室温下不同化学试剂对“唐山骨质瓷”釉面侵蚀度的定性及定量影响研究
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摘要
针对"唐山骨质瓷"地理标志产品特定的原料配比和生产工艺,选取6家不同企业生产的36件白瓷8吋平盘作为实验样品;在既定的温湿度条件下,使用酸、碱、盐、漂白剂、染色剂及消毒剂6种化学试剂对骨质瓷样品釉面持续作用一定时间后,对受侵蚀前后的釉面状态进行定性分析,并对白度和光泽度的变化情况进行定量测试,研究不同化学试剂侵蚀作用的强弱。推导得出如下结论:不同试剂对同一骨质瓷样品釉面的侵蚀强度各异,其中碱的腐蚀作用强于酸,染色剂对釉面白度和光泽度的影响大于盐类和消毒剂;不同企业生产的骨质瓷耐同一种试剂腐蚀的性能有所不同。由于测量机理不同,针对骨质瓷釉面的微小变化,白度和光泽度的波动幅度存在一定差异。本研究成果可为企业改进相关生产工艺、完善产品质量控制提供科学依据。
This paper according to the requirements of the unique production process of the Tangshan bone China geographic indication products,specified 36 pieces of bone China 8inch flat produced by 6different factories as the experimental samples.After using 6kinds of chemical reagents such as acid,alkali,salt,stain and disinfectant eroded continuously on the above samples glaze for a certain period of time under the given conditions of temperature and humidity,tested glaze whiteness and gloss of samples qualitatively.By measuring the changes of whiteness and luster after glaze erosion of samples,analyzed degree of the erosion quantitatively.Derived the following conclusions:the strength of glaze corrosion caused by different chemical reagents to bone china samples produced from the same factories were different.The corrosion effect of alkali is stronger than that of acid,and the corrosion effect of stain is stronger than that of salt and disinfectant for bone china glaze white and glossiness.The corrosion effect of each chemical reagent used for bone china samples produced by different factories is different.The corrosion effect of each chemical reagent is different for bone china samples produced by different factories.Due to different measurement principle,the rangeability of bone china glaze whiteness and luster with the glaze state changes is different.The research results can provide scientific reference to the manufacturing factories for improving the production process and the quality control.
This paper according to the requirements of the unique production process of the Tangshan bone China geographic indication products,specified 36 pieces of bone China 8inch flat produced by 6different factories as the experimental samples.After using 6kinds of chemical reagents such as acid,alkali,salt,stain and disinfectant eroded continuously on the above samples glaze for a certain period of time under the given conditions of temperature and humidity,tested glaze whiteness and gloss of samples qualitatively.By measuring the changes of whiteness and luster after glaze erosion of samples,analyzed degree of the erosion quantitatively.Derived the following conclusions:the strength of glaze corrosion caused by different chemical reagents to bone china samples produced from the same factories were different.The corrosion effect of alkali is stronger than that of acid,and the corrosion effect of stain is stronger than that of salt and disinfectant for bone china glaze white and glossiness.The corrosion effect of each chemical reagent used for bone china samples produced by different factories is different.The corrosion effect of each chemical reagent is different for bone china samples produced by different factories.Due to different measurement principle,the rangeability of bone china glaze whiteness and luster with the glaze state changes is different.The research results can provide scientific reference to the manufacturing factories for improving the production process and the quality control.
