摘要
合成具有C1对称轴的3-醛基-1,1′-联-2-萘酚荧光探针,该探针在Zn2+的存在下和手性二胺或手性氨基酸相互作用后,荧光发射波长红移至560nm处,表现出明显的荧光增强,且荧光增强强度对不同手性结构的二胺或氨基酸具有一定的选择性,具有对映选择性识别的能力。尤其针对1,2-二苯基乙二胺而言,与文献报道的3,3′-二醛基-1,1′-联-2-萘酚(C2对称轴荧光传感器)进行荧光识别的效果相比,其对映选择性识别的能力实现了从无到有的改善。
C1-symmetric 2,2′-dihydroxy-1,1′-binaphthyl-3-carbaldehyde was applied as enantioselective fluorescent sensor towards chiral diamines and amino acids in the presence of Zn2+.It exhibited great-enhanced fluorescence and moderate enantioselectivity with red-shifted signals at around 560 nm.Especially for the chiral1,2-diphenylethylenediamine,which showed no enantioselectivity fluorescent signals when were treated with the previously reported C2-symmetric fluorescent sensor 3,3′-diformyl-1,1′-bi-2-naphthol,the C1-symmetric sensor showed moderate enantioselectivity.
引文
[1] LU Z Y,ZHANG R K,LI G K.Journal of Instrumental Analysis(路振宇,张润坤,李攻科.分析测试学报),2017,36(4):570.
[2] YANG L,XU K X,WANG C J,et al.Chinese Journal of Organic Chemistry(杨丽,徐括喜,王晨娟,等.有机化学),2013,33(12):2496.
[3] SONG P,DAI Y P,WANG C Y,et al.Journal of Henan University(Natural Science)(宋盼,代艳鹏,王超玉,等.河南大学学报(自然科学版)),2017,47(6):715.
[4] HUANG H,ZHENG L F,ZOU X W,et al.Progress in Chemistry(黄辉,郑立飞,邹小伟,等.化学进展),2008,20(4):508.
[5] Pu L.ACC Chem Res,2012,45(2):150.
[6] Chin J,Kim D C,Kim H J,et al.Org Lett,2004,6(15):2591.
[7] Tang L J,Wei G F,Nandhakumar R,et al.B Kor Chem Soc,2011,32(9):3367.
[8] Xu Y M,Yu S S,Chen Q,et al.Chem Eur J,2016,22(17):5963.
[9] Huang Z,Yu S S,Wen K L,et al.Chem Sci,2014,5(9):3457.
[10]LIU F,HU X G,ZHANG H J,et al.Guangzhou Chemical Industry(刘飞,胡新根,张贺娟,等.广州化工),2010,38(3):20.
[11]Yang L,Qin S,Su X,et al.Org Biomol Chem,2010,8(2):339.