination of phthalate ester congeners and mixtures by LC/ESI-MS in sediments and biota of an urbanized marine inlet[J].Environ Sci Technol,2003,37(10):2100-2108.
[5]Parkerton T F,Konkel W J.Application of quantitative structure---activity relationships for assessing the aquatic toxicity of phthalate esters[J].Ecotoxicol Environ Saf.2000,45(1):61-78.
[6]Wang P,Wang S L,Fan C Q.Atmospheric distribution of particulate-and gas-phase phthalic esters(PAEs)in a Metropolitan City,Nanjing,East China[J].Chemosphere,2008,72(10):1567-1572.
[7]Liang P,Zhao E H,Li F.Application of dispersive liquidliquid microextraction and high-performance liquid chromatography for the determination of three phthalate esters in water samples[J].Analytica Chimica Acta,2008,609(1):53-58.
[8]Zeng F,Cui K Y,Xie Z Y,et al.Phthalate esters(PAEs):Emerging organic contaminants in agricultural soils in periurban areas around Guangzhou,China[J].Environmental Pollution,2008,156(2):425-434.
[9]Bergh C,Torgrip R,Emenius G,et al.Organophosphate and phthalate esters in air and settled dust-a multi-location indoor study[J].2011,21(1):67-76.
[10]李拥军,熊文明,陈坚文,等.固相萃取/高效液相色谱-串联质谱罗非鱼中9种邻苯二甲酸酯[J].分析测试学报,2012,31(3):278-283.
[11]肖凯恩,莫测辉,蔡全英.珠江三角洲蔬菜基地蔬菜中邻苯二甲酸酯的含量特征[J].四川环境.2012,31(3):49-55.
[12]Ikonomou M G,Blair J D,Kelly B C,et al.Ultra-trace determination of phthalate ester metabolites in seawater,sediments,and biota from an urbanized marine inlet by LC/ESI-MS/MS[J].Environ Sci Technol,2009,43:6262-6268.上接第页
[13]Fromme H,Gruber L,Seckin E,et al.Phthalates and their metabolites in breast milk:results from the Bavarian Monitoring of Breast Milk(BAMBI)[J].Environment International,2011,37(4):715-722.
[14]CHEN Hui,WANG Ai,ZHU Ruo-hua.Analysis of phthalates in plastic food-packaging bags by thin layer chromatography[J].Chin J Chromatogr,2006,24(1):70
[15]张连波,荣会,于晓礼,等.气相色谱法测定植物纤维食品包装材料中邻苯二甲酸酯类增塑剂[J].中国卫生检验杂志,2012,22(3):450-452.
[16]王丽霞,邵蕾,王明林.超声波萃取-气相色谱法测定塑料袋袋装食品中邻苯二甲酸酯[J].粮食与油脂,2012(9):38-40.
[17]Carrillo J D,Salazar C,Moreta C,et al.Determination of phthalates in wine by headspace solidphasemicroextraction followed by gas chromatographymassspectrometry:fibre comparison and selection[J].Chromatography A,2007,1164(1/2):248-261.
[18]汪倩,赵意娜,莫非,等.茄子中邻苯二甲酸(2-乙基已基)酯提取方法的初步研究[J].现代农业科技,2012(18):293-294.
[19]肖道清,马明,曹国洲.ASE-GC/MS法测定EVA塑料消费品中的7种PAEs[J].塑料科技,2015,43(03):79-83.
[20]曹勇,华晓曼,郑明珠,等.气相色谱法测定白酒中5种增塑剂的残留量[J].食品与机械,2016,32(01):59-62.
[21]周佳,潘生林,丁友超,等.高效液相色谱法测定纺织品中的邻苯二甲酸酯[J].印染助剂,2015,32(12):48-52.
[22]方道赠,王宁,张亮,等.超高效液相色谱-串联质谱法测定水产品中22种邻苯二甲酸酯类环境激素[J].农产品加工,2018(20):46-49.
[23]姑丽巴哈尔·艾合买提,阿依古丽·塔西.同位素稀释-气相色谱-质谱法测定河蚌蚌肉中邻苯二甲酸酯类残留量[J].渔业研究,2018,40(01):60-65.