引文
1杨玉泉,张垠,孔德双,等.骨质瓷的发展与研究.中国陶瓷,2011(9):13
2 李文杰,赵淑忠.唐山日用陶瓷产业格局发展路径探析.全国性科技核心期刊——陶瓷,2012(5):1416
3 中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T 5003-1999.日用陶瓷器釉面耐化学腐蚀性的测定.北京:中国标准出版社,2000-02-01
4 The ISO Central Secretariat.ISO 28706-1:2008.Determination of resistance to chemical corrosion by acids at room temperature.Switzerland:ISO Copyright Office,2008-12-01
5 The ISO Central Secretariat.ISO 28706-2:2008.Determination of resistance to chemical corrosion by boiling acids,neutral liquids and/or their vapor.Switzerland:ISO Copyright Office,2008-12-01
6 The ISO Central Secretariat.ISO 28706-3:2008.Determination of resistance to chemical corrosion by alkaline liquids using a hexagonal vessel.Switzerland:ISO copyright office,2008-12-01
7 The ISO Central Secretariat.ISO 28706-4:2008,Determination of resistance to chemical corrosion by alkaline liquids using a cylindrical vessel,Switzerland:ISO copyright office,2008-12-01
8 The ISO Central Secretariat.ISO 28706-5:2008.Incrimination of resistance to chemical corrosion-part 5determination of resistance to chemical corrosion in closed systems.Switzerland:ISO Copyright Office,2008-12-01
9 ASTM Committee C14on Glass and Glass Products.ASTM C 1203:2004(2014).Standard test method for quantitative determination of alkali resistanceof a ceramic-glass enamel.The United States:ASTM International,2014-9-23
10 ASTM Committee C14on Glass and Glass Products.ASTM C 676:2004(2009).Standard test method for detergent resistance of ceramic decorations on glass tableware.The United States:ASTM International,2009-9-21
11 张垠,孔德双,陶亚秋,等.骨质瓷用高耐酸耐碱性无铅熔块釉的研究.中国陶瓷,2007(7):6770
12 高雅春,耿谦.从物相特征探析骨质瓷抗热震性能.中国陶瓷,2003(5):3539
13 James W,Norris A W.Some physical properties of glazes.Materials Science&Application,1956,55(10):601628
14 Douglos R Eppfe.Prediction glaze color from pigment and opacifier caculations.Ceramic Industrory,1998(9):4045
15 Lakatosetal T.Viscosity temperature relations in technical glasses.Glass Tech,1972,13(3):8895
16 王爱华.论日用陶瓷釉面的光泽度.陶瓷研究,2001,16(4):3033
2 李文杰,赵淑忠.唐山日用陶瓷产业格局发展路径探析.全国性科技核心期刊——陶瓷,2012(5):1416
3 中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T 5003-1999.日用陶瓷器釉面耐化学腐蚀性的测定.北京:中国标准出版社,2000-02-01
4 The ISO Central Secretariat.ISO 28706-1:2008.Determination of resistance to chemical corrosion by acids at room temperature.Switzerland:ISO Copyright Office,2008-12-01
5 The ISO Central Secretariat.ISO 28706-2:2008.Determination of resistance to chemical corrosion by boiling acids,neutral liquids and/or their vapor.Switzerland:ISO Copyright Office,2008-12-01
6 The ISO Central Secretariat.ISO 28706-3:2008.Determination of resistance to chemical corrosion by alkaline liquids using a hexagonal vessel.Switzerland:ISO copyright office,2008-12-01
7 The ISO Central Secretariat.ISO 28706-4:2008,Determination of resistance to chemical corrosion by alkaline liquids using a cylindrical vessel,Switzerland:ISO copyright office,2008-12-01
8 The ISO Central Secretariat.ISO 28706-5:2008.Incrimination of resistance to chemical corrosion-part 5determination of resistance to chemical corrosion in closed systems.Switzerland:ISO Copyright Office,2008-12-01
9 ASTM Committee C14on Glass and Glass Products.ASTM C 1203:2004(2014).Standard test method for quantitative determination of alkali resistanceof a ceramic-glass enamel.The United States:ASTM International,2014-9-23
10 ASTM Committee C14on Glass and Glass Products.ASTM C 676:2004(2009).Standard test method for detergent resistance of ceramic decorations on glass tableware.The United States:ASTM International,2009-9-21
11 张垠,孔德双,陶亚秋,等.骨质瓷用高耐酸耐碱性无铅熔块釉的研究.中国陶瓷,2007(7):6770
12 高雅春,耿谦.从物相特征探析骨质瓷抗热震性能.中国陶瓷,2003(5):3539
13 James W,Norris A W.Some physical properties of glazes.Materials Science&Application,1956,55(10):601628
14 Douglos R Eppfe.Prediction glaze color from pigment and opacifier caculations.Ceramic Industrory,1998(9):4045
15 Lakatosetal T.Viscosity temperature relations in technical glasses.Glass Tech,1972,13(3):8895
16 王爱华.论日用陶瓷釉面的光泽度.陶瓷研究,2001,16(4):3033